CN108690209A - A kind of anti-dazzle optical coating of UV resistant and its application - Google Patents
A kind of anti-dazzle optical coating of UV resistant and its application Download PDFInfo
- Publication number
- CN108690209A CN108690209A CN201710131065.3A CN201710131065A CN108690209A CN 108690209 A CN108690209 A CN 108690209A CN 201710131065 A CN201710131065 A CN 201710131065A CN 108690209 A CN108690209 A CN 108690209A
- Authority
- CN
- China
- Prior art keywords
- parts
- film
- dazzle
- resistant
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2301/08—Cellulose derivatives
- C08J2301/10—Esters of organic acids
- C08J2301/12—Cellulose acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Laminated Bodies (AREA)
Abstract
The invention belongs to optical material fields, and in particular to a kind of anti-dazzle optical coating of UV resistant and its application.In order to solve due to light source is irradiated to screen surface the technical issues of generating dazzle in screen surface, the present invention provides a kind of anti-dazzle optical coatings of UV resistant.The film includes substrate layer and at least one layer of hard conating positioned at base material layer surface;In preparation process, the raw material of the hard conating are first configured to coating fluid, and the coating fluid includes:120-180 parts of 3-12 parts of 40-80 parts of acrylic compounds oligomer, 15-35 parts of acrylic monomer, organic filler or inorganic particulate, 2-7 parts of photoinitiator, 0.1-1 parts of wetting dispersing agent, 0.1-1 parts of levelling agent, 0.1-1 parts of UV absorbers and solvent;The number is parts by weight.The anti-dazzle optical coating of the UV resistant has excellent anti-glare properties energy.
Description
Technical field
The invention belongs to optical material fields, and in particular to a kind of anti-dazzle optical coating of UV resistant and its application.
Background technology
In recent years, various novel flat-plates show that (LCD, OLED, LED) technology and product are quickly grown, display industry and its
Market, which alternates to change in the world, to make rapid progress.Earliest untreated planar surface can Reflective inner or external strong light into
Enter human eye, generates dazzle, lead to eyes stung, the dimness of vision.Such issues that solve, the usual method is that in the table of display
Face carries out fine coarse processing.One is carry out coarse etching or printing, but the generation of this means on surface with physical method
Rough surface fining is inadequate, is only used in the display screen of low resolution, another method be added in hardening masking liquid it is micro-
, the convex lines of dimple can be formed on surface after curing of coatings, it is certain can to provide film surface while anti-dazzle for this coating
Hardness and Scratch Resistance energy, be the anti-dazzle mainstream processing method of current display.
What is prepared in the Chinese patent application that publication No. is CN 102890297A (publication date be on January 23rd, 2013) is anti-
Dizzy layer is to apply to contain translucent resin and translucency particle, anti-glare painting on a face of the base material or two faces
Layer composition and formed, and have bumps on surface, although the cured film for preparing of this method can be with to external light
Achieve the purpose that anti-dazzle, but the light penetrated for display interior backlight is beaten in the concaveconvex shape of most surface, this structure
It can play the role of subtle lens, generate the state of the pixel flicker of display, i.e., it is so-called " flash-point ".It simultaneously can be due to surface mistake
Observation is caused to have the phenomenon that whitening in coarse.
Application No. is the Chinese patent applications of 201210314648.7 (publication date is on July 17th, 2013) to disclose one kind
UV light anti-glare hard coating film, the UV light anti-glare hard coating film have preferable anti-dazzle performance and anti-fouling effect, and hardness is high,
There is preferable adhesion strength, but do not have good weatherability, especially uv-resistance energy, the open air for being unable to large area is answered
With.
Invention content
In order to solve due to light source is irradiated to screen surface the technical issues of generating dazzle in screen surface, the present invention carries
A kind of anti-dazzle optical coating of UV resistant is supplied.The anti-dazzle optical coating of the UV resistant has excellent anti-glare properties energy, meanwhile,
The anti-dazzle optical coating of the UV resistant will not because surface is excessively coarse cause made by display device surface whiten the problem of.
In order to solve the above technical problems, the present invention provides technical solution below:
The present invention provides a kind of anti-dazzle optical coating of UV resistant, and the film includes substrate layer and is located at substrate layer table
At least one layer of hard conating in face;In preparation process, the raw material of the hard conating are first configured to coating fluid, the coating fluid packet
It includes:It is 3-12 parts of 40-80 parts of acrylic compounds oligomer, 15-35 parts of acrylic monomer, organic filler or inorganic particulate, light-initiated
120-180 parts of 2-7 parts of agent, 0.1-1 parts of wetting dispersing agent, 0.1-1 parts of levelling agent, 0.1-1 parts of UV absorbers and solvent;
The number is parts by weight.
The substrate layer is transparent membrane.The hard conating has the function of anti-dazzle.
Further, in the anti-dazzle optical coating of the UV resistant, in preparation process, the former material of the hard conating
Material is first configured to coating fluid, and the coating fluid includes:60-78 parts of acrylic compounds oligomer, 15-25 parts of acrylic monomer, has
The average grain diameter of 4-9 parts of machine particle or inorganic particulate, organic filler or inorganic particulate is 2-5 microns, 2-5 parts of photoinitiator, profit
0.5-1 parts of hygroscopic water powder, 0.2-0.3 parts of levelling agent, 0.2-0.8 parts of UV absorbers, 130-150 parts of solvent.Aforementioned techniques
Scheme corresponding embodiment 1-3, embodiment 6 and 7, embodiment 11.
Further, the organic filler or inorganic particulate are referred to as transparent particles, are Light-transmitting particles.
Further, in the anti-dazzle optical coating of the UV resistant, the substrate layer is selected from polyester film, polyethylene
Film, polypropylene film, glassine paper, diacetyl cellulose film, triacetyl cellulose film, butyric acid acetylcellulose are thin
Film, polyvinyl chloride film, Vingon film, polyvinyl alcohol film, ethylene-vinyl acetate copolymer film, polyphenyl second
Alkene film, polycarbonate film, poly-methyl pentene film, polysulphone film, poly (ether ether ketone) film, Polyethersulfone membranes, polyimides are thin
One kind in film, fluorine resin film, polyamide film or acrylic resin films.
The polyester film, such as polyethylene terephthalate (PET) film, polybutylene terephthalate (PBT)
(PBT) film.
Further, in the anti-dazzle optical coating of the UV resistant, the thickness of the substrate layer is 15-250 μm.
Further, the thickness of the substrate layer is 30-200 μm.Further, the thickness of the substrate layer is 30-100
μm。
Further, in the anti-dazzle optical coating of the UV resistant, the acrylic compounds oligomer is selected from amino first
One kind in acid esters acrylate oligomer, epoxy acrylate oligomer, polyester acrylate or polyether acrylate or extremely
Few two kinds of mixture.
Further, in the anti-dazzle optical coating of the UV resistant, the acrylic monomer was selected from for two seasons penta 4
Six acrylate of alcohol, dipentaerythritol hydroxy pentaacrylate, pentaerythritol tetraacrylate, pentaerythritol triacrylate,
Trimethylene propyl triacrylate, propoxylated glycerol triacrylate, trimethylolpropane ethoxy triacrylate, 1,
6- hexanediyl esters, two propylene of propoxylated glyceryl triacrylate, tripropylene glycol diacrylate or ethylene glycol
One kind in acid esters or at least two mixture.
Further, in the anti-dazzle optical coating of the UV resistant, the material of the organic filler is selected from polyphenyl second
Alkene, polymethyl methacrylate, polyacrylate, acrylic styrene copolymer, acrylate-styrene copolymer,
Copolymer of methyl methacrylatestyrene, makrolon, polyvinyl chloride, polybutylene terephthalate (PBT), poly- terephthaldehyde
Sour glycol ester, polyamide, polyimides, polysulfones, polyphenylene oxide, polyacetals, epoxy resin, phenolic resin, silicones, melamine
Polyimide resin, benzoguanamine, polydivinylbenezene, divinyl benzene styrene copolymer, divinylbenzene-acryl ester copolymer,
Polydiallyl phthalate or one kind in triallyl isocyanurate polymer or at least two mixing, either
Above-mentioned at least two polymer.
Further, in the anti-dazzle optical coating of the UV resistant, the organic filler has spherical or elliposoidal
Shape, and the average grain diameter of the organic filler be 1-12 μm.
Further, the average grain diameter of the organic filler is 2-8 μm.
Further, the average grain diameter of the organic filler is 2-5 μm.
Further, in the anti-dazzle optical coating of the UV resistant, the inorganic particulate be selected from silicon dioxide granule,
One kind in silicon particle, aluminum hydroxide particles, magnesium hydroxide particles, aluminium oxide particles, Zirconia particles and TiO 2 particles
Or at least two mixing.
Further, the shape of the inorganic particulate is spherical or elliposoidal, and average grain diameter is 1-12 μm.Preferably,
The average grain diameter of the inorganic particulate is 2-8 μm, more preferably 2-5 μm.
Further, the average grain diameter of the inorganic particulate is 2.8 microns.Further, the inorganic particulate is Tosoh
The product that the trade mark of company's production is SS-55YC.
In anti-dazzle film of the present invention, the refractive index of the coating without organic filler or inorganic particulate is preferably
1.46-1.65 more preferably 1.49-1.60, particularly preferably be 1.49-1.53.
In above-mentioned particle size range and the ranges of indices of refraction of coating, it will not leave behind visible coating unevenness and interference be uneven
Property, and the high rigidity of antiglare layer can be obtained.
Transparent particles (organic filler or inorganic particulate) and acrylate oligomer and acrylic acid in the anti-dazzle film of the present invention
The refringence for the resin that ester monomer is formed controls between 0.01-0.3, when refringence is less than 0.01, it is difficult to obtain foot
Enough haze values, when refringence is more than 0.3, haze value can increase and light transmittance can reduce, and contrast is caused to reduce.
Further, in the film, the photoinitiator be selected from styrax, benzoin methyl ether, benzoin ethyl ether,
Benzoin isopropyl ether, styrax n-butyl ether, benzoin isobutyl ether, acetophenone, dimethylamino benzoylformaldoxime, 2,2- dimethoxys-
2- phenyl acetophenones, 2,2- diethoxy -2- phenyl acetophenones, 2- hydroxy-2-methyl -1- phenyl-propane -1- ketone, 1- hydroxyl rings
Hexyl benzophenone, 2- methyl-1s-;4- (methyl mercapto) Ben Jis ]- 2- morpholinyls-propane -1- ketone, 4- (2- hydroxyl-oxethyls) phenyl -2
(hydroxyl -2- propyl) ketone, benzophenone, to phenyl benzophenone, 4,4'Diethylamino benzophenone, dichloro benzophenone,
2-methylanthraquinone, 2- ethyl hydrazine, 2- tertiary butyls anthraquinone, 2- amino anthraquinones, 2- methyl thioxanthones, 2- ethyls thioxanthones, 2- chlorine
Thioxanthones, 2,4- dimethyl thioxanthones, 2,4- diethyl thioxanthones, benzyl dimethyl ketal, acetophenone dimethyl ketal or right
One kind in dimethylamino benzoate or at least two combination.
Further, in the film, the wetting dispersing agent is selected from BYK-161, BYK-162, BYK-163,
One kind in BYK-164, BYK-166, BYK-184, BYK-2000, BYK-2008, BYK-2009 or BYK-2050 or at least two
The mixture of kind.
Further, in the film, the levelling agent is the levelling agent of low-surface-energy.The levelling agent is selected from fluorine
Class levelling agent or type siloxane levelling agent.The type siloxane levelling agent is selected from BYK-3570, BYK-3500, BYK-310, BYK-
342, BYK-3505, TEGO-100 or TEGO-432.The fluorine class levelling agent is selected from BYK-354, KY-1203, FS-6170, JF-
1128 or JF-1129.
Further, in the film, the ultra-violet absorber is selected from UV-326, UV-327, UV-328, UV-
329, UV-292, UV-531, UV-770, UV-1130, UV-0 or UV-9.
Further, in the film, it is molten that the solvent is selected from alcohols, ketone, alkanes, benzene class, esters or ethers
One kind in agent or at least two mixture.
The alcohols solvent is selected from methanol, ethyl alcohol, isopropanol, butanol, methyl cellosolve or ethyl cellosolve.
The ketones solvent is selected from methyl ethyl ketone, espeleton, methylisobutylketone, metacetone, dipropyl ketone or hexamethylene
Ketone.
The alkanes solvent is selected from hexane, heptane or octane.
The benzene kind solvent is selected from benzene, toluene or dimethylbenzene.
The esters solvent is selected from ethyl acetate, butyl acetate or propylene glycol methyl ether acetate.
The ether solvent is selected from propylene glycol monomethyl ether.
The above-mentioned solvent being listed, can use individually, or two or more combination is used.
Further, in the film, the acrylic compounds oligomer is selected from the trade mark 6195- of Changxing company production
The product of 100 product or the trade mark CN9013NS of Sartomer's production.
Further, in the film, the acrylic monomer is selected from the trade mark EM339's of Changxing company production
The product of product or trade mark EM331.
Further, in the film, the organic filler is selected from 3 microns of average grain diameter, the production of ponding company
The product of trade mark SSX-102 or the product of trade mark SSX-100.
Further, in the film, the photoinitiator is selected from the production of the trade mark 184 of double bond chemical company production
Product.
Further, in the film, the wetting dispersing agent is selected from the trade mark BYK-2009's of BYK companies production
The product of product or trade mark BYK-2050.
Further, in the film, the levelling agent is selected from the production of the trade mark BYK-3500 of BYK companies production
Product.
Further, in the film, the UV absorbers are selected from the trade mark 1130 of BASF AG's production
Product.
Further, in the film, the mixed solvent is the mixture of toluene and propylene glycol monomethyl ether, wherein first
The mass ratio of benzene and propylene glycol monomethyl ether is:6:4.
The present invention also provides a kind of application of the anti-dazzle optical coating of the UV resistant, the film is used for display unit
Part.
Further, the film is used as display screen.
Further, during preparing the anti-dazzle optical coating of UV resistant provided by the invention, the former material of hard conating
Material is first configured to coating fluid, and coating fluid is coated with by wet coating, and the coating method of coating fluid is selected from rolling method, silk rod coating, spray
Coating, dipping coating, spin-coating method or slot coated.It is preferred that rolling method.More preferable dimple coating.
Further, the anti-dazzle film of the present invention will first carry out dried coating film before curing, can select to spontaneously dry, and dry
It is dry, the modes such as heat drying.
Further, the anti-dazzle film of the present invention is in the preferred radiation-curing of curing mode, more preferable ultraviolet curing.
Further, as energy source, mercury vapor lamp, halogen lamp, xenon lamp, metal halide lamp, N_2 laser etc. can be selected.
Further, the exposure of energy is with the cumulative exposure gauge of ultraviolet wavelength 365nm, preferably 50-500mJ/
cm2。
Further, the mist degree of the anti-dazzle film of the present invention controls between 1%-25%, and transmitance is 90% or more.
Further, the coating thickness of dry film of the anti-dazzle film of the present invention controls between 2-15 μm.
Compared with prior art, the anti-dazzle optical coating of UV resistant provided by the invention has the following advantages:This is resistance to ultraviolet
The anti-dazzle optical coating of line have excellent anti-glare properties energy, meanwhile, the film will not because surface is excessively coarse cause made by
Display device surface the problem of whitening;The film also has higher hardness, preferable abrasion resistance preferable resistance to ultraviolet
Property, comprehensive performance is preferable.The preparation method of the anti-dazzle optical coating of UV resistant provided by the invention is simple for process, easily operated.
Moreover, the glossiness (20 °) of the anti-dazzle optical coating of the UV resistant is moderate, ensure that the light for being incident on eyes is soft
With, and the anti-dazzle optical coating of UV resistant has excellent UV resistant performance, is adapted to the outdoor application of large area.It is described
The anti-dazzle optical coating of UV resistant, the performance with UV resistant, can be used for fine display surface to prevent external light source
It is irradiated to surface and generates dazzle.The anti-dazzle optical coating of the UV resistant is applied to computer monitor, and laptop duplicates
It is the OA such as machine machines (office automated machine), mobile phone, clock and watch, digital camera, portable data assistance (PDA), portable
The household electrical appliance such as the portable machines such as formula game machine, video camera, television set, micro-wave oven, the shop display machines such as information experience device
The guards equipment such as device, monitoring monitor.
Description of the drawings:
Fig. 1 be the embodiment of the present invention 1 provide UV resistant anti-dazzle optical coating under light reflection halation situation;
Fig. 2 is anti-dazzle film in the comparative example 1 reflection halation situation under light;
Fig. 3 is anti-dazzle film in the comparative example 3 reflection halation situation under light.
Specific implementation mode:
To more fully understand technical scheme of the present invention, the present invention is carried out below in conjunction with attached drawing and specific embodiment detailed
It describes in detail bright.
As shown in Figure 1, anti-dazzle film prepared by the embodiment of the present invention 1, there is halation, non-whitening under light.
As shown in Fig. 2, anti-dazzle film prepared by comparative example 1, has halation under light, whitens.Although having anti-dazzle work(
Can, but the display effect of panel is influenced, reduce ornamental experience.
As shown in figure 3, not having halation on film, the triacetyl cellulose film that comparative example 3 provides is just without anti-dazzle work(
Energy.
Film in embodiment is prepared in accordance with the following methods.
One, the preparation of coating fluid:
The organic or inorganic particle and wetting dispersing agent that formula ratio is added to the in the mixed solvent of formula ratio are stirred
After even;The acrylic compounds oligomer and acrylic monomer for adding formula ratio, after being mixed evenly;Then formula ratio is added
Photoinitiator, levelling agent and UV absorbers, after being uniformly mixed, coating fluid is made.
Two, it is coated with:
By the coating fluid of above-mentioned acquisition, being coated on triacetyl cellulose film, (Konica company produces, and film thickness 40 is micro-
Rice, trade mark KC4UA) surface on, 75-85 DEG C of drying in oven 1-10min, taking-up is 50-500mJ/cm with cumlative energy2It is purple
Outer photocuring obtains anti-dazzle film.
Further, coating fluid selects 18# rod coatings (12 microns of wet-film thickness).
Further, after coating solution, in 80 DEG C of drying in oven 2min, taking-up is 300mJ/ with cumlative energy
cm2Ultraviolet light cures, and obtains anti-dazzle film.
The test method of the properties of obtained anti-dazzle film is as follows:
(1) mist degree
According to being provided in standard ASTMD 1003, haze meter NDH-2000 is used to detect print mist degree.
(2) glossiness
Think to lead to ETB-0833 vancometers, gloss value of the test sample under 20 ° using one.
(3) pencil hardness:
With reference to JIS K-5600-5-4 specifications, with 3M-P1000 models sand paper by Mitsubishi's anisomerous H pencil points end face
It polishes, then pencil is fixed on hand propelled pencil hardometer.Five regions are chosen in film overall with width direction, add 500g weights
Code, measures respectively.Exerted oneself with hand horizontal direction, gently push pencil hardometer, movement speed 1mm/s, mobile 30-50mm away from
From after gently wiping surface with erasing rubber, being visually inspected with all directions by fluorescent lamp, see that whether there is or not scuffings, if do not drawn
Wound is then indicated through (beginning 3mm disregards).Number before H is bigger, and hardness is higher.
(4) rub resistance:
Using 339 abrasion performance testing machines of Model, 5cm × 10cm samples are cut, are fixed on abrasion performance experiment machine platform,
Using #0000 steel wool, 250g loads, rub n times back and forth, takes out sample, and visually whether there is or not scuffings for observation.Record scratches
Rubbing number N, N is higher, and number is more, illustrates that wearability is better.
(5) uv-resistance energy
Sample is put into after uncoated face paste is black in UV ageing ovens, setting working procedure is:Ultraviolet light 1w/m2,
8h is radiated, 4h is sprayed under 50 DEG C of environment of no irradiation, is a cycle with this 12h, recycles as progress 8, hereafter take out altogether
Print is exerted oneself in anti-dazzle coat side level using cross-cut tester with reference to JIS K-5600 standards, marks the 10 × 10 of right-angled intersection
100 sub-boxes.Then it is tightly attached on 10 × 10 hundred lattice with hundred lattice test tapes of 3M, waits for 90s, is kept for 180 ° and quickly torn
Except adhesive tape, whether there is or not fall off for hundred lattice floating coats of observation.OK (qualification) is indicated if not falling off, if fallen off, then it represents that uv-resistance
It can NG (unqualified).
(6) reflection halation situation:Anti-dazzle print is attached to transparent OCA glue on the acrylic board of black, in fluorescent lamp
Lower observation film surface reflected light halation situation.It is to have the function of anti-dazzle to have halation.There are halation, non-whitening, for qualification.
Embodiment 1:
The present invention provides a kind of anti-dazzle optical coating of UV resistant, and the film includes substrate layer and is located at substrate layer table
One layer of hard conating in face.The raw material of the hard conating are first configured to coating fluid, and the formula of the coating fluid is as follows:
60 parts of acrylic compounds oligomer (Changxing company produces, trade mark 6195-100), acrylic monomer (give birth to by Changxing company
Production, trade mark EM339) 25 parts, it is 9 parts of organic filler (3 microns of average grain diameter, ponding company production, trade mark SSX-102), light-initiated
5 parts of agent (double bond chemical company produces, the trade mark 184), 0.5 part of wetting dispersing agent (BYK companies produce, trade mark BYK-2009), stream
Flat 0.25 part of agent (BYK companies produce, trade mark BYK-3500), UV absorbers (BASF AG produces, the trade mark 1130)
0.25 part, mixed solvent (toluene:Propylene glycol monomethyl ether=6:4) 150 parts.
Coating layer is 300mJ/cm with cumlative energy in 80 DEG C of drying in oven 2min, taking-up2Ultraviolet light cures.
The substrate layer is triacetyl cellulose film, and thickness is 40 microns.
The performance of gained film is shown in Table 1.
Embodiment 2:
The present invention provides a kind of anti-dazzle optical coating of UV resistant, and the film includes substrate layer and is located at substrate layer table
One layer of hard conating in face.The raw material of the hard conating are first configured to coating fluid, and the formula of the coating fluid is as follows:
60 parts of acrylic compounds oligomer (Sartomer produces, trade mark CN9013NS), acrylic monomer (Changxing company
Production, trade mark EM331) 25 parts, 9 parts of organic filler (3 microns of average grain diameter, ponding company production, trade mark SSX-102), light draws
Send out 5 parts of agent (double bond chemical company produce, the trade mark 184), 0.5 part of wetting dispersing agent (BYK companies produce, trade mark BYK-2050),
0.25 part of levelling agent (BYK companies produce, trade mark BYK-3500), UV absorbers (BASF AG produces, the trade mark 1130)
0.25 part, mixed solvent (toluene:Propylene glycol monomethyl ether=6:4) 150 parts.
Coating layer is 300mJ/cm with cumlative energy in 80 DEG C of drying in oven 2min, taking-up2Ultraviolet light cures.
The substrate layer is triacetyl cellulose film, and thickness is 40 microns.
The performance of gained film is shown in Table 1.
Embodiment 3:
The present invention provides a kind of anti-dazzle optical coating of UV resistant, and the film includes substrate layer and is located at substrate layer table
One layer of hard conating in face.The raw material of the hard conating are first configured to coating fluid, and the formula of the coating fluid is as follows:
78 parts of acrylic compounds oligomer (Sartomer produces, trade mark CN9013NS), acrylic monomer (Changxing company
Production, trade mark EM339) 15 parts, 4 parts of organic filler (3 microns of average grain diameter, ponding company production, trade mark SSX-100), light draws
Send out 2 parts of agent (double bond chemical company produces, the trade mark 184), 1 part of wetting dispersing agent (BYK companies produce, trade mark BYK-2050), stream
Flat 0.2 part of agent (BYK companies produce, trade mark BYK-3500), UV absorbers (BASF AG produces, the trade mark 1130) 0.8
Part, mixed solvent (toluene:Propylene glycol monomethyl ether=6:4) 150 parts.
Coating layer is 300mJ/cm with cumlative energy in 80 DEG C of drying in oven 2min, taking-up2Ultraviolet light cures.
The substrate layer is triacetyl cellulose film, and thickness is 40 microns.
The performance of gained film is shown in Table 1.
Embodiment 4
Such as the anti-dazzle optical coating for the UV resistant that embodiment 1 provides, wherein the formula of coating fluid is as follows:
The average grain diameter of 40 parts of acrylic compounds oligomer, 35 parts of acrylic monomer, 3 parts of organic filler, organic filler is 2
Micron, 7 parts of photoinitiator, 0.1 part of wetting dispersing agent, 0.1 part of levelling agent, 0.1 part of UV absorbers.120 parts of mixed solvent.
Substrate layer is the PET that thickness is 15 microns.
Coating layer is 50mJ/cm with cumlative energy in 75 DEG C of drying in oven 10min, taking-up2Ultraviolet light cures.Coating fluid
After solidification, the thickness of dry film of hardened layer is 2-6 μm.
Embodiment 5
Such as the anti-dazzle optical coating for the UV resistant that embodiment 1 provides, wherein the formula of coating fluid is as follows:
80 parts of acrylic compounds oligomer, 15 parts of acrylic monomer, 12 parts of organic filler, the average grain diameter of organic filler are
8 microns, 6 parts of photoinitiator, 0.2 part of wetting dispersing agent, 1 part of levelling agent, 1 part of UV absorbers.180 parts of mixed solvent.Base
Material layer is the PBT that thickness is 250 microns.Coating layer is 500mJ/cm with cumlative energy in 85 DEG C of drying in oven 1min, taking-up2
Ultraviolet light cures.After coating fluid solidification, the thickness of dry film of hardened layer is 9-16 μm.
Embodiment 6
Such as the anti-dazzle optical coating for the UV resistant that embodiment 1 provides, wherein the formula of coating fluid is as follows:
The average grain diameter of 65 parts of acrylic compounds oligomer, 18 parts of acrylic monomer, 6 parts of organic filler, organic filler is 5
Micron, 3 parts of photoinitiator, 0.8 part of wetting dispersing agent, 0.25 part of levelling agent, 0.2 part of UV absorbers.Mixed solvent 130
Part.The thickness of substrate layer is 30 microns.
Embodiment 7
Such as the anti-dazzle optical coating for the UV resistant that embodiment 2 provides, wherein the formula of coating fluid is as follows:
The average grain diameter of 72 parts of acrylic compounds oligomer, 20 parts of acrylic monomer, 7 parts of organic filler, organic filler is 2
Micron, 4 parts of photoinitiator, 0.9 part of wetting dispersing agent, 0.3 part of levelling agent, 0.5 part of UV absorbers.140 parts of mixed solvent.
The thickness of substrate layer is 100 microns.
Embodiment 8
Such as the anti-dazzle optical coating for the UV resistant that embodiment 7 provides, wherein the thickness of substrate layer is 150 microns.
Embodiment 9
Such as the anti-dazzle optical coating for the UV resistant that embodiment 7 provides, wherein the thickness of substrate layer is 200 microns.
Embodiment 10
Such as the anti-dazzle optical coating for the UV resistant that embodiment 3 provides, wherein the formula of coating fluid is as follows:
75 parts of acrylic compounds oligomer, 30 parts of acrylic monomer, 10 parts of organic filler, the average grain diameter of organic filler are
7 microns, 4 parts of photoinitiator, 0.6 part of wetting dispersing agent, 0.2 part of levelling agent, 0.6 part of UV absorbers.Mixed solvent 160
Part.Substrate layer is the polypropylene film that thickness is 100 microns.
Embodiment 11:
As embodiment 1 provide UV resistant anti-dazzle optical coating, the film include substrate layer and be located at substrate layer
One layer of hard conating on surface.The raw material of the hard conating are first configured to coating fluid, and the formula of the coating fluid is as follows:
60 parts of acrylic compounds oligomer (Changxing company produces, trade mark 6195-100), acrylic monomer (give birth to by Changxing company
Production, trade mark EM339) 25 parts, 9 parts of inorganic particulate (2.8 microns of average grain diameter, Tosoh company production, trade mark SS-55YC), light draws
Send out 5 parts of agent (double bond chemical company produce, the trade mark 184), 0.5 part of wetting dispersing agent (BYK companies produce, trade mark BYK-2009),
0.25 part of levelling agent (BYK companies produce, trade mark BYK-3500), UV absorbers (BASF AG produces, the trade mark 1130)
0.25 part, mixed solvent (toluene:Propylene glycol monomethyl ether=6:4) 150 parts.
Coating layer is 300mJ/cm with cumlative energy in 80 DEG C of drying in oven 2min, taking-up2Ultraviolet light cures.
The performance of gained film is shown in Table 1.
Comparative example 1:
To 150 parts of mixed solvent (toluene:Propylene glycol monomethyl ether=6:4) add 9 parts of organic fillers (3 microns of average grain diameter,
Ponding company produces, trade mark SSX-102) and 0.5 part of wetting dispersing agent (BYK companies produce, trade mark BYK-2009), it is stirred
After uniformly, 60 parts of acrylic compounds oligomer (Changxing company produces, trade mark 6195-100) are added, 25 parts of acrylic monomers are (long
Xing companies produce, trade mark EM339), after being mixed evenly, 5 parts of photoinitiators, 184,0.5 part of levelling agent is added, and (BYK companies give birth to
Production, trade mark BYK-3500), after being uniformly mixed, coating fluid is made.Being coated on triacetyl cellulose film, (Konica is public
Department's production, 40 microns of film thickness, trade mark KC4UA) on, select 18# rod coatings (12 microns of wet-film thickness), 80 DEG C of drying in oven
2min, taking-up are 300mJ/cm with cumlative energy2Ultraviolet light cures, and obtains anti-dazzle film.The anti-dazzle film that comparative example 1 obtains
UV absorbers are free of in hardened layer.
Comparative example 2:
To 150 parts of mixed solvent (toluene:Propylene glycol monomethyl ether=6:4) (average grain diameter 10 is micro- for 13 parts of inorganic particulates of addition
Rice, W. R. Grace & Co's production, trade mark ED80) and 0.5 part of wetting dispersing agent (BYK companies produce, trade mark BYK-2009), stirring is mixed
After closing uniformly, 60 parts of acrylic compounds oligomer (Changxing company produces, trade mark 6195-100), 25 parts of acrylic monomers are added
(Changxing company produces, trade mark EM339), after being mixed evenly, 5 parts of photoinitiators, 184,0.25 part of levelling agent is added, and (BYK is public
Department's production, trade mark BYK-3500), 0.25 part of UV absorbers (BASF AG produces, the trade mark 1130) are uniformly mixed
Afterwards, coating fluid is made.It is coated on triacetyl cellulose film (Konica company produces, 40 microns of film thickness, trade mark KC4UA)
On, 18# rod coatings (12 microns of wet-film thickness) are selected, 80 DEG C of drying in oven 2min, taking-up is 300mJ/ with cumlative energy
cm2Ultraviolet light cures, and obtains anti-dazzle film.The content mistake of inorganic particulate in the hardened layer for the anti-dazzle film that comparative example 2 obtains
It is high.
Comparative example 3:
(Konica company produces triacetyl cellulose film without the coating of any masking liquid, 40 microns of film thickness, the trade mark
KC4UA)。
1 present invention of table provides the properties detection data for the film that embodiment and comparative example provide
It can be obtained by the performance test results of table 1, the mist degree of anti-dazzle film provided by the invention, the numerical value of glossiness exists
It is too high or too low not as in comparative example in one zone of reasonableness, cause the reflection halation of film bad.The present invention provides
Anti-dazzle film there is higher UV resistant performance, anti-dazzle light effect is preferable.Wherein, embodiment 1-3, embodiment 6-7, and it is real
The comprehensive performance for applying the anti-dazzle film of the offer of example 11 is more preferable.
What has been described above is only a preferred embodiment of the present invention, and present invention is not limited to the above embodiments.It is appreciated that this
The other improvements and change that field technology personnel directly export or associate without departing from the spirit and concept in the present invention
Change, is all included in the scope of protection of the present invention.
Claims (10)
1. a kind of anti-dazzle optical coating of UV resistant, which is characterized in that the film include substrate layer and be located at substrate layer table
At least one layer of hard conating in face;In preparation process, the raw material of the hard conating are first configured to coating fluid, the coating fluid packet
It includes:It is 3-12 parts of 40-80 parts of acrylic compounds oligomer, 15-35 parts of acrylic monomer, organic filler or inorganic particulate, light-initiated
120-180 parts of 2-7 parts of agent, 0.1-1 parts of wetting dispersing agent, 0.1-1 parts of levelling agent, 0.1-1 parts of UV absorbers and solvent;
The number is parts by weight.
2. film according to claim 1, which is characterized in that in preparation process, the raw material of the hard conating are first matched
Coating fluid is made, the coating fluid includes:60-78 parts of acrylic compounds oligomer, 15-25 parts of acrylic monomer, organic filler
Or 4-9 parts of inorganic particulate, the average grain diameter of organic filler or inorganic particulate is 2-5 microns, 2-5 parts of photoinitiator, wetting and dispersing
0.5-1 parts of agent, 0.2-0.3 parts of levelling agent, 0.2-0.8 parts of UV absorbers, 130-150 parts of solvent.
3. film according to claim 1, which is characterized in that the substrate layer is selected from polyester film, polyethylene film, gathers
Polypropylene film, glassine paper, diacetyl cellulose film, triacetyl cellulose film, butyric acid acetyl cellulose film, polychlorostyrene
Vinyl film, polyvinyl alcohol film, ethylene-vinyl acetate copolymer film, polystyrene film, gathers Vingon film
Carbonic ester film, poly-methyl pentene film, polysulphone film, poly (ether ether ketone) film, Polyethersulfone membranes, Kapton, fluorine tree
One kind in membrane of lipoprotein, polyamide film or acrylic resin films.
4. film according to claim 1, which is characterized in that the thickness of the substrate layer is 15-250 μm.
5. film according to claim 1, which is characterized in that the acrylic compounds oligomer is selected from carbamate propylene
One kind in acid esters oligomer, epoxy acrylate oligomer, polyester acrylate or polyether acrylate or at least two
Mixture.
6. film according to claim 1, which is characterized in that the acrylic monomer is selected from six propylene of dipentaerythritol
Acid esters, dipentaerythritol hydroxy pentaacrylate, pentaerythritol tetraacrylate, pentaerythritol triacrylate, trimethylene
Propyl triacrylate, propoxylated glycerol triacrylate, trimethylolpropane ethoxy triacrylate, 1,6-HD
In diacrylate, propoxylated glyceryl triacrylate, tripropylene glycol diacrylate or glycol diacrylate
It is a kind of or at least two mixture.
7. film according to claim 1, which is characterized in that the material of the organic filler is selected from polystyrene, poly- first
Base methyl acrylate, polyacrylate, acrylic styrene copolymer, acrylate-styrene copolymer, methyl-prop
E pioic acid methyl ester-styrol copolymer, makrolon, polyvinyl chloride, polybutylene terephthalate (PBT), poly terephthalic acid second two
Alcohol ester, polyamide, polyimides, polysulfones, polyphenylene oxide, polyacetals, epoxy resin, phenolic resin, silicones, melamine tree
Fat, benzoguanamine, polydivinylbenezene, divinyl benzene styrene copolymer, divinylbenzene-acryl ester copolymer, poly- neighbour
Dially phthalate or one kind in triallyl isocyanurate polymer or at least two mixing or above-mentioned
At least two polymer.
8. film according to claim 1, which is characterized in that the organic filler has spherical or elliposoidal shape,
And the average grain diameter of the organic filler is 1-12 μm.
9. film according to claim 1, which is characterized in that the inorganic particulate be selected from silicon dioxide granule, silicon particle,
One kind in aluminum hydroxide particles, magnesium hydroxide particles, aluminium oxide particles, Zirconia particles and TiO 2 particles or at least two
The mixing of kind.
10. a kind of application of the anti-dazzle optical coating of any one of them UV resistant among 1-9 according to claim, feature
It is, the film is used for display unit.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710131065.3A CN108690209A (en) | 2017-03-07 | 2017-03-07 | A kind of anti-dazzle optical coating of UV resistant and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710131065.3A CN108690209A (en) | 2017-03-07 | 2017-03-07 | A kind of anti-dazzle optical coating of UV resistant and its application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108690209A true CN108690209A (en) | 2018-10-23 |
Family
ID=63841943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710131065.3A Pending CN108690209A (en) | 2017-03-07 | 2017-03-07 | A kind of anti-dazzle optical coating of UV resistant and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108690209A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109810555A (en) * | 2018-12-21 | 2019-05-28 | 宁波激智科技股份有限公司 | The hardened layer coating fluid and a kind of cured film of a kind of high rigidity, anti-dazzle |
| CN110845881A (en) * | 2019-08-15 | 2020-02-28 | 上海中大洁润丝实验室科技有限公司 | Super-printing-resistant photosensitive material and screen printing plate |
| CN111454478A (en) * | 2020-03-28 | 2020-07-28 | 南京诺邦新材料有限公司 | Shading film for aircraft porthole window shade |
| CN112876953A (en) * | 2021-01-18 | 2021-06-01 | 唐山润峰复合材料有限公司 | Anti-dazzle daylighting panel |
| CN114213694A (en) * | 2021-12-24 | 2022-03-22 | 苏州诺菲纳米科技有限公司 | Anti-glare film with high haze and low flash point and preparation method thereof |
| CN114231136A (en) * | 2021-12-20 | 2022-03-25 | 江苏皇冠新材料科技有限公司 | Antibacterial AG coating liquid composition, antibacterial AG coating liquid, antibacterial AG writing film and preparation method thereof |
| CN114479152A (en) * | 2021-12-30 | 2022-05-13 | 宁波惠之星新材料科技有限公司 | High-hardness anti-dazzle film |
| CN114958050A (en) * | 2022-04-28 | 2022-08-30 | 江苏日久光电股份有限公司 | Multifunctional coating material, multifunctional film and multifunctional component |
| CN115851111A (en) * | 2022-12-29 | 2023-03-28 | 宁波惠之星新材料科技股份有限公司 | Protective layer coating and protective film |
| CN115873289A (en) * | 2022-12-21 | 2023-03-31 | 合肥乐凯科技产业有限公司 | Anti-ultraviolet hardening film with strong flexibility |
| CN116656257A (en) * | 2023-06-07 | 2023-08-29 | 精一门(常州)光学薄膜有限公司 | Explosion-proof anti-dazzle automobile film and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09127305A (en) * | 1995-10-31 | 1997-05-16 | Sumitomo Chem Co Ltd | Antidazzle film or sheet having excellent resistance against contamination |
| CN103205190A (en) * | 2012-08-30 | 2013-07-17 | 湖北航天化学技术研究所 | Ultraviolet-cured anti-dazzle hard film and application thereof |
| CN104312229A (en) * | 2014-09-28 | 2015-01-28 | 上海维凯光电新材料有限公司 | Anti-flouring anti-dazzle radiation curing coating composition |
| CN104312232A (en) * | 2014-09-28 | 2015-01-28 | 上海维凯光电新材料有限公司 | Anti-glare and anti-static light radiation curing coating composition |
| CN105038570A (en) * | 2015-07-14 | 2015-11-11 | 深圳市汇万川塑胶薄膜有限公司 | Highly scratch-resistant anti-dazzle ultraviolet-curable coating and application method therefor |
| CN105315879A (en) * | 2014-07-11 | 2016-02-10 | 湖北航天化学技术研究所 | High definition ultraviolet (UV) cured antidazzle hard film |
| CN105907287A (en) * | 2016-05-16 | 2016-08-31 | 四川龙华光电薄膜股份有限公司 | Anti-ultraviolet anti-glare anti-fingerprint hardness-increasing coating liquid composition, coating and preparation method of coating |
-
2017
- 2017-03-07 CN CN201710131065.3A patent/CN108690209A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09127305A (en) * | 1995-10-31 | 1997-05-16 | Sumitomo Chem Co Ltd | Antidazzle film or sheet having excellent resistance against contamination |
| CN103205190A (en) * | 2012-08-30 | 2013-07-17 | 湖北航天化学技术研究所 | Ultraviolet-cured anti-dazzle hard film and application thereof |
| CN105315879A (en) * | 2014-07-11 | 2016-02-10 | 湖北航天化学技术研究所 | High definition ultraviolet (UV) cured antidazzle hard film |
| CN104312229A (en) * | 2014-09-28 | 2015-01-28 | 上海维凯光电新材料有限公司 | Anti-flouring anti-dazzle radiation curing coating composition |
| CN104312232A (en) * | 2014-09-28 | 2015-01-28 | 上海维凯光电新材料有限公司 | Anti-glare and anti-static light radiation curing coating composition |
| CN105038570A (en) * | 2015-07-14 | 2015-11-11 | 深圳市汇万川塑胶薄膜有限公司 | Highly scratch-resistant anti-dazzle ultraviolet-curable coating and application method therefor |
| CN105907287A (en) * | 2016-05-16 | 2016-08-31 | 四川龙华光电薄膜股份有限公司 | Anti-ultraviolet anti-glare anti-fingerprint hardness-increasing coating liquid composition, coating and preparation method of coating |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109810555A (en) * | 2018-12-21 | 2019-05-28 | 宁波激智科技股份有限公司 | The hardened layer coating fluid and a kind of cured film of a kind of high rigidity, anti-dazzle |
| CN110845881A (en) * | 2019-08-15 | 2020-02-28 | 上海中大洁润丝实验室科技有限公司 | Super-printing-resistant photosensitive material and screen printing plate |
| CN111454478B (en) * | 2020-03-28 | 2022-09-30 | 南京诺邦新材料有限公司 | Shading film for aircraft porthole shading curtain |
| CN111454478A (en) * | 2020-03-28 | 2020-07-28 | 南京诺邦新材料有限公司 | Shading film for aircraft porthole window shade |
| CN112876953A (en) * | 2021-01-18 | 2021-06-01 | 唐山润峰复合材料有限公司 | Anti-dazzle daylighting panel |
| CN114231136A (en) * | 2021-12-20 | 2022-03-25 | 江苏皇冠新材料科技有限公司 | Antibacterial AG coating liquid composition, antibacterial AG coating liquid, antibacterial AG writing film and preparation method thereof |
| CN114213694A (en) * | 2021-12-24 | 2022-03-22 | 苏州诺菲纳米科技有限公司 | Anti-glare film with high haze and low flash point and preparation method thereof |
| CN114479152A (en) * | 2021-12-30 | 2022-05-13 | 宁波惠之星新材料科技有限公司 | High-hardness anti-dazzle film |
| CN114958050A (en) * | 2022-04-28 | 2022-08-30 | 江苏日久光电股份有限公司 | Multifunctional coating material, multifunctional film and multifunctional component |
| CN115873289A (en) * | 2022-12-21 | 2023-03-31 | 合肥乐凯科技产业有限公司 | Anti-ultraviolet hardening film with strong flexibility |
| CN115851111A (en) * | 2022-12-29 | 2023-03-28 | 宁波惠之星新材料科技股份有限公司 | Protective layer coating and protective film |
| CN116656257A (en) * | 2023-06-07 | 2023-08-29 | 精一门(常州)光学薄膜有限公司 | Explosion-proof anti-dazzle automobile film and preparation method thereof |
| CN116656257B (en) * | 2023-06-07 | 2024-03-22 | 精一门(常州)光学薄膜有限公司 | Explosion-proof anti-dazzle automobile film and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108690209A (en) | A kind of anti-dazzle optical coating of UV resistant and its application | |
| CN106338783B (en) | A kind of anti-dazzle antireflective optical film and its preparation method and application | |
| JP5944404B2 (en) | Optically cured film and method for producing the same | |
| US11326072B2 (en) | High hardness flexible hard coating film | |
| CN103620447B (en) | The manufacture method of moulding material, coating composition and moulding material | |
| TWI416161B (en) | Laser pointer visibility improving film, polarizing plate, image display, and laser pointer display method | |
| CN105315879B (en) | A kind of high-resolution UV-curing anti-glare hard coating film | |
| TW201040022A (en) | Surface protection film | |
| CN101796146A (en) | Comprise self-assembling antireflective coating through the high refractive index nanoparticles of surface modification | |
| CN109196390A (en) | Optical laminate | |
| JPWO2009025292A1 (en) | Antireflection film | |
| JP2008163339A (en) | Anti-uv coating composition and its use | |
| KR100314949B1 (en) | Attachment film for electronic display device | |
| CN112327394B (en) | Anti-glare film with high wear resistance and low flash point | |
| TW201808607A (en) | Hard coat film | |
| CN109073788A (en) | Hard coat film | |
| JP2013222153A (en) | Hard coat film, polarizing plate, front plate, and image display device | |
| JP2007127823A (en) | Optical film and its manufacturing method | |
| CN105273585A (en) | UV (ultraviolet)-blocking and antifouling coating composition, hard coating film and preparation methods | |
| JP2004287392A (en) | Optical film | |
| TW202009474A (en) | Method for evaluating fingerprint resistance, method for manufacturing optical member, and optical member capable of evaluating fingerprint resistance quantitatively with high reproductivity | |
| TW201510117A (en) | Ultraviolet-curable hard coat resin composition | |
| KR20070078893A (en) | Coating composition for low refractive layer, anti-reflection film using the same and image displaying device comprising said anti-reflection film | |
| KR102606447B1 (en) | Coatings containing clay, resin and organic solvents, protective films using the same, and products | |
| JP2005288286A (en) | Manufacturing method of hard coat film and hard coat film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181023 |
|
| RJ01 | Rejection of invention patent application after publication |