CN201873904U - Vacuum aluminum plating frosted card paper - Google Patents

Vacuum aluminum plating frosted card paper Download PDF

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Publication number
CN201873904U
CN201873904U CN2010205507575U CN201020550757U CN201873904U CN 201873904 U CN201873904 U CN 201873904U CN 2010205507575 U CN2010205507575 U CN 2010205507575U CN 201020550757 U CN201020550757 U CN 201020550757U CN 201873904 U CN201873904 U CN 201873904U
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CN
China
Prior art keywords
frosted
coating
paperboard
card paper
aluminum plating
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Expired - Lifetime
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CN2010205507575U
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Chinese (zh)
Inventor
郑迪生
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Yantai Boyuan Technology Materials Co., Ltd.
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BOYUAN TECHNOLOGY MATERIAL (YANTAI) Co Ltd
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Abstract

The utility model relates to a piece of vacuum aluminum plating frosted card paper and a production method thereof, which belong to the technical field of packaging materials and printing materials. The vacuum aluminum plating frosted card paper comprises a paper substrate, a frosted coating and an aluminum plating layer. The production process of the vacuum aluminum plating frosted card paper comprises the following steps: firstly, making a frosted coating mixture body; secondly, coating a layer of frosted coating mixture body on the paper substrate 4 to form the frosted coating; and thirdly, directly plating aluminum on the frosted surface of the frosted coating of a piece of card paper containing the frosted coating having a frosted effect to form an aluminum plating layer after the card paper enters a vacuum aluminum plating system. The vacuum aluminum plating frosted card paper has the following advantages of simple process, no glue layer, high production efficiency and no volatilization of solvents, and is an environment-friendly production process. The frosted effect is delicate and vivid, the metal texture is heavy, the frosted card paper produced can achieve the effect of screening printing after being subjected to common offset printing or gravure printing, a large amount of ink can be saved and volatilization of solvents and residual solvents of printing products can be reduced.

Description

A kind of vacuum aluminum-coated frosted paperboard
One, technical field
The utility model relates to a kind of vacuum aluminum-coated frosted paperboard, belongs to packaging material and printing material technical field.
Two, background technology
At present, the known paperboard of aluminizing that is used for high-grade packaging material has transfer aluminum plated paperboard, overlay film aluminize paperboard, direct paperboard three classes of aluminizing.From openly finding that the paperboard of back two kinds of explained hereafter substantially all is high light-card paper method patent and the document, transfer method also is mainly used to produce high light-card paper.High light-card paper will seek out rich texture, printing effect that third dimension is strong through printing, the general mode that adopts serigraphy, but screen printing ink bed thickness, dissolvent residual is many, print speed printing speed is low, be not suitable for high-grade packaging material to volatile organic content low content control requirement, be not suitable for extensive high speed printing yet.
On February 3rd, 2010, Hu Aijun discloses the radium-shine paperboard utility model patent of a kind of transfer frosted (CN201395743Y), can reach the effect of serigraphy on this paperboard by offset printing.According to the radium-shine paperboard of the described frosted of this patent paper base material, transfer adhesive water layer, aluminium lamination, release layer are arranged, release layer contains laser information, frosting.Its technology is earlier the PET basement membrane to be made the PET basement membrane of frosted structure, on PET frosted film, be coated with then release layer, laser molding, vacuum aluminum-coated, coating transfer glue, compound with paper, shift and series of process such as peel off and make.
But its shifting process more complicated of patent (CN201395743Y) according to Hu Aijun, manufacturing process need be used the PET film, be coated with release layer on the PET film, this layer material contains more organic solvent, easily environment is polluted, aluminium lamination and paper are compound need use glue, easily cause volatile organic compounds (VOCs) residual, it is not high that recombination process easily forms bubble, hickie, yield rate, easily peels off unclear when peeling off, cause PET film recycling rate of waterused low, the cost height.
Three, summary of the invention
The purpose of this utility model will overcome existing paperboard defective exactly, and a kind of direct vacuum aluminum-coated frosted paperboard of new structure is provided, and can reach serigraphy rich texture, effect that third dimension is strong by offset printing or gravure on this paperboard.
The utility model is realized by the following technical solutions:
A kind of vacuum aluminum-coated frosted paperboard comprises nethermost paper base material 4, upwards is frosted coating layer 3, aluminium coated 2 successively, directly offset printing or gravure on the aluminium coated 2;
Can also be coated with protective layer 1 on the aluminium coated 2, coating protective layer 1 can form the decorative effect of different texture with varnish or colored paint.
Be characterized in that metal-like is strong, frosted finish effect is outstanding, and third dimension is strong, and printability is good.Paper base material described in the utility model is common paperboard, as art post paperboard.
The production technology of above-mentioned vacuum aluminum-coated frosted paperboard comprises the steps
1, at first, make frosted coating mixture;
Frosted coating mixture can be water-soluble frosted coating mixture, or photocuring frosted coating mixture;
(1) water-soluble frosted coating mixture production process:
The ball milling a kind of nano level silicon oxide powder silicon oxide powder (frosting powder) that is uniformly dispersed in a kind of property of water-bearing acrylic emulsion, polyvinyl alcohol, carboxymethyl cellulose promotor composition, form a kind of coating mixture with frosted finish effect, be a kind of environment-friendly type aqueous frosted coating, among the parcel that is in organic molecule that after solidifying there is particle, the part that has is exposed to coating surface, increase scattering of light, reach the effect of delustring, thereby form mute photosphere with frosted finish effect.Simultaneously, the adding of frosting powder also can strengthen abrasion property and intensity.
Water-soluble frosted coating mixture the ratio of each component is:
Aqueous acrylic emulsion is joined for 45~60 parts
2~6 parts of polyvinyl alcohol
1~5 part of carboxymethyl cellulose
1~5 part of silicon oxide powder
20~40 parts in water
(2) ultraviolet light polymerization frosted coating mixture production process:
At a kind of composition that contains epoxy acrylate photosensitive resin, tripropylene glycol diacrylate, propoxylation trimethylolpropane triacrylate, single maleimide resin, methylethanolamine, add a spot of dispersant and levelling agent, silicon oxide powder is evenly spread to form a kind of ultraviolet light polymerization frosted coating in the said composition.
Ultraviolet light polymerization frosted coating mixture the ratio of each component is:
The epoxy acrylate photosensitive resin is joined for 30~50 parts
10~30 parts of tripropylene glycol diacrylates
15~30 parts of propoxylation trimethylolpropane triacrylates
1~5 part of single maleimide resin
0.2~1 part of methylethanolamine
2~10 parts of the modified oxidized Si powder of wax
Dispersant is an amount of
Levelling agent is an amount of
2, secondly, coating one deck frosted coating mixture forms frosted coating layer 3 on paper base material 4:
(1) above-mentioned water-soluble frosted coating mixture is coated 80-250g/m with 200-300 order cable roll on coating machine 2Paperboard light face on, the paperboard after the coating is carried out drying and forming-film at the hot drying tunnel of 80~170 ℃ of temperature, the speed of a motor vehicle 80~150m/min, solidify that the back forms and paperboard in conjunction with firm frosted coating layer 3 with frosted finish effect.
(2) described photocuring frosted coating mixture is coated 80-250g/m with 200-300 order cable roll on coating machine 2Paperboard light face on, the paperboard after the coating is solidified in the ultraviolet light polymerization passage, solidify that the back forms and paperboard in conjunction with firm frosted coating layer 3 with frosted finish effect.
3, then, the paperboard that contains the frosted coating layer of frosted finish effect enters vacuum aluminum-coated system, directly aluminizes on the frosted coating layer frosting of paperboard, forms aluminium coated 2:
The paperboard that contains the frosted coating layer enters vacuum aluminum-coated system and aluminizes, vacuum≤0.1Pa, aluminium wire is atomization under 1450~1500 ℃ of high temperature, and atomizing al deposition is on paperboard frosted layer, form aluminium coated 2, the speed of aluminizing can be regulated in 400~1000m/min scope as required; Aluminium lamination is covered in the surface of frosted coating layer, greatly strengthens the reflection of light rate, appears metal-like suddenly, forms the direct vacuum aluminizing paperboard of the frosted finish effect with extremely strong metal sense.This paperboard can be printed various patterns, also can be coated with the colored paperboard of the frosted with metal-like that colouring forms multicolour.
A kind of vacuum aluminum-coated frosted paperboard of the utility model has following beneficial effect:
Production process technology simply, does not contain glue layer, production efficiency height, and solvent-free volatilization is a kind of environment-friendly production process.The frosted finish effect exquisiteness is true to nature, and metal-like is thick and heavy, the effect that offset printing that the frosted paperboard process of being produced is common or gravure printing can reach serigraphy.Save a large amount of printing ink, reduce the dissolvent residual of solvent evaporates and printing product greatly.
Four, description of drawings
Fig. 1, a kind of vacuum aluminum-coated frosted paperboard structural representation.
Among the figure: 1, coating protective layer, 2, aluminium coated, 3, the frosted coating layer, 4, paper base material.
Five, the specific embodiment
With reference to accompanying drawing, provide the utility model specific embodiment, formation of the present utility model is described further.
Example 1:
With reference to the accompanying drawings 1, a kind of vacuum aluminum-coated frosted paperboard comprises nethermost paper base material 4, upwards is frosted coating layer 3, aluminium coated 2 successively, directly offset printing or gravure on the aluminium coated 2.
The production method of above-mentioned vacuum aluminum-coated frosted paperboard comprises the steps
(1) at first, make frosted coating mixture;
The ball milling a kind of nano level silicon oxide powder silicon oxide powder (frosting powder) that is uniformly dispersed in a kind of property of water-bearing acrylic emulsion, polyvinyl alcohol, carboxymethyl cellulose promotor composition, form a kind of coating mixture with frosted finish effect, be a kind of environment-friendly type aqueous frosted coating, among the parcel that is in organic molecule that after solidifying there is particle, the part that has is exposed to coating surface, increase scattering of light, reach extinction effect, thereby form mute photosphere with frosted finish effect.Simultaneously, the adding of frosting powder also can strengthen abrasion property and intensity.
Water-soluble frosted coating mixture the ratio of each component is:
Aqueous acrylic emulsion is joined for 45~60 parts
2~6 parts of polyvinyl alcohol
1~5 part of carboxymethyl cellulose
1~5 part of silicon oxide powder
20~40 parts in water
(2) (1) described water-soluble frosted coating mixture is coated 80-250g/m with 200-300 order cable roll on coating machine 2Paperboard light face on, the paperboard after the coating is carried out drying and forming-film at the hot drying tunnel of 80~170 ℃ of temperature, the speed of a motor vehicle 80~150m/min, solidify that the back forms and paperboard in conjunction with firm frosted coating layer 3 with frosted finish effect.
(3) then, the paperboard that contains the frosted coating layer with frosted finish effect enters vacuum aluminum-coated system, directly aluminizes on the frosted coating layer frosting of paperboard, forms aluminium coated 2:
The paperboard that contains the frosted coating layer enters vacuum aluminum-coated system and aluminizes, vacuum≤0.1Pa, aluminium wire is atomization under 1450~1500 ℃ of high temperature, and atomizing al deposition is on paperboard frosted layer, form aluminium coated 2, the speed of aluminizing can be regulated in 400~1000m/min scope as required; Aluminium lamination is covered in the surface of frosted coating layer, greatly strengthens the reflection of light rate, appears metal-like suddenly, forms the direct vacuum aluminizing paperboard of the frosted finish effect with extremely strong metal sense.This paperboard can be printed various patterns, also can be coated with the colored paperboard of the frosted with metal-like that colouring forms multicolour.
Example 2
(1) at a kind of composition that contains epoxy acrylate photosensitive resin, tripropylene glycol diacrylate, propoxylation trimethylolpropane triacrylate, single maleimide resin, methylethanolamine, add a spot of dispersant and levelling agent, silicon oxide powder is evenly spread to form a kind of ultraviolet light polymerization frosted coating in the said composition.
Ultraviolet light polymerization frosted coating mixture the ratio of each component is:
The epoxy acrylate photosensitive resin is joined for 30~50 parts
10~30 parts of tripropylene glycol diacrylates
15~30 parts of propoxylation trimethylolpropane triacrylates
1~5 part of single maleimide resin
0.2~1 part of methylethanolamine
2~10 parts of the modified oxidized Si powder of wax
Dispersant, levelling agent all adopt industry commercially available prod commonly used an amount of.
(2) (1) described ultraviolet light polymerization frosted coating is coated 80-250g/m with 200-300 order cable roll on coating machine 2Paperboard light face on, the paperboard after the coating is solidified in the ultraviolet light polymerization passage.Solidify back formation and paperboard in conjunction with firm frosted coating layer with frosted finish effect.
(3) paperboard that contains the frosted layer enters vacuum aluminum-coated system and aluminizes, vacuum≤0.1Pa, aluminium wire is atomization under 1450~1500 ℃ of high temperature, and atomizing al deposition is on paperboard frosted layer, form aluminium coated, the speed of aluminizing can be regulated in 400~1000m/min scope as required.Aluminium lamination is covered in the surface of frosted coating, greatly strengthens the reflection of light rate, appears metal-like suddenly, forms the vacuum aluminizing paperboard of the frosted finish effect with extremely strong metal sense.This paperboard can be printed various patterns, also can be coated with the colored paperboard of the frosted with metal-like that colouring forms multicolour.
A kind of vacuum aluminum-coated frosted paperboard of above embodiment and production technology thereof have following beneficial effect:
Technology simply, does not contain glue layer, production efficiency height, and solvent-free volatilization is a kind of environment-friendly production process.The frosted finish effect exquisiteness is true to nature, and metal-like is thick and heavy, the effect that offset printing that the frosted paperboard process of being produced is common or gravure printing can reach serigraphy.Save a large amount of printing ink, reduce the dissolvent residual of solvent evaporates and printing product greatly.
A kind of vacuum aluminum-coated frosted paperboard of the utility model has following beneficial effect:
Production technology simply, does not contain glue layer, production efficiency height, and solvent-free volatilization is a kind of environment-friendly production process.The paperboard that will contain the frosted coating layer is aluminized in vacuum aluminum-coated system, and aluminium lamination is attached on the frosted coating layer, greatly strengthens the reflection of light rate, highlight metal-like, formation has the vacuum aluminizing paperboard of the frosted finish effect of extremely strong metal sense, and the frosted finish effect exquisiteness is true to nature, and metal-like is thick and heavy.This paperboard can be printed various patterns, also can be coated with the colored paperboard of the frosted with metal-like that colouring forms multicolour.On this frosted paperboard, adopt the common offset printing or the mode of printing of gravure can obtain the same rich texture that has with serigraphy, the effect that third dimension is strong.Recyclable, the degraded of this paperboard, the solvent-free volatilization of production process, the production efficiency height, energy resource consumption is low, is a kind of environment-friendly highly efficient production technology.

Claims (2)

1. a vacuum aluminum-coated frosted paperboard is characterized in that covering successively frosted coating layer (3), aluminium coated (2) on paper base material (4).
2. according to the described a kind of vacuum aluminum-coated frosted paperboard of claim 1, it is characterized in that aluminium coated (2) upward covers coating protective layer (1).
CN2010205507575U 2010-09-28 2010-09-28 Vacuum aluminum plating frosted card paper Expired - Lifetime CN201873904U (en)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002895A (en) * 2010-09-28 2011-04-06 博源科技材料(烟台)有限公司 Vacuum aluminum plating ground paperboard and production method thereof
CN103343482A (en) * 2013-05-06 2013-10-09 烟台博源科技材料股份有限公司 Environment-friendly electron beam cured gold surface coating used for aluminized paperboard and preparation method thereof
CN105835552A (en) * 2016-03-23 2016-08-10 深圳市科彩印务有限公司 Laser printing PVC substrate manufacturing method
CN107059473A (en) * 2017-03-22 2017-08-18 深圳市天宝印刷有限公司 Colour code book, colour code aluminized paper and colour code aluminized paper processing technology
CN109397911A (en) * 2018-12-27 2019-03-01 贵州劲嘉新型包装材料有限公司 A kind of printing process of membrane pressure frosting technology

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002895A (en) * 2010-09-28 2011-04-06 博源科技材料(烟台)有限公司 Vacuum aluminum plating ground paperboard and production method thereof
CN102002895B (en) * 2010-09-28 2012-10-17 博源科技材料(烟台)有限公司 Vacuum aluminum plating ground paperboard and production method thereof
CN103343482A (en) * 2013-05-06 2013-10-09 烟台博源科技材料股份有限公司 Environment-friendly electron beam cured gold surface coating used for aluminized paperboard and preparation method thereof
CN105835552A (en) * 2016-03-23 2016-08-10 深圳市科彩印务有限公司 Laser printing PVC substrate manufacturing method
CN105835552B (en) * 2016-03-23 2018-07-20 深圳市科彩印务有限公司 A kind of PVC chip base production methods being suitable for directly estimating radium-shine material printing aberration
CN107059473A (en) * 2017-03-22 2017-08-18 深圳市天宝印刷有限公司 Colour code book, colour code aluminized paper and colour code aluminized paper processing technology
CN107059473B (en) * 2017-03-22 2019-04-23 深圳市天宝印刷有限公司 Colour code book, colour code aluminized paper and colour code aluminized paper processing technology
CN109397911A (en) * 2018-12-27 2019-03-01 贵州劲嘉新型包装材料有限公司 A kind of printing process of membrane pressure frosting technology

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GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: YANTAI BOYUAN TECHNOLOGY MATERIALS CO., LTD.

Free format text: FORMER NAME: BOYUAN TECHNOLOGY MATERIAL (YANTAI) CO., LTD.

CP01 Change in the name or title of a patent holder

Address after: 264003 No. three, No. 45, latitude road, hi tech Zone, Shandong, Yantai

Patentee after: Yantai Boyuan Technology Materials Co., Ltd.

Address before: 264003 No. three, No. 45, latitude road, hi tech Zone, Shandong, Yantai

Patentee before: Boyuan Technology Material (Yantai) Co., Ltd.

CX01 Expiry of patent term

Granted publication date: 20110622

CX01 Expiry of patent term