CN104312318A - Thermally-insulating waterproof coating used for automobiles - Google Patents

Thermally-insulating waterproof coating used for automobiles Download PDF

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Publication number
CN104312318A
CN104312318A CN201410502452.XA CN201410502452A CN104312318A CN 104312318 A CN104312318 A CN 104312318A CN 201410502452 A CN201410502452 A CN 201410502452A CN 104312318 A CN104312318 A CN 104312318A
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China
Prior art keywords
parts
stirring
minute
rev
raw material
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Pending
Application number
CN201410502452.XA
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Chinese (zh)
Inventor
徐泽军
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Ruizhan Tongling Technologies Co Ltd
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Ruizhan Tongling Technologies Co Ltd
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Priority to CN201410502452.XA priority Critical patent/CN104312318A/en
Publication of CN104312318A publication Critical patent/CN104312318A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Thermally-insulating waterproof coating used for automobiles is disclosed. The coating comprises following raw materials by weight: 71-80 parts of vinyl-acrylic emulsion, 1-2 parts of sodium thiocyanate, 1-2 parts of coconut oil, 2-4 parts of polyvinylidene chloride, 1-2 parts of diazolidinyl urea, 6-10 parts of fumed silica, 3-4 parts of cresyl diphenyl phosphate, 10-12 parts of nanometer carbon powder, 3-5 parts of hollow glass microbeads, 2-3 parts of aluminium nitride, 1-2 parts of antimonous oxide, 1-2 parts of dimethyl aminopropyl amine, 0.5-1 part of dibutyltin dilaurate, 14-20 parts of deionized water and 4-7 parts of an adhesion auxiliary agent. The hollow glass microbeads added into the coating can reflect a large quantity of solar infrared ray radiant heat, and reduce the surface temperature of coatings. The coating effectively insulates transmission of external heat and is good in waterproofness and high in resistance.

Description

A kind of automobile heat-insulating waterproof coating
?
Technical field
The present invention relates generally to a kind of coating, particularly relates to a kind of automobile heat-insulating waterproof coating.
Background technology
So-called coating refers to that coating body surface can form film under certain conditions and play protection, the class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Be main raw material mainly with vegetables oil greatly because of early stage coating, therefore also known as painting.Present synthetic resins is most of or all instead of vegetables oil, therefore is called coating.Application of paints is all respects in life, and coating not only requires that cohesiveness is strong, good weatherability, and resistance is high, also wants nontoxic pollution-free, therefore improves constantly the overall quality of coating for improving people's living standard, and accelerating urban development has very great meaning.
Summary of the invention
The object of the invention is just to provide a kind of automobile heat-insulating waterproof coating.
The present invention is achieved by the following technical solutions:
A kind of automobile heat-insulating waterproof coating, it is made up of the raw material of following weight parts:
Acrylate and vinyl acetate emulsion 71-80, Sodium Thiocyanate 99 1-2, cocounut oil 1-2, poly(vinylidene fluoride) 2-4, two Imidurea 1-2, gas-phase silica 6-10, phosphate toluene diphenyl ester 3-4, nano-carbon powder 10-12, hollow glass microballoon 3-5, aluminium nitride 2-3, antimonous oxide 1-2, dimethylaminopropylamine 1-2, dibutyl tin laurate 0.5-1, deionized water 14-20, adhesive aid 4-7;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 40-46, lauryl glucosyl 1-2, methyl methacrylate 2-4, ammonium persulphate 1-2, allyl polyglycol 3-4, potassium zirconium carbonate 1-2, nano-carbon powder 2-3, tetrafluoroethylene wax 2-3, nano titanium oxide 0.1-1, deionized water 6-8;
By potassium zirconium carbonate, nano-carbon powder mixing, add tetrafluoroethylene wax after stirring, at 60-70 DEG C, be uniformly mixed 10-16 minute, add allyl polyglycol, be stirred to normal temperature, join in Eva emulsion, 200-300 rev/min of dispersed with stirring 10-12 minute;
Lauryl glucosyl is joined in deionized water, after stirring, add ammonium persulphate, methyl methacrylate, 60-80 rev/min of dispersed with stirring 3-5 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 800-1000 rev/min of dispersed with stirring 2-4 minute, obtains described adhesive aid.
A preparation method for automobile heat-insulating waterproof coating, is characterized in that comprising the following steps:
By gas-phase silica, nano-carbon powder, hollow glass microballoon mixing, dibutyl tin laurate is added after stirring, 100-200 rev/min is uniformly mixed 10-16 minute, join in acrylate and vinyl acetate emulsion, add dimethylaminopropylamine, 300-400 rev/min is stirred a point 5-10 minute, mixes with each raw material of residue, 600-800 rev/min of dispersed with stirring 20-30 minute, obtains described automobile heat-insulating waterproof coating.
Advantage of the present invention is:
The hollow glass microballoon that waterproof paint of the present invention adds can reflect a lot of solar infrared radiant heat, and reduce Coated Surface Temperature, effectively can intercept the transmission of outside heat, good waterproof performance, resistance is high.
Embodiment
Embodiment 1
A kind of automobile heat-insulating waterproof coating, it is made up of the raw material of following weight parts (kilogram):
Acrylate and vinyl acetate emulsion 80, Sodium Thiocyanate 99 1, cocounut oil 1, poly(vinylidene fluoride) 4, two Imidurea 1, gas-phase silica 10, phosphate toluene diphenyl ester 4, nano-carbon powder 12, hollow glass microballoon 3, aluminium nitride 2, antimonous oxide 2, dimethylaminopropylamine 2, dibutyl tin laurate 0.5, deionized water 20, adhesive aid 7;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 46, lauryl glucosyl 2, methyl methacrylate 4, ammonium persulphate 2, allyl polyglycol 4, potassium zirconium carbonate 1, nano-carbon powder 3, tetrafluoroethylene wax 2, nano titanium oxide 0.1, deionized water 6;
By potassium zirconium carbonate, nano-carbon powder mixing, add tetrafluoroethylene wax after stirring, at 70 DEG C, be uniformly mixed 16 minutes, add allyl polyglycol, be stirred to normal temperature, join in Eva emulsion, 300 revs/min of dispersed with stirring 12 minutes;
Lauryl glucosyl is joined in deionized water, after stirring, add ammonium persulphate, methyl methacrylate, 80 revs/min of dispersed with stirring 5 minutes;
Mixed with each raw material of residue by each raw material after above-mentioned process, 1000 revs/min of dispersed with stirring 4 minutes, obtain described adhesive aid.
A preparation method for automobile heat-insulating waterproof coating, is characterized in that comprising the following steps:
By gas-phase silica, nano-carbon powder, hollow glass microballoon mixing, dibutyl tin laurate is added after stirring, 200 revs/min are uniformly mixed 16 minutes, join in acrylate and vinyl acetate emulsion, add dimethylaminopropylamine, 400 revs/min of stirrings divide 10 minutes, mix with each raw material of residue, 800 revs/min of dispersed with stirring 30 minutes, obtain described automobile heat-insulating waterproof coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).

Claims (2)

1. an automobile heat-insulating waterproof coating, is characterized in that what it was made up of the raw material of following weight parts:
Acrylate and vinyl acetate emulsion 71-80, Sodium Thiocyanate 99 1-2, cocounut oil 1-2, poly(vinylidene fluoride) 2-4, two Imidurea 1-2, gas-phase silica 6-10, phosphate toluene diphenyl ester 3-4, nano-carbon powder 10-12, hollow glass microballoon 3-5, aluminium nitride 2-3, antimonous oxide 1-2, dimethylaminopropylamine 1-2, dibutyl tin laurate 0.5-1, deionized water 14-20, adhesive aid 4-7;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 40-46, lauryl glucosyl 1-2, methyl methacrylate 2-4, ammonium persulphate 1-2, allyl polyglycol 3-4, potassium zirconium carbonate 1-2, nano-carbon powder 2-3, tetrafluoroethylene wax 2-3, nano titanium oxide 0.1-1, deionized water 6-8;
By potassium zirconium carbonate, nano-carbon powder mixing, add tetrafluoroethylene wax after stirring, at 60-70 DEG C, be uniformly mixed 10-16 minute, add allyl polyglycol, be stirred to normal temperature, join in Eva emulsion, 200-300 rev/min of dispersed with stirring 10-12 minute;
Lauryl glucosyl is joined in deionized water, after stirring, add ammonium persulphate, methyl methacrylate, 60-80 rev/min of dispersed with stirring 3-5 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 800-1000 rev/min of dispersed with stirring 2-4 minute, obtains described adhesive aid.
2. a preparation method for automobile heat-insulating waterproof coating as claimed in claim 1, is characterized in that comprising the following steps:
By gas-phase silica, nano-carbon powder, hollow glass microballoon mixing, dibutyl tin laurate is added after stirring, 100-200 rev/min is uniformly mixed 10-16 minute, join in acrylate and vinyl acetate emulsion, add dimethylaminopropylamine, 300-400 rev/min is stirred a point 5-10 minute, mixes with each raw material of residue, 600-800 rev/min of dispersed with stirring 20-30 minute, obtains described automobile heat-insulating waterproof coating.
CN201410502452.XA 2014-09-26 2014-09-26 Thermally-insulating waterproof coating used for automobiles Pending CN104312318A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410502452.XA CN104312318A (en) 2014-09-26 2014-09-26 Thermally-insulating waterproof coating used for automobiles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410502452.XA CN104312318A (en) 2014-09-26 2014-09-26 Thermally-insulating waterproof coating used for automobiles

Publications (1)

Publication Number Publication Date
CN104312318A true CN104312318A (en) 2015-01-28

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CN201410502452.XA Pending CN104312318A (en) 2014-09-26 2014-09-26 Thermally-insulating waterproof coating used for automobiles

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086671A (en) * 2015-08-05 2015-11-25 天长市巨龙车船涂料有限公司 Heat-insulation waterproof coating
CN106280730A (en) * 2016-08-14 2017-01-04 安庆市沁之源电器有限公司 A kind of gas-cooker antibiotic paint and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086671A (en) * 2015-08-05 2015-11-25 天长市巨龙车船涂料有限公司 Heat-insulation waterproof coating
CN106280730A (en) * 2016-08-14 2017-01-04 安庆市沁之源电器有限公司 A kind of gas-cooker antibiotic paint and preparation method thereof

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Application publication date: 20150128