CN108570260A - A kind of printing ink with high adhesion force performance - Google Patents

A kind of printing ink with high adhesion force performance Download PDF

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Publication number
CN108570260A
CN108570260A CN201810513278.7A CN201810513278A CN108570260A CN 108570260 A CN108570260 A CN 108570260A CN 201810513278 A CN201810513278 A CN 201810513278A CN 108570260 A CN108570260 A CN 108570260A
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CN
China
Prior art keywords
parts
printing ink
high adhesion
resin
adhesion force
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810513278.7A
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Chinese (zh)
Inventor
李峰
郑志龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
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ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd filed Critical ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
Priority to CN201810513278.7A priority Critical patent/CN108570260A/en
Publication of CN108570260A publication Critical patent/CN108570260A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104Polyesters
    • C09D11/105Alkyd resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of printing ink with high adhesion force performance, it is divided into according to raw material weight component, 26 28 parts of polyurethane resin, 22 24 parts of modified alkyd resin, 24 26 parts of water soluble acrylic resin, 35 parts of mica, 79 parts of wollastonite, 13 parts of 783 slow curing water, 24 parts of adhesion promoter, 44 46 parts of Y butyrolactone, 32 34 parts of turpentine oil, 35 parts of dispersant, 46 parts of antifoaming agent.Using technical solution of the present invention, the printing ink prepared using resin-based materials based on polyurethane resin, modified alkyd resin, water soluble acrylic resin, and using Y butyrolactone, turpentine oil as organic solvent homogenization, also adhesion promoter is added, the adhesion performance of printing ink can be improved, to improve the printing stability of printing ink, application effect is preferable.

Description

A kind of printing ink with high adhesion force performance
Technical field
The present invention relates to the technical field of printing ink more particularly to a kind of printing ink with high adhesion force performance.
Background technology
Printing is so that printing ink transfer is arrived through processes such as plate-making, Shi Mo, pressurizations the original copys such as word, picture, photo, anti-fake The material surfaces such as paper, textile, plastic products, leather, the technology of batch duplicating original copy content.
Oil plant, that is, ink of printing, is the important materials of printing, and pattern, word are shown printing by printing or air brushing On object.Ink includes main component and auxiliary element, they uniformly mix and form a kind of stickiness glue through repeat-rolling Fluid.It is made of resin, pigment, filler auxiliary agent and organic solvent etc..For books and periodicals including decoration, building decoration and electric wire The various printings such as road plank.As social demand increases, also respective extension and the growth of various ink.
The usual rate of drying of existing printing ink is excessively slow or adhesive force is bad, is easy to fall off, leads to time and resource Waste, for this purpose, it is proposed that a kind of printing ink with high adhesion force performance.
Invention content
To solve the defect of prior art, the invention discloses a kind of printing ink with high adhesion force performance.
The invention discloses a kind of printing ink with high adhesion force performance, are divided into according to raw material weight component, poly- ammonia 26-28 parts of ester resin, 22-24 parts of modified alkyd resin, 24-26 parts of water soluble acrylic resin, 3-5 parts of mica, wollastonite 7-9 Part, 1-3 parts of 783 slow curing water, 2-4 parts of adhesion promoter, 44-46 parts of Y- butyrolactone, 32-34 parts of turpentine oil, dispersant 3-5 Part, 4-6 parts of antifoaming agent.
Preferably, a kind of printing ink with high adhesion force performance, is divided into, polyurethane resin according to raw material weight component 27 parts, it is 23 parts of modified alkyd resin, 25 parts of water soluble acrylic resin, 4 parts of mica, 8 parts of wollastonite, 2 parts of 783 slow curing water, attached 3 parts of adhesion promoter, 45 parts of Y- butyrolactone, 33 parts of turpentine oil, 4 parts of dispersant, 5 parts of antifoaming agent.
Preferably, the adhesion promoter is epoxy group-methoxy functional silane.
Preferably, the dispersant is one or two kinds of mixtures of sodium tripolyphosphate, calgon.
Preferably, the antifoaming agent is natural oil.
Preferably, a kind of printing ink with high adhesion force performance, specific preparation method are as follows:
1)Weigh polyurethane resin, modified alkyd resin, water soluble acrylic resin, Y- butyrolactone, turpentine oil input homogeneous set In standby, under 1000-1500 revs/min of rotating speed, 1-2h is pre-processed;
2)It weighs in mica, wollastonite input grinder, is ground pulverization process, and cross 700-800 mesh sieve, obtains mixing and fill out Fill fine powder material;
3)By step 2)The mixed powder of middle acquisition is put into 1)In middle homogenizer, and 783 slow curing water, adhesive force promotion is added Agent, dispersant, antifoaming agent, the control of homogenizer temperature is at 80-90 DEG C, 2000-3000 revs/min of stirring 2-3h of rotating speed, then drops Temperature stands to 25-30 DEG C and places 1-2h;
4)To step 3)The middle final off-set oil black liquid for standing the mixed liquor placed and can be obtained needs through filtering.
Advantageous effect is:Using resin base material based on polyurethane resin, modified alkyd resin, water soluble acrylic resin Expect the printing ink prepared, and using Y- butyrolactone, turpentine oil as organic solvent homogenization, also add adhesion promoter, The adhesion performance that printing ink can be improved, to improve the printing stability of printing ink, application effect is preferable.
Specific implementation mode
Embodiment 1
The invention discloses a kind of printing ink with high adhesion force performance, are divided into according to raw material weight component, polyurethane tree 26 parts of fat, 22 parts of modified alkyd resin, 24 parts of water soluble acrylic resin, 3 parts of mica, 7 parts of wollastonite, 1 part of 783 slow curing water, 2 parts of adhesion promoter, 44 parts of Y- butyrolactone, 32 parts of turpentine oil, 3 parts of dispersant, 4 parts of antifoaming agent.
The adhesion promoter is epoxy group-methoxy functional silane.
The dispersant is one or two kinds of mixtures of sodium tripolyphosphate, calgon.
The antifoaming agent is natural oil.
A kind of printing ink with high adhesion force performance, specific preparation method are as follows:
1)Weigh polyurethane resin, modified alkyd resin, water soluble acrylic resin, Y- butyrolactone, turpentine oil input homogeneous set In standby, under 1000 revs/min of rotating speed, 1h is pre-processed;
2)It weighs in mica, wollastonite input grinder, is ground pulverization process, and cross 700 mesh sieve, it is thin to obtain mixing filling Powder;
3)By step 2)The mixed powder of middle acquisition is put into 1)In middle homogenizer, and 783 slow curing water, adhesive force promotion is added Agent, dispersant, antifoaming agent, the control of homogenizer temperature is at 80 DEG C, 2000 revs/min of stirring 2h of rotating speed, then is cooled to 25 DEG C, quiet Placement location 1h;
4)To step 3)The middle final off-set oil black liquid for standing the mixed liquor placed and can be obtained needs through filtering.
Embodiment 2
The invention discloses a kind of printing ink with high adhesion force performance, are divided into according to raw material weight component, polyurethane tree 27 parts of fat, 23 parts of modified alkyd resin, 25 parts of water soluble acrylic resin, 4 parts of mica, 8 parts of wollastonite, 2 parts of 783 slow curing water, 3 parts of adhesion promoter, 45 parts of Y- butyrolactone, 33 parts of turpentine oil, 4 parts of dispersant, 5 parts of antifoaming agent.
The adhesion promoter is epoxy group-methoxy functional silane.
The dispersant is one or two kinds of mixtures of sodium tripolyphosphate, calgon.
The antifoaming agent is natural oil.
A kind of printing ink with high adhesion force performance, specific preparation method are as follows:
1)Weigh polyurethane resin, modified alkyd resin, water soluble acrylic resin, Y- butyrolactone, turpentine oil input homogeneous set In standby, under 1300 revs/min of rotating speed, 1.5h is pre-processed;
2)It weighs in mica, wollastonite input grinder, is ground pulverization process, and cross 750 mesh sieve, it is thin to obtain mixing filling Powder;
3)By step 2)The mixed powder of middle acquisition is put into 1)In middle homogenizer, and 783 slow curing water, adhesive force promotion is added Agent, dispersant, antifoaming agent, the control of homogenizer temperature is at 85 DEG C, 2500 revs/min of stirring 2.5h of rotating speed, then is cooled to 28 DEG C, It stands and places 1.5h;
4)To step 3)The middle final off-set oil black liquid for standing the mixed liquor placed and can be obtained needs through filtering.
Embodiment 3
The invention discloses a kind of printing ink with high adhesion force performance, are divided into according to raw material weight component, polyurethane tree 28 parts of fat, 24 parts of modified alkyd resin, 26 parts of water soluble acrylic resin, 5 parts of mica, 9 parts of wollastonite, 3 parts of 783 slow curing water, 4 parts of adhesion promoter, 46 parts of Y- butyrolactone, 34 parts of turpentine oil, 5 parts of dispersant, 6 parts of antifoaming agent.
The adhesion promoter is epoxy group-methoxy functional silane.
The dispersant is one or two kinds of mixtures of sodium tripolyphosphate, calgon.
The antifoaming agent is natural oil.
A kind of printing ink with high adhesion force performance, specific preparation method are as follows:
1)Weigh polyurethane resin, modified alkyd resin, water soluble acrylic resin, Y- butyrolactone, turpentine oil input homogeneous set In standby, under 1500 revs/min of rotating speed, 2h is pre-processed;
2)It weighs in mica, wollastonite input grinder, is ground pulverization process, and cross 800 mesh sieve, it is thin to obtain mixing filling Powder;
3)By step 2)The mixed powder of middle acquisition is put into 1)In middle homogenizer, and 783 slow curing water, adhesive force promotion is added Agent, dispersant, antifoaming agent, the control of homogenizer temperature is at 90 DEG C, 3000 revs/min of stirring 3h of rotating speed, then is cooled to 30 DEG C, quiet Placement location 2h;
4)To step 3)The middle final off-set oil black liquid for standing the mixed liquor placed and can be obtained needs through filtering.
Finally it should be noted that:Above example is only to illustrate the present invention and not limits technology described in the invention Scheme;Therefore, although this specification with reference to above-mentioned each embodiment to present invention has been detailed description, this Field it is to be appreciated by one skilled in the art that still can modify to the present invention or equivalent replacement;And all do not depart from this The technical solution of the spirit and scope of invention and its improvement should all be covered in scope of the presently claimed invention.

Claims (6)

1. a kind of printing ink with high adhesion force performance, it is characterised in that:It is divided into according to raw material weight component, polyurethane tree 26-28 parts of fat, 22-24 parts of modified alkyd resin, 24-26 parts of water soluble acrylic resin, 3-5 parts of mica, 7-9 parts of wollastonite, 783 1-3 parts of slow curing water, 44-46 parts of Y- butyrolactone, 32-34 parts of turpentine oil, 3-5 parts of dispersant, disappear at 2-4 parts of adhesion promoter 4-6 parts of infusion.
2. a kind of printing ink with high adhesion force performance according to claim 1, it is characterised in that:According to raw material weight Amount component is divided into, 27 parts of polyurethane resin, 23 parts of modified alkyd resin, 25 parts of water soluble acrylic resin, 4 parts of mica, silicon ash 8 parts of stone, 2 parts of 783 slow curing water, 3 parts of adhesion promoter, 45 parts of Y- butyrolactone, 33 parts of turpentine oil, 4 parts of dispersant, antifoaming agent 5 Part.
3. a kind of printing ink with high adhesion force performance according to claim 1, it is characterised in that:The adhesive force Accelerating agent is epoxy group-methoxy functional silane.
4. a kind of printing ink with high adhesion force performance according to claim 1, it is characterised in that:The dispersant For sodium tripolyphosphate, one or two kinds of mixtures of calgon.
5. a kind of printing ink with high adhesion force performance according to claim 1, it is characterised in that:The antifoaming agent For natural oil.
6. a kind of printing ink with high adhesion force performance according to claim 1, it is characterised in that:It is specifically made Preparation Method is as follows:
Weigh polyurethane resin, modified alkyd resin, water soluble acrylic resin, Y- butyrolactone, turpentine oil input homogenizer In, under 1000-1500 revs/min of rotating speed, pre-process 1-2h;
It weighs in mica, wollastonite input grinder, is ground pulverization process, and cross 700-800 mesh sieve, obtains mixing filling Fine powder material;
By step 2)The mixed powder of middle acquisition is put into 1)In middle homogenizer, and 783 slow curing water, adhesive force promotion is added Agent, dispersant, antifoaming agent, the control of homogenizer temperature is at 80-90 DEG C, 2000-3000 revs/min of stirring 2-3h of rotating speed, then drops Temperature stands to 25-30 DEG C and places 1-2h;
To step 3)The middle final off-set oil black liquid for standing the mixed liquor placed and can be obtained needs through filtering.
CN201810513278.7A 2018-05-25 2018-05-25 A kind of printing ink with high adhesion force performance Pending CN108570260A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110760214A (en) * 2019-10-04 2020-02-07 北海市龙浩光电科技有限公司 High-dyne-value ultraviolet-resistant screen printing ink for glass panel
CN112778829A (en) * 2019-11-11 2021-05-11 怀化市恒大彩印包装有限公司 Environment-friendly printing ink and preparation method thereof
CN113652154A (en) * 2021-09-17 2021-11-16 苏州同构科技有限公司 Wear-resistant color paste coating with high weather resistance and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002046322A2 (en) * 2000-12-06 2002-06-13 Printar Ltd. Heat curable ink-jet ink for printing on printed circuit boards
CN1788059A (en) * 2003-06-26 2006-06-14 中国涂料株式会社 Lowly odorous solvent-based coating composition
CN103113786A (en) * 2013-03-07 2013-05-22 苏州牛剑新材料有限公司 Graphene conductive ink and preparation method thereof
CN104761950A (en) * 2015-04-29 2015-07-08 柯云 Water-resistant glass printing ink and preparation method thereof
CN106280682A (en) * 2015-05-13 2017-01-04 孙宝林 A kind of environmental protection leather aqueous stamp-pad ink and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002046322A2 (en) * 2000-12-06 2002-06-13 Printar Ltd. Heat curable ink-jet ink for printing on printed circuit boards
CN1788059A (en) * 2003-06-26 2006-06-14 中国涂料株式会社 Lowly odorous solvent-based coating composition
CN103113786A (en) * 2013-03-07 2013-05-22 苏州牛剑新材料有限公司 Graphene conductive ink and preparation method thereof
CN104761950A (en) * 2015-04-29 2015-07-08 柯云 Water-resistant glass printing ink and preparation method thereof
CN106280682A (en) * 2015-05-13 2017-01-04 孙宝林 A kind of environmental protection leather aqueous stamp-pad ink and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110760214A (en) * 2019-10-04 2020-02-07 北海市龙浩光电科技有限公司 High-dyne-value ultraviolet-resistant screen printing ink for glass panel
CN112778829A (en) * 2019-11-11 2021-05-11 怀化市恒大彩印包装有限公司 Environment-friendly printing ink and preparation method thereof
CN113652154A (en) * 2021-09-17 2021-11-16 苏州同构科技有限公司 Wear-resistant color paste coating with high weather resistance and preparation method thereof

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Application publication date: 20180925