CN106046927A - Hydrographic transfer printing ink and preparation method thereof - Google Patents
Hydrographic transfer printing ink and preparation method thereof Download PDFInfo
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- CN106046927A CN106046927A CN201610545697.XA CN201610545697A CN106046927A CN 106046927 A CN106046927 A CN 106046927A CN 201610545697 A CN201610545697 A CN 201610545697A CN 106046927 A CN106046927 A CN 106046927A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides hydrographic transfer printing LED curing series printing ink and a preparation method. The printing ink is mainly prepared from, by weight, 15-60 parts of polyurethane acrylic resin, 10-60 parts of epoxy acrylic resin, 2-20 parts of acrylic resin, 6-50 parts of dipropylene glycol diacrylate, 2-20 parts of trimethylolpropane triacrylate and 2-20 parts of photosensitized initiator. The ingredients are added in sequence according to weight parts, stirred regularly at a fixed speed and finally ground through a three-roller machine, stirring is conducted, and the printing oil is obtained. The printing ink meets the requirements of clients for surface decoration of ceramics, glass wine bottles, cosmetic bottles and the like.
Description
Technical field
The present invention relates to a kind of ink, particularly relate to a kind of water transfer ink and preparation method thereof, specifically refer to a kind of answering
It is used in glass, pottery, the metal class water water transfer LED cured printing ink being posted mark industry and preparation method thereof.
Background technology
Water transfer materials refer to substrate surface processing can the print film of global transfer picture and text, base material can be plastics
Thin film, it is also possible to be water-transfer printing paper.This print film is as text carrier, and its appearance should be a much progress of printing technology,
Because there being a lot of product to be difficult to directly print, and having had this carrier, people will be able to be schemed by ripe printing technology
Literary composition is first imprinted on the carrier of easily printing, then picture and text are transferred on stock.As have certain altitude, relatively heavier,
Grotesque article or the least article of area can use transfer printing process.Single for water transfer printing technique, fitting of it
Answering property is very wide, almost without the product that cannot transfer.
At present, most of mode of printings are both for plane or the decorating printing of almost plane stock, as thin film gravure,
Paper offset printing etc.;The stock of silk screen printing is more, can print some irregular curved surfaces, such as plastic bottle;The adaptation of bat printing
Property makes progress again than silk screen printing, but coverage is too narrow.Water transfer technique is a kind of special trans-printing new technique.Water turns
Print technology is a kind of printing utilizing hydraulic pressure that the transfer paper/plastic foil of band multicolour pattern carries out macromolecule hydrolysis.Along with people
The raising of requirement to product packaging with decoration, the purposes of water transfer is more and more extensive, can be used for Automobile Products, electronic product,
Room articles for use, daily fine work, indoor building materials etc..Principle and the perfect printing effect of its indirect printing solve many product tables
A difficult problem for face decoration, is mainly used in all kinds of pottery, applique, the transfer of metal class material etc..
Transfer ink then with the dyestuff of special nature be main make the pattern being imprinted on special paper, word etc., permissible
Because heating is allowed to transfer to the ink that other base materials get on.At present, the resin used in domestic water transfer ink, substantially state
The solid propenoic acid resin of outer import, price is high, uses existing defects, owing to the vitrification point of solid propenoic acid resin is
32 DEG C, during summer, resin particle easily melts conglomeration, could dissolve with solvent after need to breaking into pieces.And domestic thermoplastic acrylic tree
Fat, mostly uses dimethylbenzene, butyl acetate to make solvent, has penetrating odor, it is difficult to for printing industry;And, existing
Thermoplastic acrylic resin, due to molecular weight, causes being difficult to reach balance in hardness and hot strength.Examine for cost
Consider, some producer water transfer ink in utilize acrylic resin to replace acrylic resin, but there is the defect that fragility is big,
Toughener need to be added and carry out toughness reinforcing, but toughener easily migrates, cause the water the produced transfer marble paper short time to become after depositing
Crisp.Additionally, the production of existing acrylic resin is again to the process of liquid from liquid to solid, more to energy resource consumption.
Therefore, study and the current conventional high-temperature of material substitution of low-temperature bake type is sintered, the product material therefor of high energy consumption
Necessitate.But, current low-temperature bake type product material therefor is solvent volatile dry type, causes environment, human body necessarily
Hazardness;And volatile, plant capacity is high so that it is energy consumption is big, not environmentally.
Summary of the invention
For solving the problems referred to above, it is an object of the invention to provide a kind of water transfer ink.The ink low temperature that the present invention provides
Baking uses the solidification of non-volatile pollution-free LED UV cold light source, thus has the advantage of low-energy environment-friendly.
For reaching above-mentioned purpose, the present invention adopts the following technical scheme that
A kind of water transfer ink, is made up of the raw material comprising following parts by weight:
The amount of polyurethane acrylate resin can be such as 18 parts, 23 parts, 28 parts, 33 parts, 39 parts, 45 parts, 50 parts, 55 parts
Deng.
The amount of Epocryl can be such as 12 parts, 18 parts, 23 parts, 28 parts, 33 parts, 39 parts, 45 parts, 50 parts,
55 parts etc..
The amount of acrylic resin can be such as 3 parts, 7 parts, 11 parts, 16 parts, 19 parts etc..
The amount of propylene glycol diacrylate can be such as 7 parts, 11 parts, 18 parts, 23 parts, 28 parts, 33 parts, 39 parts, 45 parts,
49 parts etc..
The amount of trimethylolpropane trimethacrylate can be such as 3 parts, 7 parts, 11 parts, 16 parts, 19 parts etc..
The amount of photoinitiator can be such as 3 parts, 7 parts, 11 parts, 16 parts, 19 parts etc..
As preferably, the water transfer ink of the present invention, it is made up of the raw material comprising following parts by weight:
The present invention uses the combination of polyurethane acrylate resin and Epocryl can ensure the attachment of ink
Power.
As preferably, the water transfer ink of the present invention, also comprise: in organic pigment, defoamer, dispersant or levelling agent
One kind or two or more combination.
As preferably, the water transfer ink of the present invention, raw material by weight also comprises:
The amount of organic pigment can be such as 0.08 part, 0.15 part, 0.5 part, 1.2 parts, 2 parts, 5 parts, 8 parts, 11 parts, 14 parts
Deng.
The amount of defoamer can be such as 0.07 part, 0.12 part, 0.2 part, 0.7 part, 1.3 parts, 2 parts, 2.5 parts, 3.6 parts, 4.1
Part, 4.8 parts etc..
The amount of dispersant can be such as 0.07 part, 0.12 part, 0.2 part, 0.7 part, 1.3 parts, 2 parts, 2.5 parts, 3.6 parts, 4.1
Part, 4.8 parts etc..
The amount of levelling agent can be such as 0.07 part, 0.12 part, 0.2 part, 0.7 part, 1.3 parts, 2 parts, 2.5 parts, 3.6 parts, 4.1
Part, 4.8 parts etc..
As preferably, the water transfer ink of the present invention, raw material by weight also comprises:
As preferably, the water transfer ink of the present invention, described photoinitiator is 4-phenyl benzophenone and/or diphenyl
Oxygen phosphorus.
As preferably, the water transfer ink of the present invention, described organic pigment is permanent bordeaux, permanent yellow, permanent violet, phthalein green grass or young crops
One kind or two or more combination in blue, green, carbon black.
As preferably, the water transfer ink of the present invention, described defoamer be a kind in polymer-type defoamer or 2 kinds with
On combination.Defoamer can help froth breaking and printing off-network effect, makes printing effect more attractive in appearance.
As preferably, the water transfer ink of the present invention, described dispersant is in the block copolymer containing pigment affinity groups
One kind or two or more combination.
As preferably, the water transfer ink of the present invention, described levelling agent is polyether-modified polydimethylsiloxane blend
The one kind or two or more combination of apoplexy due to endogenous wind, the most polyether-modified polydimethylsiloxane.
As preferably, the water transfer ink of the present invention, it is made up of the raw material comprising following parts by weight:
An object of the present invention also resides in the preparation method providing water transfer ink of the present invention, including walking as follows
Rapid:
(1) by polyurethane acrylate resin, Epocryl, acrylic resin, dipropylene glycol diacrylate
Ester, trimethylolpropane trimethacrylate are stirred until homogeneous;
Optionally (2) addition organic pigment, stirring;
(3) surplus materials is added, stirring;
(4) grinding steps (3) gained mixture.
As preferably, preparation method of the present invention, in step (1), the speed of stirring is 800-1000 rev/min, stirring
Time be more than 5 minutes, preferably 10-30 minute.
As preferably, preparation method of the present invention, described in step (2), organic pigment slowly adds under stirring
Enter.
Preferably, the speed of described stirring is 800-1000 rev/min, and the time of stirring is more than 5 minutes, preferably 10-
30 minutes.
As preferably, preparation method of the present invention, in step (3), the speed of stirring is 500-800 rev/min, stirring
Time be more than 2 minutes, preferably 5-10 minute.
As preferably, preparation method of the present invention, in step (4), use three-roller is ground.
Preferably, the number of times of grinding is more than 2 times, preferably 4-6 time.
Preferably, survey 3, left, center, right thickness between machine discharging blade and the preliminary roller machine of grinding, should be less than 50 μm, preferably
Less than 35 μm.Preferably, final finished ink records ink fineness less than 5 μm, preferably smaller than 3 μm on Hegman grind gage.
Present invention have the advantage that ink uses low-temperature bake, use non-volatile pollution-free LED UV cold light source to solidify,
Thus there is the advantage of low-energy environment-friendly.
Detailed description of the invention
For the present invention is better described, it is simple to understand technical scheme, the present invention's is typical but non-limiting
Embodiment is as follows:
Embodiment 1
Raw material contains by weight: polyurethane acrylate resin 30 parts, Epocryl 20 parts, propylene
Acid resin 5 parts, propylene glycol diacrylate 10 parts, trimethylolpropane trimethacrylate 5 parts, photoinitiator 5 parts, organic
Pigment 3 parts, defoamer 0.1 part, dispersant 0.2 part, levelling agent 0.1 part.
Photoinitiator is 4-phenyl benzophenone, diphenyl phosphate oxygen;Organic pigment is permanent violet;Defoamer is polymer
Type defoamer;Dispersant is the block copolymer containing pigment affinity groups;Levelling agent is polyether-modified polydimethylsiloxane.
Concrete preparation method is as follows:
(1) number is pressed by polyurethane acrylate resin, Epocryl, acrylic resin, dipropylene glycol two
Acrylate, within 10-30 minute, to uniformly, mixing speed is 800-1000 in trimethylolpropane trimethacrylate blanking successively stirring
Rev/min.
(2) slowly pressing number under stirring and add organic pigment, stir 10-30 minute, stirring material speed is 800-
2000 revs/min.
(3) adding its remainder by number, stir 5-10 minute, mixing speed is 500-800 rev/min.
(4) use three-roller to be ground 4-6 time by mixed ink, between grinder discharging blade and preliminary roller machine, survey left, center, right three
Point thickness, should be less than 20 μm-35 μm, and final finished ink records ink fineness less than 1 μm-3 μm on Hegman grind gage.
Printing process and drying condition thereof:
1) add diluent and adjust ink viscosity, stir 10 minutes, then stand 10 minutes.
2) use 250-300 mesh grid (100-120T) screen printing, be printed on water-transfer printing paper.
3) turn dry with the solidification of LED machine cold light source on paper by print and water.
4) dried transfer paper is just transferring through soaked patterned layer disengaging and is being attached in material (glass, pottery).Forward glass to
Through baking in 170 DEG C to 30 minutes on glass, pottery.
Embodiment 2
Raw material contains by weight: polyurethane acrylate resin 35 parts, Epocryl 30 parts,
Acrylic resin 8 parts, propylene glycol diacrylate 20 parts, trimethylolpropane trimethacrylate 8 parts, photosensitive draws
Send out agent 8 parts, organic pigment 0 part, defoamer 1 part, dispersant 1 part, levelling agent part 1 part.
Photoinitiator is diphenyl phosphate oxygen;Defoamer is polymer-type defoamer;Dispersant is containing pigment affinity groups
Block copolymer;Levelling agent is polyether-modified polydimethylsiloxane.
Concrete preparation process is same as in Example 1.
Concrete printing process and drying condition thereof are same as in Example 1.
Embodiment 3
Raw material contains by weight: polyurethane acrylate resin 40 parts, Epocryl 40 parts, propylene
Acid resin 10 parts, propylene glycol diacrylate 30 parts, trimethylolpropane trimethacrylate 10 parts, photoinitiator 10 parts,
Organic pigment 8 parts, defoamer 2 parts, dispersant 2 parts, levelling agent 2 parts.
Photoinitiator is 4-phenyl benzophenone;Organic pigment is permanent bordeaux;Defoamer is polymer-type defoamer;Point
Powder is the block copolymer containing pigment affinity groups;Levelling agent is polyether-modified polydimethylsiloxane.
Concrete preparation process is same as in Example 1.
Concrete printing process and drying condition thereof are same as in Example 1.
Embodiment 4
Raw material contains by weight: polyurethane acrylate resin 15 parts, Epocryl 60 parts, propylene
Acid resin 2 parts, propylene glycol diacrylate 50 parts, trimethylolpropane trimethacrylate 2 parts, photoinitiator 2 parts, organic
Pigment 15 parts, defoamer 5 parts, levelling agent part 0.05 part.
Photoinitiator is 4-phenyl benzophenone, diphenyl phosphate oxygen;Organic pigment is permanent yellow;Defoamer is polymer
Type defoamer;Levelling agent is polyether-modified polydimethylsiloxane.
Concrete preparation process is same as in Example 1.
Concrete printing process and drying condition thereof are same as in Example 1.
Embodiment 5
Raw material contains by weight: polyurethane acrylate resin 60 parts, Epocryl 10 parts, propylene
Acid resin 20 parts, propylene glycol diacrylate 6 parts, trimethylolpropane trimethacrylate 20 parts, photoinitiator 20 parts, have
Machine pigment 0.5 part, defoamer 0.05 part, dispersant 5 parts, levelling agent part 5 parts.
Photoinitiator is 4-phenyl benzophenone, diphenyl phosphate oxygen;Organic pigment is carbon black;Defoamer is polymer-type
Defoamer;Dispersant is the block copolymer containing pigment affinity groups;Levelling agent is polyether-modified polydimethylsiloxane.
Concrete preparation process is same as in Example 1.
Concrete printing process and drying condition thereof are same as in Example 1.
The ink ink that the embodiment of the present invention prepares uses low-temperature bake, can use non-volatile pollution-free LED UV cold light source
Solidification, thus there is the advantage of low-energy environment-friendly.
Applicant states, the present invention illustrates the method detailed of the present invention by above-described embodiment, but the present invention not office
It is limited to above-mentioned method detailed, does not i.e. mean that the present invention has to rely on above-mentioned method detailed and could implement.Art
Technical staff is it will be clearly understood that any improvement in the present invention, and the equivalence of raw material each to product of the present invention is replaced and auxiliary element
Interpolation, concrete way choice etc., within the scope of all falling within protection scope of the present invention and disclosure.
Claims (10)
1. a water transfer ink, it is characterised in that be made up of the raw material comprising following parts by weight:
Water transfer ink the most according to claim 1, it is characterised in that be made up of the raw material comprising following parts by weight:
Water transfer ink the most according to claim 1 and 2, it is characterised in that also comprise: organic pigment, defoamer, dispersion
One kind or two or more combination in agent or levelling agent.
Water transfer ink the most according to claim 1 and 2, it is characterised in that raw material by weight also comprises:
Preferably, raw material also comprises by weight:
5. according to the water transfer ink described in any one of claim 1-4, it is characterised in that described photoinitiator is 4-phenyl
Benzophenone and/or diphenyl phosphate oxygen.
6. according to the water transfer ink described in claim 3 or 4, it is characterised in that described organic pigment is permanent bordeaux, forever consolidates
One kind or two or more combination in Huang, permanent violet, phthalocyanine blue, green, carbon black;
Preferably, the one kind or two or more combination during described defoamer is polymer-type defoamer;
Preferably, the one kind or two or more combination during described dispersant is the block copolymer containing pigment affinity groups;
Preferably, described levelling agent be polyether-modified polydimethylsiloxane be blended in species defoamer one kind or two or more
Combination, the most polyether-modified polydimethylsiloxane.
Water transfer ink the most according to claim 1, it is characterised in that be made up of the raw material comprising following parts by weight:
8. the preparation method of the water transfer ink described in any one of claim 1-7, comprises the steps:
(1) by polyurethane acrylate resin, Epocryl, acrylic resin, propylene glycol diacrylate, three
Hydroxymethyl-propane triacrylate is stirred until homogeneous;
Optionally (2) addition organic pigment, stirring;
(3) surplus materials is added, stirring;
(4) grinding steps (3) gained mixture.
Preparation method the most according to claim 8, it is characterised in that in step (1) speed of stirring be 800-1000 turn/
Point, the time of stirring is more than 5 minutes, preferably 10-30 minute;
Preferably, described in step (2), organic pigment is slowly added under stirring;
Preferably, the speed of described stirring is 800-1000 rev/min, and the time of stirring is more than 5 minutes, and preferably 10-30 divides
Clock.
Preparation method the most according to claim 8 or claim 9, it is characterised in that in step (3), the speed of stirring is 500-800
Rev/min, the time of stirring is more than 2 minutes, preferably 5-10 minute;
Preferably, step (4) use three-roller be ground;
Preferably, the number of times of grinding is more than 2 times, preferably 4-6 time;
Preferably, survey 3, left, center, right thickness between machine discharging blade and the preliminary roller machine of grinding, should be less than 50 μm, preferably smaller than
35μm;
Preferably, final finished ink records ink fineness less than 5 μm, preferably smaller than 3 μm on Hegman grind gage.
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CN201610545697.XA CN106046927A (en) | 2016-07-12 | 2016-07-12 | Hydrographic transfer printing ink and preparation method thereof |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108641471A (en) * | 2018-03-28 | 2018-10-12 | 深圳市美丽华科技股份有限公司 | A kind of aqueous nylon ink and preparation method thereof |
CN108912816A (en) * | 2018-09-20 | 2018-11-30 | 永修县利君科技有限公司 | A kind of cured water transfer ink of LED |
CN108997824A (en) * | 2018-09-10 | 2018-12-14 | 东莞市美吉高分子材料有限公司 | A kind of novel environment friendly LED-UV water transfer glass ink and its production method |
CN109664573A (en) * | 2018-12-25 | 2019-04-23 | 常州市华健药用包装材料股份有限公司 | A kind of cold stamping shaped composite hard sheet of printable high-intensitive solid medicinal |
CN109763353A (en) * | 2019-01-28 | 2019-05-17 | 常州蓝旗亚纺织品有限公司 | A kind of preparation method of UV-curable waterborne printing inks |
CN110328980A (en) * | 2019-08-26 | 2019-10-15 | 泉州颖彩彩印有限公司 | A kind of printing layer and preparation method thereof of radium-shine composite water transfer film |
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CN101696332A (en) * | 2009-10-28 | 2010-04-21 | 东周化学工业(昆山)有限公司 | Ultra-violet curing transfer ink |
CN103555152A (en) * | 2013-09-27 | 2014-02-05 | 上海乘鹰新材料有限公司 | UV light-cured transfer adhesive composition |
CN103602142A (en) * | 2013-12-06 | 2014-02-26 | 东周化学工业(昆山)有限公司 | Novel ultraviolet-curing transfer printing ink |
CN105733389A (en) * | 2016-04-13 | 2016-07-06 | 湖南省金海科技有限公司 | LED-UV-cured transfer printing adhesive and preparation method thereof |
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CN101696332A (en) * | 2009-10-28 | 2010-04-21 | 东周化学工业(昆山)有限公司 | Ultra-violet curing transfer ink |
CN103555152A (en) * | 2013-09-27 | 2014-02-05 | 上海乘鹰新材料有限公司 | UV light-cured transfer adhesive composition |
CN103602142A (en) * | 2013-12-06 | 2014-02-26 | 东周化学工业(昆山)有限公司 | Novel ultraviolet-curing transfer printing ink |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108641471A (en) * | 2018-03-28 | 2018-10-12 | 深圳市美丽华科技股份有限公司 | A kind of aqueous nylon ink and preparation method thereof |
CN108997824A (en) * | 2018-09-10 | 2018-12-14 | 东莞市美吉高分子材料有限公司 | A kind of novel environment friendly LED-UV water transfer glass ink and its production method |
CN108912816A (en) * | 2018-09-20 | 2018-11-30 | 永修县利君科技有限公司 | A kind of cured water transfer ink of LED |
CN109664573A (en) * | 2018-12-25 | 2019-04-23 | 常州市华健药用包装材料股份有限公司 | A kind of cold stamping shaped composite hard sheet of printable high-intensitive solid medicinal |
CN109664573B (en) * | 2018-12-25 | 2020-07-17 | 常州市华健药用包装材料股份有限公司 | Printable high-strength solid medicinal cold stamping forming composite hard sheet |
CN109763353A (en) * | 2019-01-28 | 2019-05-17 | 常州蓝旗亚纺织品有限公司 | A kind of preparation method of UV-curable waterborne printing inks |
CN110328980A (en) * | 2019-08-26 | 2019-10-15 | 泉州颖彩彩印有限公司 | A kind of printing layer and preparation method thereof of radium-shine composite water transfer film |
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