CN107059473B - Colour code book, colour code aluminized paper and colour code aluminized paper processing technology - Google Patents
Colour code book, colour code aluminized paper and colour code aluminized paper processing technology Download PDFInfo
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- CN107059473B CN107059473B CN201710176216.7A CN201710176216A CN107059473B CN 107059473 B CN107059473 B CN 107059473B CN 201710176216 A CN201710176216 A CN 201710176216A CN 107059473 B CN107059473 B CN 107059473B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/02—Metal coatings
- D21H19/04—Metal coatings applied as foil
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
- D21H19/48—Diolefins, e.g. butadiene; Aromatic vinyl monomers, e.g. styrene; Polymerisable unsaturated acids or derivatives thereof, e.g. acrylic acid
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
Abstract
The invention discloses a kind of colour code book, colour code aluminized paper and colour code aluminized paper processing technologys, its key points of the technical solution are that including original paper layer, coated in the aluminium coated on original paper layer, coated in the adhesive layer on aluminium coated, coated in the ink layer in adhesive layer, coated in the UV layer on ink layer.When this aluminize paper jam be used as colour code when, be capable of forming the background color with metal-like, background color is closer to when then carrying out colorimetric again, colorimetric excellent effect.
Description
Technical field
The present invention relates to colour code technical field, in particular to a kind of colour code book, colour code aluminized paper and colour code aluminized paper
Processing technology.
Background technique
Colour code is embodiment of the color existing for nature on paper, fabric, plastic cement, is selected for color item, is compared, and is linked up,
It is that color realizes the tool sought unity of standard in a certain range
Existing colour code paper is usually to use paper jam, when utilize the colour code of cardboard to be used for color to metal or pearl
Color difference is certainly existed when precious a kind of progress colorimetric, so needing a kind of for metal, a kind of glossiness material color of jewelry
The colour code dedicated paper being compared, so that color compares accurately.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of colour code aluminized paper, when this is aluminized
When paper is used as production colour code, it is more accurate that the color of metal and jewelry is compared.
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of colour code aluminized paper, includes original paper layer, coated in the aluminium coated on original paper layer, coated on aluminium coated
Adhesive layer, coated in the ink layer in adhesive layer, coated in the UV layer on ink layer.
Through the above technical solutions, with the color of metal, then the aluminium coated coated on original paper layer can assign paper jam
When being used as colour code, especially the colour code of metal and jewelry when, it is more natural and proper, and aluminium coated can be improved light
Then degree coats one layer of adhesive layer on surface again, ink layer can firmly be attached on aluminium coated, then exist again by adhesive layer
UV layers are coated on ink layer, it will be able to assign ink layer excellent anti-ultraviolet property, effectively prevent it that xanthochromia occurs, and plate
Aluminium layer enables to the color of ink layer brighter, and then when being used as colour code, colorimetric effect is more accurate.
The present invention is further arranged to: the ink layer includes the component of following parts by weight, 30~40 parts of trihydroxy methyls
Propane triacrylate, 20~30 parts of urethane acrylates, 15~20 parts of filler materials, 8~12 parts of initiators, 0.1~0.2 part
Levelling agent, 1~3 part of auxiliary agent, 1~2 part of calcium hydroxide, 1~21 part of diethylene glycol diacrylate.
Through the above technical solutions, trimethylolpropane tris acrylic vinegar (TMPTA) is important acrylic-functional list
Body, it can be used as comonomer and synthesizes special acrylic resin, but also as rubber, the crosslinking agent of plastics, due to ester
Radiation curing speed is very fast, therefore reaction of 90% or more the product for ultraviolet light and electron beam curable coatings and ink etc.
Property diluent, it plays diluent before radiation exposure, and direct cross-linking reaction after irradiation, becomes the one of film-forming
Part can generate excellent to enhance hardness of film, wearability and chemical-resistance, when so it is with the ink of colour code of showing signs of anger
Wearability；Contain acrylic-functional and urethane bond, the gluing after solidification in the molecule of urethane acrylate (PUA)
Agent has high-wearing feature, adhesion strength, flexibility, high-peeling strength and the excellent resistance to low temperature and polyacrylic acid of polyurethane
The optical property and weatherability of ester brilliance are a kind of radiation curing materials of high comprehensive performance, and PUA has ammonia ester bond, special
Point is that the high-polymer molecule interchain can form a variety of hydrogen bonds, so that polyurethane film has excellent mechanical endurance and flexibility,
Elongation at break is high, and film has excellent chemical-resistance and high and low temperature resistance, equally excellent to the adhesive property of aluminium coated
Good, on the one hand the addition of filler material reduces the dosage of raw material, after on the other hand enabling to ink to coat securely；Initiator can
Increase the curing rate of ink；Levelling agent promotes ink to form a smooth, smooth, uniform painting during the drying and film forming process
Film；The addition of auxiliary agent can improve processing performance, and optical property reduces cost；The addition of curing agent enables to consolidating for film
Change speed to increase；Calcium hydroxide can generate calcium carbonate with the carbon dioxide in air, and stability is high, enhances consolidating for ink layer
Change speed, and calcium hydroxide enables to the dispersion degree of ink relatively uniform, calcium hydroxide enables to the pH of system to keep
In a certain range, promotion system keeps balance, just more difficult generation coagulation, then ink dispersibility is with regard to relatively uniform, diethylene glycol
Diacrylate can increase the curing rate of ink as curing agent.
The present invention is further arranged to: filler material selection hollow silica microsphere, tricalcium phosphate, potassium peroxydisulfate and
One of calcium chloride.
Through the above technical solutions, hollow silica microsphere can be with urethane acrylate and trimethylolpropane tris
Acrylate has good compatibility and synergistic enhancing effect, so that the heat resistance of film, hardness and water resistance are significant
It improves；And same tricalcium phosphate and urethane acrylate and trimethylolpropane trimethacrylate cooperate the stabilization so that ink
Property is relatively high；Then potassium peroxydisulfate and calcium chloride also can be with urethane acrylates and trimethylolpropane tris as filler material
Crylic acid ester mixture is uniform, then stronger in the ratio of ink coating.
The present invention is further arranged to: the initiator selection polypropylene wax or polyethylene wax.
Through the above technical solutions, polypropylene wax or polyethylene wax have good dispersibility, enable to divide between component
Cloth it is relatively uniform, but also can be improved the gloss of ink.
The present invention is further arranged to: the levelling agent selects organosilicon levelling agent.
Through the above technical solutions, the surface tension gradient that organosilicon levelling agent can eliminate film coated surface is poor, prevent from contracting
The generation in hole and ripple reduces the interfacial tension of coating and substrate, enhances the coating of coating, improves adhesive force, reduces or disappear
Except shrinkage cavity caused by due to substrate.
The present invention is further arranged to: the auxiliary agent selects organic silicon defoamer, bentonite, diatomite.
Through the above technical solutions, being used as ink since the organic matter being added in ink can generate bubble when in use
When bubble hour will generate aperture, influence surface flatness, thus setting organic silicon defoamer can be effectively relieved, and
Organic silicon defoamer weatherability is excellent；Then the bentonite and diatomite being added can be employed as filler, reduce the use of main component
Amount reduces cost, while the addition of diatomite can increase the curing rate of ink, and permeability is good, and bentonite can be inhaled
Attached organic matter then makes the stability of ink more preferable, shows that service performance is excellent as color table, is not easy to decolourize.
The present invention is further arranged to: the adhesive layer includes the component of following parts by weight: 2~3 parts of polyurethane propylene
Acid esters, 4~8 parts of polyvinyl alcohol and 2~5 parts of talcum powder.
Through the above technical solutions, containing acrylic-functional and amino first in the molecule of urethane acrylate (PUA)
Acid esters key, adhesive after solidification have the high-wearing feature of polyurethane, adhesion strength, flexibility, high-peeling strength and excellent resistance to
The optical property and weatherability of cryogenic property and polyacrylate brilliance are a kind of radiation curing materials of high comprehensive performance
Material, when being used as adhesive with excellent chemical-resistance and high and low temperature resistance；Polyvinyl alcohol has strong bond, skin
Film flexibility, flatness, oil resistivity, solvent resistance, protecting colloid, gas barrier performance, wearability, energy when being used as adhesive layer
Enough incompatible between tricalcium phosphate, potassium peroxydisulfate, precipitatings easily generated so allow for connecting between adhesive layer and ink tight
It is close, so allow for the stronger of color ink attachment, as colour code in use, because often to stir use,
The adhesive force of ink is good, is just not easy Si Aose, and using effect is excellent, and talcum powder has lubricity, anti-stick, help stream, is fire resistance, anti-
Acidity, insulating properties, fusing point be high, chemically the excellent physics such as torpescence, covering power good, softness, good luster, strong adsorption force,
Chemical characteristic can increase the consistency of adhesive, thermal expansion coefficient, and shrinkage reduces, impact strength and mechanical strength.
The present invention is further arranged to: the described UV layers component including following parts by weight: 10~15 parts of polycarbonate, 10
~15 parts of urethane acrylates, 26~40 parts of Epocryls and 2~3 parts of hydroxypropyl methyl celluloses.
Through the above technical solutions, polycarbonate has excellent mechanical performance, intensity is high, and heat-resistant aging is good, resistance to molten
Agent, moisture-stable, and good insulating；Its film after solidifying of Epocryl has hardness height, glossiness good, resistance to
Corrosive nature, heat resistance and electrochemistry are excellent, so one side good luster when being coated in ink layer surface, another aspect performance
Also more stable；Hydroxypropyl methyl cellulose also has thickening capabilities, and salt tolerance low ash powder, pH stability, water-retaining property, size are steady
Qualitative, excellent film forming and extensive resistance to enzymatic, dispersibility and caking property can be improved material so being used for UV layers
It UV layers of surface smoothness and is firmly bonded with ink layer.
Another goal of the invention of the invention, a kind of processing technology of colour code aluminized paper, including following procedure of processing, step
Rapid 1: 30~40 parts of trimethylolpropane trimethacrylates are weighed according to parts by weight, 20~30 parts of urethane acrylates, 15~
20 parts of silica, tricalcium phosphate, potassium peroxydisulfate or calcium chloride, 8~12 parts of polypropylene waxes or polyethylene wax, 0.1~0.2 part has
Machine silicon levelling agent, 1~3 part of machine silicon defoaming agent, bentonite, diatomite, 1~2 part of calcium hydroxide, 1~2 part of two propylene of diethylene glycol
Acid esters, 2~3 parts of urethane acrylates, 4~8 parts of polyvinyl alcohol and 2~5 parts of talcum powder, 10~15 parts of polycarbonate, 10~
15 parts of urethane acrylates, 26~40 parts of epoxy acrylic resins and 2~3 parts of hydroxypropyl methyl celluloses, it is spare；
Step 2: by trimethylolpropane trimethacrylate, urethane acrylate, silica, tricalcium phosphate, over cure
One of sour potassium and calcium chloride, polypropylene wax or polyethylene wax, organosilicon levelling agent are uniformly mixed, and mixing speed is being 900
Rev/min, it stirs 10 minutes, then improve revolving speed to 1700 revs/min, organic silicon defoamer, bentonite, diatomite, hydrogen is added
Calcium oxide, diethylene glycol diacrylate stir 25 minutes, are filtered with 150 mesh filter screens, it is spare to obtain ink；
Step 3: urethane acrylate, polyvinyl alcohol and talcum powder are uniformly mixed, are warming up to 45 DEG C, keeps the temperature 1.5h,
It is spare to obtain adhesive；
Step 4: polycarbonate, urethane acrylate, epoxy acrylic resin and hydroxypropyl methyl cellulose are mixed
Uniformly, 245 DEG C are warming up to, is in molten, obtains UV materials for later use；
Step 5: one layer of aluminium coated being electroplated on body paper, then the adhesive on aluminium coated in coating step 3, coating is flat
Whole, then coating oil layer of ink forms ink layer in adhesive layer again, then coats UV material on ink layer again, after then drying
Form colour code aluminized paper.
Through the above technical solutions, the aluminized paper process generated through the above steps is simple, it is steady to produce the colour code come
Qualitative height, color are excellent.
Another goal of the invention of the invention, a kind of colour code book are bound by several colour codes with aluminized paper.
Through the above technical solutions, the colour code book being prepared using colour code with aluminized paper, colorimetric effect is excellent when in use
It is good, and excellent wear-resisting property, service life are longer.
In conclusion the present invention having the beneficial effect that in contrast to the prior art
1. the background color with metal-like is capable of forming when this aluminizes paper jam when being used as colour code, when then carrying out colorimetric
Relatively, colorimetric is accurate for color；
2. the ink layer of coating is uniformly dispersed, using effect is stablized.
Detailed description of the invention
Fig. 1 is the overall structure figure of embodiment 1, it is intended to indicate each layer structure of colour code aluminized paper.
Appended drawing reference: 1, original paper layer；2, aluminium coated；3, adhesive layer；4, ink layer；5, UV layers.
Specific embodiment
Invention is further described in detail with reference to embodiments.
Embodiment 1,
A kind of colour code aluminized paper, coated in the aluminium coated 2 on original paper layer 1, applies as shown in Figure 1, including original paper layer 1
The adhesive layer 3 on aluminium coated 2 is overlayed on, coated in the ink layer 4 in adhesive layer 3, coated in the UV layer 5 on ink layer 4, when the color
Mark need to only add corresponding toner when being used as colour code with aluminized paper in ink layer 4, and then the colour code paper is in production color
Multiple aluminized papers can be bound into book form when bidding documents, be then formed into colour code book.
Wherein adhesive layer 3 includes the component of following parts by weight, 2 parts of urethane acrylates, 4 parts of polyvinyl alcohol and 2 parts
Talcum powder；
Ink layer 4 includes the component of following parts by weight, 30 parts of trimethylolpropane trimethacrylates, 20 parts of polyurethane third
Olefin(e) acid ester, 15 parts of silica, 8 parts of polypropylene waxes, 0.1 part of organosilicon levelling agent, 1 part of organic silicon defoamer, 1 part of bentonite, 1
Part diatomite, 1 part of calcium hydroxide, 1 part of diethylene glycol diacrylate；
UV layer 5 includes the component of following parts by weight, 10 parts of polycarbonate, 10 parts of urethane acrylates, 26 parts of epoxies
Acrylic resin and 2 parts of hydroxypropyl methyl celluloses.
Embodiment 2
Embodiment 2 is the difference from embodiment 1 is that the content of each component is different
Adhesive layer 3 includes the component of following parts by weight, 3 parts of urethane acrylates, 5 parts of polyvinyl alcohol and 3 parts of talcums
Powder；
Ink layer 4 includes the component of following parts by weight, 32 parts of trimethylolpropane trimethacrylates, 22 parts of polyurethane third
Olefin(e) acid ester, 16 parts of tricalcium phosphates, 8 parts of polyethylene waxes, 0.2 part of organosilicon levelling agent, 2 parts of organic silicon defoamers, 2 parts of bentonites, 1
Part diatomite, 2 parts of calcium hydroxides, 2 parts of diethylene glycol diacrylates；
UV layer 5 includes the component of following parts by weight, 11 parts of polycarbonate, 11 parts of urethane acrylates, 29 parts of epoxies
Acrylic resin and 3 parts of hydroxypropyl methyl celluloses.
Embodiment 3
Embodiment 3 is the difference from embodiment 1 is that the content of each component is different
Adhesive layer 3 includes the component of following parts by weight, 2 parts of urethane acrylates, 6 parts of polyvinyl alcohol and 4 parts of talcums
Powder；
Ink layer 4 includes the component of following parts by weight, 34 parts of trimethylolpropane trimethacrylates, 24 parts of polyurethane third
Olefin(e) acid ester, 17 parts of potassium peroxydisulfates, 10 parts of polyethylene waxes, 0.1 part of organosilicon levelling agent, 3 parts of organic silicon defoamers, 1 part of bentonite,
1 part of diatomite, 1 part of calcium hydroxide, 1 part of diethylene glycol diacrylate；
UV layer 5 includes the component of following parts by weight, 12 parts of polycarbonate, 12 parts of urethane acrylates, 31 parts of epoxies
Acrylic resin and 2 parts of hydroxypropyl methyl celluloses.
Embodiment 4
Embodiment 4 is the difference from embodiment 1 is that the content of each component is different
Adhesive layer 3 includes the component of following parts by weight, 3 parts of urethane acrylates, 7 parts of polyvinyl alcohol and 5 parts of talcums
Powder；
Ink layer 4 includes the component of following parts by weight, 36 parts of trimethylolpropane trimethacrylates, 26 parts of polyurethane third
Olefin(e) acid ester, 18 parts of calcium chloride, 11 parts of polypropylene waxes, 0.2 part of organosilicon levelling agent, 2 parts of organic silicon defoamers, 1 part of bentonite, 2
Part diatomite, 2 parts of calcium hydroxides, 2 parts of diethylene glycol diacrylates；
UV layer 5 includes the component of following parts by weight, 13 parts of polycarbonate, 13 parts of urethane acrylates, 33 parts of epoxies
Acrylic resin and 3 parts of hydroxypropyl methyl celluloses.
Embodiment 5
Embodiment 5 is the difference from embodiment 1 is that the content of each component is different
Adhesive layer 3 includes the component of following parts by weight, 2 parts of urethane acrylates, 8 parts of polyvinyl alcohol and 4 parts of talcums
Powder；
Ink layer 4 includes the component of following parts by weight, 38 parts of trimethylolpropane trimethacrylates, 28 parts of polyurethane third
Olefin(e) acid ester, 19 parts of potassium peroxydisulfates, 12 parts of polyethylene waxes, 0.1 part of organosilicon levelling agent, 1 part of organic silicon defoamer, 1 part of bentonite,
1 part of diatomite, 1 part of calcium hydroxide, 2 parts of diethylene glycol diacrylates；
UV layer 5 includes the component of following parts by weight, 14 parts of polycarbonate, 14 parts of urethane acrylates, 35 parts of epoxies
Acrylic resin and 2 parts of hydroxypropyl methyl celluloses.
Embodiment 6
Embodiment 6 is the difference from embodiment 1 is that the content of each component is different
Adhesive layer 3 includes the component of following parts by weight, 3 parts of urethane acrylates, 7 parts of polyvinyl alcohol and 3 parts of talcums
Powder；
Ink layer 4 includes the component of following parts by weight, 40 parts of trimethylolpropane trimethacrylates, 30 parts of polyurethane third
Olefin(e) acid ester, 20 parts of tricalcium phosphates, 11 parts of polyethylene waxes, 0.2 part of organosilicon levelling agent, 1 part of organic silicon defoamer, 1 part of bentonite,
1 part of diatomite, 2 parts of calcium hydroxides, 1 part of diethylene glycol diacrylate；
UV layer 5 includes the component of following parts by weight, 15 parts of polycarbonate, 15 parts of urethane acrylates, 37 parts of epoxies
Acrylic resin and 3 parts of hydroxypropyl methyl celluloses.
Embodiment 7
Embodiment 7 is the difference from embodiment 1 is that the content of each component is different
Adhesive layer 3 includes the component of following parts by weight, 2 parts of urethane acrylates, 6 parts of polyvinyl alcohol and 2 parts of talcums
Powder；
Ink layer 4 includes the component of following parts by weight, 35 parts of trimethylolpropane trimethacrylates, 25 parts of polyurethane third
Olefin(e) acid ester, 18 parts of silica, 10 parts of polypropylene waxes, 0.1 part of organosilicon levelling agent, 2 parts of organic silicon defoamers, 1 part of bentonite,
1 part of diatomite, 1 part of calcium hydroxide, 2 parts of diethylene glycol diacrylates；
UV layer 5 includes the component of following parts by weight, 14 parts of polycarbonate, 14 parts of urethane acrylates, 40 parts of epoxies
Acrylic resin and 2 parts of hydroxypropyl methyl celluloses.
Embodiment 8
A kind of processing technology of colour code aluminized paper, including following procedure of processing
Step 1: the component of Examples 1 to 7 is weighed according to parts by weight, it is spare；
Step 2: by trimethylolpropane trimethacrylate, urethane acrylate, silica, tricalcium phosphate, over cure
One of sour potassium and calcium chloride, polypropylene wax or polyethylene wax, organosilicon levelling agent are uniformly mixed, and mixing speed is being 900
Rev/min, it stirs 10 minutes, then improve revolving speed to 1700 revs/min, organic silicon defoamer, bentonite, diatomite, hydrogen is added
Calcium oxide, diethylene glycol diacrylate stir 25 minutes, are filtered with 150 mesh filter screens, it is spare to obtain ink；
Step 3: urethane acrylate, polyvinyl alcohol and talcum powder are uniformly mixed, are warming up to 45 DEG C, keeps the temperature 1.5h,
It is spare to obtain adhesive；
Step 4: polycarbonate, urethane acrylate, epoxy acrylic resin and hydroxypropyl methyl cellulose are mixed
Uniformly, 245 DEG C are warming up to, is in molten, obtains UV materials for later use；
Step 5: one layer of aluminium coated 2 is electroplated on body paper, then the adhesive on aluminium coated 2 in coating step 3,
Coat it is smooth, then again in adhesive layer 3 coating oil layer of ink 4 formed ink layer 4, then again in ink layer 4
Upper coating UV material forms colour code aluminized paper after then drying.
Experiment detection
Component in Examples 1 to 7 is detected according to colour code made from embodiment 8 with aluminized paper.
1, adhesive force
Surface should be coated by film, and hand smears ashless texture；
2, wearability
Test is by dedicated friction papers on specific heavy ring；By certain number and frequency, come back and forth in printing product surface
Friction is returned, with the presence or absence of obvious scratch or is faded finally by instrument or visual observation printing product surface, the bad phenomenons such as fuzzy；
3, appearance
Coating uniform, ink layer are bright.
The laboratory test results of 1 Examples 1 to 7 of table
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 |
| Adhesive force | It is excellent | It is excellent | It is excellent | It is excellent | It is excellent | It is excellent | It is excellent |
| Wearability | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified |
| Appearance | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified |
Find that Examples 1 to 7 meets the requirements by above table, wherein selection example 4 is comparative example.
Comparative example 1
The difference of comparative example 1 and embodiment 4 is that, without containing aluminium coated, ink layer is applied directly on original paper layer, other
It is consistent with embodiment 4.
The laboratory test results of 2 comparative example 1 of table
| Detection project | Comparative example 1 | Embodiment 4 |
| Adhesive force | It is excellent | It is excellent |
| Wearability | It is qualified | It is qualified |
| Appearance | It is unqualified | It is qualified |
By above table, by comparison comparative example 1 and embodiment 4, directly by ink layer in body paper in comparative example 1
On layer, comparative experiments testing result complies with standard on adhesive force and wearability, but there are coating unevenness, oil for appearance
The color of layer of ink is not bright enough, so the setting of the aluminium coated in embodiment 4 enables to ink layer at surface, color
It is bright, it is used as colorimetric excellent effect when colour code uses.
The above is only exemplary embodiment of the invention, protection scope and is not intended to limit the present invention, this hair
Bright protection scope is determined by the attached claims.
Claims (6)
1. a kind of colour code aluminized paper, it is characterized in that: include original paper layer (1), the aluminium coated (2) being coated on original paper layer (1),
Coated in the adhesive layer (3) on aluminium coated (2), the ink layer (4) being coated on adhesive layer (3) is coated on ink layer (4)
UV layers (5)；The ink layer (4) includes the component of following parts by weight, 30 ~ 40 parts of trimethylolpropane trimethacrylates, 20 ~
30 parts of urethane acrylates, 15 ~ 20 parts of filler materials, 8 ~ 12 parts of initiators, 0.1 ~ 0.2 part of levelling agent, 1 ~ 3 part of auxiliary agent, 1 ~ 2 part
Calcium hydroxide, 1 ~ 21 part of diethylene glycol diacrylate, the initiator selection polypropylene wax or polyethylene wax；The adhesive layer
(3) include following parts by weight component: 2 ~ 3 parts of urethane acrylates, 4 ~ 8 parts of polyvinyl alcohol and 2 ~ 5 parts of talcum powder；It is described
UV layers (5) include the component of following parts by weight: 10 ~ 15 parts of polycarbonate, 10 ~ 15 parts of urethane acrylates, 26 ~ 40 parts of rings
Oxypropylene acid resin and 2 ~ 3 parts of hydroxypropyl methyl celluloses.
2. colour code aluminized paper according to claim 1, it is characterized in that: filler material selection hollow silica is micro-
One of ball, tricalcium phosphate, potassium peroxydisulfate and calcium chloride.
3. colour code aluminized paper according to claim 1, it is characterized in that: the levelling agent selects organosilicon levelling agent.
4. colour code aluminized paper according to claim 1, it is characterized in that: the auxiliary agent selects organic silicon defoamer, swelling
Soil, diatomite.
5. a kind of processing technology of colour code aluminized paper, characterized in that including following procedure of processing,
Step 1: 30 ~ 40 parts of trimethylolpropane trimethacrylates are weighed according to parts by weight, 20 ~ 30 parts of urethane acrylates,
15 ~ 20 parts of silica, tricalcium phosphate, potassium peroxydisulfate or calcium chloride, 8 ~ 12 parts of polypropylene waxes or polyethylene wax, 0.1 ~ 0.2 part
Organosilicon levelling agent, 1 ~ 3 part of machine silicon defoaming agent, bentonite, diatomite, 1 ~ 2 part of calcium hydroxide, 1 ~ 2 part of two propylene of diethylene glycol
2 ~ 3 parts of urethane acrylates of acid esters, 4 ~ 8 parts of polyvinyl alcohol and 2 ~ 5 parts of talcum powder, 10 ~ 15 parts of polycarbonate, 10 ~ 15 parts it is poly-
Urethane acrylate, 26 ~ 40 parts of epoxy acrylic resins and 2 ~ 3 parts of hydroxypropyl methyl celluloses, it is spare；
Step 2: by trimethylolpropane trimethacrylate, urethane acrylate, silica, tricalcium phosphate, potassium peroxydisulfate
One of with calcium chloride, polypropylene wax or polyethylene wax, organosilicon levelling agent are uniformly mixed, mixing speed for 900 turns/
Minute, it stirs 10 minutes, then improve revolving speed to 1700 revs/min, organic silicon defoamer, bentonite, diatomite, hydroxide is added
Calcium, diethylene glycol diacrylate stir 25 minutes, are filtered with 150 mesh filter screens, it is spare to obtain ink；
Step 3: urethane acrylate, polyvinyl alcohol and talcum powder being uniformly mixed, are warming up to 45 DEG C, 1.5h is kept the temperature, obtains glue
Glutinous agent is spare；
Step 4: polycarbonate, urethane acrylate, epoxy acrylic resin and hydroxypropyl methyl cellulose are uniformly mixed,
245 DEG C are warming up to, is in molten, obtains UV materials for later use；
Step 5: one layer of aluminium coated (2) being electroplated on body paper, then the adhesive on aluminium coated (2) in coating step 3, coating
Smooth, then coating oil layer of ink (4) forms ink layer (4) on adhesive layer (3) again, then coats UV on ink layer (4) again
Material forms colour code aluminized paper after then drying.
6. a kind of colour code book, it is characterized in that: the colour code as described in several claim 1 ~ 5 any one bound with aluminized paper and
At.
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| CN109796808B (en) * | 2019-03-04 | 2022-01-28 | 上海秉印玻璃科技有限公司 | Water-based ink and preparation method thereof |
| CN112480740A (en) * | 2020-11-27 | 2021-03-12 | 成都普瑞斯特新材料有限公司 | High-performance water-based beer label ink and preparation method thereof |
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