CN105602484B - A kind of special transfer film of ceramics and preparation method thereof - Google Patents
A kind of special transfer film of ceramics and preparation method thereof Download PDFInfo
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- CN105602484B CN105602484B CN201511012938.6A CN201511012938A CN105602484B CN 105602484 B CN105602484 B CN 105602484B CN 201511012938 A CN201511012938 A CN 201511012938A CN 105602484 B CN105602484 B CN 105602484B
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- ceramics
- special
- gum
- layer
- transfer film
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention relates to transfer technical field of membrane, and in particular to a kind of special transfer film of ceramics and preparation method thereof.A kind of special transfer film of ceramics, base membrane layer, release layer, pattern layer, gum layer, the gum layer are the special gum of ceramics from top to bottom, and the special gum of ceramics is made of the raw material of following parts by weight：Acrylic resin modified, modified epoxy, UV solidified resins, TPO photoinitiator, closing curing agent, adhesion promoter, wetting agent, n-propyl, ethyl ester coat release layer, 85 95 DEG C of drying in the way of printing on the surface of base membrane layer；With mode of printing pattern layer, 85 95 DEG C of drying are coated on the surface of release layer；The special transfer film of ceramics is obtained in the special gum of surface coating ceramic of pattern layer, 115 125 DEG C of drying in a manner of coating, with good transferring effect, adhesive force is high, the smooth bubble-free of transfer surface, and yields is high, and Costco Wholesale is low.
Description
Technical field
The present invention relates to transfer technical field of membrane, and in particular to a kind of special transfer film of ceramics and preparation method thereof.
Background technology
Transfer film is called transfer membrane, is that the pattern layer that will be printed in advance is transferred in specific article, certain to overcome
Article is difficult to the problem of directly printing.Such as ceramic film-making, due to the hardness of ceramics is big, in fragile, weight, it is difficult to using passing
Required pattern is directly printed on ceramics by the printing process of system, it is therefore desirable to which transfer film transfers pattern on ceramics.
Based on the gluing of ceramic blank plate roller coating and then transferring, this glue is generally liquid glue for ceramics transfer on the market at present,
Poor adhesive force is just fallen after soaked, and easy tos produce wrinkle and bubble in production process entirely.Major defect has：1, blanket roller
The glue flatness of painting is undesirable, easy tos produce water wave and steam bubble.2, the bigger product of the glue quantity of blanket roller coating glue at
This is heavy, and is easier to generate the stain caused by dust, high rejection rate.3, the complex process of blanket gluing, equipment cost
It is high.
Invention content
In order to overcome shortcoming and defect existing in the prior art, the purpose of the present invention is to provide a kind of special turn of ceramics
Die, with good transferring effect, adhesive force is high, the smooth bubble-free of transfer surface, and yields is high, and Costco Wholesale is low.
Another goal of the invention of the present invention is to provide a kind of preparation method of the special transfer film of ceramics, has transfer
Simple process and low cost, efficient feature.
The purpose of the invention is achieved by the following technical solution：
A kind of special transfer film of ceramics, is followed successively by base membrane layer, release layer, pattern layer, gum layer, the gum from top to bottom
Layer is the special gum of ceramics, and the special gum of ceramics is made of the raw material of following parts by weight：
30-50 parts of acrylic resin
10-30 parts of epoxy resin
3-10 parts of UV solidified resins
1-5 parts of TPO photoinitiator
Close 2-10 parts of curing agent
1-5 parts of adhesion promoter
1-4 parts of wetting agent
5-20 parts of n-propyl
5-20 parts of ethyl ester.
Specific gum formula is used specifically for the transfer in terms of ceramics through the invention, and adhesive force is good, does not generate
Bubble, and stability is good.Raw material in above-mentioned gum formula is liquid charging stock, and above-mentioned raw materials are uniformly mixed according to proportioning
It can be obtained the special gum of ceramics.
Further, the special gum of ceramics is made of the raw material of following parts by weight：
35-40 parts of acrylic resin
15-20 parts of epoxy resin
5-8 parts of UV solidified resins
1-2 parts of TPO photoinitiator
Close 5-8 parts of curing agent
2-3 parts of adhesion promoter
1-2 parts of wetting agent
9-18 parts of n-propyl
8-18 parts of ethyl ester.
Further, the special gum of ceramics is made of the raw material of following parts by weight：
35-38 parts of acrylic resin
15-18 parts of epoxy resin
5-7 parts of UV solidified resins
1-2 parts of TPO photoinitiator
Close 5-7 parts of curing agent
2-3 parts of adhesion promoter
1-2 parts of wetting agent
9-12 parts of n-propyl
8-12 parts of ethyl ester.
The ethyl ester is the second esters solvents such as ethyl acetate, Ethyl formate, ethyl propionate.
Wherein, the acrylic resin is methyl methacrylate, ethyl methacrylate, ethyl acrylate preparation
Obtained acrylic resin or maleic rosin is acrylic resin modified.Preferably maleic rosin is acrylic resin modified, wearability
Well, flexibility is good, impact strength and tensile strength are relatively high, chemical resistance is excellent and adhesion is excellent, obtained colloid
Viscosity is good, and stability is good, it is preferable to use ROHM AND HAAS B-48N products.
Epoxy resin can select commercially available three wells 820-40CX products.
Wherein, the UV solidified resins resin is unsaturated polyester (UP) resinoid or polyurethane acrylates resin.The tree
Fat is at normal temperatures solid-state, therefore can individually be printed on transfer membrane and preserve in rolls, and hot melt turns at a temperature of 180 DEG C or so
Print can melt, and penetrate into the gap of ceramic surface, be finally fitted in ceramics and pass through photocuring reaction, light-initiated with TPO
Agent and closing curing agent chemically react, and improve adhesion strength and adhesive force, and further hardening is adhered to, and improve its stability and attached
Put forth effort.
Wherein, the UV solidified resins are hard polyaminoester acrylic paint.The typical products of the substance produce for Asia
The trade mark be SE-400 product, high-quality, stability is strong, and adhesive force is good.
Wherein, the closing curing agent is the enclosed type polyisocyanate curing agent based on hexamethylene diisocyanate,
Closing NCO content is 10-12%, and Typical Representative is 3175 type product of Bayer, and obtained ceramic Special back glue is high-quality, attached
Put forth effort strong.
Wherein, the adhesion promoter is vinyl trichlorosilane, vinyltrimethoxysilane, three ethoxy of vinyl
Any one of base silane or γ-glycidol ether propyl trimethoxy silicane.Preferably γ-glycidol ether propyl trimethoxy
Base silane improves the intensity of composite material, improves caking property, improves dry/wet compressive strength.
Wherein, the wetting agent is that 5% fluorine oxygroup modified organic silicon is dissolved in methyl-isobutyl ketone, has wetting, levelling, resists
The comprehensive performance of oil and defoaming.Wetting agent it is preferable to use DOW CORNING DC-7244 products as the present invention.
A kind of preparation method of the special transfer film of ceramics, includes the following steps：
A, release layer, 85-95 DEG C of drying are coated on the surface of base membrane layer in the way of printing；
B, pattern layer, 85-95 DEG C of drying are coated on the surface of release layer using mode of printing；
C, the special gum layer of ceramics is formed in the special gum of surface coating ceramic of pattern layer in the way of coating,
115-125 DEG C of drying, gets product.
The beneficial effects of the present invention are：The present invention develops suitable for this specific technical field of ceramic transfer film
Together in ceramics transfer.Present invention mainly solves the complex process of present ceramic gluing transfer, and with high costs, rejection rate height etc. is asked
Topic.The performance of the present invention has with advantage：
1, ceramic special glue of the invention is can be coated on coiled with dry film form on film, and when use, direct uncoiling used,
Convenience in transport, storage, management.
2, the present invention is so that after glue hot melt adhesion, curing agent curing reaction when high temperature transfer, then UV light stiffened is solid
Change, being combined by three kinds of crosslinkings makes pattern adhere on ceramic blank plate securely.
3, present invention improves original gluing transfer printing process, cost is greatly reduced, also improves transfer Production of Ceramics
Yield rate.
4, the used material of the present invention meets the EU criterias such as EN-71, ROSH.
Description of the drawings
Fig. 1 is a kind of schematic cross-section of the special transfer film of ceramics of the present invention；
Reference numeral is：1 --- --- release layer 3 --- pattern layer 4 --- gum layer of base membrane layer 2.
Specific implementation mode
For the ease of the understanding of those skilled in the art, the present invention is made with reference to embodiment and attached drawing 1 further
Illustrate, the content that embodiment refers to not is limitation of the invention.
Embodiment 1
As shown in Figure 1：A kind of special transfer film of ceramics, base membrane layer 1, release layer 2, release layer 3, gum layer 4 from top to bottom,
The gum layer 4 is the special gum of ceramics, and the special gum of ceramics is made of the raw material of following parts by weight：
30 parts of acrylic resin
10 parts of epoxy resin
3 parts of UV solidified resins
1 part of TPO photoinitiator
Close 2 parts of curing agent
1 part of adhesion promoter
1 part of wetting agent
5 parts of n-propyl
5 parts of ethyl ester.
The ethyl ester is ethyl acetate.
The acrylic resin is that maleic rosin is acrylic resin modified.
The UV solidified resins are hard polyaminoester acrylic paint.
The closing curing agent is the enclosed type polyisocyanate curing agent based on hexamethylene diisocyanate, closing
NCO content is 10-12%.
The adhesion promoter is vinyl trichlorosilane.
The wetting agent is that 5% fluorine oxygroup modified organic silicon is dissolved in methyl-isobutyl ketone.
A kind of preparation method of the special transfer film of ceramics, includes the following steps：
A, in the surface of base membrane layer 1 coating 2,85 DEG C of drying of release layer in the way of printing；
B, with mode of printing in the surface of release layer 2 coating 3,85 DEG C of drying of release layer；
C, in the special gum of surface coating ceramic of release layer 3,115 DEG C of drying in a manner of coating.
Embodiment 2
A kind of special transfer film of ceramics, from top to bottom base membrane layer 1, release layer 2, release layer 3, gum layer 4, the gum layer
4 be the special gum of ceramics, and the special gum of ceramics is made of the raw material of following parts by weight：
50 parts of acrylic resin
30 parts of epoxy resin
10 parts of UV solidified resins
5 parts of TPO photoinitiator
Close 10 parts of curing agent
5 parts of adhesion promoter
4 parts of wetting agent
20 parts of n-propyl
20 parts of ethyl ester.
The ethyl ester is Ethyl formate.
The acrylic resin is the acrylic resin that methyl methacrylate is prepared
The UV solidified resins are hard polyaminoester acrylic paint.
The closing curing agent is the enclosed type polyisocyanate curing agent based on hexamethylene diisocyanate, closing
NCO content is 10-12%.
The adhesion promoter is vinyltrimethoxysilane.
The wetting agent is that 5% fluorine oxygroup modified organic silicon is dissolved in methyl-isobutyl ketone.
A kind of preparation method of the special transfer film of ceramics, includes the following steps：
A, in the surface of base membrane layer 1 coating 2,95 DEG C of drying of release layer in the way of printing；
B, with mode of printing in the surface of release layer 2 coating 3,95 DEG C of drying of release layer；
C, in the special gum of surface coating ceramic of release layer 3,125 DEG C of drying in a manner of coating.
Embodiment 3
A kind of special transfer film of ceramics, from top to bottom base membrane layer 1, release layer 2, release layer 3, gum layer 4, the gum layer
4 be the special gum of ceramics, and the special gum of ceramics is made of the raw material of following parts by weight：
40 parts of ROHM AND HAAS B-48N of acrylic resin
15 part of three well 820-40CX of epoxy resin
8 parts of Asia SE-400 of UV solidified resins
2 parts of vapour bar TPO of TPO photoinitiator
Close 8 parts of Bayers 3175 of curing agent
3 parts of DOW CORNINGs 6040 of adhesion promoter
2 parts of DOW CORNING DC-7244 of wetting agent
9 parts of n-propyl
8 parts of ethyl propionate.
A kind of preparation method of the special transfer film of ceramics, includes the following steps：
A, in the surface of base membrane layer 1 coating 2,90 DEG C of drying of release layer in the way of printing；
B, with mode of printing in the surface of release layer 2 coating 3,90 DEG C of drying of release layer；
C, in the special gum of surface coating ceramic of release layer 3,120 DEG C of drying in a manner of coating.
Embodiment 4
A kind of special transfer film of ceramics, from top to bottom base membrane layer 1, release layer 2, release layer 3, gum layer 4, the gum layer
4 be the special gum of ceramics, and the special gum of ceramics is made of the raw material of following parts by weight：
38 parts of ROHM AND HAAS B-48N of acrylic resin
18 part of three well 820-40CX of epoxy resin
7 parts of Asia SE-400 of UV solidified resins
1 part of vapour bar TPO of TPO photoinitiator
Close 7 parts of Bayers 3175 of curing agent
2 parts of DOW CORNINGs 6040 of adhesion promoter
1 part of DOW CORNING DC-7244 of wetting agent
12 parts of n-propyl
6 parts of ethyl acetate.
A kind of preparation method of the special transfer film of ceramics, includes the following steps：
A, in the surface of base membrane layer 1 coating 2,95 DEG C of drying of release layer in the way of printing；
B, with mode of printing in the surface of release layer 2 coating 3,95 DEG C of drying of release layer；
C, in the special gum of surface coating ceramic of release layer 3,125 DEG C of drying in a manner of coating.
Above-described embodiment is the preferable implementation of the present invention, and in addition to this, the present invention can be realized with other manner,
Any obvious replacement is not departed under the premise of present inventive concept within protection scope of the present invention.
Claims (7)
1. a kind of special transfer film of ceramics, is followed successively by base membrane layer, release layer, pattern layer, gum layer, feature exists from top to bottom
In：The gum layer is the special gum of ceramics, and the special gum of ceramics is made of the raw material of following parts by weight：
Closing curing agent in the special gum of ceramics is the enclosed type polyisocyanate based on hexamethylene diisocyanate
Curing agent, closing NCO content are 10-12%；Adhesion promoter in the special gum of ceramics be vinyl trichlorosilane,
It is arbitrary in vinyltrimethoxysilane, vinyltriethoxysilane or γ-glycidol ether propyl trimethoxy silicane
It is a kind of；Wetting agent in the special gum of ceramics is that 5% fluorine oxygroup modified organic silicon is dissolved in methyl-isobutyl ketone.
2. a kind of special transfer film of ceramics according to claim 1, it is characterised in that：The special gum of ceramics is by following
The raw material of parts by weight forms：
3. a kind of special transfer film of ceramics according to claim 1, it is characterised in that：The special gum of ceramics is by following
The raw material of parts by weight forms：
4. according to a kind of special transfer film of ceramics of claim 1-3 any one of them, it is characterised in that：The ceramics are special
In gum it is acrylic resin modified for maleic rosin it is acrylic resin modified.
5. according to a kind of special transfer film of ceramics of claim 1-3 any one of them, it is characterised in that：The ceramics are special
UV solidified resins in gum are unsaturated polyester (UP) resinoid or polyurethane acrylates resin.
6. according to a kind of special transfer film of ceramics of claim 1-3 any one of them, it is characterised in that：The ceramics are special
UV solidified resins in gum are hard polyaminoester acrylic paint resin.
7. a kind of preparation method of the special transfer film of ceramics of claim 1-6 any one of them, it is characterised in that：Including following
Step：
A, release layer, 85-95 DEG C of drying are coated on the surface of base membrane layer in the way of printing；
B, pattern layer, 85-95 DEG C of drying are coated on the surface of release layer using mode of printing；
C, the special gum layer of ceramics, 115-125 are formed in the special gum of surface coating ceramic of pattern layer in the way of coating
DEG C drying to get finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201511012938.6A CN105602484B (en) | 2015-12-31 | 2015-12-31 | A kind of special transfer film of ceramics and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511012938.6A CN105602484B (en) | 2015-12-31 | 2015-12-31 | A kind of special transfer film of ceramics and preparation method thereof |
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| CN105602484A CN105602484A (en) | 2016-05-25 |
| CN105602484B true CN105602484B (en) | 2018-08-17 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634717A (en) * | 2016-09-13 | 2017-05-10 | 广西大学 | Anti-corrosive high-viscosity binder and preparation method thereof |
| CN110551464A (en) * | 2018-06-01 | 2019-12-10 | 禹辉（上海）新材料科技股份有限公司 | Heat transfer glue for glass paint spraying winebottle |
| CN112172371A (en) * | 2019-07-03 | 2021-01-05 | Oppo广东移动通信有限公司 | Structural member, method for manufacturing structural member, and electronic device |
| CN112442327B (en) * | 2019-08-27 | 2022-05-27 | 上海乘鹰新材料有限公司 | Super-weather-resistant bi-component adhesive for building interior and exterior decoration |
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| CN101942277A (en) * | 2010-09-02 | 2011-01-12 | 东莞市贝特利新材料有限公司 | Ultraviolet curing transfer adhesive |
| CN102199402A (en) * | 2011-03-18 | 2011-09-28 | 武汉大学 | Ultraviolet curing adhesive for transfer printing film |
| CN102936476A (en) * | 2012-11-05 | 2013-02-20 | 中国印刷科学技术研究所 | Heat transfer printing adhesion agent, heat transfer printing film and heat transfer printing method |
-
2015
- 2015-12-31 CN CN201511012938.6A patent/CN105602484B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942277A (en) * | 2010-09-02 | 2011-01-12 | 东莞市贝特利新材料有限公司 | Ultraviolet curing transfer adhesive |
| CN102199402A (en) * | 2011-03-18 | 2011-09-28 | 武汉大学 | Ultraviolet curing adhesive for transfer printing film |
| CN102936476A (en) * | 2012-11-05 | 2013-02-20 | 中国印刷科学技术研究所 | Heat transfer printing adhesion agent, heat transfer printing film and heat transfer printing method |
Non-Patent Citations (1)
| Title |
|---|
| 玻璃基材的新型UV转印胶黏剂;邹洋 等;《中国印刷与包装研究》;20100630;第2卷(第3期);第44-49页 * |
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| CN105602484A (en) | 2016-05-25 |
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| CB02 | Change of applicant information |
Address after: Guangdong province Dongguan City Wanjiang 523000 stream Chong Wei Nan Fang Industrial Zone Applicant after: DONGGUAN ZHUOYI PRINTING PRODUCT CO., LTD. Address before: 523000 Guangdong province Dongguan City Wanjiang liuyongwei Industrial Zone Nanbo Zhuoyi printing products Co. Ltd. Applicant before: DONGGUAN ZHUOYI PRINTING PRODUCT CO., LTD. |
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| CB03 | Change of inventor or designer information |
Inventor after: Li Qibiao Inventor after: Kong Lingqing Inventor after: Li Zhuokun Inventor before: Li Guozhong Inventor before: Liu Bingquan |
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