CN104119716B - A kind of automatically cleaning water-repellent paint - Google Patents
A kind of automatically cleaning water-repellent paint Download PDFInfo
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- CN104119716B CN104119716B CN201410293033.XA CN201410293033A CN104119716B CN 104119716 B CN104119716 B CN 104119716B CN 201410293033 A CN201410293033 A CN 201410293033A CN 104119716 B CN104119716 B CN 104119716B
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- repellent paint
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- automatically cleaning
- water
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- 239000003973 paint Substances 0.000 title claims abstract description 19
- 239000005871 repellent Substances 0.000 title claims abstract description 19
- 238000004140 cleaning Methods 0.000 title claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 16
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 8
- CWNSVVHTTQBGQB-UHFFFAOYSA-N N,N-Diethyldodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CC)CC CWNSVVHTTQBGQB-UHFFFAOYSA-N 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 7
- XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 claims abstract description 7
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims abstract description 7
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000010455 vermiculite Substances 0.000 claims abstract description 7
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 7
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 7
- MFXMOUUKFMDYLM-UHFFFAOYSA-L zinc;dihydrogen phosphate Chemical compound [Zn+2].OP(O)([O-])=O.OP(O)([O-])=O MFXMOUUKFMDYLM-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000004743 Polypropylene Substances 0.000 claims abstract description 4
- 229960005070 ascorbic acid Drugs 0.000 claims abstract description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims abstract description 4
- 239000011668 ascorbic acid Substances 0.000 claims abstract description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 4
- -1 polypropylene Polymers 0.000 claims abstract description 4
- 229920001155 polypropylene Polymers 0.000 claims abstract description 4
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 33
- 238000002156 mixing Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 7
- XISFOXBYRQWDNK-UHFFFAOYSA-N 2-(2-methylphenyl)propan-2-amine;hydrochloride Chemical compound [Cl-].CC1=CC=CC=C1C(C)(C)[NH3+] XISFOXBYRQWDNK-UHFFFAOYSA-N 0.000 claims description 6
- 241001116389 Aloe Species 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 6
- 235000011399 aloe vera Nutrition 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 claims description 6
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 claims description 6
- 238000000605 extraction Methods 0.000 claims description 6
- GYCKQBWUSACYIF-UHFFFAOYSA-N o-hydroxybenzoic acid ethyl ester Natural products CCOC(=O)C1=CC=CC=C1O GYCKQBWUSACYIF-UHFFFAOYSA-N 0.000 claims description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000741 silica gel Substances 0.000 claims description 6
- 229910002027 silica gel Inorganic materials 0.000 claims description 6
- MPPQGYCZBNURDG-UHFFFAOYSA-N 2-propionyl-6-dimethylaminonaphthalene Chemical compound C1=C(N(C)C)C=CC2=CC(C(=O)CC)=CC=C21 MPPQGYCZBNURDG-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 238000004078 waterproofing Methods 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 2
- 150000007513 acids Chemical class 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 5
- 230000032683 aging Effects 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Landscapes
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Detergent Compositions (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of automatically cleaning water-repellent paint, it is made up of the raw material of following weight parts: silicone acrylic emulsion 62-70, Semen Lini oil 1-2, zinc dihydrogen phosphate 1-2, sodium lauroyl sarcosine 1-2, Glutaric Acid Dimethyl ester 2-3, maleic anhydride inoculated polypropylene 2-3, dimethyl diallyl ammonium chloride 1-2, tetrabutyl ammonium bromide 1-2, lauric acid diethyl amide 1.2-2, isopropanol 1-2, nano aluminum Alumina 3-5, vermiculite power 6-8.5, ascorbic acid 0.5-1, coalescents 6-8, deionized water 10-17, the water-repellent paint of the present invention has good heat insulating effect, resistance to wiping is strong, water proofing property is strong, automatically cleaning is effective, the film formed is stable, caking property is strong, resistance to acids and bases, good corrosion resistance, excellent storage stability, long shelf-life.
Description
Technical field
The invention mainly relates to a kind of coating, particularly relate to a kind of automatically cleaning water-repellent paint.
Background technology
Traditional waterproof material mainly has the flexible waterproof materials such as waterproof roll, water-repellent paint, sealing cement, and based on cement matrix, adds the rigidity water-proofing material of liquid medicine agent and other auxiliary agent. China's major part waterproofing work shortcoming such as loss of properties on aging, hot strength be low, temperature sensitive that all adopts conventional waterproof material, conventional waterproof material to also exist. Conventional waterproof coating is used for roof waterproof, easily caused by aging, dry and cracked, deform, fracture, the phenomenon such as layering, for indoor waterproof, for complex-shaped place, constructional difficulties, and to Seepage, quality is more difficult to ensure, people's every few years will spend substantial amounts of fund and labour force to reprocess, and not only confuse the orthobiosis of people, work and the production order, and affect the service life of whole building self-cleaning article. In order to meet the every profession and trade requirement to water-repellent paint, producing high-performance, widely used water-repellent paint is necessary.
Summary of the invention
The object of the invention is just to provide a kind of automatically cleaning water-repellent paint.
The present invention is achieved by the following technical solutions:
A kind of automatically cleaning water-repellent paint, it is made up of the raw material of following weight parts:
Silicone acrylic emulsion 62-70, Semen Lini oil 1-2, zinc dihydrogen phosphate 1-2, sodium lauroyl sarcosine 1-2, Glutaric Acid Dimethyl ester 2-3, maleic anhydride inoculated polypropylene 2-3, dimethyl diallyl ammonium chloride 1-2, tetrabutyl ammonium bromide 1-2, lauric acid diethyl amide 1.2-2, isopropanol 1-2, nano aluminum Alumina 3-5, vermiculite power 6-8.5, ascorbic acid 0.5-1, coalescents 6-8, deionized water 10-17;
Described coalescents is made up of the raw material of following weight parts:
Silicone acrylic emulsion 30-35, Aloe extraction solution 0.3-2, ethyl hydroxybenzoate 1-2, prodan 0.8-1, tetramethylolmethane 2-3, dibutyl tin laurate 0.1-0.2, micropowder silica gel 2-4, trimethyl benzyl ammonia chloride 0.8-2, deionized water 70-75;
Micropowder silica gel is mixed with tetramethylolmethane, at 65-70 DEG C stirring mixing 2-4 minute, add the 30-40% of above-mentioned deionized water weight, trimethyl benzyl ammonia chloride, 100-200 rev/min dispersed with stirring 6-12 minute, obtain dispersion liquid;
Ethyl hydroxybenzoate is mixed with Aloe extraction solution, it is stirring evenly and then adding in silicone acrylic emulsion, at 35-40 DEG C insulated and stirred 10-15 minute, add above-mentioned dispersion liquid, dibutyl tin laurate, stir to room temperature, add remain each raw material, 300-400 rev/min dispersed with stirring 7-10 minute, obtain described coalescents.
The preparation method of a kind of automatically cleaning water-repellent paint, comprises the following steps:
Sodium lauroyl sarcosine is joined in deionized water, is stirring evenly and then adding into dimethyl diallyl ammonium chloride, vermiculite power, 50-70 rev/min dispersed with stirring 3-5 minute, add Glutaric Acid Dimethyl ester, stir;
By zinc dihydrogen phosphate, the mixing of nano aluminum Alumina, adding lauric acid diethyl amide, isopropanol, at 60-70 DEG C, stirring mixing 3-5 minute, joins in silicone acrylic emulsion, stirs;
By each raw material after above-mentioned process with remain each raw material mix, 500-600 rev/min dispersed with stirring 20-30 minute, obtain described automatically cleaning water-repellent paint.
The invention have the advantage that
The water-repellent paint of the present invention has good heat insulating effect, and resistance to wiping is strong, and water proofing property is strong, and automatically cleaning is effective, and the film of formation is stable, and caking property is strong, resistance to acids and bases, good corrosion resistance, excellent storage stability, long shelf-life.
Detailed description of the invention
Embodiment 1
A kind of automatically cleaning water-repellent paint, it is made up of the raw material of following weight parts (kilogram):
Silicone acrylic emulsion 70, Semen Lini oil 2, zinc dihydrogen phosphate 1, sodium lauroyl sarcosine 2, Glutaric Acid Dimethyl ester 3, maleic anhydride inoculated polypropylene 3, dimethyl diallyl ammonium chloride 1, tetrabutyl ammonium bromide 1, lauric acid diethyl amide 1.2, isopropanol 2, nano aluminum Alumina 3, vermiculite power 8.5, ascorbic acid 0.5, coalescents 8, deionized water 17;
Described coalescents is made up of the raw material of following weight parts:
Silicone acrylic emulsion 30-35, Aloe extraction solution 0.3, ethyl hydroxybenzoate 2, prodan 0.8, tetramethylolmethane 3, dibutyl tin laurate 0.2, micropowder silica gel 4, trimethyl benzyl ammonia chloride 0.8, deionized water 75;
Micropowder silica gel is mixed with tetramethylolmethane, stirring mixing 2 minutes at 70 DEG C, add the 40% of above-mentioned deionized water weight, trimethyl benzyl ammonia chloride, 200 revs/min of dispersed with stirring 12 minutes, obtain dispersion liquid;
Ethyl hydroxybenzoate is mixed with Aloe extraction solution, is stirring evenly and then adding in silicone acrylic emulsion, insulated and stirred 15 minutes at 40 DEG C, add above-mentioned dispersion liquid, dibutyl tin laurate, stir to room temperature, add and remain each raw material, 400 revs/min of dispersed with stirring 10 minutes, obtain described coalescents.
The preparation method of a kind of automatically cleaning water-repellent paint, comprises the following steps:
Sodium lauroyl sarcosine is joined in deionized water, is stirring evenly and then adding into dimethyl diallyl ammonium chloride, vermiculite power, 70 revs/min dispersed with stirring 3-5 minute, add Glutaric Acid Dimethyl ester, stir;
By zinc dihydrogen phosphate, the mixing of nano aluminum Alumina, adding lauric acid diethyl amide, isopropanol, at 70 DEG C, stirring mixing 5 minutes, join in silicone acrylic emulsion, stir;
Each raw material after above-mentioned process is mixed with remaining each raw material, 600 revs/min of dispersed with stirring 30 minutes, obtain described automatically cleaning water-repellent paint.
Performance test:
Elongation percentage: >=300%;
Impermeability: 0.3MPa (one hour waterproof).
Claims (2)
1. an automatically cleaning water-repellent paint, it is characterised in that it is made up of the raw material of following weight parts:
Silicone acrylic emulsion 70, Semen Lini oil 2, zinc dihydrogen phosphate 1, sodium lauroyl sarcosine 2, Glutaric Acid Dimethyl ester 3, maleic anhydride inoculated polypropylene 3, dimethyl diallyl ammonium chloride 1, tetrabutyl ammonium bromide 1, lauric acid diethyl amide 1.2, isopropanol 2, nano aluminum Alumina 3, vermiculite power 8.5, ascorbic acid 0.5, coalescents 8, deionized water 17;
Described coalescents is made up of the raw material of following weight parts:
Silicone acrylic emulsion 30-35, Aloe extraction solution 0.3, ethyl hydroxybenzoate 2, prodan 0.8, tetramethylolmethane 3, dibutyl tin laurate 0.2, micropowder silica gel 4, trimethyl benzyl ammonia chloride 0.8, deionized water 75;
Micropowder silica gel is mixed with tetramethylolmethane, stirring mixing 2 minutes at 70 DEG C, add the 40% of above-mentioned deionized water weight, trimethyl benzyl ammonia chloride, 200 revs/min of dispersed with stirring 12 minutes, obtain dispersion liquid;
Ethyl hydroxybenzoate is mixed with Aloe extraction solution, is stirring evenly and then adding in silicone acrylic emulsion, insulated and stirred 15 minutes at 40 DEG C, add above-mentioned dispersion liquid, dibutyl tin laurate, stir to room temperature, add and remain each raw material, 400 revs/min of dispersed with stirring 10 minutes, obtain described coalescents.
2. the preparation method of an automatically cleaning water-repellent paint as claimed in claim 1, it is characterised in that comprise the following steps:
Sodium lauroyl sarcosine is joined in deionized water, is stirring evenly and then adding into dimethyl diallyl ammonium chloride, vermiculite power, 50-70 rev/min dispersed with stirring 3-5 minute, add Glutaric Acid Dimethyl ester, stir;
By zinc dihydrogen phosphate, the mixing of nano aluminum Alumina, adding lauric acid diethyl amide, isopropanol, at 60-70 DEG C, stirring mixing 3-5 minute, joins in silicone acrylic emulsion, stirs;
By each raw material after above-mentioned process with remain each raw material mix, 500-600 rev/min dispersed with stirring 20-30 minute, obtain described automatically cleaning water-repellent paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293033.XA CN104119716B (en) | 2014-06-26 | 2014-06-26 | A kind of automatically cleaning water-repellent paint |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410293033.XA CN104119716B (en) | 2014-06-26 | 2014-06-26 | A kind of automatically cleaning water-repellent paint |
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| CN104119716A CN104119716A (en) | 2014-10-29 |
| CN104119716B true CN104119716B (en) | 2016-06-15 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104313617A (en) * | 2014-11-07 | 2015-01-28 | 合肥大安印刷有限责任公司 | Rust-removing metal surface cleaning agent and preparation method thereof |
| CN104559695B (en) * | 2015-01-08 | 2017-01-18 | 上海贝能环保科技有限公司 | Healthy environmental-friendly paint and preparation method thereof |
| CN107245294A (en) * | 2017-08-08 | 2017-10-13 | 合肥安力电力工程有限公司 | A kind of anti-aging street lamp coating and preparation method thereof |
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| JP4855477B2 (en) * | 2008-04-09 | 2012-01-18 | Ｓｃｉ−Ｐａｉｎｔ Ｊａｐａｎ株式会社 | Thermal barrier coating material |
| CN101348595B (en) * | 2008-07-28 | 2010-12-08 | 北京大学 | Fluorine-silicon modified self-crosslinking acrylic ester emulsion preparation method |
| CN103540213B (en) * | 2013-09-26 | 2016-03-30 | 芜湖杰诺科技有限公司 | A kind of Low-cost, easy-to-clean waterproof paint |
| CN103602193B (en) * | 2013-11-29 | 2016-08-17 | 深圳市安品有机硅材料有限公司 | A kind of aqueous heavy anti-corrosion paint priming paint and preparation method thereof |
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Effective date of registration: 20240410 Address after: 262700 North Head of Pengjia Daokou San Village, Taitou Town, Shouguang City, Weifang City, Shandong Province Patentee after: Shandong Taiyun waterproof material Co.,Ltd. Country or region after: China Address before: No.18, Shaoji Ershi Road, Banta Town, Laian County, Chuzhou City, Anhui Province Patentee before: ANHUI KUAILAI WATERPROOFING & ANTI-CORROSION Co.,Ltd. Country or region before: China |
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