CN205100481U - Radiation curing tectorial membrane decorative board - Google Patents
Radiation curing tectorial membrane decorative board Download PDFInfo
- Publication number
- CN205100481U CN205100481U CN201520884346.2U CN201520884346U CN205100481U CN 205100481 U CN205100481 U CN 205100481U CN 201520884346 U CN201520884346 U CN 201520884346U CN 205100481 U CN205100481 U CN 205100481U
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- China
- Prior art keywords
- radiation curing
- film
- line
- thickness
- glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000003847 radiation curing Methods 0.000 title claims abstract description 154
- 210000002489 tectorial membrane Anatomy 0.000 title abstract 3
- -1 polypropylene Polymers 0.000 claims abstract description 35
- 230000001681 protective effect Effects 0.000 claims abstract description 33
- 239000004743 Polypropylene Substances 0.000 claims abstract description 15
- 229920001155 polypropylene Polymers 0.000 claims abstract description 15
- 239000004698 Polyethylene Substances 0.000 claims abstract description 12
- 229920000573 polyethylene Polymers 0.000 claims abstract description 12
- 239000003973 paint Substances 0.000 claims abstract description 9
- 239000000758 substrate Substances 0.000 claims description 30
- 239000011253 protective coating Substances 0.000 claims description 18
- 229920003023 plastic Polymers 0.000 claims description 12
- 239000004033 plastic Substances 0.000 claims description 12
- 239000002023 wood Substances 0.000 claims description 11
- 229920002521 macromolecule Polymers 0.000 claims description 4
- 239000003292 glue Substances 0.000 abstract description 16
- 239000000463 material Substances 0.000 abstract description 14
- 229910052751 metal Inorganic materials 0.000 abstract description 9
- 239000002184 metal Substances 0.000 abstract description 9
- 239000004568 cement Substances 0.000 abstract description 5
- 239000004575 stone Substances 0.000 abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 abstract description 4
- 239000000378 calcium silicate Substances 0.000 abstract description 4
- 229910052918 calcium silicate Inorganic materials 0.000 abstract description 4
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 3
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- 239000000919 ceramic Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
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- 238000000576 coating method Methods 0.000 description 35
- 238000001723 curing Methods 0.000 description 25
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- 230000001680 brushing effect Effects 0.000 description 15
- 238000000034 method Methods 0.000 description 15
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 13
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- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 11
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- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 5
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 5
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- QDHUQRBYCVAWEN-UHFFFAOYSA-N amino prop-2-enoate Chemical class NOC(=O)C=C QDHUQRBYCVAWEN-UHFFFAOYSA-N 0.000 description 4
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- 239000012965 benzophenone Substances 0.000 description 3
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- KNXVOGGZOFOROK-UHFFFAOYSA-N trimagnesium;dioxido(oxo)silane;hydroxy-oxido-oxosilane Chemical compound [Mg+2].[Mg+2].[Mg+2].O[Si]([O-])=O.O[Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O KNXVOGGZOFOROK-UHFFFAOYSA-N 0.000 description 3
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 2
- NLGDWWCZQDIASO-UHFFFAOYSA-N 2-hydroxy-1-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-2-phenylethanone Chemical compound OC(C(=O)c1cccc2Oc12)c1ccccc1 NLGDWWCZQDIASO-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
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- NQSMEZJWJJVYOI-UHFFFAOYSA-N Methyl 2-benzoylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 NQSMEZJWJJVYOI-UHFFFAOYSA-N 0.000 description 2
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- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 150000008062 acetophenones Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 210000002469 basement membrane Anatomy 0.000 description 2
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 2
- 150000008366 benzophenones Chemical class 0.000 description 2
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- 238000010894 electron beam technology Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
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- CKGKXGQVRVAKEA-UHFFFAOYSA-N (2-methylphenyl)-phenylmethanone Chemical compound CC1=CC=CC=C1C(=O)C1=CC=CC=C1 CKGKXGQVRVAKEA-UHFFFAOYSA-N 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
- BOCJQSFSGAZAPQ-UHFFFAOYSA-N 1-chloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl BOCJQSFSGAZAPQ-UHFFFAOYSA-N 0.000 description 1
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- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 description 1
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- IKVYHNPVKUNCJM-UHFFFAOYSA-N 4-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C(C(C)C)=CC=C2 IKVYHNPVKUNCJM-UHFFFAOYSA-N 0.000 description 1
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- FOSCDBCOYQJHPN-UHFFFAOYSA-M Cl[Mg] Chemical compound Cl[Mg] FOSCDBCOYQJHPN-UHFFFAOYSA-M 0.000 description 1
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- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 description 1
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Laminated Bodies (AREA)
Abstract
The utility model provides a radiation curing tectorial membrane decorative board, attach to first radiation curing glue film, rendition pattern layer and polypropylene protective film or polyethylene protective film on the base plate in proper order including base plate and from the bottom up. The utility model discloses a radiation curing tectorial membrane decorative board has that intensity is high, anti roll over good, the weatherability is good, the feature of environmental protection is good, the pattern is abundant, the paint film is plump, hardness is high, anti fish tail, easy cleanness, characteristics such as usage are extensive, the existing stone material of fungible, timber, ceramic tile, cement fiberboard, calcium silicate board, glass magnesium board, plastic-aluminum board, aluminium veneer, metal sheet etc..
Description
Technical field
The utility model relates to building material field, particularly a kind of radiation curing film coated decorative plate.
Background technology
At present, domestic various building and ornament materials occur in succession as insulation composite material for decoration, fire-retardant decorative material, mainly contain the decoration as exterior wall or interior wall etc. such as fiber reinforced cement board, fiber reinforced calcium silicate board, fiber reinforcement magnesium oxide plate, lightweight chloro-magnesium cement plate, magnesite board, gypseous decorating board.Current general construction technology is comparatively complicated, particularly high-building construction difficulty, and the cycle is long, and cost is high.And the reason due to substrate itself causes and can not use in part occasion.
Utility model content
The utility model is intended to solve above-described problem.The purpose of this utility model is to provide a kind of radiation curing film coated decorative plate.
The the first radiation curing glue-line, transfer pattern layer and the polypropylene protective film that comprise substrate and be attached to successively from top to bottom on substrate or polyethylene protective film.
Wherein, radiation curing film coated decorative plate also comprises the second radiation curing glue-line, and wherein the second radiation curing glue-line is between transfer pattern layer and polypropylene protective film or polyethylene protective film.
Wherein, radiation curing film coated decorative plate also comprises radiation curing protective coating, and radiation curing protective coating is between the second radiation curing glue-line and polypropylene protective film or polyethylene protective film.
Wherein, also scratch coat is provided with between substrate and the first radiation curing glue-line.
Wherein, the thickness of the first radiation curing glue-line is 1 ~ 50 μm; The thickness of the second radiation curing glue-line (40) is 1 ~ 50 μm.The thickness of radiation curing protective coating is 1 ~ 300 μm, and the glossiness of radiation curing protective coating is 2 ~ 100GU, 60 degree of gloss meters.
Wherein, the thickness of scratch coat is 1 ~ 150 μm.
Wherein, the thickness of the first radiation curing glue-line (20) is 20 μm; The thickness of the second radiation curing glue-line is 30 μm; The thickness of radiation curing protective coating is 150 μm.
Wherein, transfer film used comprises UV transfer film, heat transfer film, exempts to paint the one in transfer film.
Wherein, substrate used thereof comprises calcium-plastic board, plate moulded by wood, one in PVC board, macromolecule plate, stone-plastic plate.
Radiation curing adhesion primer in the utility model comprises acrylic ester prepolymer 30 ~ 80%, acrylate monomer 10 ~ 60%, light trigger 1 ~ 6%, auxiliary agent 0 ~ 2% and filler 0 ~ 50%.
First radiation curing glue-line and the second radiation curing glue-line comprise acrylic ester prepolymer 30 ~ 80%, acrylate monomer 10 ~ 60%, light trigger 1 ~ 5% and auxiliary agent 0 ~ 5%.
Radiation curing protective coating comprises acrylic ester prepolymer or their mixture 30 ~ 80%, acrylate monomer or their mixture 10 ~ 60%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and filler 0 ~ 50%.
Wherein, reactive acrylate's prepolymer comprises epoxy acrylate, urethane acrylate, polyester acrylate, amino acrylates, acrylate copolymer, fluorine-containing epoxy acrylate, fluorochemical urethane acrylate, fluorine-containing polyester acrylate, fluorine-containing amino acrylates, fluoro-acrylate copolymer, siliceous epoxy acrylate, silicon-based polyurethane acrylate, Silicon-containing Polyester acrylate, siliceous amino acrylates, silyl acrylate ester copolymer, fluosilicic epoxy acrylate, fluosilicic urethane acrylate, fluosilicic polyester acrylate, fluosilicic amino acrylates, one or more in silicon-fluorin acrylic acid ester copolymer.
As preferably, reactive acrylate monomer comprises butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer EHA, hydroxy-ethyl acrylate HEA, hydroxyethyl methacrylate MHEA, tri (propylene glycol) diacrylate TPGDA, propylene glycol diacrylate DPGDA, neopentylglycol diacrylate NPGDA, third oxidation neopentylglycol diacrylate PO-NPGDA, two (diethylene glycol) diacrylate PDDA of phthalic acid, 1, 6 hexanediyl ester HDDA, trimethylolpropane triacrylate TMPTA, ethoxyquin trimethylolpropane triacrylate EO-TMODA, third oxidation trimethylolpropane triacrylate PO-TMPDA, pentaerythritol triacrylate PETA, one or more in dipentaerythritol acrylate DPHA.
Light trigger comprises benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenones light trigger, Anthraquinones light trigger, thioxanthone photoinitiator, Benzophenones light trigger, acyl group are seen in oxygen compound photoinitiator and benzoic ether photoinitiator one or more.
Benzoin ether photoinitiator comprise in benzoin methyl ether, benzoin ethyl ether and benzoin isopropyl ether one or more.
Benzil ketals photoinitiator comprises benzil dimethyl ketal.
Acetophenones light trigger comprises acetophenone, 2, 2-dimethoxy-2-phenyl acetophenone, 2, 2-diethoxy-2-phenyl acetophenone, 1, 1-dichloroacetophenone, 1-hydroxy acetophenone, 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-(4-isopropyl phenyl)-2-hydroxy-2-methyl-1-acetone, 1-[4-(2-hydroxyl-oxethyl) phenyl]-2-hydroxy-2-methyl-1-acetone, one or more in 2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone and 2-benzyl-2-dimethylamino-1-(4-morpholino phenyl)-1-butanone.
Anthraquinones light trigger comprise in 2-tert-butyl group anthraquinone, 1-chloroanthraquinone and 2-amyl anthraquinone one or more.
Thioxanthone photoinitiator comprise in 2,4-dimethyl thioxanthone, 2,4-diethyl thioxanthones, 2-isopropyl thioxanthone, 4-isopropyl thioxanthone, 2-chloro thioxanthone and 2,4-diisopropyl thioxanthone one or more.
Benzophenones light trigger comprise benzophenone, 4-chlorobenzophenone, to methyl benzophenone and 4-benzoyl-4 ' one or more in-dimethyl diphenyl sulfide.
Acyl group oxygen compound photoinitiator of seeing comprises 2; 4; 6-trimethyl benzoyl diphenyl base phosphine oxide, two (2; 4,6-trimethylbenzoyl)-phenyl phosphine oxide, two (2,6-dimethylbenzoyls)-2; 4; one or more in 4-trimethylpentylphosphine oxide and 2,4,6-trimethylbenzoyl phenyl ethyoxyl phosphine oxide.
Benzoic ether photoinitiator comprise in methyl benzoylbenzoate, methyl o-benzoylbenzoate one or more.
Auxiliary agent comprise in levelling agent, defoamer and wetting dispersing agent one or more.Wherein levelling agent comprises the levelling agent of TEGO or German Bi Ke chemical company, as one or more in TEGO450, BYK358;
Defoamer comprises the defoamer of the modest or German Bi Ke chemical company of moral as one or more in DEUCHEM2700, BYK055;
Dispersing agent comprises the wetting dispersing agent of EFKA or German Bi Ke chemical company as one or more in EFKA4010, Disperbyk163.
Filler comprises one or more in the powder body materials such as French chalk, calcium carbonate, barium sulfate, flatting silica, abrasion-resistant powder, transparent powder, titanium dioxide, carbon black, bright red toner, former yellow powder, the blue or green orchid of phthalein.
A kind of film coated decorative plate of the present utility model, have that intensity highly, anti-is rolled well, good weatherability, the feature of environmental protection are good, pattern is abundant, paint film is plentiful, hardness is high, scratch resistance, the feature such as easy to clean, of many uses, alternative existing stone material, timber, ceramic tile, cement fibrolite plate, calcium silicate board, glass magnesium plate, aluminium-plastic panel, aluminum veneer, metal sheet etc.
Read the following description for exemplary embodiment with reference to accompanying drawing, other property features of the present utility model and advantage will become clear.
Accompanying drawing explanation
To be incorporated in manual and the accompanying drawing forming a part for manual shows embodiment of the present utility model, and together with the description for explaining principle of the present utility model.In the drawings, similar Reference numeral is used for key element like representation class.Accompanying drawing in the following describes is embodiments more of the present utility model, instead of whole embodiment.For those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can be obtained according to these accompanying drawings.
Fig. 1 schematically illustrates the structural representation according to radiation curing film coated decorative plate of the present utility model.
Detailed description of the invention
For making the object of the utility model embodiment, technical scheme and advantage clearly, below in conjunction with the accompanying drawing in the utility model embodiment, technical scheme in the utility model embodiment is clearly and completely described, obviously, described embodiment is the utility model part embodiment, instead of whole embodiments.Based on the embodiment in the utility model, those of ordinary skill in the art are not making the every other embodiment obtained under creative work prerequisite, all belong to the scope of the utility model protection.It should be noted that, when not conflicting, the embodiment in the application and the feature in embodiment can be combined mutually.
The utility model provides a kind of radiation curing film coated decorative plate, by selecting calcium-plastic board, plate moulded by wood, PVC board, macromolecule plate, stone-plastic plate etc. are as base material, and radiation-curable couting and patterned layer are set at substrate, form a kind of pattern various, widely used radiation curing film coated decorative plate.
As shown in Figure 1, a kind of radiation curing film coated decorative plate 1, comprises substrate 10 and the first radiation curing glue-line 20, transfer pattern layer 30 and the polypropylene protective film that are attached to successively from top to bottom on described substrate 10 or polyethylene protective film.
Wherein transfer pattern layer obtains by being installed with transfer film at the first radiation curing glue-line 20, detailed process is, transfer film is overlayed on the surface of the first radiation curing glue-line 20, after ultraviolet light or electron beam solidification, the base load film of removing transfer film, makes pattern layer on transfer film on the first radiation curing glue-line.Wherein the pattern of transfer film comprises the multiple patterns such as wood grain, decorative pattern.
Radiation curing film coated decorative plate 1 can also comprise the second radiation curing glue-line 40, and wherein the second radiation curing glue-line 40 is between transfer pattern layer 30 and polypropylene protective film or polyethylene protective film.
Radiation curing film coated decorative plate 1 also comprises radiation curing protective coating 50, when this radiation curing film coated decorative plate contains the second radiation curing glue-line 40, radiation curing protective coating 50 is between the second radiation curing glue-line 40 and described polypropylene protective film or polyethylene protective film; When this film coated decorative plate is not containing the second radiation curing glue-line, radiation curing protective coating is between transfer pattern layer 30 and described polypropylene protective film or polyethylene protective film.
Also be provided with scratch coat between substrate 10 and the first radiation curing glue-line 20, scratch coat is the one that radiation curing adheres in scratch coat and Color Basecoat.Wherein scratch coat act as improve solidification glue-line adhesive power, alkali resistance is provided, anti-corrosion function is provided, be the fullness that also can increase Bulk coat when priming paint is coloured substrate.
The top of radiation curing protective coating 50 is also provided with protective film, and protective film is polypropylene protective film or polyethylene protective film.Wherein protective film act as the scratch and scuffing that prevent lacquer painting layer.
Under normal circumstances, the thickness of the first radiation curing glue-line 20 is 1 ~ 50 μm; The thickness of the second radiation curing glue-line is 1 ~ 50 μm; The thickness of radiation curing protective coating is 1 ~ 300 μm.Considering based on decorative effect, is 2 ~ 100GU by the glossiness of radiation curing protective coating usually, 60 degree gloss meters, and gloss counts the intelligent vancometer of DR60A.
In an embodiment of the present utility model, the thickness of the first radiation curing glue-line 20 is 20 μm; The thickness of the second radiation curing glue-line is 30 μm; The thickness of radiation curing protective coating is 150 μm, and the thickness of scratch coat is 100 μm.
In addition, the substrate in the utility model comprises: calcium-plastic board, wood mould plate, PVC board, macromolecule plate, stone-plastic plate etc. and in the utility model, the various coating of all radiation curings includes uv radiation curing and electron beam solidifies two kinds of forms.
Radiation curing film coated decorative plate of the present utility model obtains by following multiple method:
method one
1) process of substrate surface: sand milling, dedusting;
2) at the external coating radiation curing attachment scratch coat of substrate, radiation curing; Application mode can adopt the modes such as roller coat, blade coating, spraying, showering or brushing, and coating layer thickness is 1 ~ 150 μm.
3) sand milling, dedusting;
4) at the external coating first radiation curing glue-line of radiation curing adhesion primer, radiation curing; Application mode can adopt the modes such as roller coat, brushing or blade coating, and the thickness of coating is 1 ~ 50 μm;
5) transfer film is overlayed, radiation curing on the surface of the first radiation curing glue-line; The workpiece overlayed enters the ultraviolet tube (high-pressure sodium lamp) that 1 ~ 6 9.6 ~ 16.8kw is housed, be cured in the curing of the metal halogen fluorescent tube (Iodine gallium light, iron lamp, dysprosium lamp etc.) of 1 ~ 53 ~ 20kw, the transmission speed of curing is 1 ~ 50 m/min;
6) remove the base load film in transfer film, obtain transfer pattern layer;
7) check;
8) protective film is pasted;
9) pack.
method two
1) process of substrate surface: sand milling, dedusting;
2) at the external coating radiation curing attachment scratch coat of substrate, radiation curing; Application mode can adopt the modes such as roller coat, blade coating, spraying, showering or brushing, and coating layer thickness is 1 ~ 150 μm.
3) sand milling, dedusting;
4) at the external coating first radiation curing glue of radiation curing attachment scratch coat, radiation curing; Application mode can adopt the modes such as roller coat, brushing or blade coating, and the thickness of coating is 1 ~ 50 μm;
5) transfer film is overlayed, radiation curing on the surface of the first radiation curing glue; The workpiece overlayed enters the ultraviolet tube (high-pressure sodium lamp) that 1 ~ 6 9.6 ~ 16.8kw is housed, be cured in the curing of the metal halogen fluorescent tube (Iodine gallium light, iron lamp, dysprosium lamp etc.) of 1 ~ 53 ~ 20kw, the transmission speed of curing is 1 ~ 50 m/min;
6) remove the base load film in transfer film, obtain transfer pattern layer;
7) application second radiation curing glue-line again on transfer pattern layer, radiation curing; Application mode can adopt the modes such as roller coat, brushing or spraying, and the thickness of coating is 1 ~ 50 μm;
8) application ultraviolet light polymerization protection surface layer on the second radiation curing glue-line, radiation curing; Application mode can adopt the modes such as roller coat, showering or spraying, and the thickness of coating is 1 ~ 300 μm, gloss be 2 ~ 100 degree adjustable, with 60 degree of gloss meters;
9) check;
10) protective film is pasted;
11) pack.
method three
1) process of substrate surface: sand milling, dedusting;
2) at the external coating radiation curing attachment scratch coat of substrate, radiation curing; Application mode can adopt the modes such as roller coat, blade coating, spraying, showering or brushing, and coating layer thickness is 1 ~ 150 μm.
3) sand milling, dedusting;
4) application radiation curing Color Basecoat on radiation curing attachment scratch coat, radiation curing; Application mode can adopt the modes such as roller coat, blade coating, spraying, showering or brushing, and coating layer thickness is 1 ~ 150 μm.
5) sand milling, dedusting;
6) at the external coating first radiation curing glue-line of radiation curing Color Basecoat, radiation curing; Application mode can adopt the modes such as roller coat, brushing or blade coating, and the thickness of coating is 1 ~ 50 μm;
7) transfer film is overlayed, radiation curing on the surface of the first radiation curing glue-line; The workpiece overlayed enters the ultraviolet tube (high-pressure sodium lamp) that 1 ~ 6 9.6 ~ 16.8kw is housed, be cured in the curing of the metal halogen fluorescent tube (Iodine gallium light, iron lamp, dysprosium lamp etc.) of 1 ~ 53 ~ 20kw, the transmission speed of curing is 1 ~ 50 m/min;
8) remove the base load film in transfer film, obtain transfer pattern layer;
9) check;
10) protective film is pasted;
11) pack.
method four
1) process of substrate surface: sand milling, dedusting;
2) at the external coating radiation curing attachment scratch coat of substrate, radiation curing; Application mode can adopt the modes such as roller coat, blade coating, spraying, showering or brushing, and coating layer thickness is 1 ~ 150 μm.
3) sand milling, dedusting;
4) application radiation curing coloured substrate on radiation curable primary, radiation curing; Application mode can adopt the modes such as roller coat, blade coating, spraying, showering or brushing, and coating layer thickness is 1 ~ 150 μm.
5) sand milling, dedusting;
6) at the external coating first radiation curing glue-line of radiation curing coloured substrate, radiation curing; Application mode can adopt the modes such as roller coat, brushing or blade coating, and the thickness of coating is 1 ~ 50 μm;
7) transfer film is overlayed, radiation curing on the surface of the first radiation curing glue-line; The workpiece overlayed enters the ultraviolet tube high-pressure sodium lamp that 1 ~ 6 9.6 ~ 16.8kw is housed, and be cured in the curing of the metal halogen fluorescent tube Iodine gallium light, iron lamp, dysprosium lamp etc. of 1 ~ 53 ~ 20kw, the transmission speed of curing is 1 ~ 50 m/min;
8) the base load film in transfer film is removed, by the time transfer pattern layer;
9) application second radiation curing glue again on transfer pattern layer, radiation curing; Application mode can adopt the modes such as roller coat, brushing or spraying, and the thickness of coating is 1 ~ 50 μm;
10) application ultraviolet light polymerization protection surface layer on the second radiation curing glue-line, radiation curing; Application mode can adopt the modes such as roller coat, showering or spraying, and the thickness of coating is 1 ~ 300 μm, gloss be 2 ~ 100 degree adjustable, with 60 degree of gloss meters;
11) check;
12) protective film is pasted;
13) pack.
method five
1) process of substrate surface: sand milling, dedusting;
2) at the external coating first radiation curing glue-line of substrate, radiation curing; Application mode can adopt the modes such as roller coat, brushing or blade coating, and the thickness of coating is 1 ~ 50 μm;
3) transfer film is overlayed, radiation curing on the surface of the first radiation curing glue-line; The workpiece overlayed enters the ultraviolet tube high-pressure sodium lamp that 1 ~ 6 9.6 ~ 16.8kw is housed, and be cured in the curing of the metal halogen fluorescent tube Iodine gallium light, iron lamp, dysprosium lamp etc. of 1 ~ 53 ~ 20kw, the transmission speed of curing is 1 ~ 50 m/min;
4) remove the base load film in transfer film, obtain transfer pattern layer;
5) check;
6) protective film is pasted;
7) pack.
method six
1) process of substrate surface: sand milling, dedusting;
2) at the external coating first radiation curing glue-line of substrate, radiation curing; Application mode can adopt the modes such as roller coat, brushing or blade coating, and the thickness of coating is 1 ~ 50 μm;
3) transfer film is overlayed, radiation curing on the surface of the first radiation curing glue; The workpiece overlayed enters the ultraviolet tube high-pressure sodium lamp that 1 ~ 6 9.6 ~ 16.8kw is housed, and be cured in the curing of the metal halogen fluorescent tube Iodine gallium light, iron lamp, dysprosium lamp etc. of 1 ~ 53 ~ 20kw, the transmission speed of curing is 1 ~ 50 m/min;
4) remove the base load film in transfer film, obtain transfer pattern layer;
5) application second radiation curing glue-line again on transfer pattern layer, radiation curing; Application mode can adopt the modes such as roller coat, brushing or spraying, and the thickness of coating is 1 ~ 50 μm;
6) application ultraviolet light polymerization protection surface layer on the second radiation curing glue-line, radiation curing; Application mode can adopt the modes such as roller coat, showering or spraying, and the thickness of coating is 1 ~ 300 μm, gloss be 2 ~ 100 degree adjustable, with 60 degree of gloss meters;
7) check;
8) protective film is pasted;
9) pack.
Below the form by embodiment is described further peritonaeum decorative panel of the present utility model.
Embodiment 1: radiation curing decorative panel moulded by imitative cartoon wood
Decorative panel base material is that plate moulded by wood, first by the sanding on base material 10 surface, dedusting, then roller coat thickness is the radiation curing glue 20 of 10 microns, enter and 1 9.6kw uviol lamp (high-pressure sodium lamp) is housed, transmission speed is the curing of 6 ms/min, after solidification, again after radiation curing glue surface overlays the transfer film 30 (exempting from paint film) being printed on cartoon pattern, enter the curing that the transmission speed that 4 16.8kw gallium lamps are housed is 6 ms/min, after solidification, criterion of acceptability is reached through test rating, paste polypropylene diaphragm, obtain imitative cartoon wood and mould radiation curing decorative panel finished product.
The percentage by weight of radiation curing glue consists of: urethane acrylate 25%; acrylate copolymer 25%, EO3-TMPTA20%; DPGDA15%; 1-hydroxy-cyclohexyl phenyl ketone 2%; 2; 4,6-trimethyl benzoyl diphenyl base phosphine oxide 2%, 2-benzyl-2-dimethylamino-1-(4-morpholino phenyl)-1-butanone 3%, DEUCHEM27000.2%, BYK0550.3%.
Embodiment 2: wood grain calcium moulds wear-resisting radiation curing decorative panel
Decorative panel base material is calcium-plastic board, first by the sanding on base material 10 surface, dedusting, then be the 50 micron radiation solidification attachment ends 60 at base material 10 surface roller coating thickness, after enter 2 7.6kw high-pressure sodium lamps be housed, transmission speed is the curing of 9 ms/min, after solidification, and sanding, dedusting, then roller coat thickness is the radiation curing glue 20 of 10 microns, enters and 1 9.6kw high-pressure sodium lamp is housed, transmission speed is the curing of 9 ms/min, after solidification, then overlay on surface be printed on wood grain transfer film 30 after, enter and 4 16.8kw gallium lamps be housed, iron lamp, mercury lamp, mercury lamp, transmission speed is the curing of 9 ms/min, after solidification, removes basement membrane, then is the radiation curing glue 40 of 12 microns at patterned surfaces roller coat thickness, enters and 2 11.2kw gallium lamps are housed, transmission speed is the curing of 9 ms/min, and after semi-solid preparation, then be 50 microns at surface roller coating thickness, gloss is the wear-resisting matte surface 50 of radiation curing of 30 degree (60 degree of gloss meters), enters and 4 16.8kw gallium lamps are housed, iron lamp, mercury lamp, mercury lamp, transmission speed is the curing of 9 ms/min, after solidification, reaches criterion of acceptability through test rating, pastes polypropylene diaphragm, obtains imitative wood grain calcium and mould wear-resisting radiation curing decorative panel finished product.
The percentage by weight at the radiation curing attachment end consists of: polyester acrylate 15%, epoxy acrylate 20%, NPGDA25%, HDDA5%, French chalk 30%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 4.5%, EFKA40100.5%.
The percentage by weight of radiation curing glue 20 consists of: epoxy acrylate 20%; acrylate copolymer 30%, TMPTA32.5%; HDDA10%; 2-hydroxy-2-methyl-1-phenyl-1-acetone 5%; 2; 4,6-trimethyl benzoyl diphenyl base phosphine oxide 2%, TEGO4500.3%, DEUCHEM27000.2%.
The percentage by weight of radiation curing glue 40 consists of: urethane acrylate 10%, acrylate copolymer 40%, HEMA25%, EO3-TMPTA5%, flatting silica 5, transparent powder 7%2-hydroxy-2-methyl-1-phenyl-1-acetone 5%, 1-hydroxy-cyclohexyl phenyl ketone 2%, EFKA0.5%, BYK0550.5%.
The percentage by weight of the wear-resisting finish paint of radiation curing consists of: urethane acrylate 20%, epoxy acrylate 30%, HDDA15%, TMPTA15%, 1-hydroxy-cyclohexyl phenyl ketone 4%, flatting silica 5%, abrasion-resistant powder 10%, BYK0550.2%, EFKA40100.5%, TEGO4500.3%.
Embodiment 3: parian stone moulds radiation curing exterior decoration plate
Refer to figure.Decorative panel base material is stone-plastic plate, first by substrate 10 surface dust, then enters 2 9.6kw high-pressure sodium lamps are housed after base material 10 surface roller coating thickness is 11 microns of attachment ends 60, transmission speed is the curing of 15 ms/min, after solidification, and sanding, dedusting, then roller coat thickness is the radiation curing white primary coat 70 of 50 microns, enters and 4 11.2kw gallium lamps are housed, gallium lamp, iron lamp, high-pressure sodium lamp, transmission speed is the curing of 15 ms/min, after solidification, then is enter after 20 micron radiation solidify glue 20 1 7.6kw high-pressure sodium lamp is housed at surface roller coating thickness, transmission speed is the curing of 15 ms/min, after semi-solid preparation, then after surface overlays and is printed on marblized transfer film 30, enters and 5 16.8kw gallium lamps are housed, gallium lamp, iron lamp, iron lamp, mercury lamp, transmission speed is the curing of 15 ms/min, after solidification, goes out basement membrane, then is the radiation curing glue 40 of 8um at surface roller coating thickness, enters and 3 9.6kw high-pressure sodium lamps are housed, transmission speed is the curing of 15 ms/min, after semi-solid preparation, then surface roller coating 30 microns, gloss is 70 degree of (60 degree of gloss meters) radiation curing fluosilicic finish paints, enters and 5 16.8kw gallium lamps are housed, gallium lamp, iron lamp, mercury lamp, mercury lamp, transmission speed is the curing of 15 ms/min, after solidification, reaches criterion of acceptability through test rating, pastes polypropylene diaphragm 9, obtains parian stone and mould radiation curing exterior decoration board finished product.
The percentage by weight at the radiation curing attachment end consists of: pure third acrylate 20%, polyester acrylate 20%, TPGDA10%, DPGDA15%, French chalk 30%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 4.5%, BYK0550.2%, EFKA40100.3%.
The percentage by weight at the radiation curing white end consists of: epoxy acrylate 10%; urethane acrylate 20%; NPGDA20%; TMPTA20%; titanium dioxide 22%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 4.5%, 2; 4,6-trimethyl benzoyl diphenyl base phosphine oxide 3%, EFKA40100.5%.
The percentage by weight of radiation curing glue 20 consists of: epoxy acrylate 10%; urethane acrylate 20%; acrylate copolymer 30%, TMPTA22%; NPGDA10%; 2-hydroxy-2-methyl-1-phenyl-1-acetone 2.5%, 2,4; 6-trimethyl benzoyl diphenyl base phosphine oxide 2%, 2-benzyl-2-dimethylamino-1-(4-morpholino phenyl)-1-butanone 3%, TEGO4500.2%, BYK0550.3%.
The percentage by weight of radiation curing glue 40 consists of: urethane acrylate 25%, acrylate copolymer 35%, HEMA10%, TPGDA21.5%, 1-hydroxy-cyclohexyl phenyl ketone 6%, Ciba50502%, TEGO4500.5%.
The percentage by weight in radiation curing fluosilicic face consists of: urethane acrylate 8%, fluorochemical urethane acrylate 15%, fluoro-acrylate copolymer 30%, TMPTA15%, DPGDA10%, Ciba1844%, delustring slurry 15%, BYK0550.5%, Ciba50502%, TEGO4500.5%.
In sum, a kind of radiation curing film coated decorative plate of the present utility model, have that intensity highly, anti-is rolled well, good weatherability, the feature of environmental protection are good, pattern is abundant, paint film is plentiful, hardness is high, scratch resistance, the feature such as easy to clean, of many uses, alternative existing stone material, timber, ceramic tile, cement fibrolite plate, calcium silicate board, glass magnesium plate, aluminium-plastic panel, aluminum veneer, metal sheet etc.
Last it is noted that above embodiment is only in order to illustrate the technical solution of the utility model, be not intended to limit.Although be described in detail the utility model with reference to previous embodiment, those of ordinary skill in the art is to be understood that: it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature; And these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of each embodiment technical scheme of the utility model.
Claims (9)
1. a radiation curing film coated decorative plate (1); it is characterized in that, comprise substrate (10) and the first radiation curing glue-line (20), transfer pattern layer (30) and the polypropylene protective film that are attached to successively from top to bottom on described substrate (10) or polyethylene protective film.
2. decorative panel as claimed in claim 1, is characterized in that,
Described radiation curing film coated decorative plate (1) also comprises the second radiation curing glue-line (40), and wherein said second radiation curing glue-line (40) is positioned between transfer pattern layer (30) and described polypropylene protective film or polyethylene protective film.
3. decorative panel as claimed in claim 2, is characterized in that,
Described radiation curing film coated decorative plate (1) also comprises radiation curing protective coating (50), and described radiation curing protective coating (50) is positioned between described second radiation curing glue-line (40) and described polypropylene protective film or polyethylene protective film.
4. decorative panel as claimed in claim 1, is characterized in that,
Also scratch coat is provided with between described substrate (10) and described first radiation curing glue-line (20).
5. decorative panel as claimed in claim 3, is characterized in that,
The thickness of described first radiation curing glue-line (20) is 1 ~ 50 μm; The thickness of described second radiation curing glue-line (40) is 1 ~ 50 μm; The thickness of described radiation curing protective coating (50) is 1 ~ 300 μm, and the glossiness of described radiation curing protective coating (50) is 2 ~ 100GU, 60 degree of gloss meters.
6. decorative panel as claimed in claim 4, is characterized in that,
The thickness of described scratch coat is 1 ~ 150 μm.
7. decorative panel as claimed in claim 5, is characterized in that,
The thickness of described first radiation curing glue-line (20) is 20 μm; The thickness of described second radiation curing glue-line is 30 μm; The thickness of described radiation curing protective coating is 150 μm.
8. decorative panel as claimed in claim 1, is characterized in that,
Transfer film used comprises UV transfer film, heat transfer film or exempts to paint the one in transfer film.
9. decorative panel as claimed in claim 1, is characterized in that
Substrate used thereof comprises calcium-plastic board, plate moulded by wood, one in PVC board, macromolecule plate or stone-plastic plate.
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| CN201520884346.2U CN205100481U (en) | 2015-11-04 | 2015-11-04 | Radiation curing tectorial membrane decorative board |
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| CN201520884346.2U CN205100481U (en) | 2015-11-04 | 2015-11-04 | Radiation curing tectorial membrane decorative board |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109677051A (en) * | 2018-12-29 | 2019-04-26 | 中材华晟科技无锡有限公司 | A kind of decorative panel and its processing technology |
| CN111873572A (en) * | 2020-08-21 | 2020-11-03 | 苏州兴禾源复合材料有限公司 | Heat transfer printing color coating steel plate and production process |
| CN112238656A (en) * | 2020-10-10 | 2021-01-19 | 安徽森泰木塑科技地板有限公司 | Plate with transfer printing pattern decoration layer and preparation method thereof |
| US11285694B1 (en) | 2020-12-31 | 2022-03-29 | Zhejiang Yongyu Furniture Co., Ltd. | Composite decorative board and manufacturing method thereof |
-
2015
- 2015-11-04 CN CN201520884346.2U patent/CN205100481U/en active Active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109677051A (en) * | 2018-12-29 | 2019-04-26 | 中材华晟科技无锡有限公司 | A kind of decorative panel and its processing technology |
| CN111873572A (en) * | 2020-08-21 | 2020-11-03 | 苏州兴禾源复合材料有限公司 | Heat transfer printing color coating steel plate and production process |
| CN112238656A (en) * | 2020-10-10 | 2021-01-19 | 安徽森泰木塑科技地板有限公司 | Plate with transfer printing pattern decoration layer and preparation method thereof |
| CN112238656B (en) * | 2020-10-10 | 2021-08-06 | 安徽森泰木塑科技地板有限公司 | Plate with transfer printing pattern decoration layer and preparation method thereof |
| WO2022073262A1 (en) * | 2020-10-10 | 2022-04-14 | 安徽森泰木塑科技地板有限公司 | Board having transferred patterned decorative layer, and preparation method therefor |
| US11285694B1 (en) | 2020-12-31 | 2022-03-29 | Zhejiang Yongyu Furniture Co., Ltd. | Composite decorative board and manufacturing method thereof |
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