CN201679177U - UV cured transfer film metal decorative board - Google Patents
UV cured transfer film metal decorative board Download PDFInfo
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- CN201679177U CN201679177U CN2010200469844U CN201020046984U CN201679177U CN 201679177 U CN201679177 U CN 201679177U CN 2010200469844 U CN2010200469844 U CN 2010200469844U CN 201020046984 U CN201020046984 U CN 201020046984U CN 201679177 U CN201679177 U CN 201679177U
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Abstract
The utility model belongs to the field of building materials and decoration, and relates to a UV (ultraviolet) cured transfer film metal decorative board which comprises a traditional metal base board processed with polishing, sanding and sand blasting, a UV curable adhesive coating printed on the surface of the metal base board, and a transfer film layer arranged on the surface of the UV curable adhesive coating, wherein the transfer film layer is transferred from a UV cured transfer film. If the transfer film layer is a UV cured transfer film with a base load film, a UV cured paint protecting layer is applied on the base load film. If the transfer film layer is a UV cured transfer film with no base load film, a UV cured protective varnish coating, instead of the UV cured paint protecting layer, is applied on the surface of the transfer film layer, and then a polypropylene or polythene protective thin film used for protecting the surface of an object against scratches is attached onto the UV cured protective varnish coating.
Description
Technical field
The utility model belongs to the building materials and ornaments field, relates to the ultra-violet curing transfer film decorative panel that the surface produces by the application ultraviolet-curing paint, particularly ultra-violet curing transfer film metal lagging.
Background technology
At present, day by day increase luxurious day by day with various interior decorations along with building, country requires also more and more higher to the environmental protection of building, energy-conservation and fire prevention etc., therefore, various composite materials occur in succession, and the coating process of metal sheet surfaces such as present aluminium-plastic panel and aluminum veneer is earlier metal sheet surfaces such as aluminium-plastic panel and aluminum veneer to be carried out pickling, chromaking, after the washing baking, carry out the roller coat or the spray-coating of 2～3 coating again on its surface, and then multiple tracks technology such as toast.But the long construction period of technique scheme, cost height, energy consumption height, VOC discharge value are big; Therefore, this technology is reformed imperative.The preparation method of ultraviolet light curing overlay film metal sheet has that equipment investment is low, working (machining) efficiency is high, energy consumption is low, the VOC free discharging, and the ultraviolet light curing overlay film metal lagging has good weatherability, the feature of environmental protection is good, color pattern is abundant, paint film is plentiful, hardness is high, scratch resistance, anti-soil is easy to clean and nonflammable advantage.
Summary of the invention
The purpose of this utility model provides a kind of color and pattern is abundant, and ornamental and the strong ultra-violet curing transfer film metal lagging of protectiveness.
The external coating that ultra-violet curing transfer film metal lagging of the present utility model is the substrate metal plate after carrying out PROCESS FOR TREATMENT such as conventional polishing, sanding, sandblast has ultraviolet cured adhesive (be called for short UV and solidify glue) coating, and the transfer printing rete that is obtained by the transfer printing of ultra-violet curing transfer film is arranged at the ultraviolet cured adhesive coating surface.
Described transfer printing rete is the ultra-violet curing transfer film that has or do not have the base load film.
Have the ultraviolet-curing paint topping on the base load film of the described ultra-violet curing transfer film that has a base load film.
Not having the ultraviolet-curing paint topping on the described ultra-violet curing transfer film that does not have a base load film, is that the external coating at the transfer printing rete has ultraviolet light polymerization protection varnish coat.
Described ultraviolet light polymerization protection varnish coat surface is further posted and is used to protect body surface to avoid scuffing, abrasive polypropylene or polyethylene protective film.
The thickness of described ultraviolet light polymerization gel coating is 2～100 μ m, and the thickness of preferred coatings is 5～100 μ m.
The thickness of described ultraviolet light polymerization protection varnish coat is 10～100 μ m.
Described metal sheet is volume aluminium, iron plate or the corrosion resistant plate etc. of aluminum veneer, preparation aluminium-plastic panel.
Described ultra-violet curing transfer film is the product of CN200910088641.6.The ultra-violet curing transfer film that has the ultraviolet-curing paint topping on the described base load film; be on the base load film, parting agent layer to be arranged; the ultraviolet-curing paint topping is arranged on parting agent layer; UV curable ink decorative pattern layer is arranged on the ultraviolet-curing paint topping; ultraviolet-curing paint background color layer is arranged on UV curable ink decorative pattern layer, and (the ultra-violet curing transfer film is after transfer interpreter carries out transfer printing; do not remove the base load film, promptly obtain ultra-violet curing transfer film metal lagging).
The described ultra-violet curing transfer film that does not have the ultraviolet-curing paint topping; be on the base load film, parting agent layer to be arranged; UV curable ink decorative pattern layer is arranged on parting agent layer; ultraviolet-curing paint background color layer is arranged on UV curable ink decorative pattern layer, and (the ultra-violet curing transfer film is after transfer interpreter carries out transfer printing; application ultraviolet light polymerization protection varnish is coated with after removing the base load film; and further post be used to protect that body surface is avoided scratching, abrasive polypropylene or polyethylene protective film, promptly obtain ultra-violet curing transfer film metal lagging).
The thickness of described parting agent layer can be coated with or prints according to desired thickness, is preferably 1～100 micron.
The thickness of described ultraviolet-curing paint topping can be coated with or prints according to desired thickness, is preferably 1～100 micron.
The thickness of described UV curable ink decorative pattern layer can be coated with or prints according to desired thickness, is preferably 1～100 micron.
The thickness of described ultraviolet-curing paint background color layer can be coated with or prints according to desired thickness, is preferably 1～100 micron.
By weight percentage, the mould release that is used to obtain parting agent layer is: the mixture of cellulose family 20～50%, wax class 1～30%, silicone oil 0～10%, butanone 0～20% (preferred 10～20%), ethyl acetate 0～15% (preferred 5～15), acrylic ester prepolymer 5～20%, acrylate monomer 5～20%, light trigger 1～6%.
By weight percentage, the ultraviolet-curing paint that is used to obtain the ultraviolet-curing paint topping is for being:
A: the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～6%, auxiliary agent 0～2%, filler 0～50%, butanone 0～10%, ethyl acetate 0～15%; Or
B: the mixture of acrylic ester prepolymer 10～80%, acrylate monomer 5～50%, light trigger 1～6%, auxiliary agent 0～2%, filler 0～50%, delustring auxiliary agent 1～50%, butanone 0～10%, ethyl acetate 0～15%.
By weight percentage, the UV curable ink that is used to obtain UV curable ink decorative pattern layer is: the mixture of acrylic ester prepolymer 10～60%, acrylate monomer 5～50%, light trigger 1～5%, auxiliary agent 0～2%, filler 0～50%, toner 5～30%, resin 5～30%, butanone 0～10%, ethyl acetate 0～15%.
By weight percentage, the ultraviolet-curing paint that is used to obtain ultraviolet-curing paint background color layer is: the mixture of acrylic ester prepolymer 10～50%, acrylate monomer 10～40%, light trigger 1～5%, auxiliary agent 0～2%, filler 0～30%, toner 5～30%, resin 5～50%, butanone 0～10%, ethyl acetate 0～15%.
Described base load film be a kind of in polypropylene screen, polyethylene film, polychloroethylene film, the PETG film etc.
Described polypropylene screen can be the modified polypropene film.
Described cellulose family is a CMC etc.
Described wax class is modified paraffin, palm wax or their mixture etc.
Described silicone oil is selected from least a in the group that methyl-silicone oil, polymethylphenyl siloxane fluid, hydroxy silicon oil etc. are formed.
Described acrylic ester prepolymer is selected from least a in the group that epoxy acrylate, fluorine-containing epoxy acrylate, urethane acrylate, fluorochemical urethane acrylate, polyester acrylate, fluorine-containing polyester acrylate, amino acrylates, fluorine-containing amino acrylates, acrylate copolymer, fluoro-acrylate copolymer etc. are formed.
Described acrylate monomer is: 1. single functionality monomer, as butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer (EHA), hydroxy-ethyl acrylate (HEA), hydroxyethyl methacrylate (MHEA), acrylic acid trifluoro ethyl ester, trifluoroethyl methacrylate, acrylic acid hexafluoro butyl ester, methacrylic acid hexafluoro butyl ester, dodecafluorhe-ptylacrylate or methacrylic acid ten difluoro heptyl esters etc.; 2. two functionality monomer, as tri (propylene glycol) diacrylate (TPGDA), propylene glycol diacrylate (DPGDA), neopentylglycol diacrylate (NPGDA), the third oxidation neopentylglycol diacrylate (PO-NPGDA), two (diethylene glycol) diacrylates (PDDA) of phthalic acid or 1,6 hexanediyl ester (HDDA) etc.; 3. polyfunctionality monomer, as trimethylolpropane triacrylate (TMPTA), ethoxyquin trimethylolpropane triacrylate (EO-TMPTA), the third oxidation trimethylolpropane triacrylate (PO-TMPTA), pentaerythritol triacrylate (PETA) or dipentaerythritol acrylate (DPHA) etc., common at least a in the group of being formed with above-mentioned acrylate monomer etc. as application.
Described resin is selected from least a in the group that modified polyvinyl acetate, polyamide, thermoplastic acrylic etc. are formed.
Described modified polyvinyl acetate is vinyl chloride vinylacetate, ethylene vinyl acetate etc. or their mixture.
Described light trigger is selected from see at least a in the group that oxygen compound photoinitiator, benzoic ether photoinitiator formed of benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenones light trigger, anthraquinone photoinitiator, thioxanthone photoinitiator, Benzophenones light trigger, acyl group.
Described benzoin ether photoinitiator is selected from least a in the group that benzoin methyl ether, benzoin ethylether, benzoin isopropyl ether etc. are formed.
Described benzil ketals photoinitiator is a benzil dimethyl ketal etc.
Described acetophenones light trigger is selected from acetophenone, 2,2-dimethoxy-2-phenyl acetophenone, 2,2-diethoxy-2-phenyl acetophenone, 1, the 1-dichloroacetophenone, the 1-hydroxy acetophenone, 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-(4-isopropyl phenyl)-2-hydroxy-2-methyl-1-acetone, 1-[4-(2-hydroxyl-oxethyl) phenyl]-2-hydroxy-2-methyl-1-acetone, 2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone, at least a in the 2-benzyl-2-dimethylamino-1-group that (4-morpholinyl phenyl)-1-butanone etc. is formed.
Described anthraquinone photoinitiator is selected from least a in the group that 2-tert-butyl group anthraquinone, 1-chloroanthraquinone, 2-amyl anthraquinone etc. are formed.
Described thioxanthone photoinitiator is selected from 2,4-dimethyl thia anthrone, 2,4-diethyl thioxanthone, 2-isopropyl thioxanthone, 4-isopropyl thioxanthone, 2-chloro thioxanthone, 2, at least a in the group that 4-diisopropyl thioxanthone etc. is formed.
Described Benzophenones light trigger is selected from benzophenone, 4-chlorobenzophenone, at least a in methyldiphenyl ketone, the group that 4-benzoyl-4 '-dimethyl diphenyl sulfide etc. is formed.
The described acyl group oxygen compound photoinitiator of seeing is selected from 2; 4; 6-trimethylbenzoyl diphenyl phosphine oxide, two (2; 4, the 6-trimethylbenzoyl)-phenyl phosphine oxide, two (2, the 6-dimethylbenzoyl)-2; 4; 4-tri-methyl-amyl phosphine oxide, 2,4, at least a in the group that 6-trimethylbenzoyl phenyl ethoxy phosphine oxide etc. is formed.
Described benzoic ether photoinitiator is benzoylbenzoic acid methyl esters, methyl o-benzoylbenzoate or their mixture etc.
Described auxiliary agent is preferably selected from least a in the group that wetting dispersing agent (as Disperbyk 103, Disperbyk 163 or their mixture etc.) of the defoamer (as BYK052, BYK055 or their mixture etc.) of the levelling agent (as BYK306, BYK358 or their mixture etc.) of German Bi Ke chemical company, German Bi Ke chemical company, German Bi Ke chemical company etc. formed.
Described filler is at least a in the group formed such as French chalk, calcium carbonate, barium sulfate.
Described toner is selected from least a in carbon black, titanium dioxide, titanium ultramarine, former Huang, the group of being formed such as bright red.
Described delustring auxiliary agent is the delustring wax slurry delustring wax slurry of company (preferred Japanese GIFU), mute light powder or their mixture etc.
The preparation method of described ultra-violet curing transfer film: on the base load film, evenly be coated with or the printing mould release, carry out infrared curing then, on the base load film, obtain parting agent layer; Evenly coating or printing have anti-scratchly on parting agent layer, and the ultraviolet light polymerization protection layer for paint of wear-resisting effect carries out UV-irradiation then and solidifies, and obtains the ultraviolet-curing paint topping; Even coating or printing have the UV curable ink of pattern decorative effect on the ultraviolet-curing paint topping, carry out UV-irradiation then and solidify, and obtain UV curable ink decorative pattern layer; On UV curable ink decorative pattern layer, evenly be coated with or printing ultraviolet light polymerization background color coating, carry out UV-irradiation then and solidify, obtain having the ultra-violet curing transfer film of ultraviolet-curing paint topping; Or
On the base load film, evenly be coated with or the printing mould release, carry out infrared curing then, on the base load film, obtain parting agent layer; Even coating or printing have the UV curable ink of pattern decorative effect on parting agent layer, carry out UV-irradiation then and solidify, and obtain UV curable ink decorative pattern layer; On UV curable ink decorative pattern layer, evenly be coated with or printing ultraviolet light polymerization background color coating, carry out UV-irradiation then and solidify, do not had the ultra-violet curing transfer film of ultraviolet-curing paint topping.
Described base load film can carry out preliminary treatment earlier, and the preliminary treatment of described base load film is to carry out 60～200 ℃ baking according to the difference of base load membrane material to shrink in advance, destatics.
Described infrared curing is that the infrared rays heating-up temperature is transferred to 20～150 ℃, flow time 0.01～10 minute, and mould release is fully solidified.
The technology that above-mentioned UV-irradiation solidifies is: at the ultraviolet tube that 1～3 3～20kw is housed (high-pressure sodium lamp); carry out UV-irradiation in the photo solidification machine of the metal halogen fluorescent tube of 0～3 3～20kw (Iodine gallium light, iron lamp, dysprosium lamp etc.); the wavelength of used light source is 200～600nm; the coating of ultraviolet light polymerization protection layer for paint, UV curable ink, ultraviolet light polymerization background color coating is solidified, and the transmission speed of photo solidification machine is 1～200 meter/minute.
PROCESS FOR TREATMENT such as polish in the surface at the substrate metal plate described in the ultra-violet curing transfer film metal lagging of the present utility model, sanding, sandblast:
1. be meant and adopt sander to carry out sanding oil removing, roughening treatment on the surface of substrate metal plate.
2. adopt the mode of sandblast to carry out oil removing, roughening treatment on the surface of metal sheet.
3. present traditional pre-treatment mode: pickling is carried out on the surface, chromaking, washing baking.
Described ultraviolet light polymerization gel coating is the technology application of adopting roller coat or spraying, and the thickness of coating is 2～100 μ m, and the thickness of preferred coatings is 5～100 μ m.
Described ultraviolet light polymerization protection varnish coat is the technology application of adopting roller coat, showering or spraying, and the thickness of coating is 10～100 μ m, and gloss is that 10～100 degree (60 degree gloss meter) are adjustable.
Ultra-violet curing transfer film metal lagging of the present utility model can prepare by the following method:
(1). PROCESS FOR TREATMENT such as conventional polishing, sanding, sandblast are carried out on the surface to base material (as aluminum veneer);
(2). application ultraviolet cured adhesive on the base material of step (1) (be called for short UV and solidify glue) coating;
(3). photocuring;
(4). transfer printing has or does not have the ultra-violet curing transfer film (adopting transfer interpreter to carry out transfer printing) of ultraviolet-curing paint topping on the base material of step (3);
(5). photocuring;
(6). remove the base load film (adopting artificial or the automatic film rolling machine) of the ultra-violet curing transfer film that does not have the ultraviolet-curing paint topping;
(7). infrared levelling
(8). application ultraviolet light polymerization protection varnish on the base material of step (7);
(9). infrared levelling or natural levelling;
(10). photocuring;
(11). check (whether the ultra-violet curing transfer film metal lagging of check making is qualified);
(12). pasting protective film (pastes the film of polypropylene or polyethylene etc. on the surface of the ultra-violet curing transfer film metal lagging through being up to the standards, be used to protect ultra-violet curing transfer film metal lagging surface to avoid scratching, abrading, the surface light solidified coating of decorative panel is protected);
(13). packing.
Remarks: the ultra-violet curing transfer film itself has no step (6)-(10) and the step (12) of topping;
Or
(1). PROCESS FOR TREATMENT such as conventional polishing, sanding, sandblast are carried out on the surface to base material (as aluminium volume, iron plate or the corrosion resistant plate of aluminum veneer, preparation aluminium-plastic panel);
(2). application ultraviolet cured adhesive on the base material of step (1) (be called for short UV and solidify glue) coating;
(3). photocuring;
(4). transfer printing has or does not have the ultra-violet curing transfer film (adopting transfer interpreter to carry out transfer printing) of ultraviolet-curing paint topping on the base material of step (3);
(5). photocuring;
(6). remove the base load film (adopting artificial or the automatic film rolling machine) of the ultra-violet curing transfer film that does not have the ultraviolet-curing paint topping;
(7). infrared levelling
(8). application ultraviolet light polymerization protection varnish on the base material of step (7);
(9). infrared levelling or natural levelling;
(10). photocuring;
(11). check (whether the ultra-violet curing transfer film metal lagging of check making is qualified);
(12). the aluminium volume of preparation aluminium-plastic panel is combined into aluminium-plastic panel
(13). pasting protective film (pastes the film of polypropylene or polyethylene etc. on the surface of the ultra-violet curing transfer film metal lagging through being up to the standards, be used to protect ultra-violet curing transfer film metal lagging surface to avoid scratching, abrading, the surface light solidified coating of decorative panel is protected);
(14). packing.
Remarks: the ultra-violet curing transfer film itself has no step (6)-(10) and the step of topping
(13)；
In the method for preparation ultra-violet curing transfer film metal lagging of the present utility model, described photocuring is: photocuring adopts ultraviolet light polymerization, be coated with the workpiece that installs and enter the ultraviolet tube (high-pressure sodium lamp) that 1～6 3～20kw is housed, carry out illumination in the photo solidification machine of the metal halogen fluorescent tube of 0～3 3～20kw (Iodine gallium light, iron lamp, dysprosium lamp etc.), make light solidifying coating solidify 5～50 meters/minute of speed.Described infrared levelling: infrared levelling transfers to 20～120 ℃ with infrared rays leveling machine temperature, flow time 0.1～10 minute.
Employed ultraviolet cured adhesive in the utility model (be called for short UV and solidify glue), ultraviolet light polymerization protection varnish are the coating in this area, UV glue.
By weight percentage, common described ultraviolet cured adhesive by acrylic ester prepolymer 10～85%,
Acrylate monomer 5～80%, light trigger 1～6%, 0～5% composition of auxiliary agent;
By weight percentage, common described ultraviolet light polymerization protection varnish is made up of acrylic ester prepolymer 10～80%, acrylate monomer 10～80%, light trigger 1～15%, auxiliary agent 0～5%, 0～30% of filler.
Described acrylic ester prepolymer is selected from least a in the group that epoxy acrylate, fluorine-containing epoxy acrylate, urethane acrylate, fluorochemical urethane acrylate, polyester acrylate, fluorine-containing polyester acrylate, amino acrylates, fluorine-containing amino acrylates, acrylate copolymer, fluoro-acrylate copolymer etc. are formed.
Described acrylate monomer is: 1. single functionality monomer, as butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer (EHA), hydroxy-ethyl acrylate (HEA), hydroxyethyl methacrylate (MHEA), acrylic acid trifluoro ethyl ester, trifluoroethyl methacrylate, acrylic acid hexafluoro butyl ester, methacrylic acid hexafluoro butyl ester, dodecafluorhe-ptylacrylate or methacrylic acid ten difluoro heptyl esters etc.; 2. two functionality monomer, as tri (propylene glycol) diacrylate (TPGDA), propylene glycol diacrylate (DPGDA), neopentylglycol diacrylate (NPGDA), the third oxidation neopentylglycol diacrylate (PO-NPGDA), two (diethylene glycol) diacrylates (PDDA) of phthalic acid or 1,6 hexanediyl ester (HDDA) etc.; 3. polyfunctionality monomer, as trimethylolpropane triacrylate (TMPTA), ethoxyquin trimethylolpropane triacrylate (EO-TMPTA), the third oxidation trimethylolpropane triacrylate (PO-TMPTA), pentaerythritol triacrylate (PETA) or dipentaerythritol acrylate (DPHA) etc., common at least a in the group of being formed with above-mentioned acrylate monomer etc. as application.
Described light trigger is selected from see at least a in the group that oxygen compound photoinitiator, benzoic ether photoinitiator formed of benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenones light trigger, anthraquinone photoinitiator, thioxanthone photoinitiator, Benzophenones light trigger, acyl group.
Described benzoin ether photoinitiator is selected from least a in the group that benzoin methyl ether, benzoin ethylether, benzoin isopropyl ether etc. are formed.
Described benzil ketals photoinitiator is a benzil dimethyl ketal etc.
Described acetophenones light trigger is selected from acetophenone, 2,2-dimethoxy-2-phenyl acetophenone, 2,2-diethoxy-2-phenyl acetophenone, 1, the 1-dichloroacetophenone, the 1-hydroxy acetophenone, 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-(4-isopropyl phenyl)-2-hydroxy-2-methyl-1-acetone, 1-[4-(2-hydroxyl-oxethyl) phenyl]-2-hydroxy-2-methyl-1-acetone, 2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone, at least a in the 2-benzyl-2-dimethylamino-1-group that (4-morpholinyl phenyl)-1-butanone etc. is formed.
Described anthraquinone photoinitiator is selected from least a in the group that 2-tert-butyl group anthraquinone, 1-chloroanthraquinone, 2-amyl anthraquinone etc. are formed.
Described thioxanthone photoinitiator is selected from 2,4-dimethyl thia anthrone, 2,4-diethyl thioxanthone, 2-isopropyl thioxanthone, 4-isopropyl thioxanthone, 2-chloro thioxanthone, 2, at least a in the group that 4-diisopropyl thioxanthone etc. is formed.
Described Benzophenones light trigger is selected from benzophenone, 4-chlorobenzophenone, at least a in methyldiphenyl ketone, the group that 4-benzoyl-4 '-dimethyl diphenyl sulfide etc. is formed.
The described acyl group oxygen compound photoinitiator of seeing is selected from 2; 4; 6-trimethylbenzoyl diphenyl phosphine oxide, two (2; 4, the 6-trimethylbenzoyl)-phenyl phosphine oxide, two (2, the 6-dimethylbenzoyl)-2; 4; 4-tri-methyl-amyl phosphine oxide, 2,4, at least a in the group that 6-trimethylbenzoyl phenyl ethoxy phosphine oxide etc. is formed.
Described benzoic ether photoinitiator is benzoylbenzoic acid methyl esters, methyl o-benzoylbenzoate or their mixture etc.
Described auxiliary agent is preferably selected from least a in the group that wetting dispersing agent (as Disperbyk 103, Disperbyk 163 or their mixture etc.) of the defoamer (as BYK052, BYK055 or their mixture etc.) of the levelling agent (as BYK306, BYK358 or their mixture etc.) of German Bi Ke chemical company, German Bi Ke chemical company, German Bi Ke chemical company etc. formed.
Described filler is powder body materials such as delustring slurry or flatting silica.
Ultra-violet curing transfer film metal lagging of the present utility model has good weatherability, and the feature of environmental protection is good, and color pattern is abundant; paint film is plentiful, hardness height, scratch resistance; anti-soil is easy to clean, has better decorative effect and protection effect than the decorative board for wall that generally uses at present.
The preparation method of ultra-violet curing transfer film metal lagging of the present utility model has that required production site is little, and equipment investment is low, production efficiency height, less energy consumption, the advantage of pollution-free grade.
Description of drawings
Fig. 1. a kind of structure cross-sectional schematic of ultra-violet curing transfer film metal lagging of the present utility model.
Fig. 2. the another kind of structure cross-sectional schematic of ultra-violet curing transfer film metal lagging of the present utility model.
Reference numeral
1. substrate 2. ultraviolet light polymerization gel coatings 3. transfer printing retes
4. ultraviolet light polymerization is protected varnish 5. diaphragms
The specific embodiment
The used ultra-violet curing transfer film that has the ultraviolet-curing paint topping among the embodiment; as previously mentioned; be on the base load film, parting agent layer to be arranged; the ultraviolet-curing paint topping is arranged on parting agent layer; UV curable ink decorative pattern layer is arranged on the ultraviolet-curing paint topping; ultraviolet-curing paint background color layer (preparation of ultra-violet curing transfer film, and the composition of described coating and printing ink as previously mentioned) is arranged on UV curable ink decorative pattern layer.
The ultra-violet curing transfer film that does not have the ultraviolet-curing paint topping; as previously mentioned; be on the base load film, parting agent layer to be arranged; UV curable ink decorative pattern layer is arranged on parting agent layer; ultraviolet-curing paint background color layer (preparation of ultra-violet curing transfer film, and the composition of described coating and printing ink as previously mentioned) is arranged on UV curable ink decorative pattern layer.
Embodiment 1: cover marblized aluminum veneer
Seeing also Fig. 1. overlay film aluminum veneer base material is an aluminum veneer, earlier aluminum veneer matrix 1 is carried out PROCESS FOR TREATMENT such as conventional polishing, sanding, sandblast, and removes the greasy dirt on surface, dust; At the thick ultraviolet light polymerization gel coating 2 of external coating one deck 2 μ m of aluminum veneer matrix, send into then 6 16.8kw uviol lamps (Halogen lamp LED) are housed again, transmission speed is to carry out photocuring in 15 meters/minute the photo solidification machine; Again at the ultraviolet cured adhesive coating surface, by not having the marblized ultra-violet curing transfer film of being printed on of ultraviolet-curing paint topping transfer printing one deck transfer printing rete 3; Then above-mentioned aluminum veneer is sent into 6 16.8kw uviol lamps (Halogen lamp LED) are housed, transmission speed is to carry out photocuring in 15 meters/minute the photo solidification machine, and removing and entering temperature behind the base load film of the ultra-violet curing transfer film that does not have the ultraviolet-curing paint topping is levelling 2 minutes under 90 ℃ the infrared rays; Showering one layer thickness is 100 μ m on transfer printing rete 3 again; and gloss is the ultraviolet light polymerization protection varnish 4 of the Gao Guang of 65 degree (60 degree gloss meter); be that levelling enters after 1 minute 3 13kw uviol lamps (high-pressure sodium lamp) are housed under 60 ℃ the infrared rays in temperature; transmission speed is in 15 meters/minute the photo solidification machine; behind the photocuring; reach criterion of acceptability through test rating, paste polypropylene diaphragm 5, promptly get parian aluminum veneer finished product.
The percentage by weight of ultraviolet cured adhesive consists of: fluorochemical urethane acrylate 25%, fluorine-containing polyester acrylate 25%, urethane acrylate 15%, acrylic acid trifluoro ethyl ester 20%, PO-NPGDA10%, 1-hydroxy-cyclohexyl phenyl ketone 2.5%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, BYK0520.2%, Disperbyk 1030.3%.
The percentage by weight of ultraviolet light polymerization protection varnish consists of: fluorine-containing epoxy acrylate 10%, fluorochemical urethane acrylate 25%, fluoro-acrylate copolymer 20%; TMPTA 20%, DPGDA15%, 1-hydroxy acetophenone 4.5%; BYK 0550.2%, and BYK 3580.3%, flatting silica 5%
Embodiment 2: the aluminium-plastic panel that covers graining
See also Fig. 1.Base material is the aluminium volume of preparation aluminium-plastic panel, and the aluminium volume matrix 1 that will prepare aluminium-plastic panel earlier carries out PROCESS FOR TREATMENT such as conventional polishing, sanding, sandblast, and removes the greasy dirt on surface, dust; Surface roller coating one layer thickness at the aluminium volume matrix of preparation aluminium-plastic panel is the ultraviolet light polymerization gel coating 2 of 100 μ m again, sends into then 3 16.8kw uviol lamps (Halogen lamp LED) are housed, and transmission speed is to carry out photocuring in 8 meters/minute the photo solidification machine; Again at the ultraviolet cured adhesive coating surface, by the ultra-violet curing transfer film transfer printing one deck transfer printing rete 3 that is printed on wood grain that does not have the ultraviolet-curing paint topping; Then above-mentioned aluminium volume is sent into 3 16.8kw uviol lamps (Halogen lamp LED) are housed, transmission speed is to carry out photocuring in 8 meters/minute the photo solidification machine, removing and entering temperature behind the base load film of the ultra-violet curing transfer film that does not have the ultraviolet-curing paint topping is levelling 2 minutes under 90 ℃ the infrared rays, external coating one layer thickness at transfer printing rete 3 is 10 μ m again, and gloss is the ultraviolet light polymerization protection varnish 4 of half mute light of 60 degree (60 degree gloss meter), be that levelling enters after 1 minute 3 16.8kw uviol lamps (Halogen lamp LED) are housed under 50 ℃ the infrared rays in temperature, transmission speed is in 8 meters/minute the photo solidification machine, behind the photocuring, reach criterion of acceptability through test rating, promptly get and imitate the graining boards half-finished product; Be cut into and require size, be combined into aluminium-plastic panel, paste polypropylene diaphragm 5.
The percentage by weight of ultraviolet cured adhesive consists of: fluorochemical urethane acrylate 25%, fluorine-containing polyester acrylate 25%, urethane acrylate 15%, acrylic acid trifluoro ethyl ester 20%, PO-NPGDA10%, 1-hydroxy-cyclohexyl phenyl ketone 2.5%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, BYK052 0.2%, and Disperbyk 103 0.3%.
The percentage by weight of the ultraviolet light polymerization protection varnish of half mute light consists of: urethane acrylate 15%; fluorochemical urethane acrylate 45%; acrylate copolymer 10%; TMPTA 9%, PETA10%, 1-hydroxy-cyclohexyl phenyl ketone 4%; flatting silica 6%; BYK 0550.2%, and BYK 3060.3%, and Disperbyk 1030.5%.
Embodiment 3: the aluminium-plastic panel that covers metallochrome-silver color
See also Fig. 1.Base material is the aluminium volume of preparation aluminium-plastic panel, and the aluminium volume matrix 1 that will prepare aluminium-plastic panel earlier carries out PROCESS FOR TREATMENT such as conventional polishing, sanding, sandblast, and removes the greasy dirt on surface, dust; Surface roller coating one layer thickness at the aluminium volume matrix of preparation aluminium-plastic panel is the ultraviolet light polymerization gel coating 2 of 10 μ m again, sends into then 3 16.8kw uviol lamps (Halogen lamp LED) are housed, and transmission speed is to carry out photocuring in 8 meters/minute the photo solidification machine; Again at the ultraviolet cured adhesive coating surface, by the ultra-violet curing transfer film transfer printing one deck transfer printing rete 3 that is printed on metallochrome-silver color that does not have the ultraviolet-curing paint topping; Then above-mentioned aluminium volume is sent into 3 16.8kw uviol lamps (Halogen lamp LED) are housed, transmission speed is to carry out photocuring in 8 meters/minute the photo solidification machine, removing and entering temperature behind the base load film of the ultra-violet curing transfer film that does not have the ultraviolet-curing paint topping is levelling 2 minutes under 90 ℃ the infrared rays, external coating one layer thickness at transfer printing rete 3 is 20 μ m again, and gloss is the ultraviolet light polymerization protection varnish 4 of half mute light of 30 degree (60 degree gloss meter), be that levelling enters after 1 minute 3 16.8kw uviol lamps (Halogen lamp LED) are housed under 50 ℃ the infrared rays in temperature, transmission speed is in 8 meters/minute the photo solidification machine, behind the photocuring, reach criterion of acceptability through test rating, promptly get metallochrome-silver color aluminium-plastic panel semiproduct; Be cut into and require size, be combined into aluminium-plastic panel, paste polypropylene diaphragm 5.
The percentage by weight of ultraviolet cured adhesive consists of: fluorochemical urethane acrylate 25%, fluorine-containing polyester acrylate 25%, urethane acrylate 15%, acrylic acid trifluoro ethyl ester 20%, PO-NPGDA10%, 1-hydroxy-cyclohexyl phenyl ketone 2.5%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, BYK0520.2%, Disperbyk 1030.3%.
The percentage by weight of ultraviolet light polymerization protection varnish consists of: urethane acrylate 10%; fluorochemical urethane acrylate 40%; acrylate copolymer 10%; TMPTA 15%, and PETA 10%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 4%; delustring slurry 10%; BYK 0550.2%, and BYK 3060.3%, and Disperbyk 1030.5%.
Embodiment 4: the aluminum veneer that covers real look-blueness
Seeing also Fig. 1. base material is an aluminum veneer, earlier aluminum veneer matrix 1 is carried out PROCESS FOR TREATMENT such as conventional polishing, sanding, sandblast, and removes the greasy dirt on surface, dust; At the thick ultraviolet light polymerization gel coating 2 of external coating one deck 10 μ m of aluminum veneer matrix, send into then 3 16.8kw uviol lamps (Halogen lamp LED) are housed again, transmission speed is to carry out photocuring in 8 meters/minute the photo solidification machine; Again at the ultraviolet cured adhesive coating surface, by the ultra-violet curing transfer film transfer printing one deck transfer printing rete 3 that does not have the real look of being printed on of ultraviolet-curing paint topping-blueness; Then above-mentioned aluminum veneer is sent into 3 16.8kw uviol lamps (Halogen lamp LED) are housed, transmission speed is to carry out photocuring in 8 meters/minute the photo solidification machine, and removing and entering temperature behind the base load film of the ultra-violet curing transfer film that does not have the ultraviolet-curing paint topping is levelling 2 minutes under 90 ℃ the infrared rays; Roller coat one deck thickness is 30 μ m on transfer printing rete 3 again; and gloss is the ultraviolet light polymerization protection varnish 4 of half mute light of 20 degree (60 degree gloss meter); be that levelling enters after 1 minute 3 16.8kw uviol lamps (high-pressure sodium lamp) are housed under 50 ℃ the infrared rays in temperature; transmission speed is in 8 meters/minute the photo solidification machine; behind the photocuring; reach criterion of acceptability through test rating, paste polypropylene diaphragm 5, promptly get real look-blue aluminum veneer finished product.
The percentage by weight of ultraviolet cured adhesive consists of: fluorochemical urethane acrylate 25%, fluorine-containing polyester acrylate 25%, urethane acrylate 15%, acrylic acid trifluoro ethyl ester 20%, PO-NPGDA10%, 1-hydroxy-cyclohexyl phenyl ketone 2.5%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, BYK0520.2%, Disperbyk 1030.3%.
The percentage by weight of ultraviolet light polymerization protection varnish consists of: fluorine-containing polyester acrylate 10%; contain epoxy acrylate 5%; fluorochemical urethane acrylate 35%, acrylate copolymer 5%, TMPTA15%; PETA 5%; 1-hydroxy-cyclohexyl phenyl ketone 4%, delustring slurry 20%, BYK 0550.2%; BYK 3060.3%, and Disperbyk 1030.5%.
Embodiment 5: the stainless steel decorated sheet that covers imitative wood grain
Seeing also Fig. 1. overlay film stainless steel decorated sheet base material is a corrosion resistant plate, earlier corrosion resistant plate matrix 1 is carried out PROCESS FOR TREATMENT such as conventional polishing, sanding, sandblast, and removes the greasy dirt on surface, dust; At the thick ultraviolet light polymerization gel coating 2 of external coating one deck 2 μ m of corrosion resistant plate matrix, send into then 6 16.8kw uviol lamps (Halogen lamp LED) are housed again, transmission speed is to carry out photocuring in 15 meters/minute the photo solidification machine; Again at the ultraviolet cured adhesive coating surface, by the ultra-violet curing transfer film transfer printing one deck transfer printing rete 3 that is printed on imitative wood grain that does not have the ultraviolet-curing paint topping; Then above-mentioned corrosion resistant plate is sent into 6 16.8kw uviol lamps (Halogen lamp LED) are housed, transmission speed is to carry out photocuring in 15 meters/minute the photo solidification machine, and removing and entering temperature behind the base load film of the ultra-violet curing transfer film that does not have the ultraviolet-curing paint topping is levelling 2 minutes under 90 ℃ the infrared rays; Showering one layer thickness is 100 μ m on transfer printing rete 3 again; and gloss is the ultraviolet light polymerization protection varnish 4 of the Gao Guang of 65 degree (60 degree gloss meter); be that levelling enters after 1 minute 3 13kw uviol lamps (high-pressure sodium lamp) are housed under 60 ℃ the infrared rays in temperature; transmission speed is in 15 meters/minute the photo solidification machine; behind the photocuring; reach criterion of acceptability through test rating, paste polypropylene diaphragm 5, promptly get the stainless steel decorated sheet finished product of imitating wood grain.
The percentage by weight of ultraviolet cured adhesive consists of: fluorochemical urethane acrylate 25%, fluorine-containing polyester acrylate 25%, urethane acrylate 15%, acrylic acid trifluoro ethyl ester 20%, PO-NPGDA10%, 1-hydroxy-cyclohexyl phenyl ketone 2.5%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, BYK0520.2%, Disperbyk 1030.3%.
The percentage by weight of ultraviolet light polymerization protection varnish consists of: fluorine-containing epoxy acrylate 10%, fluorochemical urethane acrylate 30%, fluoro-acrylate copolymer 25%; TMPTA15%, DPGDA10%, 1-hydroxy acetophenone 4.5%; BYK 0550.2%, and BYK 3580.3%, flatting silica 5%
Embodiment 6: the aluminium-plastic panel that covers graining
See also Fig. 2.Base material is the aluminium volume of preparation aluminium-plastic panel, and the aluminium volume matrix 1 that will prepare aluminium-plastic panel earlier carries out PROCESS FOR TREATMENT such as conventional polishing, sanding, sandblast, and removes the greasy dirt on surface, dust; Surface roller coating one layer thickness at the aluminium volume matrix of preparation aluminium-plastic panel is the ultraviolet light polymerization gel coating 2 of 100 μ m again, sends into then 3 16.8kw uviol lamps (Halogen lamp LED) are housed, and transmission speed is to carry out photocuring in 8 meters/minute the photo solidification machine; Again at the ultraviolet cured adhesive coating surface, by the ultra-violet curing transfer film transfer printing one deck transfer printing rete 3 that is printed on wood grain that has the ultraviolet-curing paint topping; Then above-mentioned aluminium volume is sent into 3 16.8kw uviol lamps (Halogen lamp LED) are housed, transmission speed is to carry out photocuring in 8 meters/minute the photo solidification machine, reaches criterion of acceptability through test rating, promptly gets and imitates the graining boards half-finished product; Be cut into and require size, be combined into aluminium-plastic panel.
The percentage by weight of ultraviolet cured adhesive consists of: fluorochemical urethane acrylate 25%, fluorine-containing polyester acrylate 25%, urethane acrylate 15%, acrylic acid trifluoro ethyl ester 20%, PO-NPGDA10%, 1-hydroxy-cyclohexyl phenyl ketone 2.5%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, BYK0520.2%, Disperbyk 1030.3%.
The percentage by weight of the ultraviolet light polymerization protection varnish of half mute light consists of: urethane acrylate 15%; fluorochemical urethane acrylate 45%; acrylate copolymer 10%; TMPTA 9%, PETA10%, 1-hydroxy-cyclohexyl phenyl ketone 4%; flatting silica 6%; BYK 0550.2%, and BYK 3060.3%, and Disperbyk 1030.5%.
Claims (10)
1. ultra-violet curing transfer film metal lagging, it is characterized in that: the external coating at the substrate metal plate has the ultraviolet light polymerization gel coating, and the transfer printing rete that is obtained by the transfer printing of ultra-violet curing transfer film is arranged at the ultraviolet cured adhesive coating surface.
2. ultra-violet curing transfer film metal lagging according to claim 1 is characterized in that: described transfer printing rete is the ultra-violet curing transfer film that has or do not have the base load film.
3. ultra-violet curing transfer film metal lagging according to claim 2 is characterized in that: have the ultraviolet-curing paint topping on the base load film of the described ultra-violet curing transfer film that has a base load film.
4. according to the described ultra-violet curing transfer film of claim 2 metal lagging; it is characterized in that: do not have the ultraviolet-curing paint topping on the described ultra-violet curing transfer film that does not have a base load film, ultraviolet light polymerization protection varnish coat is arranged at the external coating of transfer printing rete.
5. according to the described ultra-violet curing transfer film of claim 4 metal lagging, it is characterized in that: polypropylene or polyethylene sheeting are posted in described ultraviolet light polymerization protection varnish coat surface.
6. according to claim 4 or 5 described ultra-violet curing transfer film metal laggings, it is characterized in that: the thickness of described ultraviolet light polymerization protection varnish coat is 10～100 μ m.
7. according to the described ultra-violet curing transfer film of claim 1 metal lagging, it is characterized in that: the thickness of described ultraviolet light polymerization gel coating is 2～100 μ m.
8. according to the described ultra-violet curing transfer film of claim 3 metal lagging; it is characterized in that: the ultra-violet curing transfer film that has the ultraviolet-curing paint topping on the described base load film; be on the base load film, parting agent layer to be arranged; the ultraviolet-curing paint topping is arranged on parting agent layer; UV curable ink decorative pattern layer is arranged on the ultraviolet-curing paint topping, ultraviolet-curing paint background color layer is arranged on UV curable ink decorative pattern layer.
9. according to the described ultra-violet curing transfer film of claim 4 metal lagging; it is characterized in that: the described ultra-violet curing transfer film that does not have the ultraviolet-curing paint topping; be on the base load film, parting agent layer to be arranged; UV curable ink decorative pattern layer is arranged on parting agent layer, ultraviolet-curing paint background color layer is arranged on UV curable ink decorative pattern layer.
10. according to the described ultra-violet curing transfer film of claim 1 metal lagging, it is characterized in that: described metal sheet is volume aluminium, iron plate or the corrosion resistant plate of aluminum veneer, preparation aluminium-plastic panel.
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| CN2010200469844U CN201679177U (en) | 2010-01-21 | 2010-01-21 | UV cured transfer film metal decorative board |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010200469844U CN201679177U (en) | 2010-01-21 | 2010-01-21 | UV cured transfer film metal decorative board |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102248826A (en) * | 2011-04-22 | 2011-11-23 | 巴洛克木业(中山)有限公司 | Manufacturing process of high-definition three-dimensional ultraviolet curing paint transfer floor |
| CN102794960A (en) * | 2012-07-10 | 2012-11-28 | 苏州市星辰科技有限公司 | Anti-static release liner as well as preparation method and equipment thereof |
| CN103031066A (en) * | 2012-12-30 | 2013-04-10 | 南通万德电子工业有限公司 | Photocuring transfer printing material |
| CN103602258A (en) * | 2013-12-06 | 2014-02-26 | 东周化学工业（昆山）有限公司 | Ultraviolet-curing finish coat adhesive |
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| CN107400455A (en) * | 2016-05-19 | 2017-11-28 | 嘉兴艾森压烫科技有限公司 | A kind of thermal transfer UV mould releases and preparation method thereof |
| CN107450758A (en) * | 2016-05-31 | 2017-12-08 | 北京小米移动软件有限公司 | The method of pattern-making, metal shell and terminal device in metal surface |
| CN110293733A (en) * | 2019-05-30 | 2019-10-01 | 芜湖卷烟材料厂 | A kind of release internal lining paper of silicone oil and preparation method thereof |
| CN110466270A (en) * | 2019-08-26 | 2019-11-19 | 上海南朝印刷有限公司 | A kind of steel seal printing technology |
| CN110722845A (en) * | 2019-10-23 | 2020-01-24 | 苏州欧邦塑胶有限公司 | Alloy stainless steel film and production method thereof |
| CN110816103A (en) * | 2019-09-20 | 2020-02-21 | 安徽省浦菲尔建材有限公司 | Water transfer printing film pasting process for aluminum veneer |
| CN112221768A (en) * | 2019-08-20 | 2021-01-15 | 杭州浙达精益机电技术股份有限公司 | Preparation method of color steel plate and color steel plate production equipment |
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| CN102248826A (en) * | 2011-04-22 | 2011-11-23 | 巴洛克木业(中山)有限公司 | Manufacturing process of high-definition three-dimensional ultraviolet curing paint transfer floor |
| CN102794960B (en) * | 2012-07-10 | 2015-06-03 | 苏州市星辰科技有限公司 | Anti-static release liner as well as preparation method thereof |
| CN102794960A (en) * | 2012-07-10 | 2012-11-28 | 苏州市星辰科技有限公司 | Anti-static release liner as well as preparation method and equipment thereof |
| CN103031066A (en) * | 2012-12-30 | 2013-04-10 | 南通万德电子工业有限公司 | Photocuring transfer printing material |
| CN103031066B (en) * | 2012-12-30 | 2014-09-03 | 南通万德科技有限公司 | Photocuring transfer printing material |
| CN103640355A (en) * | 2013-12-05 | 2014-03-19 | 通达宏泰科技(苏州)有限公司 | Film laminating process for notebook computer metal shell |
| CN103640355B (en) * | 2013-12-05 | 2015-06-03 | 通达宏泰科技(苏州)有限公司 | Film laminating process for notebook computer metal shell |
| CN103602258B (en) * | 2013-12-06 | 2016-04-06 | 东周化学工业（昆山）有限公司 | UV-curable finish coat adhesive agent |
| CN103602258A (en) * | 2013-12-06 | 2014-02-26 | 东周化学工业（昆山）有限公司 | Ultraviolet-curing finish coat adhesive |
| CN107400455A (en) * | 2016-05-19 | 2017-11-28 | 嘉兴艾森压烫科技有限公司 | A kind of thermal transfer UV mould releases and preparation method thereof |
| CN107450758A (en) * | 2016-05-31 | 2017-12-08 | 北京小米移动软件有限公司 | The method of pattern-making, metal shell and terminal device in metal surface |
| CN110293733A (en) * | 2019-05-30 | 2019-10-01 | 芜湖卷烟材料厂 | A kind of release internal lining paper of silicone oil and preparation method thereof |
| CN110293733B (en) * | 2019-05-30 | 2021-05-28 | 芜湖卷烟材料厂 | Silicone oil release liner paper and preparation method thereof |
| CN112221768A (en) * | 2019-08-20 | 2021-01-15 | 杭州浙达精益机电技术股份有限公司 | Preparation method of color steel plate and color steel plate production equipment |
| CN112221768B (en) * | 2019-08-20 | 2022-02-22 | 杭州浙达精益机电技术股份有限公司 | Preparation method of color steel plate |
| CN110466270A (en) * | 2019-08-26 | 2019-11-19 | 上海南朝印刷有限公司 | A kind of steel seal printing technology |
| CN110816103A (en) * | 2019-09-20 | 2020-02-21 | 安徽省浦菲尔建材有限公司 | Water transfer printing film pasting process for aluminum veneer |
| CN110722845A (en) * | 2019-10-23 | 2020-01-24 | 苏州欧邦塑胶有限公司 | Alloy stainless steel film and production method thereof |
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Address after: 519050 Zhuhai City, Sichuan Province, South Water Chemical Industry Zone Patentee after: Zhuhai Dongcheng light curing new materials Limited by Share Ltd Address before: 519050 Zhuhai City, Sichuan Province, chemical industry zone Patentee before: Zhuhai Dongcheng UV Materials Co., Ltd. |
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Granted publication date: 20101222 |