CN106543913A - A kind of multifunctional nano film and preparation method thereof - Google Patents
A kind of multifunctional nano film and preparation method thereof Download PDFInfo
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- CN106543913A CN106543913A CN201510609236.XA CN201510609236A CN106543913A CN 106543913 A CN106543913 A CN 106543913A CN 201510609236 A CN201510609236 A CN 201510609236A CN 106543913 A CN106543913 A CN 106543913A
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Abstract
The invention discloses a kind of multifunctional nano film, ground floor PET basement membranes upper surface the first composite glue of coating；The second composite glue, second layer PET basement membranes lower surface coating mounting layer acrylic acid glue are coated between ground floor PET basement membranes and second layer PET basement membranes；Glue-line lower surface patch third layer PET mould release membrance, the mylar that release layer is processed using surface mental retardationization are installed.Multifunctional nano film of the present invention has the several functions such as antibacterial, mould proof, antifog, antistatic, hot phase transformation, form and aspect change, uvioresistant, sound insulation, explosion-proof, can be widely used for automobile, the sight glass surfaces such as building, can both play energy-saving environmental protection safety protective action, it is also possible to improve comfort level.The invention also discloses the preparation method of multifunctional nano film.
Description
Technical field
The present invention relates to a kind of multifunctional nano film, particularly with antibacterial, mould proof, antifog, antistatic,
The multifunctional nano film that the several functions such as hot phase transformation, form and aspect change, uvioresistant, sound insulation, explosion-proof are integrated,
Additionally, the invention also discloses the preparation method of aforementioned multifunctional nano film.
Background technology
Sun thermal isolation film is the common energy-saving material of a class, is generally used for the industrial circles such as building, automobile.
Solar film common in the market is mainly made up of 5 parts, including surface scratch resistance coating, PET base material
Layer, composite bed, mounting layer, release film layer.Surface anti-scratch layer is usually used ultraviolet-curing paint shape
Into composite bed generally adds the Nano heat insulation mediums such as ATO, ITO and UV absorbent, PET basement membrane tables
Face is generally caused with certain heat-insulated using silver, aluminum, the metal coating such as copper or magnetron sputtering process surface
And anti-ultraviolet function, but this solar film function is more single, do not possess at the same have antibacterial, it is mould proof,
The several functions such as antifog, antistatic, form and aspect change, hot phase transformation, it is impossible to meet growing diversification
The market demand.
Chinese patent CN202702775U discloses a kind of anti-scratch antifouling solar energy thermal isolation film, is bonded at solar energy
Oil stain, stain in thermal isolation film effectively can be removed with rag when sticking to its surface at any time, have certain easy
Clean function.Chinese patent CN103075608A discloses a kind of antioxidation and strengthens thermal isolation film, and top layer is oxygen
Change film, certain aging-resistant effect can be played.As Chinese patent CN1065826A discloses a kind of height
Intensity light transmission film production technology, strengthens its anti-dew performance by coating anti-fog coating in thin film upper and lower surface.
In published Chinese patent there is not yet, while have antibacterial, mould proof, antifog, antistatic, color
The several functions solar film such as phase transformation, hot phase transformation, anti-ultraviolet, sound insulation, explosion-proof.Whether automobile or
Building field, the solar film of the strong moderate cost for needing there are several functions simultaneously on market, therefore,
It solves such market flaw.
The content of the invention
For the above-mentioned deficiency of prior art, according to embodiments of the present invention, it is desirable to provide a kind of to have simultaneously
Antibacterial, mould proof, antifog, antistatic, form and aspect change, hot phase transformation, anti-ultraviolet, sound insulation, explosion-proof etc. are more
The multifunctional nano film of function is planted, and proposes the preparation method of the multifunctional nano film.
According to embodiment, a kind of multifunctional nano film that the present invention is provided, its innovative point is, ground floor
PET basement membranes upper surface is coated with the first composite glue；Apply between ground floor PET basement membranes and second layer PET basement membranes
The second composite glue of cloth, second layer PET basement membranes lower surface coating mounting layer acrylic acid glue；Glue-line is installed
Lower surface pastes third layer PET mould release membrance, the mylar that release layer is processed using surface mental retardationization.
According to one embodiment, in aforementioned multifunctional nano film of the invention,
The composition and its weight portion of the first composite glue be：1. 60～90 parts of UV-cured resin, 2.
One 10～50 parts of composite Nano slurry；1. 2. mix 30-50 minutes after use 0.5-1.5um filter pressings
Filter, the first composite glue is obtained, wherein：
The composition and its weight portion of the first composite Nano slurry be：1. 1～5 part of triclosan powder body, 2. dioxy
Change 3～8 parts of titanium valve body, 3. 5～10 parts of conductive zinc oxide powder, 4. 70～90 parts of butanone, 5. disperse
Agent BYK-204,1～2 part；1. 2. 3. 4. 5. it is sequentially placed in planet rapid dispersion machine, then is added 1-3
Zirconium ancient unit of weight, equal to 1/24 liang of a diameter of 0.2-0.4mm of times powder body sum total weight calculation amount, speed setting are that 5000-7000 turns/h,
The first composite Nano slurry is obtained after batch dispersion 3-7 hour.
According to one embodiment, in aforementioned multifunctional nano film of the invention, the composition of the first composite glue and
Its weight portion is：1. 60 parts of UV-cured resin, 2. 40 parts of the first composite Nano slurry；
The composition weight portion of the first composite Nano slurry is：1. 3 parts of triclosan powder body, 2. titanium dioxide powder
5 parts of body, 3. 8 parts of conductive zinc oxide powder, 4. 80 parts of butanone, 5. dispersant B YK-204,1 part.
According to one embodiment, in aforementioned multifunctional nano film of the invention, the composition of the second composite glue and
Its weight portion is：1. vanadium dioxide nano slurry 0.3-1 parts, 2. photosensitive colour-changing slurry 0.1-0.5 parts,
3. 2～4 parts of UV absorbent, 4. 30～50 parts of acrylic acid glue, 5. 40～50 parts of diluent；
1. filtered with 1um filter pressings after 2. 3. 4. 5. mixing 40 minutes, the second composite glue is obtained, wherein：
The composition and its weight portion of aforementioned vanadium dioxide nano slurry be：1. vanadium dioxide nano powder 5～50
Part, 2. 1～5 part of dispersant B YK-164,3. 30 parts～90 parts of solvent toluene；1. 2. 3. it is put into row
Zirconium oxide ancient unit of weight, equal to 1/24 liang of a diameter of 0.5mm is placed in the batch can of star rapid dispersion machine, speed setting is 3000 turns
/ 1h, batch dispersion obtains primary particle size after 16 hours be the vanadium dioxide nano slurry less than 10nm；
Aforementioned light-sensitive become mill base material composition and its weight portion into：1. 10～20 parts of photosensitive colour-changing powder body, 2.
80 parts～90 parts of solvent toluene；1. 2. mixed, stirred 30 minutes, obtained photosensitive complexion changed slurry；
Aforementioned UV absorbent is BP-2, is obtained with the BP-2 powder body of butanone dissolving 30%
Obtain the ultraviolet absorbent solution that solid content is 30%；
Aforementioned acrylic acid glue is polyacrylate pressure-sensitive, and solid content is 40%.
According to one embodiment, in aforementioned multifunctional nano film of the invention, the composition of the second composite glue and
Its weight portion is：3. 3 parts of UV absorbent, 4. 40 parts of acrylic acid glue, 5. 40 parts of diluent；
The composition and its weight portion of vanadium dioxide nano slurry be：1. 20 parts of vanadium dioxide nano powder, 2. disperse
1 part of agent, 3. 79 parts of solvent toluene；The composition and its weight portion of photosensitive colour-changing slurry be：1. photosensitive colour-changing
15 parts of powder body, 2. 85 parts of solvent toluene.
According to embodiment, the preparation method of multifunctional nano film of the present invention, comprise the steps：
Using VO coatings and ultraviolet light polymerization mode, the first compound adhesive is coated with ground floor PET membrane surfaces
Water；
Be coated with using VO and the mode that is heating and curing, first the second compound adhesive is coated with second layer PET membrane surfaces
Water, while being combined a PET basement membranes again；
Acrylate pressure-sensitive adhesive is coated on into the second pet layer and forms mounting layer, then which is combined with release layer.
According to one embodiment, in the preparation method of aforementioned multifunctional nano film of the invention, the first compound adhesive
The build that water is formed is 3um, the sharp energy 400mj of ultraviolet light light；Mounting layer build is 8um.
According to one embodiment, in the preparation method of aforementioned multifunctional nano film of the invention, coating first is multiple
After rubber alloy water, the second composite glue and acrylate pressure-sensitive adhesive, it is dried at 100-140 DEG C, stands
10-14h。
Relative to prior art, multifunctional nano film of the present invention, which is structural and functional to show, first
Layer PET basement membranes upper surface applies with the function such as antifog, antibacterial, mould proof, antistatic, wear-resisting first again
Rubber alloy water；Between the first pet layer basement membrane and second layer PET basement membranes apply with hot phase transformation, form and aspect become,
Second composite glue of the functions such as UV resistance, applies mounting layer acrylate glue in second layer PET basement membranes lower surface
Water；Glue-line lower surface patch third layer PET mould release membrance is installed, release layer is using gathering that surface mental retardationization is processed
Ester film, therefore multifunctional nano film of the present invention has antibacterial, mould proof, antifog, antistatic, color simultaneously
The several functions such as phase transformation, hot phase transformation, anti-ultraviolet, sound insulation, explosion-proof.
Description of the drawings
Fig. 1 is the structural representation of multifunctional nano film of the present invention (in figure：Compound 1 function of glue coating correspondence
In the first composite glue coating；Compound 2 function of glue coating correspond to the second composite glue coating).
Specific embodiment
Below in conjunction with the accompanying drawings and specific embodiment, the present invention is expanded on further.These embodiments are interpreted as
It is merely to illustrate the present invention rather than limits the scope of the invention.Reading record of the present invention
After content, those skilled in the art can be made various changes or modifications to the present invention, these equivalence changes
The scope of the claims in the present invention is fallen into equally with modification.
Raw material used in following examples of the present invention is as being commercially available prod without especially sign.
Embodiment 1
1st, prepare the first composite Nano slurry
1. triclosan powder body：3 parts.2. titanium dioxide (TIO2) powder body：5 parts.3. conductive zinc oxide (ZnO)
Powder body：8 parts.4. butanone：80 parts.5. dispersant, BYK-204:1 part.1. 2. 3. 4. 5. put successively
Add zirconium ancient unit of weight, equal to 1/24 liang of a diameter of 0.3mm of 2 times of powder body sum total weight calculation amounts in entering planet rapid dispersion machine again, turn
Speed is set as 6000 turns/1h, and batch dispersion obtains the first composite Nano slurry after 5 hours.
2nd, prepare the first complex function coating：
1. UV-cured resin：60 parts, 2. the first composite Nano slurry：40 parts, 1. 2. mixing is stirred
Filtered with 1um filter pressings after mixing 40 minutes, placed in conveying tank, be coated with using VO and ultraviolet light polymerization
Mode completes the first composite glue coating in the ground floor PET membrane surfaces of 23um thickness.Build
3um, ultraviolet light light swash energy 400mj.
3rd, prepare vanadium dioxide nano slurry：
1. vanadium dioxide nano powder：20 parts.②BYK-164:1 part.3. toluene：79 parts.1. 2.
3. zirconium oxide ancient unit of weight, equal to 1/24 liang of a diameter of 0.5mm, speed setting are placed in being put into the batch can of planet rapid dispersion machine
For 3000 turns/1h, batch dispersion obtains primary particle size after 16 hours be that the vanadium dioxide less than 10nm is received
Rice ＆ peanut milk material.
4th, prepare photosensitive colour-changing slurry：
1. photosensitive colour-changing powder body is taken according to weight portion：15 parts.2. toluene：85 parts.1. 2. mixed
Just photosensitive complexion changed slurry is obtained after 30 minutes.Darken when illumination is strong Lycoperdon polymorphum Vitt, lighter when illumination is weak.
5th, the second composite glue, composite membrane, multifunctional nano film are prepared.
According to weight portion, 1. vanadium dioxide nano slurry：0.3 part.2. photosensitive colour-changing slurry：0.2 part,
3. UV absorbent：3 parts, 4. acrylic acid glue：40 parts, 5. diluent：40 parts, 1. 2. 3.
4. 5. mix 40 minutes after with 1um filter pressings filter, place in conveying tank, using VO be coated with
The mode that is heating and curing first completes coating in second layer PET membrane surfaces, while a PET basement membranes are combined again,
Just obtain the composite membrane of the second composite glue coating of coating.In second layer 23um thickness PET basement membrane lower surfaces
Mounting layer acrylic acid glue is repasted, the PET mould release membrances that glue-line lower surface pastes third layer 23um thickness again is installed,
The mylar that release layer is processed using surface mental retardationization, structure such as Fig. 1 of obtained multifunctional nano film
It is shown.
Measure according to usual method, infrared barrier rate 20%, ultraviolet isolating rate in 20 degree of ambient temperatures
99%, it is seen that light transmission rate 65%, escherichia coli sterilizing rate 99.99%, 20 degree of antifog contact angle, surface
8 power ohmcms of resistance 10, case hardness 4H are wear-resisting, when ambient temperature is 50 degree, 50
Infrared barrier rate 70%, ultraviolet isolating rate 99%, it is seen that light transmission rate 65%, large intestine during degree ambient temperature
Bacillus sterilizing rate 99.99%, anti-mold effect are good, 20 degree of antifog contact angle, 8 powers of sheet resistance 10
Ohmcm.Case hardness 4H is wear-resisting.
Multifunctional nano film obtained in the present embodiment is placed 2 months under the conditions of atmosphere at room temperature, according to
GB/T16719-2008 tests its anti-fog performance for 1 grade, and when depletion of YANG light irradiation, multifunctional nano film is two
The bronze colour of vanadium oxide, as the color for increasing multifunctional nano film of sunlight intensity is by bronze colour
Crossfade into dark-grey light green color.
Embodiment 2
Prepare the formula of the first composite glue and the first composite coating and the second composite coating technique are formed with real
Apply example 1 identical.
The the second composite glue formula for preparing the proposition of embodiment 2 is as follows：According to weight portion, 1. vanadium dioxide
Nano pulp：0.4 part.2. photosensitive colour-changing slurry：0.3 part, 3. UV absorbent：3 parts, 4. third
Olefin(e) acid glue：40 parts, 5. diluent：40 parts.
Measure according to usual method, infrared barrier rate 18%, ultraviolet isolating rate in 20 degree of ambient temperatures
99%, it is seen that light transmission rate 63%, escherichia coli sterilizing rate 99.99%, 20 degree of antifog contact angle, surface
8 power ohmcms of resistance 10, case hardness 4H are wear-resisting, when ambient temperature is 50 degree, 50
Infrared barrier rate 72%, ultraviolet isolating rate 99%, it is seen that light transmission rate 63%, large intestine during degree ambient temperature
Bacillus sterilizing rate 99.99%, anti-mold effect are good, 20 degree of antifog contact angle, and case hardness 4H is wear-resisting.
Multifunctional nano film obtained in the present embodiment is placed 2 months under the conditions of atmosphere at room temperature, according to
GB/T16719-2008 tests its anti-fog performance for 1 grade, and when depletion of YANG light irradiation, multifunctional nano film is two
The bronze colour of vanadium oxide, as the color for increasing multifunctional nano film of sunlight intensity is by bronze colour
Crossfade into dark-grey light green color.
Embodiment 3
Prepare the formula of the first composite glue and the first composite coating and the second composite coating technique are formed with real
Apply example 1 identical.
The the second composite glue formula for preparing the proposition of embodiment 2 is as follows：According to weight portion, 1. vanadium dioxide
Nano pulp：0.5 part.2. photosensitive colour-changing slurry：0.4 part, 3. UV absorbent：3 parts, 4. third
Olefin(e) acid glue：40 parts, 5. diluent：40 parts.
Measure according to usual method, infrared barrier rate 16%, ultraviolet isolating rate in 20 degree of ambient temperatures
99%, it is seen that light transmission rate 61%, escherichia coli sterilizing rate 99.99%, 20 degree of antifog contact angle, surface
8 power ohmcms of resistance 10, case hardness 4H are wear-resisting, when ambient temperature is 50 degree, 50
Infrared barrier rate 74%, ultraviolet isolating rate 99%, it is seen that light transmission rate 63%, large intestine during degree ambient temperature
Bacillus sterilizing rate 99.99%, anti-mold effect are good, 20 degree of antifog contact angle, and case hardness 4H is wear-resisting.
Multifunctional nano film obtained in the present embodiment is placed 2 months under the conditions of atmosphere at room temperature, according to
GB/T16719-2008 tests its anti-fog performance for 1 grade, and when depletion of YANG light irradiation, multifunctional nano film is two
The bronze colour of vanadium oxide, as the color for increasing multifunctional nano film of sunlight intensity is by bronze colour
Crossfade into dark-grey light green color.
Embodiment 4
Prepare the formula of the first composite glue and the first composite coating and the second composite coating technique are formed with real
Apply example 1 identical.
The the second composite glue formula for preparing the proposition of embodiment 2 is as follows：According to weight portion, 1. vanadium dioxide
Nano pulp：0.5 part.2. photosensitive colour-changing slurry：0.4 part, 3. UV absorbent：3 parts, 4. third
Olefin(e) acid glue：40 parts, 5. diluent：40 parts.
Measure according to usual method, infrared barrier rate 16%, ultraviolet isolating rate in 20 degree of ambient temperatures
99%, it is seen that light transmission rate 59%, escherichia coli sterilizing rate 99.99%, 20 degree of antifog contact angle, surface
8 power ohmcms of resistance 10, case hardness 4H are wear-resisting, when ambient temperature is 50 degree, 50
Infrared barrier rate 74%, ultraviolet isolating rate 99%, it is seen that light transmission rate 59%, large intestine during degree ambient temperature
Bacillus sterilizing rate 99.99%, anti-mold effect are good, 20 degree of antifog contact angle, and case hardness 4H is wear-resisting.
Multifunctional nano film obtained in the present embodiment is placed 2 months under the conditions of atmosphere at room temperature, according to
GB/T16719-2008 tests its anti-fog performance for 1 grade, and when depletion of YANG light irradiation, multifunctional nano film is two
The bronze colour of vanadium oxide, as the color for increasing multifunctional nano film of sunlight intensity is by bronze colour
Crossfade into dark-grey light green color.
Claims (8)
1. a kind of multifunctional nano film, it is characterised in that ground floor PET basement membranes upper surface coating first is multiple
Rubber alloy water；The second composite glue, the second layer are coated between ground floor PET basement membranes and second layer PET basement membranes
PET basement membranes lower surface is coated with mounting layer acrylic acid glue；Glue-line lower surface patch third layer PET mould release membrance is installed,
The mylar that release layer is processed using surface mental retardationization.
2. multifunctional nano film according to claim 1, it is characterised in that the first composite glue
Composition and its weight portion are：1. 60～90 parts of UV-cured resin, 2. the first composite Nano slurry 10～
50 parts；Filtered with 0.5-1.5um filter pressings 1. 2. mixing after 30-50 minutes, be obtained first and be combined
Glue, wherein：
The composition and its weight portion of the first composite Nano slurry be：1. 1～5 part of triclosan powder body, 2. dioxy
Change 3～8 parts of titanium valve body, 3. 5～10 parts of conductive zinc oxide powder, 4. 70～90 parts of butanone, 5. disperse
Agent BYK-204,1～2 part；1. 2. 3. 4. 5. it is sequentially placed in planet rapid dispersion machine, then is added 1-3
Zirconium ancient unit of weight, equal to 1/24 liang of a diameter of 0.2-0.4mm of times powder body sum total weight calculation amount, speed setting are that 5000-7000 turns/h,
The first composite Nano slurry is obtained after batch dispersion 3-7 hour.
3. multifunctional nano film according to claim 1, it is characterised in that the first composite glue
Composition and its weight portion are：1. 60 parts of UV-cured resin, 2. 40 parts of the first composite Nano slurry；
The composition weight portion of the first composite Nano slurry is：1. 3 parts of triclosan powder body, 2. titanium dioxide powder
5 parts of body, 3. 8 parts of conductive zinc oxide powder, 4. 80 parts of butanone, 5. dispersant B YK-204,1 part.
4. a kind of multifunctional nano film described in claim 1, it is characterised in that the second composite glue
Composition and its weight portion are：1. vanadium dioxide nano slurry 0.3-1 parts, 2. photosensitive colour-changing slurry 0.1-0.5
Part, 3. 2～4 parts of UV absorbent, 4. 30～50 parts of acrylic acid glue, 5. 40～50 parts of diluent；
Being filtered with 1um filter pressings after 1. 2. 3. 4. 5. mixing 40 minutes, the second composite glue is obtained, wherein：
The composition and its weight portion of aforementioned vanadium dioxide nano slurry be：1. vanadium dioxide nano powder 5～50
Part, 2. dispersant B YK-1641～5 part, 3. 30 parts～90 parts of solvent toluene；1. 2. 3. it is put into row
Zirconium oxide ancient unit of weight, equal to 1/24 liang of a diameter of 0.5mm is placed in the batch can of star rapid dispersion machine, speed setting is 3000 turns
/ 1h, batch dispersion obtains primary particle size after 16 hours be the vanadium dioxide nano slurry less than 10nm；
Aforementioned light-sensitive become mill base material composition and its weight portion into：1. 10～20 parts of photosensitive colour-changing powder body, 2.
80 parts～90 parts of solvent toluene；1. 2. mixed, stirred 30 minutes, obtained photosensitive complexion changed slurry；
Aforementioned UV absorbent is BP-2, is obtained with the BP-2 powder body of butanone dissolving 30%
Obtain the ultraviolet absorbent solution that solid content is 30%；
Aforementioned acrylic acid glue is polyacrylate pressure-sensitive, and solid content is 40%.
5. multifunctional nano film according to claim 1, it is characterised in that the second composite glue
Composition and its weight portion are：3. 3 parts of UV absorbent, 4. 40 parts of acrylic acid glue, 5. diluent 40
Part；The composition and its weight portion of vanadium dioxide nano slurry be：1. 20 parts of vanadium dioxide nano powder, 2.
1 part of dispersant, 3. 79 parts of solvent toluene；The composition and its weight portion of photosensitive colour-changing slurry be：1. it is photosensitive
Change colour 15 parts of powder body, 2. 85 parts of solvent toluene.
6. the preparation method of the multifunctional nano film described in claim 1-5, it is characterised in that include as
Lower step：
Using VO coatings and ultraviolet light polymerization mode, the first compound adhesive is coated with ground floor PET membrane surfaces
Water；
Be coated with using VO and the mode that is heating and curing, first the second compound adhesive is coated with second layer PET membrane surfaces
Water, while being combined a PET basement membranes again；
Acrylate pressure-sensitive adhesive is coated on into the second pet layer and forms mounting layer, then which is combined with release layer.
7. the preparation method of multifunctional nano film according to claim 7, it is characterised in that first
The build that composite glue is formed is 3um, the sharp energy 400mj of ultraviolet light light；Mounting layer build is
8um。
8. the preparation method of the multifunctional nano film according to claim 6 or 7, it is characterised in that
After being coated with the first composite glue, the second composite glue and acrylate pressure-sensitive adhesive, it is dried at 100-140 DEG C,
Stand 10-14h.
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| CN201510609236.XA CN106543913A (en) | 2015-09-23 | 2015-09-23 | A kind of multifunctional nano film and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510609236.XA CN106543913A (en) | 2015-09-23 | 2015-09-23 | A kind of multifunctional nano film and preparation method thereof |
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Family
ID=58365656
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135603A (en) * | 2018-08-02 | 2019-01-04 | 江苏双星彩塑新材料股份有限公司 | A kind of antibacterial explosion-proof fenestrated membrane |
| CN112029431A (en) * | 2020-09-11 | 2020-12-04 | 湖南尚鑫新材料科技有限公司 | Heat-insulating explosion-proof film for automobile front windshield glass |
| CN112029434A (en) * | 2020-09-11 | 2020-12-04 | 湖南尚鑫新材料科技有限公司 | Heat-insulating explosion-proof film for automobile front windshield glass |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1990610A (en) * | 2005-12-29 | 2007-07-04 | 第一毛织株式会社 | Antibacterial and anti-static multifunctional hard coating composition |
| CN104277727A (en) * | 2013-07-03 | 2015-01-14 | 上海追光科技有限公司 | Multifunctional nanometer composite heat insulation film and making method thereof |
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2015
- 2015-09-23 CN CN201510609236.XA patent/CN106543913A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1990610A (en) * | 2005-12-29 | 2007-07-04 | 第一毛织株式会社 | Antibacterial and anti-static multifunctional hard coating composition |
| CN104277727A (en) * | 2013-07-03 | 2015-01-14 | 上海追光科技有限公司 | Multifunctional nanometer composite heat insulation film and making method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135603A (en) * | 2018-08-02 | 2019-01-04 | 江苏双星彩塑新材料股份有限公司 | A kind of antibacterial explosion-proof fenestrated membrane |
| CN109135603B (en) * | 2018-08-02 | 2023-01-17 | 江苏双星彩塑新材料股份有限公司 | Antibacterial explosion-proof window film |
| CN112029431A (en) * | 2020-09-11 | 2020-12-04 | 湖南尚鑫新材料科技有限公司 | Heat-insulating explosion-proof film for automobile front windshield glass |
| CN112029434A (en) * | 2020-09-11 | 2020-12-04 | 湖南尚鑫新材料科技有限公司 | Heat-insulating explosion-proof film for automobile front windshield glass |
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Application publication date: 20170329 |