CN104312319A - High-grade perlite powder waterproof coating used for automobiles - Google Patents
High-grade perlite powder waterproof coating used for automobiles Download PDFInfo
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- CN104312319A CN104312319A CN201410502455.3A CN201410502455A CN104312319A CN 104312319 A CN104312319 A CN 104312319A CN 201410502455 A CN201410502455 A CN 201410502455A CN 104312319 A CN104312319 A CN 104312319A
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- Prior art keywords
- stirring
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- perlite powder
- dispersed
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
High-grade perlite powder waterproof coating used for automobiles is disclosed. The coating comprises following raw materials by weight: 80-90 parts of vinyl-acrylic emulsion, 1-2 parts of phthalic anhydride, 2-3 parts of polytetrahydrofuran glycol, 1-2 parts of sodium 2,4,5-trichlorobenzenesulphonate, 3-4 parts of thermoplastic polyurethane elastomer, 4-6 parts of expanded perlite powder, 1-2 parts of zinc borate, 0.1-0.3 part of 1-hydroxycyclohexyl phenyl ketone, 0.8-1 part of N,N-diethylaniline, 2-3 parts of pentaerythritol, 4-5 parts of diisodecyl phthalate, 15-25 parts of deionized water and 4-7 parts of a bonding auxiliary agent. The expanded perlite powder added into the waterproof coating is good in dispersibility and fluidity, and is capable of reducing the using amount of auxiliary agents in the coating, enhancing compatibility among the materials, and enhancing stability of the coating. The coating is high in waterproofness, good in decoration performance and environmental friendly and is especially suitable for middle- or top- grade places.
Description
?
Technical field
The present invention relates generally to a kind of coating, particularly relates to the high-grade perlite powder waterproof paint of a kind of automobile.
Background technology
So-called coating refers to that coating body surface can form film under certain conditions and play protection, the class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Be main raw material mainly with vegetables oil greatly because of early stage coating, therefore also known as painting.Present synthetic resins is most of or all instead of vegetables oil, therefore is called coating.Application of paints is all respects in life, and coating not only requires that cohesiveness is strong, good weatherability, and resistance is high, also wants nontoxic pollution-free, therefore improves constantly the overall quality of coating for improving people's living standard, and accelerating urban development has very great meaning.
Summary of the invention
The object of the invention is just to provide the high-grade perlite powder waterproof paint of a kind of automobile.
The present invention is achieved by the following technical solutions:
The high-grade perlite powder waterproof paint of a kind of automobile, it is made up of the raw material of following weight parts:
Acrylate and vinyl acetate emulsion 80-90, Tetra hydro Phthalic anhydride 1-2, PTMG 2-3,2,4,5-trichlorobenzene sodium sulfonate 1-2, Polyurethane Thermoplastic Elastomer 3-4, swelling perlite powder 4-6, zinc borate 1-2,1-hydroxycyclohexyl phenyl ketone 0.1-0.3, N, N-Diethyl Aniline 0.8-1, tetramethylolmethane 2-3, Di Iso Decyl Phthalate 4-5, deionized water 15-25, adhesive aid 4-7;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 40-46, lauryl glucosyl 1-2, methyl methacrylate 2-4, ammonium persulphate 1-2, allyl polyglycol 3-4, potassium zirconium carbonate 1-2, nano-carbon powder 2-3, tetrafluoroethylene wax 2-3, nano titanium oxide 0.1-1, deionized water 6-8;
By potassium zirconium carbonate, nano-carbon powder mixing, add tetrafluoroethylene wax after stirring, at 60-70 DEG C, be uniformly mixed 10-16 minute, add allyl polyglycol, be stirred to normal temperature, join in Eva emulsion, 200-300 rev/min of dispersed with stirring 10-12 minute;
Lauryl glucosyl is joined in deionized water, after stirring, add ammonium persulphate, methyl methacrylate, 60-80 rev/min of dispersed with stirring 3-5 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 800-1000 rev/min of dispersed with stirring 2-4 minute, obtains described adhesive aid.
An automobile preparation method for high-grade perlite powder waterproof paint, is characterized in that comprising the following steps:
By swelling perlite powder, zinc borate, Polyurethane Thermoplastic Elastomer mixing, Di Iso Decyl Phthalate, N is added after stirring, N-Diethyl Aniline, 3-5 minute is uniformly mixed at 40-60 DEG C, add the 60-70% of above-mentioned acrylate and vinyl acetate emulsion weight, 100-200 rev/min of dispersed with stirring 10-14 minute;
Remaining acrylate and vinyl acetate emulsion is mixed with deionized water, adds 2,4,5-trichlorobenzene sodium sulfonate, stir, add PTMG, 50-60 rev/min of dispersed with stirring 5-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 600-800 rev/min of dispersed with stirring 20-30 minute, obtains the high-grade perlite powder waterproof paint of described automobile.
Advantage of the present invention is:
The swelling perlite powder dispersiveness that waterproof paint of the present invention adds and good fluidity, can reduce the usage quantity of auxiliary agent in coating, can also strengthen the consistency of each storeroom, improve the stability of coating, water-repellancy is strong, good decorative property, environmental protection, is specially adapted to medium-to-high grade place.
Embodiment
Embodiment 1
The high-grade perlite powder waterproof paint of a kind of automobile, it is made up of the raw material of following weight parts (kilogram):
Acrylate and vinyl acetate emulsion 90, Tetra hydro Phthalic anhydride 1, PTMG 2,2,4,5-trichlorobenzene sodium sulfonate 2, Polyurethane Thermoplastic Elastomer 3, swelling perlite powder 6, zinc borate 2,1-hydroxycyclohexyl phenyl ketone 0.3, N, N-Diethyl Aniline 0.8, tetramethylolmethane 3, Di Iso Decyl Phthalate 5, deionized water 25, adhesive aid 4-7;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 46, lauryl glucosyl 1, methyl methacrylate 2, ammonium persulphate 2, allyl polyglycol 3, potassium zirconium carbonate 1, nano-carbon powder 3, tetrafluoroethylene wax 3, nano titanium oxide 0.1, deionized water 8;
By potassium zirconium carbonate, nano-carbon powder mixing, add tetrafluoroethylene wax after stirring, at 70 DEG C, be uniformly mixed 16 minutes, add allyl polyglycol, be stirred to normal temperature, join in Eva emulsion, 200 revs/min of dispersed with stirring 12 minutes;
Lauryl glucosyl is joined in deionized water, after stirring, add ammonium persulphate, methyl methacrylate, 60 revs/min of dispersed with stirring 5 minutes;
Mixed with each raw material of residue by each raw material after above-mentioned process, 1000 revs/min of dispersed with stirring 4 minutes, obtain described adhesive aid.
An automobile preparation method for high-grade perlite powder waterproof paint, is characterized in that comprising the following steps:
By swelling perlite powder, zinc borate, Polyurethane Thermoplastic Elastomer mixing, add Di Iso Decyl Phthalate, N, N-Diethyl Aniline after stirring, at 60 DEG C, be uniformly mixed 3 minutes, add 70%, 200 revs/min of dispersed with stirring 14 minutes of above-mentioned acrylate and vinyl acetate emulsion weight;
Remaining acrylate and vinyl acetate emulsion is mixed with deionized water, adds 2,4,5-trichlorobenzene sodium sulfonate, stir, add PTMG, 60 revs/min of dispersed with stirring 10 minutes;
Mixed with each raw material of residue by each raw material after above-mentioned process, 800 revs/min of dispersed with stirring 30 minutes, obtain the high-grade perlite powder waterproof paint of described automobile.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).
Claims (2)
1. the high-grade perlite powder waterproof paint of automobile, is characterized in that what it was made up of the raw material of following weight parts:
Acrylate and vinyl acetate emulsion 80-90, Tetra hydro Phthalic anhydride 1-2, PTMG 2-3,2,4,5-trichlorobenzene sodium sulfonate 1-2, Polyurethane Thermoplastic Elastomer 3-4, swelling perlite powder 4-6, zinc borate 1-2,1-hydroxycyclohexyl phenyl ketone 0.1-0.3, N, N-Diethyl Aniline 0.8-1, tetramethylolmethane 2-3, Di Iso Decyl Phthalate 4-5, deionized water 15-25, adhesive aid 4-7;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 40-46, lauryl glucosyl 1-2, methyl methacrylate 2-4, ammonium persulphate 1-2, allyl polyglycol 3-4, potassium zirconium carbonate 1-2, nano-carbon powder 2-3, tetrafluoroethylene wax 2-3, nano titanium oxide 0.1-1, deionized water 6-8;
By potassium zirconium carbonate, nano-carbon powder mixing, add tetrafluoroethylene wax after stirring, at 60-70 DEG C, be uniformly mixed 10-16 minute, add allyl polyglycol, be stirred to normal temperature, join in Eva emulsion, 200-300 rev/min of dispersed with stirring 10-12 minute;
Lauryl glucosyl is joined in deionized water, after stirring, add ammonium persulphate, methyl methacrylate, 60-80 rev/min of dispersed with stirring 3-5 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 800-1000 rev/min of dispersed with stirring 2-4 minute, obtains described adhesive aid.
2. an automobile as claimed in claim 1 preparation method for high-grade perlite powder waterproof paint, is characterized in that comprising the following steps:
By swelling perlite powder, zinc borate, Polyurethane Thermoplastic Elastomer mixing, Di Iso Decyl Phthalate, N is added after stirring, N-Diethyl Aniline, 3-5 minute is uniformly mixed at 40-60 DEG C, add the 60-70% of above-mentioned acrylate and vinyl acetate emulsion weight, 100-200 rev/min of dispersed with stirring 10-14 minute;
Remaining acrylate and vinyl acetate emulsion is mixed with deionized water, adds 2,4,5-trichlorobenzene sodium sulfonate, stir, add PTMG, 50-60 rev/min of dispersed with stirring 5-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 600-800 rev/min of dispersed with stirring 20-30 minute, obtains the high-grade perlite powder waterproof paint of described automobile.
Priority Applications (1)
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CN201410502455.3A CN104312319A (en) | 2014-09-26 | 2014-09-26 | High-grade perlite powder waterproof coating used for automobiles |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105086671A (en) * | 2015-08-05 | 2015-11-25 | 天长市巨龙车船涂料有限公司 | Heat-insulation waterproof coating |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5049198A (en) * | 1988-06-10 | 1991-09-17 | Ribas Roger S | Calcium sulfate process for the coproduction of Portland cement clinker and concentrated sulfur dioxide adequate to manufacture sulfuric acid |
CN103614020A (en) * | 2013-10-28 | 2014-03-05 | 蚌埠凯盛工程技术有限公司 | Thermostable waterproof coating |
CN103666144A (en) * | 2013-09-10 | 2014-03-26 | 铜陵市肆得科技有限责任公司 | Acrylic resin antirust paint for vehicle and preparation method thereof |
-
2014
- 2014-09-26 CN CN201410502455.3A patent/CN104312319A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5049198A (en) * | 1988-06-10 | 1991-09-17 | Ribas Roger S | Calcium sulfate process for the coproduction of Portland cement clinker and concentrated sulfur dioxide adequate to manufacture sulfuric acid |
CN103666144A (en) * | 2013-09-10 | 2014-03-26 | 铜陵市肆得科技有限责任公司 | Acrylic resin antirust paint for vehicle and preparation method thereof |
CN103614020A (en) * | 2013-10-28 | 2014-03-05 | 蚌埠凯盛工程技术有限公司 | Thermostable waterproof coating |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105086671A (en) * | 2015-08-05 | 2015-11-25 | 天长市巨龙车船涂料有限公司 | Heat-insulation waterproof coating |
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