CN114475070A - Transfer film and preparation method thereof, preparation method of PEVA decorative film and PEVA decorative film - Google Patents
Transfer film and preparation method thereof, preparation method of PEVA decorative film and PEVA decorative film Download PDFInfo
- Publication number
- CN114475070A CN114475070A CN202210188854.1A CN202210188854A CN114475070A CN 114475070 A CN114475070 A CN 114475070A CN 202210188854 A CN202210188854 A CN 202210188854A CN 114475070 A CN114475070 A CN 114475070A
- Authority
- CN
- China
- Prior art keywords
- film
- parts
- layer
- peva
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/04—Physical treatment, e.g. heating, irradiating
- D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Decoration By Transfer Pictures (AREA)
Abstract
The invention discloses a transfer film and a preparation method thereof, a preparation method of a PEVA decorative film and the PEVA decorative film. Wherein, the rendition membrane, including the substrate layer that sets gradually, from type layer, waterborne protective layer, aluminize layer and waterborne gum layer, its safety ring protects, and the pattern rendition rate on the aluminize layer is high. The PEVA decorative film is prepared by transferring the aluminum-plated pattern onto the PEVA film through the transfer printing film, and has good flexibility, good water resistance and wear resistance and biodegradability.
Description
Technical Field
The invention relates to the field of decorative films, in particular to a transfer film and a preparation method thereof, a preparation method of a PEVA decorative film and the PEVA decorative film.
Background
The table mat, the shower curtain and the like are products commonly used in home, can play a role in water resistance and separation, and can also be used as decorative materials to improve the attractiveness of indoor environment. Among them, the plastic table mat and bath curtain are popular because of their advantages of good waterproof property, strong processability, various styles, difficult yellowing and wrinkling.
The laser aluminized table mat is a transparent table mat with laser patterns, the laser patterns can show different colors when being observed from different angles, and the laser patterns are formed on materials through an aluminizing process. The laser aluminized table mat can be prepared by thermally transferring a laser pattern onto the base film through the transfer film. In the actual production of the table mat or bath curtain material, if the laser pattern to be transferred is composed of a plurality of dispersed fine patterns, such as stars, flowers and the like, the problem of incomplete pattern transfer often occurs after the transfer, and part of the pattern is stripped along with the substrate layer.
In addition, the existing laser aluminized decorative film has the problems of difficult degradation, organic solvent volatilization and the like which are not environment-friendly. Some products adopt a base film containing a plasticizer and heavy metals, and if the base film is used as a table mat, the safety of dining is seriously threatened.
It is seen that improvements and enhancements to the prior art are needed.
Disclosure of Invention
In view of the defects of the prior art, the invention aims to provide a transfer film and a preparation method thereof, a preparation method of a PEVA decorative film and the PEVA decorative film, and aims to solve the technical problem of incomplete transfer of an aluminum-plated layer pattern on the transfer film in the prior art and improve the environmental protection and safety of the decorative film.
In order to achieve the purpose, the invention adopts the following technical scheme:
a transfer printing film comprises a base material layer, a release layer, a water-based protective layer, an aluminum-plated layer and a water-based back glue layer which are sequentially arranged; the water-based back glue layer comprises the following components in parts by weight: 20-30 parts of waterborne polyamide resin, 60-80 parts of waterborne polyurethane resin, 1-3 parts of vinyl alkoxy phosphate, 0.1-0.3 part of defoaming agent and 0.1-0.5 part of inorganic antibacterial mildew preventive.
The transfer printing film comprises the following components in parts by weight: 60-70 parts of water-based acrylic resin, 20-30 parts of water-based epoxy resin and 0.2-0.5 part of flatting agent.
The transfer printing film is characterized in that the leveling agent is an organic silicon leveling agent.
The transfer printing film comprises a release layer and a transfer printing layer, wherein the release layer comprises the following components in parts by weight: 8-10 parts of polyethylene glycol, 4-5 parts of non-silicon release agent and 68-70 parts of isopropanol.
The transfer printing film, wherein the inorganic antibacterial mildew preventive contains nano TiO2Or nano Ag-TiO2A particulate inorganic phosphate.
The transfer printing film, wherein, the substrate layer is the PP membrane.
A preparation method of a transfer printing film is used for preparing the transfer printing film and comprises the following steps:
a001, coating a release agent on the substrate layer, and drying to obtain a release layer;
step A002, coating a water-based protective layer on the release layer, and drying;
step A003, aluminum plating is carried out on the aqueous protective layer to form an aluminum plated layer;
and step A004, coating a water-based back glue layer on the aluminum plating layer, and drying to obtain the transfer printing film.
The preparation method of the transfer printing film comprises the step A004, wherein the drying temperature is 80-100 ℃, and the time is 4-6 minutes.
A preparation method of a PEVA decorative film comprises the following steps of:
s001, adding 20-40 parts of PE and 60-80 parts of EVA into a high-speed mixer for mixing;
s002, preparing a bottom film from the mixed material through a tape casting process; in the casting process, the temperature is controlled at 180-200 ℃;
step S003, before the basement membrane is cooled and shaped, the surface of the basement membrane is pasted with the transfer printing film, the pattern on the transfer printing film is transferred to the basement membrane through thermal bonding, the base material layer is torn down, cooled and rolled to obtain the PEVA decorative film.
The PEVA decorative film prepared by the preparation method has good flexibility, good water resistance and wear resistance and is biodegradable.
Has the advantages that:
the invention provides a transfer printing film, which adopts a water-based protective layer and a water-based back glue layer, avoids the use of an organic solvent, and ensures the safety and environmental protection in the manufacturing and using processes. In addition, the vinyl alkoxy phosphate is added into the water-based back glue layer, so that the binding capacity to metal materials can be increased, the aluminum-plated materials can be better transferred to the bottom film, and the reject ratio of products is reduced.
The invention also provides a preparation method of the transfer printing film, which is safe and environment-friendly, does not generate organic solvents, does not cause toxicity to production workers, and does not discharge harmful waste gas.
The invention also provides a preparation method of the PEVA decorative film, the transfer printing film is attached after the bottom film is subjected to the casting process, the transfer printing process is integrated into the existing bottom film production process, the manufacturing efficiency is improved, and the manufacturing steps and the energy consumption are reduced.
The invention also provides the PEVA decorative film which is a non-toxic, safe and environment-friendly material, has good biodegradability, is environment-friendly, and has good flexibility and good water resistance and wear resistance.
Detailed Description
The present invention provides a transfer film and a method for preparing the same, a method for preparing a PEVA decorative film, and the present invention is further described in detail below with reference to examples in order to make the objects, technical solutions, and effects of the present invention clearer and clearer. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
The invention provides a transfer printing film which comprises a base material layer, a release layer, a water-based protective layer, an aluminum-plated layer and a water-based back glue layer, wherein the base material layer, the release layer, the water-based protective layer, the aluminum-plated layer and the water-based back glue layer are sequentially arranged; the water-based back glue layer comprises the following components in parts by weight: 20-30 parts of waterborne polyamide resin, 60-80 parts of waterborne polyurethane resin, 1-3 parts of vinyl alkoxy phosphate, 0.1-0.3 part of defoaming agent and 0.1-0.5 part of inorganic antibacterial mildew preventive. Wherein, the waterborne polyamide resin and the waterborne polyurethane resin have the best bonding effect when matched under the proportion range. Due to the existence of the phosphoric acid group, the vinyl alkoxy phosphate can generate a compact passivated phosphate structure with the metal material aluminum, the connection with the aluminum is strengthened, and therefore, the transfer printing rate of the aluminum plating pattern is obviously improved, and in addition, the vinyl alkoxy phosphate can also improve the reaction stability, the wetting dispersibility and the gloss. The inorganic antibacterial mildew inhibitor is used for prolonging the service life of products and inhibiting the occurrence of bacterial plaque and mildew.
The water-based protective layer comprises the following components in parts by weight: 60-70 parts of water-based acrylic resin, 20-30 parts of water-based epoxy resin and 0.2-0.5 part of flatting agent. Wherein the aqueous acrylic resin can improve the water resistance and wear resistance of the aqueous protective layer. The aqueous epoxy resin can improve the flexibility of the aqueous protective layer and can improve the curing speed.
The leveling agent is an organic silicon leveling agent. The organosilicon leveling agent can increase the fluidity of system components and improve the water resistance and flexibility of the protective layer.
The release layer comprises the following components in parts by weight: 8-10 parts of polyethylene glycol, 4-5 parts of non-silicon release agent and 68-70 parts of isopropanol. The stripping effect of the base material layer is best under the component proportion.
The inorganic antibacterial mildew inhibitor is a compound containing nano TiO2Or nano Ag-TiO2Particulate inorganic phosphate, nano TiO2Or the silver ions have broad-spectrum antibacterial and bactericidal effects, so that the transfer printing film can keep long-acting antibacterial effect after transfer printing, and the occurrence of bacterial plaque is inhibited.
The substrate layer is a PP film. The PP film has good toughness and higher tensile strength, is not easy to break when being peeled off, and is convenient to recycle.
A preparation method of a transfer printing film is used for preparing the transfer printing film and comprises the following steps:
a001, coating a release agent on the substrate layer, and drying to obtain a release layer;
step A002, coating a water-based protective layer on the release layer, and drying;
step A003, aluminum plating is carried out on the aqueous protective layer to form an aluminum plated layer; specifically, the aluminum plating layer can be a pattern or a pattern with a laser effect, such as a star pattern, letters, cartoon patterns and the like.
And step A004, coating a water-based back glue layer on the aluminum plating layer, and drying to obtain the transfer printing film.
In the step A004, the drying temperature is 80-100 ℃, and the drying time is 4-6 minutes.
A preparation method of a PEVA decorative film comprises the following steps of:
s001, adding 20-40 parts of PE and 60-80 parts of EVA into a high-speed mixer for mixing;
s002, preparing a bottom film from the mixed material through a tape casting process; in the casting process, the temperature is controlled at 180-200 ℃;
step S003, before the basement membrane is cooled and shaped, the surface of the basement membrane is pasted with the transfer printing film, the pattern on the transfer printing film is transferred to the basement membrane through thermal bonding, the base material layer is torn down, cooled and rolled to obtain the PEVA decorative film.
When the temperature of the PEVA base film prepared after the casting process is finished is kept at 180-200 ℃, the transfer film is subjected to heat lamination, and the heat lamination process is arranged before cooling and shaping, so that the preparation efficiency can be improved, and the energy consumption can be reduced. The PEVA bottom film does not need to be preheated again.
A PEVA decorative film is prepared by the preparation method of the PEVA decorative film. The protective layer, the aluminum coating and the back glue layer of the transfer printing film are attached to the PEVA base film after transfer printing, the obtained PEVA decorative film is good in transparency and flexibility, the inorganic antibacterial mildew preventive in the back glue can also be used for inhibiting bacterial plaque on the PEVA base film, and the attractiveness and sanitary safety of the PEVA decorative film are kept.
Example 1
A transfer printing film comprises a base material layer, a release layer, a water-based protective layer, an aluminum-plated layer and a water-based back glue layer which are sequentially arranged; the water-based back glue layer comprises the following components in parts by weight: 20 parts of waterborne polyamide resin, 78 parts of waterborne polyurethane resin, 2 parts of vinyl alkoxy phosphate, 0.1 part of defoaming agent and 0.5 part of inorganic antibacterial mildew inhibitor. The inorganic antibacterial mildew inhibitor is a compound containing nano TiO2Or nano Ag-TiO2A particulate inorganic phosphate.
The substrate layer is a PP film.
The water-based protective layer comprises the following components in parts by weight: 65 parts of water-based acrylic resin, 28 parts of water-based epoxy resin and 0.2 part of flatting agent; the leveling agent is an organic silicon leveling agent.
The release layer comprises the following components in parts by weight: 10 parts of polyethylene glycol, 5 parts of non-silicon release agent and 70 parts of isopropanol.
A preparation method of a transfer printing film is used for preparing the transfer printing film and comprises the following steps:
a001, coating a release agent on the substrate layer, and drying to obtain a release layer;
step A002, coating a water-based protective layer on the release layer, and drying;
step A003, aluminum plating is carried out on the aqueous protective layer to form an aluminum plated layer;
and step A004, coating a water-based back glue layer on the aluminum plating layer, and drying to obtain the transfer printing film.
In the step A004, the drying temperature is 90 ℃ and the drying time is 6 minutes.
Example 2
A transfer printing film comprises a base material layer, a release layer, a water-based protective layer, an aluminum-plated layer and a water-based back glue layer which are sequentially arranged; the water-based back glue layer comprises the following components in parts by weight: 28 parts of waterborne polyamide resin, 60 parts of waterborne polyurethane resin, 2.5 parts of vinyl alkoxy phosphate, 0.3 part of defoaming agent and 0.2 part of inorganic antibacterial mildew inhibitor. The inorganic antibacterial mildew inhibitor is a compound containing nano TiO2Or nano Ag-TiO2A particulate inorganic phosphate.
The substrate layer is a PP film.
The water-based protective layer comprises the following components in parts by weight: 60 parts of water-based acrylic resin, 30 parts of water-based epoxy resin and 0.5 part of flatting agent; the leveling agent is an organic silicon leveling agent.
The release layer comprises the following components in parts by weight: 10 parts of polyethylene glycol, 5 parts of non-silicon release agent and 70 parts of isopropanol.
A preparation method of a transfer printing film is used for preparing the transfer printing film and comprises the following steps:
a001, coating a release agent on the substrate layer, and drying to obtain a release layer;
step A002, coating a water-based protective layer on the release layer, and drying;
step A003, aluminum plating is carried out on the aqueous protective layer to form an aluminum plated layer;
and step A004, coating a water-based back glue layer on the aluminum plating layer, and drying to obtain the transfer printing film.
In the step A004, the drying temperature is 100 ℃, and the time is 4 minutes.
Example 3
A transfer printing film comprises a base material layer, a release layer, a water-based protective layer, an aluminum-plated layer and a water-based back glue layer which are sequentially arranged; the water-based back glue layer comprises the following components in parts by weight: 30 parts of waterborne polyamide resin, 70 parts of waterborne polyurethane resin, 2 parts of vinyl alkoxy phosphate, 0.1 part of defoaming agent and 0.2 part of inorganic antibacterial mildew inhibitor. The inorganic antibacterial mildew inhibitor is a compound containing nano TiO2Or nano Ag-TiO2A particulate inorganic phosphate.
The substrate layer is a PP film.
The water-based protective layer comprises the following components in parts by weight: 65 parts of water-based acrylic resin, 28 parts of water-based epoxy resin and 0.2 part of flatting agent; the leveling agent is an organic silicon leveling agent.
The release layer comprises the following components in parts by weight: 10 parts of polyethylene glycol, 5 parts of non-silicon release agent and 70 parts of isopropanol.
A preparation method of a transfer printing film is used for preparing the transfer printing film and comprises the following steps:
a001, coating a release agent on the substrate layer, and drying to obtain a release layer;
step A002, coating a water-based protective layer on the release layer, and drying;
step A003, aluminum plating is carried out on the aqueous protective layer to form an aluminum plated layer;
and step A004, coating a water-based back glue layer on the aluminum plating layer, and drying to obtain the transfer printing film.
In the step A004, the drying temperature is 90 ℃ and the drying time is 6 minutes.
Example 4
A PEVA decorative film and a preparation method thereof comprise the following steps:
s001, adding 20 parts of PE and 80 parts of EVA into a high-speed mixer for mixing;
s002, preparing a bottom film from the mixed material through a tape casting process; in the casting process, the temperature is controlled at 190 ℃;
and S003, before cooling and shaping the bottom film, adhering the transfer printing film prepared in the embodiment 1 to the surface of the bottom film, transferring the pattern patterns on the transfer printing film to the bottom film through hot adhesion for 30s, tearing off the PP film base material layer, cooling and rolling to obtain the PEVA decorative film.
Example 5
A PEVA decorative film and a preparation method thereof comprise the following steps:
s001, adding 30 parts of PE and 70 parts of EVA into a high-speed mixer for mixing;
s002, preparing a bottom film from the mixed material through a tape casting process; in the casting process, the temperature is controlled at 200 ℃;
and S003, before cooling and shaping the bottom film, adhering the transfer printing film prepared in the embodiment 2 to the surface of the bottom film, transferring the pattern patterns on the transfer printing film to the bottom film through hot adhesion for 30s, tearing off the PP film base material layer, cooling and rolling to obtain the PEVA decorative film.
Example 6
A PEVA decorative film and a preparation method thereof comprise the following steps:
s001, adding 30 parts of PE and 70 parts of EVA into a high-speed mixer for mixing;
s002, preparing a bottom film from the mixed material through a tape casting process; in the casting process, the temperature is controlled at 200 ℃;
and S003, before cooling and shaping the bottom film, adhering the transfer printing film prepared in the embodiment 3 to the surface of the bottom film, transferring the pattern patterns on the transfer printing film to the bottom film through hot adhesion for 30s, tearing off the PP film base material layer, cooling and rolling to obtain the PEVA decorative film.
In examples 3 to 6, the aluminum plating pattern was completely transferred to the PEVA film after peeling the PP film, and the obtained PEVA decorative film was high in transparency and good in flexibility, and the surface of the PEVA decorative film was good in dry-through property and was not sticky. The PP film is smoothly stripped without obvious protective layer residue.
It should be understood that equivalents and modifications of the technical solution and inventive concept thereof may occur to those skilled in the art, and all such modifications and alterations should fall within the scope of the appended claims.
Claims (10)
1. The transfer printing film is characterized by comprising a base material layer, a release layer, a water-based protective layer, an aluminum plating layer and a water-based back glue layer which are sequentially arranged; the water-based back glue layer comprises the following components in parts by weight: 20-30 parts of waterborne polyamide resin, 60-80 parts of waterborne polyurethane resin, 1-3 parts of vinyl alkoxy phosphate, 0.1-0.3 part of defoaming agent and 0.1-0.5 part of inorganic antibacterial mildew preventive.
2. The transfer film according to claim 1, wherein the aqueous protective layer comprises the following components in parts by weight: 60-70 parts of water-based acrylic resin, 20-30 parts of water-based epoxy resin and 0.2-0.5 part of flatting agent.
3. The transfer film according to claim 2, wherein the leveling agent is an organosilicon leveling agent.
4. The transfer film according to claim 1, wherein the release layer comprises the following components in parts by weight: 8-10 parts of polyethylene glycol, 4-5 parts of non-silicon release agent and 68-70 parts of isopropanol.
5. The transfer film according to claim 1, wherein the inorganic antibacterial and antifungal agent is a film containing nano-TiO2Or nano Ag-TiO2A particulate inorganic phosphate.
6. The transfer film according to claim 1, wherein the substrate layer is a PP film.
7. A method for manufacturing a transfer film, the method being used for manufacturing the transfer film according to any one of claims 1 to 6, comprising the steps of:
a001, coating a release agent on the substrate layer, and drying to obtain a release layer;
step A002, coating a water-based protective layer on the release layer, and drying;
step A003, aluminum plating is carried out on the aqueous protective layer to form an aluminum plated layer;
and step A004, coating a water-based back glue layer on the aluminum plating layer, and drying to obtain the transfer printing film.
8. The method according to claim 7, wherein in the step a004, the baking temperature is 80 to 100 ℃ and the time is 4 to 6 minutes.
9. The preparation method of the PEVA decorative film is characterized by comprising the following steps of:
s001, adding 20-40 parts of PE and 60-80 parts of EVA into a high-speed mixer for mixing;
s002, preparing a bottom film from the mixed material through a tape casting process; in the casting process, the temperature is controlled at 180-200 ℃;
step S003, before the base film is cooled and shaped, the transfer printing film of any one of claims 1 to 6 is adhered to the surface of the base film, the decorative pattern on the transfer printing film is transferred to the base film through thermal bonding, the base material layer is torn off, cooled and rolled, and the PEVA decorative film is obtained.
10. A PEVA decorative film, characterized by being produced by the production method of the PEVA decorative film of claim 9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210188854.1A CN114475070B (en) | 2022-02-28 | 2022-02-28 | PEVA decorative film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210188854.1A CN114475070B (en) | 2022-02-28 | 2022-02-28 | PEVA decorative film and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114475070A true CN114475070A (en) | 2022-05-13 |
| CN114475070B CN114475070B (en) | 2023-06-06 |
Family
ID=81485132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210188854.1A Active CN114475070B (en) | 2022-02-28 | 2022-02-28 | PEVA decorative film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114475070B (en) |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6277229B1 (en) * | 1995-08-25 | 2001-08-21 | Avery Dennison Corporation | Image transfer sheets and a method of manufacturing the same |
| JP2003320796A (en) * | 2002-02-27 | 2003-11-11 | Yoshino Kogyosho Co Ltd | Curved surface transfer sheet and transfer method, and molded object decorated by transfer method |
| US20040202828A1 (en) * | 2002-02-07 | 2004-10-14 | C.I. Kasei Company, Limited | Decorative sheet and method for producing the same |
| CN104263311A (en) * | 2014-09-04 | 2015-01-07 | 武汉华工图像技术开发有限公司 | UV (ultraviolet) cold stamping glue |
| CN105802570A (en) * | 2016-05-15 | 2016-07-27 | 上海万汉实业有限公司 | Transfer water-based hot-melt adhesive and preparation method thereof |
| CN105818560A (en) * | 2016-04-05 | 2016-08-03 | 云南玉溪东魅包装材料有限公司 | Environment-friendly skip hot-stamping alumite hot-stamping foil and preparation method thereof |
| CN106317796A (en) * | 2015-07-02 | 2017-01-11 | 江苏华信新材料股份有限公司 | PETG cast film and preparation process thereof |
| CN106349957A (en) * | 2016-08-30 | 2017-01-25 | 惠州市赛亚实业有限公司 | Aluminizing-packaged solvent-residue-free adhesive and preparing method thereof |
| JP2017179116A (en) * | 2016-03-30 | 2017-10-05 | 日本ゼオン株式会社 | Stripe pattern-like self-adsorptive foam sheet |
| CN108528079A (en) * | 2018-04-16 | 2018-09-14 | 江苏学泰印务有限公司 | The wear-resisting local dumb light heat transfer film of one kind and its production technology |
| CN109666442A (en) * | 2018-12-19 | 2019-04-23 | 湖北银琅兴科技发展有限公司 | A kind of aqueous novel environment friendly thermal transfer glue |
| CN110157083A (en) * | 2019-04-09 | 2019-08-23 | 东莞市宏恩塑胶制品有限公司 | One kind climb pad foamed material and application its made from climb pad and preparation process |
| CN112026420A (en) * | 2020-09-09 | 2020-12-04 | 浙江驰怀烫印科技股份有限公司 | Highlight gold stamping foil |
-
2022
- 2022-02-28 CN CN202210188854.1A patent/CN114475070B/en active Active
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6277229B1 (en) * | 1995-08-25 | 2001-08-21 | Avery Dennison Corporation | Image transfer sheets and a method of manufacturing the same |
| US20040202828A1 (en) * | 2002-02-07 | 2004-10-14 | C.I. Kasei Company, Limited | Decorative sheet and method for producing the same |
| JP2003320796A (en) * | 2002-02-27 | 2003-11-11 | Yoshino Kogyosho Co Ltd | Curved surface transfer sheet and transfer method, and molded object decorated by transfer method |
| CN104263311A (en) * | 2014-09-04 | 2015-01-07 | 武汉华工图像技术开发有限公司 | UV (ultraviolet) cold stamping glue |
| CN106317796A (en) * | 2015-07-02 | 2017-01-11 | 江苏华信新材料股份有限公司 | PETG cast film and preparation process thereof |
| JP2017179116A (en) * | 2016-03-30 | 2017-10-05 | 日本ゼオン株式会社 | Stripe pattern-like self-adsorptive foam sheet |
| CN105818560A (en) * | 2016-04-05 | 2016-08-03 | 云南玉溪东魅包装材料有限公司 | Environment-friendly skip hot-stamping alumite hot-stamping foil and preparation method thereof |
| CN105802570A (en) * | 2016-05-15 | 2016-07-27 | 上海万汉实业有限公司 | Transfer water-based hot-melt adhesive and preparation method thereof |
| CN106349957A (en) * | 2016-08-30 | 2017-01-25 | 惠州市赛亚实业有限公司 | Aluminizing-packaged solvent-residue-free adhesive and preparing method thereof |
| CN108528079A (en) * | 2018-04-16 | 2018-09-14 | 江苏学泰印务有限公司 | The wear-resisting local dumb light heat transfer film of one kind and its production technology |
| CN109666442A (en) * | 2018-12-19 | 2019-04-23 | 湖北银琅兴科技发展有限公司 | A kind of aqueous novel environment friendly thermal transfer glue |
| CN110157083A (en) * | 2019-04-09 | 2019-08-23 | 东莞市宏恩塑胶制品有限公司 | One kind climb pad foamed material and application its made from climb pad and preparation process |
| CN112026420A (en) * | 2020-09-09 | 2020-12-04 | 浙江驰怀烫印科技股份有限公司 | Highlight gold stamping foil |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114475070B (en) | 2023-06-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101292003A (en) | Polyfunctional epoxy resin coating composition containing rust-preventive pigment, coating film obtained therefrom, base coated with the coating film, and method of rust prevention | |
| CN102533068B (en) | Ultraviolet curing aluminized transferring coating and preparation method and application thereof | |
| CN104263233B (en) | A kind of temporary protective coating compositions based on modified polyurethane and preparation method thereof | |
| CN106893423A (en) | Agricultural machinery aqueous amino-stoving varnish and preparation method thereof | |
| CN103045044A (en) | Energy-saving and environment-friendly powder coating and preparation method thereof | |
| CN101613559A (en) | Hydrophilic nano zinc based composite coating | |
| CN102791478A (en) | Black metal sheet | |
| CN106967357A (en) | Environment-friendly type aqueous Stripable paint and preparation | |
| CN108300277A (en) | A kind of 3D laser carvings high-flexibility UV type PVD finishing coats | |
| CN102414018A (en) | Protective film for automotive wheel | |
| CN102311715A (en) | Healant for chemical pipes and preparation method thereof | |
| WO2000058086A1 (en) | Protective coating of metal and product therefrom | |
| CN110615957A (en) | Strippable protective film and preparation method thereof | |
| CN105462323A (en) | Peelable chemical-erosion-resistant protective paint and preparation method and application thereof | |
| CN107286319A (en) | A kind of water-borne UV-curing resin of organic fluorine richness and preparation method thereof | |
| CN112694805A (en) | Low-temperature baking water-based electrosilvering coating and preparation method thereof | |
| CN110724447A (en) | Water-based digital printing primer and preparation method thereof | |
| CN108395749A (en) | A kind of anticorrosive coating and preparation method thereof | |
| CN102516447A (en) | Synthetic method and application of urea monomer modified hydroxyl acrylic emulsion | |
| CN114475070A (en) | Transfer film and preparation method thereof, preparation method of PEVA decorative film and PEVA decorative film | |
| CN102505561A (en) | Electron beam curing surface protective coating for direct vacuum aluminum-plated paper and preparation method thereof | |
| CN107011748A (en) | Glass inorganic agent and its application for glass plastic rubber member surface spray treatment | |
| CN112515321B (en) | Nail patch and method for manufacturing same | |
| CN102414017A (en) | Protective film for automotive wheel | |
| CN111621206A (en) | Color-adjustable water-based self-thickening building coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |