CN108676317A - A kind of preparation method of the ABS plastic with marble grain and antibacterial functions - Google Patents
A kind of preparation method of the ABS plastic with marble grain and antibacterial functions Download PDFInfo
- Publication number
- CN108676317A CN108676317A CN201810610270.2A CN201810610270A CN108676317A CN 108676317 A CN108676317 A CN 108676317A CN 201810610270 A CN201810610270 A CN 201810610270A CN 108676317 A CN108676317 A CN 108676317A
- Authority
- CN
- China
- Prior art keywords
- parts
- natural
- abs plastic
- preparation
- antibacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
Abstract
The present invention relates to plastics preparing technical field, the preparation method of specially a kind of ABS plastic with marble grain and antibacterial functions.In order to solve the ABS plastic poor mechanical property of traditional imitation marble effect, the problems such as antibacterial ability is poor, the present invention provides a kind of preparation methods of the ABS plastic with marble grain and antibacterial functions.Its raw material includes parts by weight meter:80 92 parts of ABS resin, 0.5 1 parts of natural plasticizer, 0.5 1 parts of natural, 12 parts of natural antibacterial agent, 25 parts of Masterbatch, marble particle mix 10 15 parts.When preparing ABS plastic, first by ABS resin, natural plasticizer; natural; it after natural anti-wear agent and natural antibacterial agent mixing, then mixes with color masterbatch and marble particle, the natural antibacterial ABS plastic of marbling effect is prepared using twin screw extruder.The natural antibacterial ABS plastic being prepared through the present invention has good antibacterial effect in preparing cosmetic package.
Description
Technical field
The present invention relates to plastics preparing technical field, specially a kind of ABS modelings with marble grain and antibacterial functions
The preparation method of material.
Background technology
Acrylonitrile/butadiene/styrene copolymer (ABS) is a kind of function admirable, widely used engineering plastics.It has
There is heat-resist, case hardness is high, dimensionally stable, chemical resistance and electrical property are good, is easy to molding and is machined etc.
Good comprehensive performance, and secondary operation can be carried out to its product.At present ABS have become cosmetics packaging material predominant plastics kind it
One.The ABS plastic of traditional imitation marble effect is prepared, this method by the way of adding spot pigment or marble particle
The serious mechanical property for reducing ABS.In addition, in the today for advocating health, environmental protection, ABS is used to be in direct contact with people
When cosmetics packaging material, not requiring nothing more than material has good performance, but also requires material environmental protection, health, has antibacterial
Function.Therefore, the ABS plastic of marbling effect of the exploitation with environment-friendly antibacterial will be with huge market prospects.
Invention content
In order to solve the ABS plastic poor mechanical property of traditional imitation marble effect, the problems such as antibacterial environment protection function is poor, this
Invention provides a kind of preparation method of the ABS plastic with marble grain and antibacterial functions.
In order to achieve the above-mentioned object of the invention, technical solution provided by the invention is：One kind having marble grain and antibacterial
The preparation method of the ABS plastic of function, which is characterized in that meter includes following raw material in parts by weight:80-92 parts of ABS resin, day
Right 0.5-1 parts of plasticizer, 0.5-1 parts of natural, 1-2 parts of natural antibacterial agent, 2-5 parts of Masterbatch, marble particle 10-
15 parts.
Preferably, the natural plasticizer is one or both of epoxidized soybean oil, anacardol yl acetate.
Preferably, the natural is one or more in tea polyphenols, vitamin C, gallic acid.
Preferably, the preparation method of the natural antibacterial agent is：Radix Glycyrrhizae, rosemary, cordate houttuynia, aloe are dried respectively
Afterwards, powder is crushed to obtain；Radix Glycyrrhizae, rosemary, cordate houttuynia, Alose are pressed 1：1：1：After 1 mass ratio mixing, the second with 75%
Alcohol-water mixtures are according to 1：The mass volume ratio of 15-20 mixes then, the ultrasonic extraction under the conditions of the power of 400W, 40-60 DEG C
After 25-30min, filtering, freeze-drying is to get natural antibacterial agent after filtrate is concentrated.
Preferably, the Masterbatch preparation method is：It is counted in parts by weight by 95-98 parts of ABS resins, 1-2 parts of color
After powder, 0.2-0.5 parts of antioxidant, the mixing of 1-2 parts of glycerine, prepared up to Masterbatch through Shooting Technique.
The present invention also provides a kind of preparation method of the ABS plastic with marble grain and antibacterial functions, features
It is：Include the following steps
（1）ABS resin, natural plasticizer, natural, natural antibacterial agent high-speed stirred are uniformly mixed；
（2）By step（1）Obtained mixture and Masterbatch, marble particle mixed at high speed are uniform；
（3）By step（2）The mixture of gained extruding pelletization in twin screw extruder obtains the natural anti-of marbling effect
Bacterium ABS plastic.
Preferably, step（1）Described in high-speed stirred rotating speed be 10000-12000rpm/min, mixing time 5-
10min。
Preferably, step（3）Described in granulation conditions be：By the Double-screw temperature of twin screw extruder in 190-
220 DEG C of segmentations are set, and head temperature is 190-200 DEG C；Screw rod rotating speed is 300-400rpm/min；Pelleter speed is 600-
800rpm/min。
Compared with prior art, the preparation of a kind of ABS plastic with marble grain and antibacterial functions of the present invention
Method has the advantages that：The ABS plastic of marbling effect prepared by the present invention has high glaze, color and luster texture good etc. excellent
Point；Natural plasticizer, which is added, can not only increase the mechanical performance of plastics, while avoid addition phthalate toxic
Plasticizer improves the safety of plastics；The durability that natural increases plastics is added；Natural antibacterial is added
Agent so that plastics have good antibacterial effect.The natural antibacterial ABS plastic that the present invention is prepared is preparing cosmetic package
In have good antibacterial effect.
Specific implementation mode
【Embodiment 1】
The preparation of natural antibacterial agent：Respectively by after Radix Glycyrrhizae, rosemary, cordate houttuynia, aloe drying, powder is crushed to obtain；By Radix Glycyrrhizae, fan
Repeatedly perfume, cordate houttuynia, Alose press 1：1：1：After 1 mass ratio mixing, the ethanol-water mixture with 75% is according to 1：18 matter
Measure volume ratio mixing then, after ultrasonic extraction 25min under the conditions of the power of 400W, 50 DEG C, filtering freezes after concentrating filtrate
Drying is to get natural antibacterial agent.
The preparation of Masterbatch：It is counted in parts by weight by 97 parts of ABS resins, 1.5 parts of toner, 0.5 part of antioxidant, 1
After the glycerine mixing of part, prepared up to Masterbatch through Shooting Technique.
The preparation of natural antibacterial ABS plastic：
（1）In parts by weight score also known as take 84 parts of ABS resin, 1 part of epoxidized soybean oil, 1 part of tea polyphenols, 1 part of natural antibacterial agent,
3 parts of Masterbatch, marble particle mix 10 parts；
（2）ABS resin, natural plasticizer, vitamin C, natural antibacterial agent high-speed stirred are uniformly mixed；
（3）By step（2）Obtained mixture and Masterbatch, marble particle mixed at high speed are uniform；
（4）By step（3）The mixture of gained extruding pelletization in twin screw extruder, by double spiral shells of twin screw extruder
Swing arm temperature is segmented at 190-220 DEG C and sets, and head temperature is 190 DEG C；Screw rod rotating speed is 340rpm/min；Pelleter speed
For 600rpm/min, the natural antibacterial ABS plastic of marbling effect is obtained.
【Embodiment 2】
The preparation of natural antibacterial agent：Respectively by after Radix Glycyrrhizae, rosemary, cordate houttuynia, aloe drying, powder is crushed to obtain；By Radix Glycyrrhizae, fan
Repeatedly perfume, cordate houttuynia, Alose press 1：1：1：After 1 mass ratio mixing, the ethanol-water mixture with 75% is according to 1：18 matter
Measure volume ratio mixing then, after ultrasonic extraction 25min under the conditions of the power of 400W, 50 DEG C, filtering freezes after concentrating filtrate
Drying is to get natural antibacterial agent.
The preparation of Masterbatch：It is counted in parts by weight by 97 parts of ABS resins, 1.7 parts of toner, 0.3 part of antioxidant, 1
After the glycerine mixing of part, prepared up to Masterbatch through Shooting Technique.
The preparation of natural antibacterial ABS plastic：
（1）Score also known as takes 80 parts of ABS resin, 1 part of anacardol yl acetate, vitamin e1 part, natural antibacterial in parts by weight
1 part of agent, 3 parts of Masterbatch, marble particle mix 14 parts；
（2）ABS resin, natural plasticizer, tea polyphenols, natural antibacterial agent high-speed stirred are uniformly mixed；
（3）By step（2）Obtained mixture and Masterbatch, marble particle mixed at high speed are uniform；
（4）By step（3）The mixture of gained extruding pelletization in twin screw extruder, by double spiral shells of twin screw extruder
Swing arm temperature is segmented at 190-220 DEG C and sets, and head temperature is 190 DEG C；Screw rod rotating speed is 400rpm/min；Pelleter speed
For 500rpm/min, the natural antibacterial ABS plastic of marbling effect is obtained.
【Embodiment 3】
The preparation of natural antibacterial agent：Respectively by after Radix Glycyrrhizae, rosemary, cordate houttuynia, aloe drying, powder is crushed to obtain；By Radix Glycyrrhizae, fan
Repeatedly perfume, cordate houttuynia, Alose press 1：1：1：After 1 mass ratio mixing, the ethanol-water mixture with 75% is according to 1：18 matter
Measure volume ratio mixing then, after ultrasonic extraction 25min under the conditions of the power of 400W, 50 DEG C, filtering freezes after concentrating filtrate
Drying is to get natural antibacterial agent.
The preparation of Masterbatch：It is counted in parts by weight by 97 parts of ABS resins, 1 part of toner, 0.5 part of antioxidant, 1.5
After the glycerine mixing of part, prepared up to Masterbatch through Shooting Technique.
The preparation of natural antibacterial ABS plastic：
（1）Score also known as takes 82 parts of ABS resin, 2 parts of epoxidized soybean oil, 1 part of gallic acid, natural antibacterial agent 1 in parts by weight
Part, 4 parts of Masterbatch, marble particle mix 10 parts；
（2）ABS resin, natural plasticizer, gallic acid, natural antibacterial agent high-speed stirred are uniformly mixed；
（3）By step（2）Obtained mixture and Masterbatch, marble particle mixed at high speed are uniform；
（4）By step（3）The mixture of gained extruding pelletization in twin screw extruder, by double spiral shells of twin screw extruder
Swing arm temperature is segmented at 190-220 DEG C and sets, and head temperature is 190 DEG C；Screw rod rotating speed is 500rpm/min；Pelleter speed
For 600rpm/min, the natural antibacterial ABS plastic of marbling effect is obtained.
The performance of prepared natural antibacterial ABS plastic in 1 embodiment 1-3 of table
Tensile strength and bending strength in the present invention respectively according to national standard GB/T1040.2-2006, GB/T9341-2000 into
Row test, from Table 2, it can be seen that natural antibacterial ABS plastic good mechanical properties prepared by the present invention.
For the ordinary skill in the art, specific embodiment is only exemplarily described the present invention,
Obviously the present invention specific implementation is not subject to the restrictions described above, as long as use the inventive concept and technical scheme of the present invention into
The improvement of capable various unsubstantialities, or it is not improved by the present invention design and technical solution directly apply to other occasions
, within protection scope of the present invention.
Claims (8)
1. a kind of preparation method of the ABS plastic with marble grain and antibacterial functions, which is characterized in that count in parts by weight
Including following raw material:80-92 parts of ABS resin, plasticizer 0.5-1 parts natural, 0.5-1 parts of natural, natural antibacterial agent
1-2 parts, 2-5 parts of Masterbatch, 10-15 parts of marble particle.
2. a kind of preparation method of ABS plastic with marble grain and antibacterial functions according to claim 1, special
Sign is that the natural plasticizer is one or both of epoxidized soybean oil, anacardol yl acetate.
3. a kind of preparation method of ABS plastic with marble grain and antibacterial functions according to claim 1, special
Sign is that the natural is one or more in tea polyphenols, vitamin C, gallic acid.
4. a kind of preparation method of ABS plastic with marble grain and antibacterial functions according to claim 1, special
Sign is that the preparation method of the natural antibacterial agent is：Respectively by after Radix Glycyrrhizae, rosemary, cordate houttuynia, aloe drying, crush
Obtain powder；Radix Glycyrrhizae, rosemary, cordate houttuynia, Alose are pressed 1：1：1：After 1 mass ratio mixing, the alcohol-water with 75% is mixed
Liquid is closed according to 1：After the mass volume ratio mixing of 15-20, the ultrasonic extraction 25-30min under the conditions of the power of 400W, 40-60 DEG C
Afterwards, it filters, freeze-drying is to get natural antibacterial agent after filtrate is concentrated.
5. a kind of preparation method of ABS plastic with marble grain and antibacterial functions according to claim 1, special
Sign is that the Masterbatch preparation method is：It is counted in parts by weight by 95-98 parts of ABS resins, 1-2 parts of toner, 0.2-
After 0.5 part of antioxidant, the mixing of 1-2 parts of glycerine, prepared up to Masterbatch through Shooting Technique.
6. according to a kind of preparation of the ABS plastic with marble grain and antibacterial functions of claim 1-5 any one of them
Method, which is characterized in that include the following steps：
（1）ABS resin, natural plasticizer, natural, natural antibacterial agent high-speed stirred are uniformly mixed；
（2）By step（1）Obtained mixture and Masterbatch, marble particle mixed at high speed are uniform；
（3）By step（2）The mixture of gained extruding pelletization in twin screw extruder obtains the natural anti-of marbling effect
Bacterium ABS plastic.
7. a kind of preparation method of ABS plastic with marble grain and antibacterial functions according to claim 6, special
Sign is step（1）Described in high-speed stirred rotating speed be 10000-12000rpm/min, mixing time 5-10min.
8. a kind of preparation method of ABS plastic with marble grain and antibacterial functions according to claim 6, special
Sign is step（3）Described in granulation conditions be：The Double-screw temperature of twin screw extruder is segmented at 190-220 DEG C
If good, head temperature is 190-200 DEG C；Screw rod rotating speed is 300-400rpm/min；Pelleter speed is 600-800rpm/
min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810610270.2A CN108676317A (en) | 2018-06-13 | 2018-06-13 | A kind of preparation method of the ABS plastic with marble grain and antibacterial functions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810610270.2A CN108676317A (en) | 2018-06-13 | 2018-06-13 | A kind of preparation method of the ABS plastic with marble grain and antibacterial functions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108676317A true CN108676317A (en) | 2018-10-19 |
Family
ID=63811120
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810610270.2A Pending CN108676317A (en) | 2018-06-13 | 2018-06-13 | A kind of preparation method of the ABS plastic with marble grain and antibacterial functions |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108676317A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094476A (en) * | 2020-09-30 | 2020-12-18 | 深圳市鑫鹏宇塑胶有限公司 | Antibacterial wear-resistant ABS plastic and preparation method thereof |
| CN113845745A (en) * | 2021-10-28 | 2021-12-28 | 杭州润森化妆品包装有限公司 | ABS modified plastic for cosmetic bottle cap and preparation method thereof |
| CN115433440A (en) * | 2022-08-29 | 2022-12-06 | 福建华峰新材料有限公司 | Natural herbal antibacterial master batch for polymeric fiber, preparation method and fabric containing natural plant antibacterial component |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181075A (en) * | 2011-05-06 | 2011-09-14 | 浙江理工大学 | Natural anti-oxidation degradable packing material |
| CN104530629A (en) * | 2014-11-13 | 2015-04-22 | 苏州威尔德工贸有限公司 | An antibacterial ABS composite material used for plastic toys and a preparing method thereof |
| CN105255093A (en) * | 2015-11-03 | 2016-01-20 | 四川长虹电器股份有限公司 | Marble-imitated ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
-
2018
- 2018-06-13 CN CN201810610270.2A patent/CN108676317A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181075A (en) * | 2011-05-06 | 2011-09-14 | 浙江理工大学 | Natural anti-oxidation degradable packing material |
| CN104530629A (en) * | 2014-11-13 | 2015-04-22 | 苏州威尔德工贸有限公司 | An antibacterial ABS composite material used for plastic toys and a preparing method thereof |
| CN105255093A (en) * | 2015-11-03 | 2016-01-20 | 四川长虹电器股份有限公司 | Marble-imitated ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094476A (en) * | 2020-09-30 | 2020-12-18 | 深圳市鑫鹏宇塑胶有限公司 | Antibacterial wear-resistant ABS plastic and preparation method thereof |
| CN113845745A (en) * | 2021-10-28 | 2021-12-28 | 杭州润森化妆品包装有限公司 | ABS modified plastic for cosmetic bottle cap and preparation method thereof |
| CN113845745B (en) * | 2021-10-28 | 2023-10-13 | 杭州润森化妆品包装有限公司 | ABS modified plastic for cosmetic bottle caps and preparation method thereof |
| CN115433440A (en) * | 2022-08-29 | 2022-12-06 | 福建华峰新材料有限公司 | Natural herbal antibacterial master batch for polymeric fiber, preparation method and fabric containing natural plant antibacterial component |
| CN115433440B (en) * | 2022-08-29 | 2023-11-14 | 福建华峰新材料有限公司 | Natural herbal antibacterial master batch for polymeric fibers, preparation method and fabric containing natural grass and wood antibacterial components |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103146164B (en) | For the nanometer plasticizing polylactic acid material and preparation method thereof of rapid shaping | |
| CN104087024B (en) | A kind of have modified calcium carbonate of antibacterial antioxidant effect and preparation method thereof | |
| CN108676317A (en) | A kind of preparation method of the ABS plastic with marble grain and antibacterial functions | |
| CN108485245B (en) | Universal black master batch and preparation method thereof | |
| CN108676316A (en) | A kind of preparation method of the ABS/PA6 plastics with marble grain effect | |
| CN105754278B (en) | A kind of nano inorganic mother particles of antibacterial plastics and preparation method thereof | |
| CN101319068A (en) | White master batch applied for polyolefin film and preparation method thereof | |
| CN101456973A (en) | UPVC/grading complex formulation inorganic powder composite material and preparation method thereof | |
| CN105504713A (en) | Polylactic acid microspherical modified material for 3D printing and preparation method thereof | |
| CN113292688A (en) | Preparation method of composite antibacterial agent and antibacterial plastic | |
| CN110305474A (en) | A kind of low temperature resistant flame retardant polyamide compoiste material and preparation method thereof | |
| CN105440490A (en) | Compound PVC-based cable material containing modified bagasse and preparation method thereof | |
| CN108047666A (en) | A kind of tensile strength environmentally-friendly plastic Masterbatch macromolecule carrier and its manufacturing method | |
| CN108641181A (en) | A kind of toughening type master batch and preparation method thereof | |
| CN108546367A (en) | A kind of high dispersive flame-proof ABS Masterbatch and preparation method thereof | |
| CN100340608C (en) | Soy bean protein/aluminium hydrate nano composite material, its prepn. and uses | |
| CN113842372B (en) | Starch-based capsule coat and preparation method and application thereof | |
| JP3789709B2 (en) | Cosmetics containing spherical composite powder | |
| CN104761858A (en) | Solid-color PC color master batch with toughening effect, and preparation method thereof | |
| CN108395604A (en) | A kind of hyperconcetration carrier-free plastic master batch and its preparation process and production system | |
| CN108690269B (en) | Antioxidant polypropylene and preparation method thereof | |
| CN105199364A (en) | Flame-retardant aging-resistant PPO-HIPS polymer alloy and preparation method thereof | |
| CN113462057A (en) | Environment-friendly color master batch and preparation method thereof | |
| CN108819001B (en) | Manufacturing process of urea molding plastic particles with antibacterial, antistatic and high gloss | |
| CN105482278A (en) | Insect expelling type chlorinated polyethylene compound cable material containing pomegranate rind and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181019 |