CN108530975A - A kind of high-property water-based detergent for ink and preparation method thereof - Google Patents
A kind of high-property water-based detergent for ink and preparation method thereof Download PDFInfo
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- CN108530975A CN108530975A CN201810341997.5A CN201810341997A CN108530975A CN 108530975 A CN108530975 A CN 108530975A CN 201810341997 A CN201810341997 A CN 201810341997A CN 108530975 A CN108530975 A CN 108530975A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
Abstract
The invention discloses a kind of high-property water-based detergent for ink and preparation method thereof, the raw material of the cleaning agent includes：Triton X-100, enuatrol, glycerine, benzotriazole, sodium nitrite, cetearyl glucoside, lauryl glucose carboxylic acid sodium, Cocoamidopropyl betaine, trisodium citrate, lauric acid diethyl amide, Tween 80, sorbester p17,4A zeolite molecular sieves, sodium tripolyphosphate, bentonite, deionized water.Cleaning ability of the present invention is strong, suitable for being adhered to the removing of the indissoluble cured printing ink dirt on ink spraying equipment, and does not corrode metal equipment.
Description
Technical field
The invention belongs to cleaning agent technical fields, and in particular to a kind of high-property water-based detergent for ink and its preparation side
Method.
Background technology
Since the 21th century, with rapid development of economy, the yield and demand of printing packaging product are continuously increased；
Ink is consumable material important in printing packaging process of producing product, and domestic ink consumption figure is more than 300,000 t within 2015.Due to
The cleaning problem of ink is frequently referred in printing process, so detergent for ink receives always industry concern.Printing ink is
By the coarse dispersion system for the stabilization that pigment, link stuff and various auxiliary agents form, main component is that grease/synthetic resin is organic
Object and colorant class inorganic matter.During printing ink cleaning, most important task is that removal is securely attached to printing
The grease type ink film on object surface, the cleaning efficiency to ink film of cleaning agent are the key that weigh cleaning agent dirt-removing power power.It is early
Phase printing enterprise's industry generally using being organic solvent class detergent for ink, can quickly, thoroughly remove ink pellet surface at
The cleaning effect of membrane substance, ink is very high.
The main component of traditional ink cleaning agent is：Mineral oil based on gasoline and kerosene and with arene, ketone
With the organic solvent based on ethers etc..Although the cleaning performance of traditional detergent for ink is good, rate of drying block is cheap,
Simple production process；But it is poor that there is also safeties, organic volatile（VOC）Content is high, endangers the health etc. of printing worker
Disadvantage.This makes environmentally protective, safety and efficient detergent for ink cause people and more and more pay close attention to.Aqua type ink
Cleaning agent is added suitable water or complete water consumption substitution organic solvent in conventional clean agent and is formed, this makes aqua type
The content of organic solvent substantially reduces in ink detergent for ink, reduces organic solvent and makees to the swollen of ink roller and blanket
With reducing the damage of printing equipment；The volatility and flash-point for reducing cleaning agent improve the feature of environmental protection and safety of cleaning agent
Property.
Invention content
The object of the present invention is to provide a kind of high-property water-based detergent for ink and preparation method thereof.
A kind of high-property water-based detergent for ink, raw material include：Triton X-100, enuatrol, glycerine, benzo
Triazole, sodium nitrite, cetearyl glucoside, lauryl glucose carboxylic acid sodium, Cocoamidopropyl betaine, citric acid
Trisodium, lauric acid diethyl amide, Tween 80, sorbester p17,4A zeolite molecular sieves, sodium tripolyphosphate, bentonite, deionized water.
Preferably, the high-property water-based detergent for ink, raw material include in parts by weight：Triton X-100
2-5 parts, 1-3 parts of enuatrol, 0.5-1 parts of glycerine, 1-3 parts of benzotriazole, 2-5 parts of sodium nitrite, cetearyl glucoside
2-4 parts, 1-4 parts of lauryl glucose carboxylic acid sodium, 2-5 parts of Cocoamidopropyl betaine, 0.5-1 parts of trisodium citrate, bay
Sour diglycollic amide 1-3 parts, 1-2 parts of Tween 80,2-4 parts of sorbester p17,4-8 parts of 4A zeolite molecular sieves, sodium tripolyphosphate 1-2
Part, 1-2 parts of bentonite, 20-40 parts of deionized water.
Preferably, the high-property water-based detergent for ink, raw material include in parts by weight：Triton X-100
4 parts, 2 parts of enuatrol, 0.8 part of glycerine, 2 parts of benzotriazole, 4 parts of sodium nitrite, 3 parts of cetearyl glucoside, lauryl
2 parts of glucose carboxylic acid sodium, 4 parts of Cocoamidopropyl betaine, 0.7 part of trisodium citrate, 2 parts of lauric acid diethyl amide are spat
80 1.5 parts of temperature, 3 parts of sorbester p17,7 parts of 4A zeolite molecular sieves, 1.5 parts of sodium tripolyphosphate, 1.5 parts of bentonite, deionized water 18
Part.
The preparation method of above-mentioned high-property water-based detergent for ink, includes the following steps：
Step 1, the deionized water of half dosage is added in stirred tank, Triton X-100, oil is added while stirring
Sour sodium, cetearyl glucoside, lauryl glucose carboxylic acid sodium, Cocoamidopropyl betaine, lauric acid diethyl amide,
Stirring obtains mixed liquor A to being completely dissolved；
Step 2, the deionized water of remaining dosage is added in stirred tank, glycerine, benzotriazole, tween is added while stirring
80, sorbester p17, sodium tripolyphosphate stir to being completely dissolved, obtain mixed liquid B；
Step 3, mixed liquor A and mixed liquid B are mixed, remaining ingredient are added under stirring condition, adjust pH to 6-7 to get.
Preferably, the constant temperature of stirred tank is kept the temperature at 50-60 DEG C in step 2.
Preferably, step 3 adjusts pH using dilute sulfuric acid.
The present invention is using Triton X-100, cetearyl glucoside, lauryl glucose carboxylic acid sodium, cocounut oil
The host agent of amido propyl betaine and sodium oleae mixture as cleaning agent, not only high temperature performance is stablized, but also has good
Decontamination, emulsification, wetability and stronger degreasing power；It is slow using benzotriazole, sodium nitrite and sodium citrate composition antirust
Agent is lost, to alleviate corrosivity of the cleaning agent to printing equipment；The all remarkable profit of lauric acid diethyl amide, Tween 80 and sorbester p17
Wet, infiltration, emulsification, peptizaiton, can promote cleaning action of the host agent to ink；And 4A zeolite molecular sieves and bentonite can be with
Promote adhewsive action of the host agent on ink and its film forming matter, extends the residence time.
Cleaning ability of the present invention is strong, suitable for being adhered to the removing of the indissoluble cured printing ink dirt on ink spraying equipment, and
And do not corrode metal equipment.
Specific implementation mode
Embodiment 1
High-property water-based detergent for ink, raw material include in parts by weight：2 parts of Triton X-100,1 part of enuatrol,
0.5 part of glycerine, 1 part of benzotriazole, 2 parts of sodium nitrite, 2 parts of cetearyl glucoside, lauryl glucose carboxylic acid sodium 1
Part, 2 parts of Cocoamidopropyl betaine, 0.5 part of trisodium citrate, 1 part of lauric acid diethyl amide, 1 part of Tween 80, sapn
80 2 parts, 4 parts of 4A zeolite molecular sieves, 1 part of sodium tripolyphosphate, 1 part of bentonite, 20 parts of deionized water.
The preparation method of above-mentioned high-property water-based detergent for ink, includes the following steps：
Step 1, the deionized water of half dosage is added in stirred tank, Triton X-100, oil is added while stirring
Sour sodium, cetearyl glucoside, lauryl glucose carboxylic acid sodium, Cocoamidopropyl betaine, lauric acid diethyl amide,
Stirring obtains mixed liquor A to being completely dissolved；
Step 2, the deionized water of remaining dosage is added in stirred tank, be heated to 50-60 DEG C and kept the temperature, is added while stirring sweet
Oil, benzotriazole, Tween 80, sorbester p17, sodium tripolyphosphate stir to being completely dissolved, obtain mixed liquid B；
Step 3, mixed liquor A and mixed liquid B are mixed, remaining ingredient is added under stirring condition, using 10%（v/v）Dilute sulfuric acid tune
Save pH to 6-7 to get.
For the detergency of gained cleaning agent up to 99.8%, no flash-point is all non-corrosive to No. 45 steel and duralumin.Using scouring
The heavy dirt of ink on printing machine surface can be all cleaned with spray, and using rear equipment surface without discoloration.
Embodiment 2
High-property water-based detergent for ink, raw material include in parts by weight：3 parts of Triton X-100,2 parts of enuatrol,
0.7 part of glycerine, 2 parts of benzotriazole, 4 parts of sodium nitrite, 3 parts of cetearyl glucoside, lauryl glucose carboxylic acid sodium 2
Part, 4 parts of Cocoamidopropyl betaine, 0.8 part of trisodium citrate, 2 parts of lauric acid diethyl amide, 1.5 parts of Tween 80, department
80 3 parts of disk, 7 parts of 4A zeolite molecular sieves, 1.4 parts of sodium tripolyphosphate, 1.5 parts of bentonite, 27 parts of deionized water.
The preparation method of above-mentioned high-property water-based detergent for ink, includes the following steps：
Step 1, the deionized water of half dosage is added in stirred tank, Triton X-100, oil is added while stirring
Sour sodium, cetearyl glucoside, lauryl glucose carboxylic acid sodium, Cocoamidopropyl betaine, lauric acid diethyl amide,
Stirring obtains mixed liquor A to being completely dissolved；
Step 2, the deionized water of remaining dosage is added in stirred tank, be heated to 50-60 DEG C and kept the temperature, is added while stirring sweet
Oil, benzotriazole, Tween 80, sorbester p17, sodium tripolyphosphate stir to being completely dissolved, obtain mixed liquid B；
Step 3, mixed liquor A and mixed liquid B are mixed, remaining ingredient is added under stirring condition, using 10%（v/v）Dilute sulfuric acid tune
Save pH to 6-7 to get.
For the detergency of gained cleaning agent up to 99.6%, no flash-point is all non-corrosive to No. 45 steel and duralumin.Using scouring
The heavy dirt of ink on printing machine surface can be all cleaned with spray, and using rear equipment surface without discoloration.
Embodiment 3
High-property water-based detergent for ink, raw material include in parts by weight：4 parts of Triton X-100,2 parts of enuatrol,
0.8 part of glycerine, 2 parts of benzotriazole, 4 parts of sodium nitrite, 3 parts of cetearyl glucoside, lauryl glucose carboxylic acid sodium 2
Part, 4 parts of Cocoamidopropyl betaine, 0.7 part of trisodium citrate, 2 parts of lauric acid diethyl amide, 1.5 parts of Tween 80, department
80 3 parts of disk, 7 parts of 4A zeolite molecular sieves, 1.5 parts of sodium tripolyphosphate, 1.5 parts of bentonite, 18 parts of deionized water.
The preparation method of above-mentioned high-property water-based detergent for ink, includes the following steps：
Step 1, the deionized water of half dosage is added in stirred tank, Triton X-100, oil is added while stirring
Sour sodium, cetearyl glucoside, lauryl glucose carboxylic acid sodium, Cocoamidopropyl betaine, lauric acid diethyl amide,
Stirring obtains mixed liquor A to being completely dissolved；
Step 2, the deionized water of remaining dosage is added in stirred tank, be heated to 50-60 DEG C and kept the temperature, is added while stirring sweet
Oil, benzotriazole, Tween 80, sorbester p17, sodium tripolyphosphate stir to being completely dissolved, obtain mixed liquid B；
Step 3, mixed liquor A and mixed liquid B are mixed, remaining ingredient is added under stirring condition, using 10%（v/v）Dilute sulfuric acid tune
Save pH to 6-7 to get.
For the detergency of gained cleaning agent up to 99.7%, no flash-point is all non-corrosive to No. 45 steel and duralumin.Using scouring
The heavy dirt of ink on printing machine surface can be all cleaned with spray, and using rear equipment surface without discoloration.
Embodiment 4
High-property water-based detergent for ink, raw material include in parts by weight：5 parts of Triton X-100,3 parts of enuatrol,
1 part of glycerine, 3 parts of benzotriazole, 5 parts of sodium nitrite, 4 parts of cetearyl glucoside, 4 parts of lauryl glucose carboxylic acid sodium,
5 parts of Cocoamidopropyl betaine, 1 part of trisodium citrate, 3 parts of lauric acid diethyl amide, 2 parts of Tween 80, sorbester p17 4
Part, 8 parts of 4A zeolite molecular sieves, 2 parts of sodium tripolyphosphate, 2 parts of bentonite, 40 parts of deionized water.
The preparation method of above-mentioned high-property water-based detergent for ink, includes the following steps：
Step 1, the deionized water of half dosage is added in stirred tank, Triton X-100, oil is added while stirring
Sour sodium, cetearyl glucoside, lauryl glucose carboxylic acid sodium, Cocoamidopropyl betaine, lauric acid diethyl amide,
Stirring obtains mixed liquor A to being completely dissolved；
Step 2, the deionized water of remaining dosage is added in stirred tank, be heated to 50-60 DEG C and kept the temperature, is added while stirring sweet
Oil, benzotriazole, Tween 80, sorbester p17, sodium tripolyphosphate stir to being completely dissolved, obtain mixed liquid B；
Step 3, mixed liquor A and mixed liquid B are mixed, remaining ingredient is added under stirring condition, using 10%（v/v）Dilute sulfuric acid tune
Save pH to 6-7 to get.
For the detergency of gained cleaning agent up to 99.6%, no flash-point is all non-corrosive to No. 45 steel and duralumin.Using scouring
The heavy dirt of ink on printing machine surface can be all cleaned with spray, and using rear equipment surface without discoloration.
Claims (6)
1. a kind of high-property water-based detergent for ink, it is characterised in that：Raw material includes：Triton X-100, enuatrol,
Glycerine, benzotriazole, sodium nitrite, cetearyl glucoside, lauryl glucose carboxylic acid sodium, cocamidopropyl propyl amide beet
Alkali, trisodium citrate, lauric acid diethyl amide, Tween 80, sorbester p17,4A zeolite molecular sieves, sodium tripolyphosphate, bentonite,
Deionized water.
2. according to its high-property water-based detergent for ink described in claim 1, it is characterised in that：Raw material wraps in parts by weight
It includes：2-5 parts of Triton X-100,1-3 parts of enuatrol, 0.5-1 parts of glycerine, 1-3 parts of benzotriazole, sodium nitrite 2-
5 parts, 2-4 parts of cetearyl glucoside, 1-4 parts of lauryl glucose carboxylic acid sodium, 2-5 parts of Cocoamidopropyl betaine, lemon
0.5-1 parts of lemon acid trisodium, 1-3 parts of lauric acid diethyl amide, 1-2 parts of Tween 80,2-4 parts of sorbester p17,4A zeolite molecular sieves
4-8 parts, 1-2 parts of sodium tripolyphosphate, 1-2 parts of bentonite, 20-40 parts of deionized water.
3. according to its high-property water-based detergent for ink described in claim 1, it is characterised in that：Raw material wraps in parts by weight
It includes：4 parts of Triton X-100,2 parts of enuatrol, 0.8 part of glycerine, 2 parts of benzotriazole, 4 parts of sodium nitrite, spermaceti is hard
3 parts of aliphatic radical glucoside, 2 parts of lauryl glucose carboxylic acid sodium, 4 parts of Cocoamidopropyl betaine, 0.7 part of trisodium citrate, the moon
2 parts of cinnamic acid diglycollic amide, 1.5 parts of Tween 80,3 parts of sorbester p17,7 parts of 4A zeolite molecular sieves, 1.5 parts of sodium tripolyphosphate are swollen
1.5 parts of profit soil, 18 parts of deionized water.
4. the preparation method of high-property water-based detergent for ink described in claim 1, it is characterised in that：Include the following steps：
Step 1, the deionized water of half dosage is added in stirred tank, Triton X-100, oil is added while stirring
Sour sodium, cetearyl glucoside, lauryl glucose carboxylic acid sodium, Cocoamidopropyl betaine, lauric acid diethyl amide,
Stirring obtains mixed liquor A to being completely dissolved；
Step 2, the deionized water of remaining dosage is added in stirred tank, glycerine, benzotriazole, tween is added while stirring
80, sorbester p17, sodium tripolyphosphate stir to being completely dissolved, obtain mixed liquid B；
Step 3, mixed liquor A and mixed liquid B are mixed, remaining ingredient are added under stirring condition, adjust pH to 6-7 to get.
5. the preparation method of high-property water-based detergent for ink according to claim 1, it is characterised in that：It is stirred in step 2
The constant temperature for mixing kettle is kept the temperature at 50-60 DEG C.
6. the preparation method of high-property water-based detergent for ink according to claim 1, it is characterised in that：Step 3 uses
Dilute sulfuric acid adjusts pH.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810341997.5A CN108530975A (en) | 2018-04-17 | 2018-04-17 | A kind of high-property water-based detergent for ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810341997.5A CN108530975A (en) | 2018-04-17 | 2018-04-17 | A kind of high-property water-based detergent for ink and preparation method thereof |
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| CN108530975A true CN108530975A (en) | 2018-09-14 |
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| CN201810341997.5A Withdrawn CN108530975A (en) | 2018-04-17 | 2018-04-17 | A kind of high-property water-based detergent for ink and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113105781A (en) * | 2021-04-12 | 2021-07-13 | 南京信息工程大学 | Efficient environment-friendly water-based ink cleaning agent and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952425A (en) * | 2012-11-19 | 2013-03-06 | 南京信息工程大学 | Water-based printing ink cleaning agent and preparation method thereof |
| CN103881467A (en) * | 2012-12-21 | 2014-06-25 | 朱勇强 | Neutral deinking agent and preparation method thereof |
| CN105331181A (en) * | 2015-12-07 | 2016-02-17 | 北京印刷学院 | High-performance printing ink detergent and preparing method thereof |
| CN107353700A (en) * | 2017-06-14 | 2017-11-17 | 广东红日星实业有限公司 | A kind of new and effective water-based ink cleaning agent and preparation method thereof |
-
2018
- 2018-04-17 CN CN201810341997.5A patent/CN108530975A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952425A (en) * | 2012-11-19 | 2013-03-06 | 南京信息工程大学 | Water-based printing ink cleaning agent and preparation method thereof |
| CN103881467A (en) * | 2012-12-21 | 2014-06-25 | 朱勇强 | Neutral deinking agent and preparation method thereof |
| CN105331181A (en) * | 2015-12-07 | 2016-02-17 | 北京印刷学院 | High-performance printing ink detergent and preparing method thereof |
| CN107353700A (en) * | 2017-06-14 | 2017-11-17 | 广东红日星实业有限公司 | A kind of new and effective water-based ink cleaning agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113105781A (en) * | 2021-04-12 | 2021-07-13 | 南京信息工程大学 | Efficient environment-friendly water-based ink cleaning agent and preparation method thereof |
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Application publication date: 20180914 |