CN108528079A - The wear-resisting local dumb light heat transfer film of one kind and its production technology - Google Patents
The wear-resisting local dumb light heat transfer film of one kind and its production technology Download PDFInfo
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- CN108528079A CN108528079A CN201810335803.0A CN201810335803A CN108528079A CN 108528079 A CN108528079 A CN 108528079A CN 201810335803 A CN201810335803 A CN 201810335803A CN 108528079 A CN108528079 A CN 108528079A
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 238000005516 engineering process Methods 0.000 title claims description 9
- 239000010410 layer Substances 0.000 claims abstract description 56
- 239000011241 protective layer Substances 0.000 claims abstract description 49
- 239000003292 glue Substances 0.000 claims abstract description 41
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 27
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052709 silver Inorganic materials 0.000 claims abstract description 27
- 239000004332 silver Substances 0.000 claims abstract description 27
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 24
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 24
- 210000002469 basement membrane Anatomy 0.000 claims abstract description 22
- 239000004411 aluminium Substances 0.000 claims abstract description 18
- -1 polypropylene Polymers 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 239000004743 Polypropylene Substances 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000741 silica gel Substances 0.000 claims abstract description 10
- 229910002027 silica gel Inorganic materials 0.000 claims abstract description 10
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 7
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- 239000012948 isocyanate Substances 0.000 claims description 13
- 150000002513 isocyanates Chemical class 0.000 claims description 13
- 238000007639 printing Methods 0.000 claims description 12
- 239000004925 Acrylic resin Substances 0.000 claims description 10
- 229920000178 Acrylic resin Polymers 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- 238000007711 solidification Methods 0.000 claims description 8
- 230000008023 solidification Effects 0.000 claims description 8
- 238000005269 aluminizing Methods 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 238000003854 Surface Print Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000012994 photoredox catalyst Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 239000006227 byproduct Substances 0.000 claims description 2
- 210000004379 membrane Anatomy 0.000 abstract description 4
- 239000012528 membrane Substances 0.000 abstract description 4
- 238000009966 trimming Methods 0.000 abstract description 4
- 239000010408 film Substances 0.000 description 29
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
The present invention provides a kind of wear-resisting seamless silver lustre rear enclosure glue heat transfer film; including applying area and window region; the applying area includes from top to bottom PET basement membranes, release layer, ink layer, the first protective layer, the second protective layer, aluminium coated and glue-line successively; the window region is PET basement membranes, and the glue-line includes the component of following weight fraction：Chlorinated polypropylene 22 ~ 30%；Chlorination EUA3 ~ 7%；Aldehyde ketone resin 5 ~ 10%；Adhesion promoter 5 ~ 10%；Solvent 45 ~ 55%.The wear-resisting seamless silver lustre rear enclosure glue heat transfer film, it can easily be realized and be completely stripped by silica gel wheel transfer, picture and text are completely transferred on stock, transfer membrane area is reduced in the case where ensureing that pattern dimension is constant, reduces production cost, and the picture and text after transfer are wear-resisting seamless, without glue tracks, non-trimming, nothing left film, service life is long, and simple production process, has a wide range of application.
Description
Technical field
The present invention relates to a kind of wear-resisting seamless silver lustre rear enclosure glue heat transfer films and its production technology.
Background technology
Heat transfer film be it is a kind of graph text information is printed on carrier thin film, then by the hot stamping equipment of profession through certain
Temperature and pressure graph text information is stripped down from carrier film under the bonding effect of hot melt adhesive, be transferred to corresponding base material
On, such as daily necessities, stationery, building material, it invests and is transferred the required graph text information of base material and color, it is made not only to have
Certain also has certain decorative effect using function.
Existing silver lustre, bright gold thermal transfer film, because equipment is there are uncertainty when transfer, transfer film production there are it is indefinite because
Element, the problems such as easy ting produce residual glue tracks, bubble, trace, rubbish, overlap, remaining film after transfer, increase the remaining film of cleaning,
The expenses such as the process of overlap and artificial, energy consumption, and when in use many inconvenience are brought to client.
Invention content
Above-mentioned to solve the problems, such as, the purpose of the present invention is to provide a kind of wear-resisting seamless silver lustre rear enclosure glue heat to turn
Die.The wear-resisting seamless silver lustre rear enclosure glue heat transfer film can be realized easily by silica gel wheel transfer and be completely stripped, will schemed
Text is completely transferred on stock, and transfer membrane area is reduced in the case where ensureing that pattern dimension is constant, reduces production cost, is turned
Picture and text after print are wear-resisting seamless, and service life is long, and simple production process, has a wide range of application.
In order to achieve the above objectives, the technical scheme is that：
A kind of wear-resisting seamless silver lustre rear enclosure glue heat transfer film, including applying area and window region, the applying area from top to bottom according to
Secondary includes PET basement membranes, release layer, ink layer, the first protective layer, the second protective layer, aluminium coated and glue-line, and the window region is
PET basement membranes, the glue-line include the component of following weight fraction：Chlorinated polypropylene 22 ~ 30%；Chlorination EUA3 ~ 7%；Aldehyde ketone resin 5
~10%；Adhesion promoter 5 ~ 10%；Solvent 45 ~ 55%.The wear-resisting seamless silver lustre rear enclosure glue heat transfer film, including applying area
And window region, the position for there are picture and text is provided with release layer, ink layer, the first protective layer, the second protective layer, aluminium coated and glue
Layer, the position of picture and text is not without release layer, ink layer, the first protective layer, the second protective layer, aluminium coated and glue-line, saving
The losses of each layer raw material reduces transfer membrane area in the case where ensureing that pattern dimension is constant, reduces production cost；Using
The structure of the double protective layers of interlayer double exposure has high protectiveness to the silver lustre after transfer, wear-resisting seamless, reduces loss, improves
Service life；Simultaneously use glue-line can avoid transfer after generate residual glue tracks, bubble, trace, rubbish, overlap,
The problems such as remaining film, strong adhesive force, trimming be good, non yellowing, transfer temperature are low, efficient and environmentally friendly, greatly improves product quality,
Glue-line is detected by SGS, TUV testing agency, and polycyclic aromatic hydrocarbons (PAH), ROHS, heavy metal, organotin, o- benzoic acid content are
It is up to standard.
Further, first protective layer is 150 ~ 175 mesh.
Further, second protective layer is 175 ~ 200 mesh.
Further, the thickness of first protective layer is 0.1 ~ 0.15mm, the thickness of the second protective layer is 0.05 ~
0.1mm。
Further, first, second protective layer includes acrylic resin modified and isocyanates, modified acroleic acid
The weight ratio of resin and isocyanates is 9 ~ 13：1.
Further, the PET basement membranes are transparent smooth surface structure.
A kind of production technology of wear-resisting seamless silver lustre rear enclosure glue heat transfer film, includes the following steps：
1）PET basement membranes：The smooth PET basement membranes in surface are chosen, it is spare after cleaning and drying；
2）Apply release layer：Use two kinds of acrylic acid that molecular weight is 110 for 11000, TG points and molecular weight is 5800, TG points are 98
Resin is merged with lipid solvent and benzene kind solvent, the flowability liquid that solid content is 25% is formed, using the side of intaglio printing
Formula is coated on the applying area of PET basement membranes, and the halftone cable used is 150 ~ 220 lines/inch, and coating machine speed is 30 ~ 60m/
Min is dried after the completion of coating at 60 ~ 75 DEG C, and release layer can completely disengage at high temperature under high pressure with PET basement membranes；Release layer
Coating line number is 70 lines, and wet coating amount is 6.0-7.0g/m2, dry-coated amount is 1.2-1.4g/m2；
3）Oiling layer of ink：Using electronical line shaft printing machine in release layer surface printing ink layer, print speed printing speed is 80 ~ 120m/min,
Ink layer uses high-temperature resisting pigment ink；
4）Apply the first protective layer：Acrylic resin modified and isocyanates is uniformly mixed, using the side of electronical line shaft intaglio printing
Formula coats the first protective layer on ink layer, is dried at 90 ~ 100 DEG C, and speed is 10 ~ 20m/min, modified acroleic acid tree
Fat and isocyanates reaction, curing molding, improve consistency and hardness, and high temperature resistant；
5）Apply the second protective layer：Continue to coat acrylic resin modified and isocyanate mixture on the first protective layer, be formed
Second protective layer is dried at 80 ~ 90 DEG C, and speed is 10 ~ 20m/min；
6）Clean ink：The ink for coating extra is cleaned up；
7）Constant temperature oven cures：By product be put into constant temperature oven successively solidification 16 ~ for 24 hours, solidification temperature be 60 ~ 70 DEG C；
8）Rewinding；
9）It is vacuum aluminum-coated：Product progress after solidification is vacuum aluminum-coated, when vacuum degree reaches 10, carried out on aluminium wire to evaporation boat
Dissolving is sprayed on the second protective layer；
10）Wash aluminium：The pond that product after aluminizing is 5 meters by length, the position for not needing aluminium layer is cleaned up completely；
11）Secondary rewinding；
12）Rubberised layer：Chlorinated polypropylene, chlorination EUA, aldehyde ketone resin, adhesion promoter and solvent are mixed in proportion,
The secondary set glue of glue is formed by glue-line in layer surface of aluminizing using electronical line shaft glue spreader, and dry；
13）Transfer：It is that 80 degree of silica gel wheel is heated to 260 DEG C by hardness, by the thermal energy of silica gel wheel, extruding force by heat transfer film
Decorative pattern transfer on the substrate.The preparation method of the wear-resisting seamless silver lustre rear enclosure glue heat transfer film is simple, product trimming
Property it is good, long with wear-resisting, strong adhesive force, word is clear, production operation changeability is small, can easily have been realized by silica gel wheel transfer
Picture and text are completely transferred on stock by whole stripping, applying area pattern transfer after seam crossing do not have glue tracks, bubble, trace,
The problems such as rubbish, overlap, remaining film, avoids the remaining film of cleaning, the process of overlap and artificial, energy consumption, improves production efficiency, be suitable for
The product that cost of manufacture is high, the production cycle is grown.
Further, the step 13）In stock be ABS, AS, PS, PC, PP, metal, timber and glass.It is described
Wear-resisting seamless silver lustre rear enclosure glue heat transfer film can be adapted for surfaces of various materials, be widely used in stationery, stationery, daily necessities
Equal fields.
The beneficial effects of the present invention are：
A kind of wear-resisting seamless silver lustre rear enclosure glue heat transfer film of the present invention, has metal-like, is transferred by silica gel wheel
It can easily realize and completely strip, picture and text are completely transferred on stock, be reduced in the case where ensureing that pattern dimension is constant
Membrane area is transferred, reduces production cost, the picture and text after transfer are wear-resisting seamless, and no glue tracks, non-trimming, nothing left film use the longevity
Life length, and simple production process, have a wide range of application.
Description of the drawings
Fig. 1 is a kind of structural schematic diagram of wear-resisting seamless silver lustre rear enclosure glue heat transfer film provided by the present invention.
Wherein：1 is applying area, and 10 be PET basement membranes, and 11 be release layer, and 12 be ink layer, and 13 be the first protective layer, and 14 are
Second protective layer, 15 be aluminium coated, and 16 be glue-line, and 2 be window region.
Specific implementation mode
Embodiment
Be a kind of wear-resisting seamless silver lustre rear enclosure glue heat transfer film of the present invention referring to Fig. 1, including applying area 1 and
Window region 2, the applying area 1 from top to bottom successively include PET basement membranes 10, release layer 11, ink layer 12, the first protective layer 13,
Second protective layer 14, aluminium coated 15 and glue-line 16, the window region 2 are PET basement membranes 10, and the glue-line 16 includes following weight point
Several components：Chlorinated polypropylene 27%；Chlorination EUA 5%；Aldehyde ketone resin 7%；Adhesion promoter 8%；Solvent 53%.
Further, first protective layer 13 is 175 mesh.
Further, second protective layer 14 is 200 mesh.
Further, the thickness of first protective layer 13 is 0.1mm, and the thickness of the second protective layer 14 is 0.08mm.
Further, first, second protective layer 13,14 includes acrylic resin modified and isocyanates, is modified third
The weight ratio of olefin(e) acid resin and isocyanates is 10：1.
Further, the PET basement membranes are transparent smooth surface structure.
A kind of production technology of wear-resisting seamless silver lustre rear enclosure glue heat transfer film, includes the following steps：
1）PET basement membranes：The smooth PET basement membranes in surface are chosen, it is spare after cleaning and drying；
2）Apply release layer：Use two kinds of acrylic acid that molecular weight is 110 for 11000, TG points and molecular weight is 5800, TG points are 98
Resin is merged with lipid solvent and benzene kind solvent, the flowability liquid that solid content is 25% is formed, using the side of intaglio printing
Formula is coated on the applying area of PET basement membranes, and the halftone cable used is 200 lines/inch, and coating machine speed is 50m/min, coating
It is dried at 70 DEG C after the completion；It is 70 lines that release layer, which is coated with line number,（The mesh of 1 line=2.5）, wet coating amount is 6.0-7.0g/m2, dry-coated
Cloth amount is 1.2-1.4g/m2；
3）Oiling layer of ink：Using electronical line shaft printing machine in release layer surface printing ink layer, print speed printing speed 90m/min, ink
Layer uses high-temperature resisting pigment ink；
4）Apply the first protective layer：Acrylic resin modified and isocyanates is uniformly mixed, using the side of electronical line shaft intaglio printing
Formula coats the first protective layer on ink layer, is dried at 100 DEG C, speed 15m/min；
5）Apply the second protective layer：Continue to coat acrylic resin modified and isocyanate mixture on the first protective layer, be formed
Second protective layer is dried at 90 DEG C, speed 20m/min；
6）Clean ink：The ink for coating extra is cleaned up；；
7）Constant temperature oven cures：Product is put into constant temperature oven and successively cures 36h, solidification temperature is 75 DEG C；
8）Rewinding；
9）It is vacuum aluminum-coated：Product progress after solidification is vacuum aluminum-coated, when vacuum degree reaches 10, carried out on aluminium wire to evaporation boat
Dissolving is sprayed on the second protective layer；
10）Wash aluminium：The pond that product after aluminizing is 5 meters by length, the position for not needing aluminium layer is cleaned up completely；
11）Secondary rewinding；
12）Rubberised layer：Chlorinated polypropylene, chlorination EUA, aldehyde ketone resin, adhesion promoter and solvent are mixed in proportion,
The secondary set glue of glue is formed by glue-line in layer surface of aluminizing using electronical line shaft glue spreader, and dry；
13）Transfer：It is that 80 degree of silica gel wheel is heated to 260 DEG C by hardness, by the thermal energy of silica gel wheel, extruding force by heat transfer film
Decorative pattern transfer on the substrate.
Further, the step 13）In stock be ABS, AS, PS, PC, PP, metal, timber and glass.
The wear-resisting seamless silver lustre rear enclosure glue heat transfer film that is prepared is bright-colored, three-dimensional sense is strong, level is abundant, surface
Smooth, strong adhesive force, wear-resisting property are good, easy to operate, efficient pollution-free.Silver lustre rear enclosure glue can accomplish that glue-line is scalable
0.5mm（Glue-line and ink layer）, release scalable 0.5mm（Glue-line and release layer）.Heat transfer film is made applying area and window region,
The position for there are picture and text is provided with release layer, ink layer, the first protective layer, the second protective layer, aluminium coated and glue-line, without picture and text
Position do not have release layer, ink layer, the first protective layer, the second protective layer, aluminium coated and glue-line, will not on workpiece after transfer
Have any trace, remaining film, overlap, have high brightness, strong adhesive force, word are clear, glue tracks are small, transfer after plastics part
The advantages such as upper no dirty point.
The performance of wear-resisting seamless silver lustre rear enclosure glue heat transfer film in embodiment is tested, it is as a result as follows：
Using instrument：GT-7035-UB ultraviolet lights, 45 watts carry out color inhibition detection, ultra violet lamp 4 hours, test to embodiment
As a result it is xanthochromia class 4 grade or more.
Using instrument：Abrasion-resistant testing machine, counterweight loading 0.5KG, friction media are that erasing rubber is wear-resisting to embodiment progress
Detection, friction 3000 times or more is without abrasion.
Film surface after dipping in alcohol wipe transfer with cloth, is wiped 25 times, colour-fast, surface is bright back and forth with 200g pressure with alcohol
Degree does not change.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting.Although with reference to compared with
Good embodiment describes the invention in detail, it will be understood by those of ordinary skill in the art that, it can be to the technology of invention
Scheme is modified or replaced equivalently, and without departing from the range of technical solution of the present invention, should all cover the power in the present invention
In sharp claimed range.
Claims (8)
1. a kind of wear-resisting seamless silver lustre rear enclosure glue heat transfer film, which is characterized in that including applying area（1）And window region（2）, institute
State applying area（1）Include from top to bottom PET basement membranes successively（10）, release layer（11）, ink layer（12）, the first protective layer（13）、
Second protective layer（14）, aluminium coated（15）And glue-line（16）, the window region（2）For PET basement membranes（10）, the glue-line（16）Packet
Include the component of following weight fraction：Chlorinated polypropylene 22 ~ 30%；Chlorination EUA3 ~ 7%；Aldehyde ketone resin 5 ~ 10%；Adhesion promoter 5
~10%；Solvent 45 ~ 55%.
2. wear-resisting seamless silver lustre rear enclosure glue heat transfer film according to claim 1, which is characterized in that first protection
Layer（13）For 150 ~ 175 mesh.
3. wear-resisting seamless silver lustre rear enclosure glue heat transfer film according to claim 1, which is characterized in that second protection
Layer（14）For 175 ~ 200 mesh.
4. wear-resisting seamless silver lustre rear enclosure glue heat transfer film according to claim 1, which is characterized in that first protection
Layer（13）Thickness be 0.1 ~ 0.15mm, the second protective layer（14）Thickness be 0.05 ~ 0.1mm.
5. wear-resisting seamless silver lustre rear enclosure glue heat transfer film according to claim 1, which is characterized in that described first,
Two protective layers（13）（14）Including acrylic resin modified and isocyanates, acrylic resin modified and isocyanates weight
Than being 9 ~ 13：1.
6. wear-resisting seamless silver lustre rear enclosure glue heat transfer film according to claim 1, which is characterized in that the PET basement membranes
（10）For transparent smooth surface structure.
7. the production technology of the wear-resisting seamless silver lustre rear enclosure glue heat transfer film as described in claim 1 ~ 6, which is characterized in that packet
Include following steps：
1）PET basement membranes：The smooth PET basement membranes in surface are chosen, it is spare after cleaning and drying；
2）Apply release layer：Use two kinds of acrylic acid that molecular weight is 110 for 11000, TG points and molecular weight is 5800, TG points are 98
Resin is merged with lipid solvent and benzene kind solvent, the flowability liquid that solid content is 25% is formed, using the side of intaglio printing
Formula is coated on the applying area of PET basement membranes, and the halftone cable used is 150 ~ 220 lines/inch, and coating machine speed is 30 ~ 60m/
Min is dried after the completion of coating at 60 ~ 75 DEG C；It is 70 lines that release layer, which is coated with line number, and wet coating amount is 6.0-7.0g/m2, dry-coated
Cloth amount is 1.2-1.4g/m2；
3）Oiling layer of ink：Using electronical line shaft printing machine in release layer surface printing ink layer, print speed printing speed is 80 ~ 120m/min,
Ink layer uses high-temperature resisting pigment ink；
4）Apply the first protective layer：Acrylic resin modified and isocyanates is uniformly mixed, using the side of electronical line shaft intaglio printing
Formula coats the first protective layer on ink layer, is dried at 90 ~ 100 DEG C, and speed is 10 ~ 20m/min；
5）Apply the second protective layer：Continue to coat acrylic resin modified and isocyanate mixture on the first protective layer, be formed
Second protective layer is dried at 80 ~ 90 DEG C, and speed is 10 ~ 20m/min；
6）Clean ink：The ink for coating extra is cleaned up；
7）Constant temperature oven cures：By product be put into constant temperature oven successively solidification 16 ~ for 24 hours, solidification temperature be 60 ~ 70 DEG C；
8）Rewinding；
9）It is vacuum aluminum-coated：Product progress after solidification is vacuum aluminum-coated, when vacuum degree reaches 10, carried out on aluminium wire to evaporation boat
Dissolving is sprayed on the second protective layer；
10）Wash aluminium：The pond that product after aluminizing is 5 meters by length, the position for not needing aluminium layer is cleaned up completely；
11）Secondary rewinding；
12）Rubberised layer：Chlorinated polypropylene, chlorination EUA, aldehyde ketone resin, adhesion promoter and solvent are mixed in proportion,
The secondary set glue of glue is formed by glue-line in layer surface of aluminizing using electronical line shaft glue spreader, and dry；
13）Transfer：It is that 80 degree of silica gel wheel is heated to 260 DEG C by hardness, by the thermal energy of silica gel wheel, extruding force by heat transfer film
Decorative pattern transfer on the substrate.
8. the production technology of wear-resisting seamless silver lustre rear enclosure glue heat transfer film according to claim 7, which is characterized in that institute
State step 13）In stock be ABS, AS, PS, PC, PP, metal, timber and glass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810335803.0A CN108528079A (en) | 2018-04-16 | 2018-04-16 | The wear-resisting local dumb light heat transfer film of one kind and its production technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810335803.0A CN108528079A (en) | 2018-04-16 | 2018-04-16 | The wear-resisting local dumb light heat transfer film of one kind and its production technology |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108528079A true CN108528079A (en) | 2018-09-14 |
Family
ID=63480181
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810335803.0A Pending CN108528079A (en) | 2018-04-16 | 2018-04-16 | The wear-resisting local dumb light heat transfer film of one kind and its production technology |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109593493A (en) * | 2018-11-30 | 2019-04-09 | 香洋新材料（江苏）有限公司 | A kind of heat transfer film glue for TRITAN glasss of material surfaces decoration |
| CN112497946A (en) * | 2020-11-26 | 2021-03-16 | 武汉华工图像技术开发有限公司 | Electrochemical aluminum foil and preparation method thereof |
| CN114475070A (en) * | 2022-02-28 | 2022-05-13 | 广东远华新材料股份有限公司 | Transfer film and preparation method thereof, preparation method of PEVA decorative film and PEVA decorative film |
| CN114728538A (en) * | 2019-10-15 | 2022-07-08 | 雷恩哈德库兹基金两合公司 | Transfer film, member, and method for producing same |
| CN114749354A (en) * | 2022-03-17 | 2022-07-15 | 苏州万德福尔新材料有限公司 | Preparation method of hot stamping foil |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102310674A (en) * | 2010-07-01 | 2012-01-11 | 锣洋科技股份有限公司 | Decoration film, decoration device, and method for manufacturing decoration device |
| CN102774158A (en) * | 2012-07-31 | 2012-11-14 | 中国印刷科学技术研究所 | Large-breadth ultraviolet (UV) gold stamping method and hot stamping film |
| CN103303048A (en) * | 2012-03-12 | 2013-09-18 | 凸版印刷株式会社 | Decorative transfer Film and finished product |
| CN103862903A (en) * | 2012-12-11 | 2014-06-18 | 黄北江 | Novel water transfer printing coating film |
| TW201507879A (en) * | 2013-08-21 | 2015-03-01 | Ying-Chi Chan | Water transfer printing film of digital printing |
| CN206154928U (en) * | 2016-11-16 | 2017-05-10 | 上海鸿元展印有限公司 | No chromatography limit silver lustre bright gold effect rendition membrane |
| CN107599659A (en) * | 2017-08-28 | 2018-01-19 | 江苏学泰印务有限公司 | The production technology of pressure laser transfer printing film after a kind of |
| CN107629603A (en) * | 2017-10-19 | 2018-01-26 | 武汉华工图像技术开发有限公司 | Wear-resisting chromatograph coating and the wear-resisting chromatograph of formation, wear-resisting anodized aluminium and preparation method thereof |
| CN108543685A (en) * | 2018-04-16 | 2018-09-18 | 江苏学泰印务有限公司 | A kind of wear-resisting seamless silver lustre rear enclosure glue heat transfer film and its production technology |
-
2018
- 2018-04-16 CN CN201810335803.0A patent/CN108528079A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102310674A (en) * | 2010-07-01 | 2012-01-11 | 锣洋科技股份有限公司 | Decoration film, decoration device, and method for manufacturing decoration device |
| CN103303048A (en) * | 2012-03-12 | 2013-09-18 | 凸版印刷株式会社 | Decorative transfer Film and finished product |
| CN102774158A (en) * | 2012-07-31 | 2012-11-14 | 中国印刷科学技术研究所 | Large-breadth ultraviolet (UV) gold stamping method and hot stamping film |
| CN103862903A (en) * | 2012-12-11 | 2014-06-18 | 黄北江 | Novel water transfer printing coating film |
| TW201507879A (en) * | 2013-08-21 | 2015-03-01 | Ying-Chi Chan | Water transfer printing film of digital printing |
| CN206154928U (en) * | 2016-11-16 | 2017-05-10 | 上海鸿元展印有限公司 | No chromatography limit silver lustre bright gold effect rendition membrane |
| CN107599659A (en) * | 2017-08-28 | 2018-01-19 | 江苏学泰印务有限公司 | The production technology of pressure laser transfer printing film after a kind of |
| CN107629603A (en) * | 2017-10-19 | 2018-01-26 | 武汉华工图像技术开发有限公司 | Wear-resisting chromatograph coating and the wear-resisting chromatograph of formation, wear-resisting anodized aluminium and preparation method thereof |
| CN108543685A (en) * | 2018-04-16 | 2018-09-18 | 江苏学泰印务有限公司 | A kind of wear-resisting seamless silver lustre rear enclosure glue heat transfer film and its production technology |
Non-Patent Citations (1)
| Title |
|---|
| 邓建等: "《家庭工业致富新门路 100条》", vol. 1, 化学工业出版社, pages: 97 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109593493A (en) * | 2018-11-30 | 2019-04-09 | 香洋新材料（江苏）有限公司 | A kind of heat transfer film glue for TRITAN glasss of material surfaces decoration |
| CN114728538A (en) * | 2019-10-15 | 2022-07-08 | 雷恩哈德库兹基金两合公司 | Transfer film, member, and method for producing same |
| CN114728538B (en) * | 2019-10-15 | 2023-11-24 | 雷恩哈德库兹基金两合公司 | Transfer film, member, and method for producing same |
| CN112497946A (en) * | 2020-11-26 | 2021-03-16 | 武汉华工图像技术开发有限公司 | Electrochemical aluminum foil and preparation method thereof |
| CN112497946B (en) * | 2020-11-26 | 2022-07-29 | 武汉华工图像技术开发有限公司 | Electrochemical aluminum foil and preparation method thereof |
| CN114475070A (en) * | 2022-02-28 | 2022-05-13 | 广东远华新材料股份有限公司 | Transfer film and preparation method thereof, preparation method of PEVA decorative film and PEVA decorative film |
| CN114749354A (en) * | 2022-03-17 | 2022-07-15 | 苏州万德福尔新材料有限公司 | Preparation method of hot stamping foil |
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