CN105969299B - The preparation method of noresidue gluing advertisement consumptive material - Google Patents
The preparation method of noresidue gluing advertisement consumptive material Download PDFInfo
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- CN105969299B CN105969299B CN201610365018.0A CN201610365018A CN105969299B CN 105969299 B CN105969299 B CN 105969299B CN 201610365018 A CN201610365018 A CN 201610365018A CN 105969299 B CN105969299 B CN 105969299B
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- parts
- noresidue
- gluing
- consumptive material
- adhesive layer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2483/00—Presence of polysiloxane
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention discloses the preparation methods of noresidue gluing advertisement consumptive material.It for the adhesive of noresidue gluing advertisement consumptive material, is made of the raw material of following mass parts: 100 parts of vinyl terminated polysiloxane, 100-150 parts of solvent, 1-5 parts of crosslinking agent, 1-5 parts of promotor, 1-5 parts of catalyst.Noresidue gluing advertisement consumptive material, including printing layer, and the adhesive layer preparation method being arranged in printing layer, comprising steps of 1) be uniformly mixed other compositions in addition to crosslinking agent, promotor, catalyst, crosslinking agent, promotor are added, is uniformly mixed, catalyst is added, is mixed；2) material after mixing is coated below printing layer, forms adhesive layer；3) in adhesive layer following settings release film, winding.Advertisement consumptive material good weatherability of the invention, initial bonding strength is low, and hold viscosity energy is good, has preferable high temperature resistance and light transmittance, tears this consumptive material from surface is posted, and remains without residue glue.
Description
Technical field
The present invention relates to the preparation methods of noresidue gluing advertisement consumptive material.
Background technique
Billboard is widely used to life various aspects as a kind of mass medium mode.Wherein, billboard
Carrier-gum is also pressure-sensitive table printing material, be with paper, plastic film and glue, the production of the materials such as release paper and
A kind of digital printing field application advertisement consumptive material, its front can have glue with air brushing picture or pattern, the back side, can paste
On panel, wall, KT plate, the carriers such as glass, vehicle body.
Glass and ads. on vehicle are repeated carrier at present, and other advertisements are largely disposable carrier.For example gum produces
After product printing pattern, directly mounting overlays on KT plate or wall, when replacing again, needs to replace KT plate together, or wall is clear
Reason is clean, needs wall advertisement to protect wall, and most of mounting, which overlays on panel or KT plate, to be shown.And glass and vehicle
Body advertisement itself needs to retain respective feature, and common gum is affixed directly to glass or body paint surface, is greater than 1 using the time
After a month, it is easy for the problem of glue residual occur, the stickup time is longer, and residual is more serious, is more difficult to clear up.Mainly because
It is pressure-sensitive acrylate for common glue, is easy to be influenced by temperature and ultraviolet light in use, meanwhile, solvent goes out
Now further volatilization, leads to adhesion strength substantial increase, greater than the cohesive force of material, to residue glue phenomenon occur.
Summary of the invention
The purpose of the present invention is to provide the preparation methods of noresidue gluing advertisement consumptive material.
The technical solution used in the present invention is:
For the adhesive of noresidue gluing advertisement consumptive material, it is made of the raw material of following mass parts: ethenyl blocking
100 parts of polysiloxanes, 100-150 parts of solvent, 1-5 parts of crosslinking agent, 1-5 parts of promotor, 1-5 parts of catalyst.
The vinyl terminated polysiloxane is selected from the dimethyl (siloxanes and polysiloxanes) of mono-vinyl sealing end, end
At least one of vinyl poly- (dimethyl siloxane).
The viscosity of the ethenyl blocking dimethyl silicone polymer is 8000 ~ 30000mpa.s/25 DEG C.
The crosslinking agent is containing hydrogen silicone oil.
The catalyst is platinum compounds and/or platinum complex；The promotor is coupling agent.
Noresidue gluing advertisement consumptive material, including printing layer, and the adhesive layer being arranged under printing layer；Wherein, described
Adhesive layer is made of above-mentioned raw materials.
The printing layer is made of basement membrane and setting in epilamellar printed coating；Or printing layer is surface printing
The plastic foil of functionalization or other printing materials.
The basement membrane is the composite membrane of one of PP film, BOPP film, PET film, BOPET film or two or more formation.
It further include the release film being arranged under adhesive layer.
The preparation method of noresidue gluing advertisement consumptive material, comprising steps of
1) other compositions in addition to crosslinking agent, promotor, catalyst are uniformly mixed, add crosslinking agent, promotor,
It is uniformly mixed, adds catalyst, mix；
2) material after mixing is coated below printing layer, forms adhesive layer；
3) in adhesive layer following settings release film, winding.
The beneficial effects of the present invention are:
Advertisement consumptive material good weatherability of the invention, initial bonding strength is low, and hold viscosity energy is good, with preferable high temperature resistance and thoroughly
Light rate tears this consumptive material from surface is posted, and remains without residue glue.
It is more specific:
(1), noresidue gluing advertisement consumptive material good weatherability of the present invention, noresidue, replacement is convenient, cleans without inorganic agent.
(2), noresidue gluing advertisement consumptive material of the present invention just glues low, quick and easy for installation, can be posted in smooth glass repeatedly,
Plank, iron plate, aluminium-plastic panel, frosting.
(3), noresidue gluing advertisement consumptive material of the present invention and preparation method thereof is curing type adhesive, and dissolvent residual is few, more
Add environmental protection.
(4), noresidue gluing advertisement consumptive material of the present invention and preparation method thereof, processing method is simple, easily realizes that industry is automatic
Metaplasia produces, high production efficiency.
Specific embodiment
For the adhesive of noresidue gluing advertisement consumptive material, it is made of the raw material of following mass parts: ethenyl blocking
100 parts of polysiloxanes, 100-150 parts of solvent, 1-5 parts of crosslinking agent, 1-5 parts of promotor, 1-5 parts of catalyst.
Preferably, the vinyl terminated polysiloxane is selected from dimethyl (siloxanes and the poly- silicon of mono-vinyl sealing end
Oxygen alkane), at least one of end-vinyl poly- (dimethyl siloxane)；The structural formula of end-vinyl poly- (dimethyl siloxane) shows
It means:
Preferably, the dimethyl (siloxanes and polysiloxanes) or end-vinyl poly- (two of selected mono-vinyl sealing end
Methylsiloxane) viscosity be 8000 ~ 30000mpa.s/25 DEG C.
Preferably, the crosslinking agent is containing hydrogen silicone oil；It is further preferred that hydrogen content is 0.5-2%.
Preferably, the catalyst is platinum compounds and/or platinum complex；Such as: the aqueous isopropanol of chloroplatinic acid,
Platinum-tetramethyl divinyl disiloxane complex compound, platinum-t etram-ethyltetravinylcyclotetrasiloxane complex compound.
Preferably, the crosslinking agent is coupling agent；It is further preferred that being silane coupling agent, titanate coupling agent, aluminium
At least one of acid esters coupling agent, zirconium ester coupling agent, rare-earth coupling agent；It still more preferably, is silane coupling agent, example
For example at least one of KH550, KH560, KH570.
Noresidue gluing advertisement consumptive material, including printing layer, and the adhesive layer being arranged under printing layer；Wherein, described
Adhesive layer is made of above-mentioned raw materials.
Preferably, the thickness of dry film of adhesive layer is 5-50 μm；It is further preferred that just gluing is No. 2-6 after adhesive layer is dry
Ball is held and is glued not slide for 24 hours.
Preferably, the printing layer is made of basement membrane and setting in epilamellar printed coating；Or printing layer is
The plastic foil of surface printing functionalization；It or is other well known printing material such as paper.
Preferably, the basement membrane is one of PP film, BOPP film, PET film, BOPET film or two or more formation
Composite membrane；The form of composite membrane is the preparation of existing well-known technique, such as composite co-extruding film；Or pass through adhesive for single film
The composite membrane being adhesively-bonded together to form.
Surface-functionalized meaning be by plastic foil (one of PP film, BOPP film, PET film, BOPET film, or
The composite membrane of two or more formation) surface is handled (such as corona), so that the surface tension on its surface changes, thus suitable
It closes and bears fixing printing ink or other printing materials.
It preferably, further include the release film being arranged on adhesive layer；It is further preferred that the release film be PE, PP or
PET film, or the leaching membrane paper without silicone oil.
Preferably, the solvent in aromatic hydrocarbon solvent, ketones solvent, esters solvent, fat hydrocarbon solvent extremely
Few one kind；It is further preferred that being at least one of toluene, ethyl acetate, methyl ethyl ketone, heptane.
It is corresponding, the preparation method of noresidue gluing advertisement consumptive material, comprising steps of
1) other compositions in addition to crosslinking agent, promotor, catalyst are uniformly mixed, add crosslinking agent, promotor,
It is uniformly mixed, adds catalyst, mix；
2) material after mixing is coated on the opposite face in the printable face of printing layer, forms adhesive layer；
3) release film, winding are set in another side surface of adhesive layer.
Preferably, coating uses coating technique in the prior art；It is further preferred that the technique of coating is reticulate pattern roller coating
Cloth, blade coating, one of three kinds of coating methods of slope flow coating, technological temperature parameter are 90-130 DEG C, and curing time is 2-8 points
Clock.
The present invention is described further combined with specific embodiments below:
Embodiment 1:
A kind of noresidue gluing advertisement consumptive material of the present embodiment and preparation method thereof, this method use blade coating technique.
Step 1), raw material proportioning are as follows: 100 parts of the dimethyl (siloxanes and polysiloxanes) of mono-vinyl sealing end, molten
100 parts of agent toluene, crosslinking agent containing hydrogen silicone oil (hydrogen content: 1.5%) 2 parts, 1 part of promotor KH550, catalyst chloroplatinic acid it is different
3 parts of propanol solution.The dimethyl (siloxanes and polysiloxanes) of mono-vinyl sealing end and solvent are added to the container and are stirred evenly,
Crosslinking agent, promotor are sequentially added, is spaced 10-15 minutes, is eventually adding catalyst and stirs evenly.The mono-vinyl sealing end
Dimethyl (siloxanes and polysiloxanes) viscosity is 10000mpa.s.
The glue prepared by blade coating technique, is coated on printable PET film surface, most by step 2
High-temperature is 130 DEG C, and curing time is 4 minutes, prepare adhesive layer with a thickness of 20 microns, the adhesive layer is by adjusting scraper
Gap control.
Fitting PET film or leaching membrane paper before step 3) winding.
Embodiment 2:
A kind of noresidue gluing advertisement consumptive material of the present embodiment and preparation method thereof, this method are coated with work using anilox roll
Skill.
Step 1), raw material proportioning are as follows: 100 parts of end-vinyl poly- (dimethyl siloxane), solvent ethyl acetate 150
Part, crosslinking agent containing hydrogen silicone oil (hydrogen content: 1.5%) 3 parts, 2 parts of promotor KH560, the aqueous isopropanol 2 of catalyst chloroplatinic acid
Part.End-vinyl poly- (dimethyl siloxane) and solvent are added to the container and are stirred evenly, crosslinking agent, promotor are sequentially added,
Interval 10-15 minutes, is eventually adding catalyst and stirs evenly.Poly- (dimethyl siloxane) viscosity of end-vinyl is
20000mpa.s。
The glue prepared by reticulate pattern roll coating process, is coated on printable layer PET film surface by step 2,
Maximum temperature be 130 DEG C, curing time be 5 minutes, prepare adhesive layer with a thickness of 10 microns, the adhesive layer is by adjusting net
Line roller mesh number is controlled.
Fitting PP film or leaching membrane paper before step 3) winding.
Embodiment 3:
A kind of noresidue gluing advertisement consumptive material of the present embodiment and preparation method thereof, this method are coated with work using anilox roll
Skill.
Step 1), raw material proportioning are as follows: 100 parts of end-vinyl poly- (dimethyl siloxane), solvent ethyl acetate 130
Part, crosslinking agent containing hydrogen silicone oil (hydrogen content: 1.5%) 3 parts, 2 parts of promotor KH570, the aqueous isopropanol 3 of catalyst chloroplatinic acid
Part.End-vinyl poly- (dimethyl siloxane) and solvent are added to the container and are stirred evenly, crosslinking agent, promotor are sequentially added,
Interval 10-15 minutes, is eventually adding catalyst and stirs evenly.Poly- (dimethyl siloxane) viscosity of end-vinyl is
20000mpa.s。
The glue prepared by transfer coating technology, is coated on printable layer PET film surface, most by step 2
High-temperature be 130 DEG C, curing time be 5 minutes, prepare adhesive layer with a thickness of 50 microns, the adhesive layer is by adjusting transfer
Roller is controlled with upper glue roller gap.
Fitting PP film or leaching membrane paper before step 3) winding.
The noresidue gluing advertisement consumptive material of embodiment 1 is tested, as a result such as the following table 1:
Table 1:
Claims (6)
1. being used for the adhesive of noresidue gluing advertisement consumptive material, be made of the raw material of following mass parts: ethenyl blocking is poly-
100 parts of siloxanes, 100-150 parts of solvent, 1-5 parts of crosslinking agent, 1-5 parts of promotor, 1-5 parts of catalyst；The vinyl envelope
Hold the structural formula of polysiloxanes are as follows:Its viscosity is 8000~30000mpa.s/25 DEG C；
The crosslinking agent is containing hydrogen silicone oil；The catalyst is platinum compounds and/or platinum complex；The promotor is coupling
Agent；The coupling agent is at least one of KH550, KH560, KH570.
2. noresidue gluing advertisement consumptive material, it is characterised in that: including printing layer, and the adhesive layer being arranged under printing layer；Its
In, the adhesive layer is made of the raw material of claim 1.
3. noresidue gluing advertisement consumptive material according to claim 2, it is characterised in that: the printing layer by basement membrane and
Setting is formed in epilamellar printed coating；Or printing layer is the plastic foil of surface printing functionalization.
4. noresidue gluing advertisement consumptive material according to claim 3, it is characterised in that: the basement membrane is PP film, PET film
One of.
5. noresidue gluing advertisement consumptive material according to claim 4, it is characterised in that: further include being arranged under adhesive layer
Release film.
6. the preparation method of noresidue gluing advertisement consumptive material described in claim 2-5, it is characterised in that: comprising steps of
1) other compositions in addition to crosslinking agent, promotor, catalyst are uniformly mixed, add crosslinking agent, promotor, mixed
Uniformly, catalyst is added, is mixed；
2) material after mixing is coated below printing layer, forms adhesive layer；
3) in adhesive layer following settings release film, winding.
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| CN201610365018.0A CN105969299B (en) | 2016-05-26 | 2016-05-26 | The preparation method of noresidue gluing advertisement consumptive material |
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| CN201610365018.0A CN105969299B (en) | 2016-05-26 | 2016-05-26 | The preparation method of noresidue gluing advertisement consumptive material |
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| CN105969299B true CN105969299B (en) | 2019-07-23 |
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| CN106497504A (en) * | 2016-11-21 | 2017-03-15 | 广西华纳新材料科技有限公司 | A kind of weatherability photovoltaic glue and preparation method thereof |
| CN107459939A (en) * | 2017-08-15 | 2017-12-12 | 广州新莱福磁电有限公司 | High-performance plastic cement magnetic material and preparation method thereof |
| CN115770718A (en) * | 2022-11-09 | 2023-03-10 | 东莞市匠心有机硅科技有限公司 | Coating method for combining colored Thermoplastic Polyurethane (TPU) and liquid silica gel |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104144781A (en) * | 2012-02-23 | 2014-11-12 | 台湾道康宁股份有限公司 | Pressure sensitive adhesive sheet and method of producing thereof |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104144781A (en) * | 2012-02-23 | 2014-11-12 | 台湾道康宁股份有限公司 | Pressure sensitive adhesive sheet and method of producing thereof |
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Address after: No.4, Canghai 4th Road, Yonghe Economic Zone, Guangzhou Economic and Technological Development Zone, Guangzhou, Guangdong 511356 Patentee after: Guangzhou xinlaifu New Material Co.,Ltd. Address before: No.4, Canghai 4th Road, Yonghe Economic Zone, Guangzhou Economic and Technological Development Zone, Guangzhou, Guangdong 511356 Patentee before: Guangzhou Newlife Magnet Electricity Co.,Ltd. |
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