CN104119756B - A kind of anti-low temperature water-repellent paint - Google Patents
A kind of anti-low temperature water-repellent paint Download PDFInfo
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- CN104119756B CN104119756B CN201410293095.0A CN201410293095A CN104119756B CN 104119756 B CN104119756 B CN 104119756B CN 201410293095 A CN201410293095 A CN 201410293095A CN 104119756 B CN104119756 B CN 104119756B
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- repellent paint
- low temperature
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- 239000003973 paint Substances 0.000 title claims abstract description 21
- 239000005871 repellent Substances 0.000 title claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 10
- IMYZYCNQZDBZBQ-SJORKVTESA-N (9S,10R)-epoxyoctadecanoic acid Chemical compound CCCCCCCC[C@H]1O[C@H]1CCCCCCCC(O)=O IMYZYCNQZDBZBQ-SJORKVTESA-N 0.000 claims abstract description 7
- 229920001661 Chitosan Polymers 0.000 claims abstract description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 7
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229910001634 calcium fluoride Inorganic materials 0.000 claims abstract description 7
- 239000010881 fly ash Substances 0.000 claims abstract description 7
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011701 zinc Substances 0.000 claims abstract description 7
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 7
- SRWKSFRBHIWJSD-UHFFFAOYSA-N 6-cyclohexylhexan-1-ol Chemical compound OCCCCCCC1CCCCC1 SRWKSFRBHIWJSD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 241001122767 Theaceae Species 0.000 claims abstract description 4
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- -1 carbon alcohols ester Chemical class 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims abstract description 4
- 239000004575 stone Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 27
- 238000002156 mixing Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 7
- XISFOXBYRQWDNK-UHFFFAOYSA-N 2-(2-methylphenyl)propan-2-amine;hydrochloride Chemical compound [Cl-].CC1=CC=CC=C1C(C)(C)[NH3+] XISFOXBYRQWDNK-UHFFFAOYSA-N 0.000 claims description 6
- 241001116389 Aloe Species 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 6
- 235000011399 aloe vera Nutrition 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 claims description 6
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 claims description 6
- 238000000605 extraction Methods 0.000 claims description 6
- GYCKQBWUSACYIF-UHFFFAOYSA-N o-hydroxybenzoic acid ethyl ester Natural products CCOC(=O)C1=CC=CC=C1O GYCKQBWUSACYIF-UHFFFAOYSA-N 0.000 claims description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000741 silica gel Substances 0.000 claims description 6
- 229910002027 silica gel Inorganic materials 0.000 claims description 6
- ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 claims description 3
- MPPQGYCZBNURDG-UHFFFAOYSA-N 2-propionyl-6-dimethylaminonaphthalene Chemical compound C1=C(N(C)C)C=CC2=CC(C(=O)CC)=CC=C21 MPPQGYCZBNURDG-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- CCDRPBGPIXPGRW-JNKODXNQSA-N (4as,6ar,6as,6br,8ar,9r,10s,12ar,14bs)-9-(hydroxymethyl)-2,2,6a,6b,9,12a-hexamethyl-10-[(3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylic acid Chemical compound O([C@H]1CC[C@]2(C)[C@H]3CC=C4[C@@]([C@@]3(CC[C@H]2[C@@]1(CO)C)C)(C)CC[C@]1(CCC(C[C@H]14)(C)C)C(O)=O)C1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O CCDRPBGPIXPGRW-JNKODXNQSA-N 0.000 claims description 2
- PALNVYHUKHRDOP-UHFFFAOYSA-N UNPD162310 Natural products COC(=O)C1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(OC6OC(CO)C(O)C(OC7OC(CO)C(O)C(O)C7O)C6O)C(C)(C)C5CCC34C)C2C1)C(=O)O PALNVYHUKHRDOP-UHFFFAOYSA-N 0.000 claims description 2
- 238000010276 construction Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 239000012528 membrane Substances 0.000 abstract description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 abstract description 2
- 229930182490 saponin Natural products 0.000 abstract description 2
- 150000007949 saponins Chemical class 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 238000010422 painting Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 5
- 230000032683 aging Effects 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of anti-low temperature water-repellent paint, it is made up of the raw material of following weight parts: silicone acrylic emulsion 61.3-70, tea saponin 1-2, chitosan 2-3, flyash 4-7, barium metaborate 2-3.1, double, two ten four carbon alcohols ester 0.8-2, epoxyoleic acid butyl ester 1-2, cyclohexanhexanol 2-3, N-cyclohexyl-N-diphenyl-para-phenylene diamine 0.2-0.4, calcium fluoride 2-3, medical stone powder 4-6, zinc dialkyl dithiophosphate 0.1-0.2, coalescents 5-8, deionized water 10-18, the water-repellent paint of the present invention can store at subzero 20 DEG C, transport, winter construction film forming is fast, drying time is short, without harmful organic volatile solvent, belong to Environmental-protecwaterproof waterproof paint, painting membrane stability is high, better resistance, good waterproof performance.
Description
Technical field
The invention mainly relates to a kind of coating, particularly relate to a kind of anti-low temperature water-repellent paint.
Background technology
Traditional waterproof material mainly has the flexible waterproof materials such as waterproof roll, water-repellent paint, sealing cement, and based on cement matrix, adds the rigidity water-proofing material of liquid medicine agent and other auxiliary agent. China's major part waterproofing work shortcoming such as loss of properties on aging, hot strength be low, temperature sensitive that all adopts conventional waterproof material, conventional waterproof material to also exist. Conventional waterproof coating is used for roof waterproof, easily caused by aging, dry and cracked, deform, fracture, the phenomenon such as layering, for indoor waterproof, for complex-shaped place, constructional difficulties, and to Seepage, quality is more difficult to ensure, people's every few years will spend substantial amounts of fund and labour force to reprocess, and not only confuse the orthobiosis of people, work and the production order, and affect the service life of the anti-low temperature thing in whole building. In order to meet the every profession and trade requirement to water-repellent paint, producing high-performance, widely used water-repellent paint is necessary.
Summary of the invention
The object of the invention is just to provide a kind of anti-low temperature water-repellent paint.
The present invention is achieved by the following technical solutions:
A kind of anti-low temperature water-repellent paint, it is made up of the raw material of following weight parts:
Silicone acrylic emulsion 61.3-70, tea saponin 1-2, chitosan 2-3, flyash 4-7, barium metaborate 2-3.1, double; two ten four carbon alcohols ester 0.8-2, epoxyoleic acid butyl ester 1-2, cyclohexanhexanol 2-3, N cyclohexyl N' phenyl P phenylene diamine 0.2-0.4, calcium fluoride 2-3, medical stone powder 4-6, zinc dialkyl dithiophosphate 0.1-0.2, coalescents 5-8, deionized water 10-17;
Described coalescents is made up of the raw material of following weight parts:
Silicone acrylic emulsion 30-35, Aloe extraction solution 0.3-2, ethyl hydroxybenzoate 1-2, prodan 0.8-1, tetramethylolmethane 2-3, dibutyl tin laurate 0.1-0.2, micropowder silica gel 2-4, trimethyl benzyl ammonia chloride 0.8-2, deionized water 70-75;
Micropowder silica gel is mixed with tetramethylolmethane, at 65-70 DEG C stirring mixing 2-4 minute, add the 30-40% of above-mentioned deionized water weight, trimethyl benzyl ammonia chloride, 100-200 rev/min dispersed with stirring 6-12 minute, obtain dispersion liquid;
Ethyl hydroxybenzoate is mixed with Aloe extraction solution, it is stirring evenly and then adding in silicone acrylic emulsion, at 35-40 DEG C insulated and stirred 10-15 minute, add above-mentioned dispersion liquid, dibutyl tin laurate, stir to room temperature, add remain each raw material, 300-400 rev/min dispersed with stirring 7-10 minute, obtain described coalescents.
The preparation method of a kind of anti-low temperature water-repellent paint, it is characterised in that comprise the following steps:
By flyash, calcium fluoride mixing, join epoxyoleic acid butyl ester, at 60-70 DEG C stirring mixing 3-5 minute, add zinc dialkyl dithiophosphate, stirring to room temperature, join in deionized water, add chitosan, 50-70 rev/min dispersed with stirring 3-6 minute;
By each raw material after above-mentioned process with remain each raw material mix, 500-600 rev/min dispersed with stirring 20-30 minute, obtain described anti-low temperature water-repellent paint.
The invention have the advantage that
The water-repellent paint of the present invention can store at subzero 20 DEG C, transport, and winter construction film forming is fast, drying time is short, without harmful organic volatile solvent, belongs to Environmental-protecwaterproof waterproof paint, is coated with membrane stability high, better resistance, good waterproof performance.
Detailed description of the invention
Embodiment 1
A kind of anti-low temperature water-repellent paint, it is made up of the raw material of following weight parts (kilogram):
Silicone acrylic emulsion 61.3, tea saponin 2, chitosan 3, flyash 4-7, barium metaborate 3.1, double; two ten four carbon alcohols esters 0.8, epoxyoleic acid butyl ester 2, cyclohexanhexanol 2, N cyclohexyl N' phenyl P phenylene diamine 0.4, calcium fluoride 3, medical stone powder 6, zinc dialkyl dithiophosphate 0.2, coalescents 5, deionized water 17;
Described coalescents is made up of the raw material of following weight parts:
Silicone acrylic emulsion 30-35, Aloe extraction solution 0.3, ethyl hydroxybenzoate 1, prodan 0.8, tetramethylolmethane 2, dibutyl tin laurate 0.2, micropowder silica gel 4, trimethyl benzyl ammonia chloride 0.8, deionized water 75;
Micropowder silica gel is mixed with tetramethylolmethane, stirring mixing 4 minutes at 70 DEG C, add the 40% of above-mentioned deionized water weight, trimethyl benzyl ammonia chloride, 200 revs/min of dispersed with stirring 12 minutes, obtain dispersion liquid;
Ethyl hydroxybenzoate is mixed with Aloe extraction solution, is stirring evenly and then adding in silicone acrylic emulsion, insulated and stirred 15 minutes at 40 DEG C, add above-mentioned dispersion liquid, dibutyl tin laurate, stir to room temperature, add and remain each raw material, 400 revs/min of dispersed with stirring 10 minutes, obtain described coalescents.
The preparation method of a kind of anti-low temperature water-repellent paint, comprises the following steps:
By flyash, calcium fluoride mixing, join epoxyoleic acid butyl ester, stirring mixing 5 minutes at 70 DEG C, add zinc dialkyl dithiophosphate, stirring, to room temperature, joins in deionized water, adds chitosan, 70 revs/min of dispersed with stirring 3 minutes;
Each raw material after above-mentioned process is mixed with remaining each raw material, 600 revs/min of dispersed with stirring 20 minutes, obtain described anti-low temperature water-repellent paint.
Performance test:
Elongation percentage: >=300%;
Impermeability: 0.3MPa (one hour waterproof).
Claims (2)
1. an anti-low temperature water-repellent paint, it is characterised in that it is made up of the raw material of following weight parts: silicone acrylic emulsion 61.3, tea saponin 2, chitosan 3, flyash 4-7, barium metaborate 3.1, double; two ten four carbon alcohols esters 0.8, epoxyoleic acid butyl ester 2, cyclohexanhexanol 2, N cyclohexyl N' phenyl P phenylene diamine 0.4, calcium fluoride 3, medical stone powder 6, zinc dialkyl dithiophosphate 0.2, coalescents 5, deionized water 17;
Described coalescents is made up of the raw material of following weight parts:
Silicone acrylic emulsion 30-35, Aloe extraction solution 0.3, ethyl hydroxybenzoate 1, prodan 0.8, tetramethylolmethane 2, dibutyl tin laurate 0.2, micropowder silica gel 4, trimethyl benzyl ammonia chloride 0.8, deionized water 75;
Micropowder silica gel is mixed with tetramethylolmethane, stirring mixing 4 minutes at 70 DEG C, add the 40% of above-mentioned deionized water weight, trimethyl benzyl ammonia chloride, 200 revs/min of dispersed with stirring 12 minutes, obtain dispersion liquid;
Ethyl hydroxybenzoate is mixed with Aloe extraction solution, is stirring evenly and then adding in silicone acrylic emulsion, insulated and stirred 15 minutes at 40 DEG C, add above-mentioned dispersion liquid, dibutyl tin laurate, stir to room temperature, add and remain each raw material, 400 revs/min of dispersed with stirring 10 minutes, obtain described coalescents.
2. the preparation method of an anti-low temperature water-repellent paint as claimed in claim 1, it is characterized in that comprising the following steps: by flyash, calcium fluoride mixing, join epoxyoleic acid butyl ester, stirring mixing 5 minutes at 70 DEG C, adding zinc dialkyl dithiophosphate, stirring, to room temperature, joins in deionized water, add chitosan, 70 revs/min of dispersed with stirring 3 minutes;
Each raw material after above-mentioned process is mixed with remaining each raw material, 600 revs/min of dispersed with stirring 20 minutes, obtain described anti-low temperature water-repellent paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293095.0A CN104119756B (en) | 2014-06-26 | 2014-06-26 | A kind of anti-low temperature water-repellent paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293095.0A CN104119756B (en) | 2014-06-26 | 2014-06-26 | A kind of anti-low temperature water-repellent paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104119756A CN104119756A (en) | 2014-10-29 |
| CN104119756B true CN104119756B (en) | 2016-06-15 |
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| CN201410293095.0A Active CN104119756B (en) | 2014-06-26 | 2014-06-26 | A kind of anti-low temperature water-repellent paint |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400343A (en) * | 2015-12-08 | 2016-03-16 | 黄涌芮 | Low temperature resistant coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005187543A (en) * | 2003-12-24 | 2005-07-14 | Kansai Paint Co Ltd | Thermosetting metallic powder coating composition and forming method of metallic powder coating film |
| CN103351675B (en) * | 2013-06-20 | 2015-12-23 | 滁州麦斯特新型建材有限公司 | A kind of washability exterior coating and preparation method thereof |
| CN103351672B (en) * | 2013-06-20 | 2016-05-04 | 滁州麦斯特新型建材有限公司 | A kind of environmental protection exterior coating and preparation method thereof |
| CN103602156A (en) * | 2013-10-21 | 2014-02-26 | 青岛海伴诚远塑业有限公司 | Novel exterior wall waterproof coating |
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| Publication number | Publication date |
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| CN104119756A (en) | 2014-10-29 |
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Effective date of registration: 20240416 Address after: 262736 Beiyangtou Village, Taitou Town, Shouguang City, Weifang City, Shandong Province Patentee after: Weifang Jiankai Waterproof Material Co.,Ltd. Country or region after: China Address before: No.18, Shaoji Ershi Road, Banta Town, Laian County, Chuzhou City, Anhui Province Patentee before: ANHUI KUAILAI WATERPROOFING & ANTI-CORROSION Co.,Ltd. Country or region before: China |