CN109593493A - A kind of heat transfer film glue for TRITAN glasss of material surfaces decoration - Google Patents
A kind of heat transfer film glue for TRITAN glasss of material surfaces decoration Download PDFInfo
- Publication number
- CN109593493A CN109593493A CN201811454060.5A CN201811454060A CN109593493A CN 109593493 A CN109593493 A CN 109593493A CN 201811454060 A CN201811454060 A CN 201811454060A CN 109593493 A CN109593493 A CN 109593493A
- Authority
- CN
- China
- Prior art keywords
- tritan
- parts
- glasss
- heat transfer
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/26—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention discloses a kind of heat transfer film glue for TRITAN glasss of material surfaces decoration, including following ingredient according to the mass fraction: 15-40 parts of modified chlorinated polyolefin；0-5 parts of vinyl chloride-vinyl acetate resin；5-10 parts of tackifying resin；1-5 parts of antiseize resin；50-85 parts of solvent.The heat transfer film glue and there can be excellent transfer fastness with TRITAN glass materials, and have to different hardness, different types of TRITAN material and preferably transfer fastness, versatility is preferable；And the glue has excellent water-fast, salt spray resistance, using boiling water boiling 4 hours or more performances without significant change；And the resin softening point that glue uses is moderate, there is outstanding anti-reflective viscosity energy, easily winds.
Description
Technical field
The present invention relates to the technical fields of adhesive, and in particular to a kind of heat turn for TRITAN glasss of material surfaces decoration
Die glue and preparation method thereof.
Background technique
TRITAN glasss of full name are Tritan Copolyester, are the copolyesters of new generation of Eastman company exploitation.Due to
Pursuit of the people to quality of the life and health, market also increasingly improves the environmental requirement of plastic cement raw material, relative to first
PC glasss, TRITAN glasss in polymerization production process without BPA ingredient, BPA will not be discharged in use, meet environmental requirement
And FDA, and TRITAN glasss are as clear as crystal, it is excellent in cushion effect, heatproof is high, easily molded, there is excellent anti-ization, hydrolytic resistance
Can, it is more and more in industrial applications such as articles for babies, cup and medical supplies.
Heat transfer film is a kind of dielectric material of caloric transfer printing technology.Thermal transfer decoration technology is disposable by heat transfer film
Decorative pattern in thermal transfer, is needed on the process on decorative building material surface, being formed high-quality facing film by heating.In thermal transfer
In the process, separate protective layer and pattern layer from polyester substrate using the collective effect of heat and pressure, hot melt adhesive makes entirely to fill
It adorns layer and substrate is permanently glued.Therefore, it is necessary to develop a kind of heat transfer film glue for TRITAN glasss of material surfaces decoration.
Summary of the invention
The object of the present invention is to provide a kind of heat transfer film glue and its system for TRITAN glasss of material surface decorations
Preparation Method solves one or more of the above-mentioned prior art problem.
The present invention provides a kind of heat transfer film glue for TRITAN glasss of material surfaces decoration, including presses mass fraction
The following ingredient of meter:
15-40 parts of modified chlorinated polyolefin；
0-5 parts of vinyl chloride-vinyl acetate resin；
5-10 parts of tackifying resin；
1-5 parts of antiseize resin；
50-85 parts of solvent.
In some embodiments, it is 35 maleic acid modified chlorinated polyolefins below that modified chlorinated polyolefin, which is chlorinity,
Hydrocarbon.
In some embodiments, vinyl chloride-vinyl acetate resin is carboxyl acid modified ternary chlorine vinegar resin.
In some embodiments, tackifying resin is one or more of Petropols, rosin resin.
In some embodiments, the flatting silica for the fumed silica system that antiseize resin is 10 microns of partial size <
In some embodiments, solvent be toluene, it is butanone, ethyl acetate, n-propyl acetate, a kind of in n-butyl acetate
Or it is several.
The utility model has the advantages that
1, the glue of the embodiment of the present invention can have excellent transfer fastness with TRITAN glasss of materials, and to different hardness, no
The TRITAN material of same type has preferable transfer fastness, and versatility is preferable；
2, the glue of the embodiment of the present invention had excellent water-fast, salt spray resistance, using boiling water boiling 4 hours or more performances
Without significant change；
3, the resin softening point that the glue of the embodiment of the present invention uses is moderate, there is outstanding anti-reflective viscosity energy, easily winds.
Specific embodiment
The present invention is described in more detail below by embodiment.
Embodiment 1
It is a kind of for TRITAN glasss of material surfaces decoration heat transfer film comprised the following steps that with glue production technique:
(1) first by whole solvents, i.e., 20 parts of toluene, 30 parts of ethyl acetate are put into reaction kettle, blender speed 800
Rev/min；
(2) it is kept stirring and is 35 maleic acid modified chloridized polyolefins below, 5 parts of petroleum by 15 parts of chlorinity
Resin is successively put into reaction kettle, is stirred 1 hour or so, 1000 revs/min of revolving speed；
(3) after stirring to solution clear, the delustring for the fumed silica system that the partial size for being added 1 part is 1 micron
Powder, stir 30min, 1000 revs/min of revolving speed
(4) it is packed using 220 mesh filter screen filtrations.
Embodiment 2
It is a kind of for TRITAN glasss of material surfaces decoration heat transfer film comprised the following steps that with glue production technique:
(1) first by whole solvents, i.e., 30 parts of butanone, 40 parts of ethyl acetate are put into reaction kettle, blender speed 800
Rev/min；
(2) it is kept stirring and is 35 maleic acid modified chloridized polyolefins below, 2 parts of carboxylic acid by 20 parts of chlorinity
Modified ternary chlorine vinegar resin, 8 parts of rosin resin are successively put into reaction kettle, are stirred 1 hour or so, 1000 revs/min of revolving speed
Clock；
(3) after stirring to solution clear, the delustring for the fumed silica system that the partial size for being added 2 parts is 5 microns
Powder, stir 30min, 1000 revs/min of revolving speed；
(4) it is packed using 220 mesh filter screen filtrations.
Embodiment 3
It is a kind of for TRITAN glasss of material surfaces decoration heat transfer film comprised the following steps that with glue production technique:
(1) first by whole solvents, i.e., 85 parts of ethyl acetate is put into reaction kettle, 800 revs/min of blender speed；
(2) it is kept stirring and is 35 maleic acid modified chloridized polyolefins below, 5 parts of carboxylic acid by 40 parts of chlorinity
Modified ternary chlorine vinegar resin, 10 parts of Petropols are successively put into reaction kettle, are stirred 1 hour or so, 1000 revs/min of revolving speed
Clock；
(3) after stirring to solution clear, the delustring for the fumed silica system that the partial size for being added 5 parts is 9 microns
Powder, stir 30min, 1000 revs/min of revolving speed；
(4) it is packed using 220 mesh filter screen filtrations.
The heat transfer film glue for being used for TRITAN glasss of material surfaces decoration that embodiment 1 is produced is coated with by following technique
It is tested for the property on heat transfer film: wherein heat transfer film technique: PET- mould release-ink.For TRITAN glasss of material tables
The heat transfer film glue knitting technology of face decoration: above-mentioned glue is diluted by 40%, 150-175 mesh anilox roll using esters solvent
Coating, machine speed 100m/min, drying temperature is at 100 DEG C or so.The transfer film of coated glue is transferred to TRITAN glasss of base
On material, it is tested for the property.
Minimum turn of the heat transfer film glue for TRITAN glasss of material surfaces decoration of the exploitation of the embodiment of the present invention 1
Print temperature, transfer fastness, anti-reflective viscosity energy, transparency and cutting property meet test request.
The heat transfer film glue and existing transfer film for TRITAN glasss of material surfaces decoration of the embodiment of the present invention
It is compared with glue:
1, the glue of the embodiment of the present invention can have excellent transfer fastness with TRITAN glasss of materials, and to different hardness, no
The TRITAN material of same type has preferable transfer fastness, and versatility is preferable；
2, the glue of the embodiment of the present invention had excellent water-fast, salt spray resistance, using boiling water boiling 4 hours or more performances
Without significant change；
3, the resin softening point that the glue of the embodiment of the present invention uses is moderate, there is outstanding anti-reflective viscosity energy, easily winds.
What has been described above is only a preferred embodiment of the present invention, it is noted that for those skilled in the art,
Without depart from that overall concept of the invention, several changes and improvements can also be made, these also should be considered as of the invention
Protection scope.
Claims (6)
1. a kind of heat transfer film glue for TRITAN glasss of material surfaces decoration, which is characterized in that including pressing mass fraction
The following ingredient of meter:
15-40 parts of modified chlorinated polyolefin；
0-5 parts of vinyl chloride-vinyl acetate resin；
5-10 parts of tackifying resin；
1-5 parts of antiseize resin；
50-85 parts of solvent.
2. a kind of heat transfer film glue for TRITAN glasss of material surfaces decoration according to claim 1, feature
It is, the modified chlorinated polyolefin is that chlorinity is 35 maleic acid modified chloridized polyolefins below.
3. a kind of heat transfer film glue for TRITAN glasss of material surfaces decoration according to claim 1, feature
It is, the vinyl chloride-vinyl acetate resin is carboxyl acid modified ternary chlorine vinegar resin.
4. a kind of heat transfer film glue for TRITAN glasss of material surfaces decoration according to claim 1, feature
It is, the tackifying resin is one or more of Petropols, rosin resin.
5. a kind of heat transfer film glue for TRITAN glasss of material surfaces decoration according to claim 1, feature
It is, the flatting silica for the fumed silica system that the antiseize resin is 10 microns of partial size <.
6. a kind of heat transfer film glue for TRITAN glasss of material surfaces decoration according to claim 1, feature
It is, the solvent is toluene, butanone, ethyl acetate, n-propyl acetate, one or more of in n-butyl acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811454060.5A CN109593493A (en) | 2018-11-30 | 2018-11-30 | A kind of heat transfer film glue for TRITAN glasss of material surfaces decoration |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811454060.5A CN109593493A (en) | 2018-11-30 | 2018-11-30 | A kind of heat transfer film glue for TRITAN glasss of material surfaces decoration |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109593493A true CN109593493A (en) | 2019-04-09 |
Family
ID=65959978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811454060.5A Pending CN109593493A (en) | 2018-11-30 | 2018-11-30 | A kind of heat transfer film glue for TRITAN glasss of material surfaces decoration |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109593493A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58183774A (en) * | 1982-04-21 | 1983-10-27 | Toyo Kasei Kogyo Kk | Modified chlorinated polyolefin adhesive and preparation thereof |
| JPH10279913A (en) * | 1997-04-09 | 1998-10-20 | Toyo Ink Mfg Co Ltd | Heat sensitive adhesive and heat sensitive adhesive sheet |
| CN101870855A (en) * | 2010-07-14 | 2010-10-27 | 浙江德尚化工科技有限公司 | Electrochemical aluminum hot stamping adhesive agent and preparation method thereof |
| CN104342068A (en) * | 2013-07-29 | 2015-02-11 | 禹辉(上海)转印材料有限公司 | Transfer printing PP glue and preparation method thereof |
| CN106808820A (en) * | 2017-01-05 | 2017-06-09 | 广东宏达印业股份有限公司 | A kind of digital printing standby transfer film, preparation method and applications |
| CN107502236A (en) * | 2017-08-31 | 2017-12-22 | 浙江佑谦特种材料有限公司 | A kind of water-based PP adhesives and preparation method thereof |
| CN108251023A (en) * | 2016-12-28 | 2018-07-06 | 上海邦中高分子材料有限公司 | A kind of effective adhering resin of lined with PVC steel plastic compount and its preparation method and application |
| CN108528079A (en) * | 2018-04-16 | 2018-09-14 | 江苏学泰印务有限公司 | The wear-resisting local dumb light heat transfer film of one kind and its production technology |
-
2018
- 2018-11-30 CN CN201811454060.5A patent/CN109593493A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58183774A (en) * | 1982-04-21 | 1983-10-27 | Toyo Kasei Kogyo Kk | Modified chlorinated polyolefin adhesive and preparation thereof |
| JPH10279913A (en) * | 1997-04-09 | 1998-10-20 | Toyo Ink Mfg Co Ltd | Heat sensitive adhesive and heat sensitive adhesive sheet |
| CN101870855A (en) * | 2010-07-14 | 2010-10-27 | 浙江德尚化工科技有限公司 | Electrochemical aluminum hot stamping adhesive agent and preparation method thereof |
| CN104342068A (en) * | 2013-07-29 | 2015-02-11 | 禹辉(上海)转印材料有限公司 | Transfer printing PP glue and preparation method thereof |
| CN108251023A (en) * | 2016-12-28 | 2018-07-06 | 上海邦中高分子材料有限公司 | A kind of effective adhering resin of lined with PVC steel plastic compount and its preparation method and application |
| CN106808820A (en) * | 2017-01-05 | 2017-06-09 | 广东宏达印业股份有限公司 | A kind of digital printing standby transfer film, preparation method and applications |
| CN107502236A (en) * | 2017-08-31 | 2017-12-22 | 浙江佑谦特种材料有限公司 | A kind of water-based PP adhesives and preparation method thereof |
| CN108528079A (en) * | 2018-04-16 | 2018-09-14 | 江苏学泰印务有限公司 | The wear-resisting local dumb light heat transfer film of one kind and its production technology |
Non-Patent Citations (1)
| Title |
|---|
| 永田宏二等: "《功能性特种胶粘剂》", 31 July 1991, 化学工业出版社 * |
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Application publication date: 20190409 |