CN104250470B - The antistatic environment-friendly ink of waste vegetable oil pin for a kind of huge profit - Google Patents

The antistatic environment-friendly ink of waste vegetable oil pin for a kind of huge profit Download PDF

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Publication number
CN104250470B
CN104250470B CN201410445760.3A CN201410445760A CN104250470B CN 104250470 B CN104250470 B CN 104250470B CN 201410445760 A CN201410445760 A CN 201410445760A CN 104250470 B CN104250470 B CN 104250470B
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China
Prior art keywords
vegetable oil
ink
waste vegetable
oil pin
friendly
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CN201410445760.3A
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CN104250470A (en
Inventor
徐明克
裴大伟
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ANHUI YAMEI PRINTING INK INDUSTRIAL Co Ltd
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ANHUI YAMEI PRINTING INK INDUSTRIAL Co Ltd
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Abstract

The present invention relates to environment-friendly ink development field, the antistatic environment-friendly ink that is specifically related to a kind of huge profit waste vegetable oil pin, this ink is made up of the raw material of following weight portion: phosphorus pentoxide 1-2, environmental-friendly pigment 8-11, stearic acid diethylene glycol dilaurate 2-4, contracting two glycerine 4-6, a lauryl methacrylate 8-10, polyvinyl butyral resin 20-26, waste vegetable oil pin 1-3, n-butanol 10-14, butyl glycol ether 12-18, bleaching earth are appropriate, auxiliary agent 1-2; Ink of the present invention is not containing benzene, ketones solvent, environmental protection low toxicity utilizes the bleaching earth that contains phosphorus pentoxide to carry out deodorization, decolouring, impurity elimination, dry processing to waste vegetable oil pin in production technology, reach reduce production costs, object that resource huge profit is used, again in conjunction with other composition, make ink of the present invention not only have good printing adaptability, and strong with the cementitiousness of base material, coating surface implies pearly-lustre, good decorating effect, be difficult for producing static, production technology is simple, and printing process is efficient.

Description

The antistatic environment-friendly ink of waste vegetable oil pin for a kind of huge profit
Technical field
The present invention relates to a kind of environment-friendly ink, be specifically related to the antistatic environment-friendly ink of a kind of huge profit waste vegetable oil pin.
Background technology
Ink is used in a large number in printing industry, it is mainly by resin, pigment, solvent, the compositions such as auxiliary agent form, the ink major part that printing industry is used is at present solvent type ink, this class ink can give out the VOCs that human body and environment is had to harm, some ink directly contacting with human body may work the mischief to health, some harmful substance even can be penetrated into food by packaging, in the packing material such as cigarette and medicine, therefore develop the most important thing that feature of environmental protection ink is Future Development, to fundamentally improve the feature of environmental protection of ink, need to set about from changing ink formulations, adopt novel environment friendly material to replace traditional poisonous and harmful element, obtain gratifying rate of drying simultaneously, serviceability and good printing adaptability.
Summary of the invention
The object of the invention is to, the antistatic environment-friendly ink of a kind of huge profit waste vegetable oil pin is provided, to achieve these goals, the technical solution used in the present invention is as follows:
The antistatic environment-friendly ink of waste vegetable oil pin for a kind of huge profit, it is characterized in that, this ink is made up of the raw material of following weight portion: phosphorus pentoxide 1-2, environmental-friendly pigment 8-11, stearic acid diethylene glycol dilaurate 2-4, contracting two glycerine 4-6, a lauryl methacrylate 8-10, polyvinyl butyral resin 20-26, waste vegetable oil pin 1-3, n-butanol 10-14, butyl glycol ether 12-18, bleaching earth are appropriate, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight portion: propane diols phenylate 4-5, OPE 5-8, GDMA 2-3, deionized water 15-18, neopelex 1-3, EGME 2-3, preparation method is: first OPE is heated to molten condition, then dropwise add GDMA, in dropping process, do not stop to stir with the speed of 800-1000 rev/min, after dropwising, constant temperature keeps 20-30min for subsequent use, again other residual components is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution is made stable emulsion with OPE-dimethacrylate ethanol ester admixture mix and blend again.
The antistatic environment-friendly ink of waste vegetable oil pin for described a kind of huge profit, its preparation process is: first bleaching earth being dropped into the concentration of being prepared by phosphorus pentoxide is to disperse completely in the 4-5% aqueous solution, low temperature drying after immersion 2-3h, and utilize the powder of gained to decolour, be dried and process waste vegetable oil pin, waste vegetable oil pin after treatment mixes with other residual components, high-speed stirred disperses to drop into grinding machine for grinding after 30-50min, to the particle diameter≤10 μ m of gained slurry, to obtain final product.
First the advantage of ink of the present invention is its feature of environmental protection, the solvent low toxic and environment-friendly of employing, and or not containing benzene, ketones solvent, other raw material is to human body yet and environment is nontoxic or the composition of low toxicity, waste vegetable oil pin in raw material is discarded object common in productive life, for fear of the wasting of resources, the bleaching earth that utilization of the present invention contains phosphorus pentoxide carries out deodorization to waste vegetable oil pin, decolouring, impurity elimination, dry processing, thereby can in resin emulsion, mix use, reach the object reducing production costs, be combined with again drying aid, accelerate auxiliary agent and other composition of film forming effect, make ink of the present invention compared with existing product, not only have good printing adaptability, and strong with the cementitiousness of base material, coating surface implies pearly-lustre, good decorating effect, be difficult for producing static, production technology is simple, printing process is efficient.
Detailed description of the invention
Embodiment
Ink prepared by the present embodiment is made up of the raw material of following weight portion: phosphorus pentoxide 1, environmental-friendly pigment 9, stearic acid diethylene glycol dilaurate 3, contracting two glycerine 5, lauryl methacrylate 10, polyvinyl butyral resin 23, waste vegetable oil pin 3, n-butanol 12, butyl glycol ether 18, bleaching earth are appropriate, auxiliary agent 2.
Wherein auxiliary agent is made up of the raw material of following weight portion: propane diols phenylate 5, OPE 8, GDMA 3, deionized water 18, neopelex 1, EGME 2, preparation method is: first OPE is heated to molten condition, then dropwise add GDMA, in dropping process, do not stop to stir with the speed of 1000 revs/min, after dropwising, constant temperature keeps 30min for subsequent use, again other residual components is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution is made stable emulsion with OPE-dimethacrylate ethanol ester admixture mix and blend again.
The preparation process of this printing-ink is: first bleaching earth being dropped into the concentration of being prepared by phosphorus pentoxide is to disperse completely in 5% aqueous solution, low temperature drying after immersion 3h, and utilize the powder of gained to decolour, be dried and process waste vegetable oil pin, waste vegetable oil pin after treatment mixes with other residual components, high-speed stirred disperses to drop into grinding machine for grinding after 50min, to the particle diameter≤10 μ m of gained slurry, to obtain final product.
By prepared the present embodiment ink printing, on PET plate, after its bone dry, according to corresponding national examination criteria, this ink in the performance test results of substrate surface is:

Claims (2)

1. the antistatic environment-friendly ink of a huge profit use waste vegetable oil pin, it is characterized in that, this printing-ink is made up of the raw material of following weight portion: phosphorus pentoxide 1-2, environmental-friendly pigment 8-11, stearic acid diethylene glycol dilaurate 2-4, contracting two glycerine 4-6, a lauryl methacrylate 8-10, polyvinyl butyral resin 20-26, waste vegetable oil pin 1-3, n-butanol 10-14, butyl glycol ether 12-18, bleaching earth are appropriate, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight portion: propane diols phenylate 4-5, OPE 5-8, GDMA 2-3, deionized water 15-18, neopelex 1-3, EGME 2-3, preparation method is: first OPE is heated to molten condition, then dropwise add GDMA, in dropping process, do not stop to stir with the speed of 800-1000 rev/min, after dropwising, constant temperature keeps 20-30min for subsequent use, again other residual components is mixed with deionized water, after each composition dissolves completely, solution is heated to boiling, gained aqueous phase solution is made stable emulsion with OPE-dimethacrylate ethanol ester admixture mix and blend again.
2. the antistatic environment-friendly ink of waste vegetable oil pin for a kind of huge profit as claimed in claim 1, its preparation process is: first bleaching earth being dropped into the concentration of being prepared by phosphorus pentoxide is to disperse completely in the 4-5% aqueous solution, low temperature drying after immersion 2-3h, and utilize the powder of gained to decolour, be dried and process waste vegetable oil pin, waste vegetable oil pin after treatment mixes with other residual components, high-speed stirred disperses to drop into grinding machine for grinding after 30-50min, to the particle diameter≤10 μ m of gained slurry, to obtain final product.
CN201410445760.3A 2014-09-03 2014-09-03 The antistatic environment-friendly ink of waste vegetable oil pin for a kind of huge profit Active CN104250470B (en)

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CN201410445760.3A CN104250470B (en) 2014-09-03 2014-09-03 The antistatic environment-friendly ink of waste vegetable oil pin for a kind of huge profit

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CN104250470B true CN104250470B (en) 2016-05-18

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1077470A (en) * 1993-05-20 1993-10-20 清华大学 The adhesion promoter that is used for photosensitive solder resist
JPH08120206A (en) * 1994-10-21 1996-05-14 Tombow Pencil Co Ltd Fluorescent ink composition for water-based ballpoint pen
KR20020058117A (en) * 2000-12-29 2002-07-12 민태영 Near-infrared absorber, method for preparing same and ink including same
CN1810895A (en) * 2005-09-09 2006-08-02 诸城市腾霞油墨有限公司 Environment protection plastic printing ink and its prepn
CN103725085A (en) * 2013-12-26 2014-04-16 中山大学 Stereoscopic offset printing ink prepared by using waste vegetable oil foots as well as preparation method and application of stereoscopic offset printing ink

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050282928A1 (en) * 2004-06-21 2005-12-22 Tyau-Jeen Lin Ink jet ink

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1077470A (en) * 1993-05-20 1993-10-20 清华大学 The adhesion promoter that is used for photosensitive solder resist
JPH08120206A (en) * 1994-10-21 1996-05-14 Tombow Pencil Co Ltd Fluorescent ink composition for water-based ballpoint pen
KR20020058117A (en) * 2000-12-29 2002-07-12 민태영 Near-infrared absorber, method for preparing same and ink including same
CN1810895A (en) * 2005-09-09 2006-08-02 诸城市腾霞油墨有限公司 Environment protection plastic printing ink and its prepn
CN103725085A (en) * 2013-12-26 2014-04-16 中山大学 Stereoscopic offset printing ink prepared by using waste vegetable oil foots as well as preparation method and application of stereoscopic offset printing ink

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