CN106013672A - Radiation curable coating decorative board - Google Patents
Radiation curable coating decorative board Download PDFInfo
- Publication number
- CN106013672A CN106013672A CN201610392649.1A CN201610392649A CN106013672A CN 106013672 A CN106013672 A CN 106013672A CN 201610392649 A CN201610392649 A CN 201610392649A CN 106013672 A CN106013672 A CN 106013672A
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- CN
- China
- Prior art keywords
- radiation curable
- radiation curing
- decorative panel
- curable coating
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920001427 mPEG Polymers 0.000 description 1
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 description 1
- FNVQPLCHYJQMHP-UHFFFAOYSA-N methyl prop-2-enoate oxolane Chemical compound C(C=C)(=O)OC.O1CCCC1 FNVQPLCHYJQMHP-UHFFFAOYSA-N 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 description 1
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical group C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0871—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a radiation curable coating decorative board. The radiation curable coating decorative board comprises a decorative board base body A. The surface of the decorative board base body A is coated with a radiation curable color primer layer B and a radiation curable color coating or printing ink layer C in sequence. Preferably, the surface of the radiation curable color coating or printing ink layer C is also coated with a transparent varnish layer D, a water-based inorganic gel layer E and a water-based photocatalyst sterilizing and anti-staining layer F. Compared with the prior art, an oriented strand board or an oriented stalk board or a wood-wool board or a straw board or a bamboo wool board is adopted as the base body of the decorative board, raw materials are easy to get, the cost is low, and the radiation curable coating decorative board has the advantages of being good in wear-resisting property and environmental protection property, rich in color and pattern, strong in three-dimensional sense, high in hardness, resistant to scratches, contamination and bacteria, easy to clean, capable of killing bacteria and the like and can be widely used in the fields such as partition walls, partitions, ceilings, walls, furniture and office table tops.
Description
Technical field
The invention belongs to architectural decoration material field, particularly to a kind of radiation curable coating decorative panel.
Background technology
Current oriented wood chipboard and orientation stalk board are narrow, mainly at decoration, field of constructional ornament application surface
It is to embody well owing to the dicoration on its surface could not reach.But, random people's living standard
Improving constantly, demand in this respect is more and more vigorous, and market in urgent need is with low cost, good decorative property, merit
The decorative panel that energy property is strong.
Summary of the invention
The technical problem to be solved in the present invention be overcome existing oriented wood chipboard and orientation stalk board, wood wool board,
Present in compressed straw slab, bamboo filament plate are actually used, dicoration is strong, apply narrow deficiency, it is provided that a kind of
Radiation curable coating decorative panel, its dicoration is more preferable, functional higher, and with low cost.
The present invention solves above-mentioned technical problem and is adopted the technical scheme that: a kind of radiation curable coating decoration
Plate, including a decorative panel matrix, described matrix surface is coated with radiation curing colored bottom enamelled coating, spoke successively
Penetrate curing chromatic coating or ink layer.
As preferably, described radiation curing colour-wash or ink layer surface are also coated with transparent clear.
As preferably, described radiation curing colour-wash or ink layer surface are also coated with aqueous inorganic gel
Layer and aqueous photo-catalytic sterilization, sterilizing, anti-soil layer.
As preferably, described transparent clear surface is also coated with aqueous inorganic gel layer and aqueous photocatalyst
Sterilization, sterilizing, anti-soil layer.
As preferably, described radiation curing colour-wash or ink layer surface are also coated with aqueous photocatalyst and kill
Bacterium, sterilizing, anti-soil layer.
As preferably, described transparent clear surface is also coated with aqueous photo-catalytic sterilization, sterilizing, anti-soil
Layer.
As preferably, the radiation curing coloured substrate used by described radiation curing colored bottom enamelled coating is by acrylic acid
Ester prepolymer 10～80%, acrylate monomer 10～60%, light trigger 3～12%, auxiliary agent 0～2%,
Pigment 1～50% and filler 0～30%, color essence 0～50% formed；Described radiation curing colour-wash,
Radiation curing colour-wash used by ink layer, ink by acrylic ester prepolymer 10～80%, acrylic acid
Ester monomer 10～60%, light trigger 3～6%, auxiliary agent 0～2%, pigment 1～50% and filler 0～30%,
Color essence 0～50% is formed；Radiation curing clear varnish used by described radiation curing transparent clear is by third
Olefin(e) acid ester prepolymer 10～80%, acrylate monomer 10～60%, light trigger 3～6%, auxiliary agent 0～
2% and filler 0～50% formed.
As preferably, described radiation curing colored bottom enamelled coating, radiation curing colour-wash or ink layer, thoroughly
The thickness of bright layer of varnish is 0～200um, described aqueous inorganic gel layer and aqueous photo-catalytic sterilization,
Sterilizing, the thickness of anti-soil layer are 0～50um.
As preferably, the mode of described application includes roller coat, showering, dip-coating, sprays or brush.
As preferably, described decorative panel matrix includes oriented wood chipboard, orientation stalk board, wood wool board, rice
Grass plate or bamboo filament plate.
Compared with the existing technology, the present invention has and will be apparent below outstanding feature and remarkable advantage:
1. low cost.With oriented wood chipboard, orientation stalk board, wood wool board, compressed straw slab, bamboo wood combine or
Bamboo filament plate is matrix, and raw material is easy to get, with low cost.
2. application is wide.Have that anti-wear performance is good, the feature of environmental protection is good, color pattern is abundant, third dimension is strong, hard
The advantages such as degree height, scratch resistance, easy to clean, anti-soil, antibacterial, sterilization；Can be widely used for partition wall, partition,
The fields such as variola, metope, furniture, office table top.
Following description for exemplary embodiment is read with reference to the drawings, other property features of the present invention
Will become apparent from advantage.
Accompanying drawing explanation
The accompanying drawing of the part being incorporated in description and constitute description shows the enforcement of the present invention
Example, and together with the description for explaining the principle of the present invention.In the drawings, similar accompanying drawing mark
Note is used for representing similar key element.Below describe in accompanying drawing be some embodiments of the present invention rather than
All embodiments.For those of ordinary skill in the art, on the premise of not paying creative work,
Other accompanying drawing can be obtained according to these accompanying drawings.
Fig. 1 is the structural representation of the present invention.Wherein: A is decorative panel matrix；B is that radiation curing is color
Color basecoat；C is radiation curing colour-wash or ink layer.
Fig. 2 is the structural representation of the present invention.Wherein: A is decorative panel matrix；B is that radiation curing is color
Color basecoat；C is radiation curing colour-wash or ink layer；D is transparent clear.
Fig. 3 is the structural representation of the present invention.Wherein: A is decorative panel matrix；B is that radiation curing is color
Color basecoat；C is radiation curing colour-wash or ink layer；E is aqueous inorganic gel layer；F is aqueous
Photo-catalytic sterilization, sterilizing, anti-soil layer.
Fig. 4 is the structural representation of the present invention.Wherein: A is decorative panel matrix；B is that radiation curing is colored
Prime coat；C is radiation curing colour-wash or ink layer；D is transparent clear；E is that aqueous inorganic coagulates
Glue-line；F is aqueous photo-catalytic sterilization, sterilizing, anti-soil layer.
Fig. 5 is the structural representation of the present invention.Wherein: A is decorative panel matrix；B is that radiation curing is colored
Prime coat；C is radiation curing colour-wash or ink layer；F is aqueous photo-catalytic sterilization, sterilizing, anti-soil
Layer.
Fig. 6 is the structural representation of the present invention.Wherein: A is decorative panel matrix；B is that radiation curing is colored
Prime coat；C is radiation curing colour-wash or ink layer；D is transparent clear；F is aqueous photocatalyst
Sterilization, sterilizing, anti-soil layer.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with this
Accompanying drawing in bright embodiment, is clearly and completely described the technical scheme in the embodiment of the present invention,
Obviously, described embodiment is a part of embodiment of the present invention rather than whole embodiments.Based on
Embodiment in the present invention, those of ordinary skill in the art are obtained under not making creative work premise
The every other embodiment obtained, broadly falls into the scope of protection of the invention.It should be noted that do not conflicting
In the case of, the embodiment in the application and the feature in embodiment can mutual combination in any.
The present invention is further elaborated with embodiment below in conjunction with the accompanying drawings.
Embodiment 1
A kind of radiation curable coating decorative panel, produces: (1) is by oriented shaving substrate A as follows
Carry out fixed thick process by contact calibrating machine to process with surface；(2) application coloured substrate on substrate A
Layer B；(3) radiation curing；(4) on the basis of step (3), sanding surface, dedusting are carried out；(5)
Application colour-wash or ink layer C on the basis of step (4)；(6) radiation curing；(7) inspection；
(8) pasting protective film；(9) packaging.
Embodiment 2
A kind of radiation curable coating decorative panel, produces as follows: it is fixed that wood wool substrate A is passed through by (1)
Thick sander carries out fixed thick process and processes with surface；(2) at substrate A external coating colored bottom enamelled coating B；
(3) radiation curing；(4) on the basis of step (3), sanding surface, dedusting are carried out；(5) exist
Application colour-wash or ink layer C on the basis of step (4)；(6) radiation curing；(7) in step
(6) application transparent clear D on the basis of；(8) radiation curing；(9) inspection；(10) patch is protected
Cuticula；(11) packaging.
Embodiment 3
A kind of radiation curable coating decorative panel, produces as follows: it is fixed that straw substrate A is passed through by (1)
Thick sander carries out fixed thick process and processes with surface；(2) at substrate A external coating colored bottom enamelled coating B；
(3) radiation curing；(4) on the basis of step (3), sanding surface, dedusting are carried out；(5) exist
Application colour-wash or ink layer C on the basis of step (4)；(6) radiation curing；(7) in (6)
On the basis of application aqueous inorganic gel layer E；(8) on the basis of (7), application aqueous photocatalyst kills
Bacterium, sterilizing, anti-soil layer F；(9) inspection；(10) pasting protective film；(11) packaging.
Embodiment 4
A kind of radiation curable coating decorative panel, produces as follows: it is fixed that bamboo silk substrate A is passed through by (1)
Thick sander carries out fixed thick process and processes with surface；(2) at substrate A external coating colored bottom enamelled coating B；
(3) radiation curing；(4) on the basis of step (3), sanding surface, dedusting are carried out；(5) exist
Application colour-wash or ink layer C on the basis of step (4)；(6) radiation curing；(7) in step
(6) application transparent clear D on the basis of；(8) radiation curing；(9) in the base of step (8)
Application aqueous inorganic gel layer E on plinth；(10) on the basis of step (9), application aqueous photocatalyst kills
Bacterium, sterilizing, anti-soil layer F；(11) inspection；(12) pasting protective film；(13) packaging.
Embodiment 5
A kind of radiation curable coating decorative panel, produces as follows: it is fixed that Caulis et Folium Oryzae substrate A is passed through by (1)
Thick sander carries out fixed thick process and processes with surface；(2) at substrate A external coating colored bottom enamelled coating B；
(3) radiation curing；(4) on the basis of step (3), sanding surface, dedusting are carried out；(5) exist
Application colour-wash or ink layer C on the basis of step (4)；(6) radiation curing；(7) in step
(6) application aqueous photo-catalytic sterilization, sterilizing, anti-soil layer F on the basis of；(8) inspection；(9) patch
Protecting film；(10) packaging.
Embodiment 6
A kind of radiation curable coating decorative panel, produces: (1) is by oriented shaving substrate A as follows
Carry out fixed thick process by contact calibrating machine to process with surface；(2) at substrate A external coating coloured substrate
Layer B；(3) radiation curing；(4) on the basis of step (3), sanding surface, dedusting are carried out；(5)
Application colour-wash or ink layer C on the basis of step (4)；(6) radiation curing；(7) in step
Suddenly application transparent clear D on the basis of (6)；(8) radiation curing；(9) in step (8)
On the basis of application aqueous photo-catalytic sterilization, sterilizing, anti-soil layer F；(10) inspection；(11) patch protection
Film；(12) packaging.
In embodiment 1-6, radiation curing coloured substrate by acrylic ester prepolymer 10～80%, propylene
Acid ester monomer 10～60%, light trigger 3～12%, auxiliary agent 0～2%, pigment 1～50% and filler 0～
30%, color essence 0～50% is formed；Radiation curing colour-wash, ink by acrylic ester prepolymer 10～
80%, acrylate monomer 10～60%, light trigger 3～6%, auxiliary agent 0～2%, pigment 1～50% and
Filler 0～30%, color essence 0～50% formed；Radiation curing clear varnish by acrylic ester prepolymer 10～
80%, acrylate monomer 10～60%, light trigger 3～6%, auxiliary agent 0～2% and filler 0～50% institute
Composition.
Wherein, acrylic ester prepolymer is epoxy acrylate, urethane acrylate, polyester acrylic
One or more in ester, amino acrylates, acrylate copolymer.
Reactive acrylate monomer is selected from butyl acrylate, ethoxyethoxyethyl acrylate
EOEOEA, 2-phenoxyethyl acrylate PHEA, isobornyl acrylate IBOA, dodecyl acrylate
LA, lauryl methacrylate LMA, octadecyl acrylate SA, octadecyl methacrylate SMA, four
Hydrogen furanacrylate THFA, tetrahydrofuran methyl acrylate THFMA, cyclohexyl acrylate, propylene
Acid different monooctyl ester EHA, 2-(Acryloyloxy)ethanol HEA, hydroxyethyl methylacrylate MHEA, tripropylene glycol
Diacrylate TPGDA, propylene glycol diacrylate DPGDA, neopentylglycol diacrylate NPGDA,
Third oxidation neopentylglycol diacrylate PO2-NPGDA, double (diethylene glycol) two propylene of phthalic acid
Acid esters PDDA, 1,6 hexanediyl ester HDDA, Isosorbide-5-Nitrae butanediol diacrylate BDDA, neighbour
Phthalic acid TEGDMA PTDMA, three contracting TEGDMAs
TEGDMA, (4) ethoxylated bisphenol a diacrylate EO4-BPADA, trimethylolpropane tris propylene
Acid esters TMPTA, (3) ethoxyquin trimethylolpropane trimethacrylate EO3-TMPTA, (9) ethoxyquin
Trimethylolpropane trimethacrylate EO9-TMTA, (9) ethoxyquin trimethylol propane trimethyl acrylic acid
Ester EO9-TMPMA, the third oxidation trimethylolpropane trimethacrylate PO3-TMPDA, glycerol propoxylate 3 third
Olefin(e) acid ester PO3-GTA, pentaerythritol triacrylate PETA, dipentaerythritol acrylate DPHA,
Ring trimethylolpropane dimethoxym ethane acrylate CTFA, methoxy poly (ethylene glycol) (340) acrylate
MPEG (340) A, Polyethylene Glycol (200) diacrylate PEG (200) DA, Polyethylene Glycol (400) two
The group that acrylate PEG (400) DA, Polyethylene Glycol (600) diacrylate PEG (600) DA are formed
In at least one.
Light trigger be benzoin ether light trigger, benzil ketals light trigger, 1-Phenylethanone. light trigger,
Anthraquinone light trigger, thioxanthone photo initiator, benzophenone light trigger, acyl group oxygen compound light of seeing draws
Send out one or more in agent, benzoate light trigger.
Benzoin ether light trigger is in benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether
One or more；Benzil ketals light trigger is benzil dimethyl ketal；1-Phenylethanone. light trigger
For 1-Phenylethanone., 2,2-dimethoxy-2-phenyl acetophenone, 2,2-diethoxy-2-phenyl acetophenone, 1,1-
Dichloroacetophenone, 1-hydroxy acetophenone, 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-benzene
Base-1-acetone, 1-(4-isopropyl phenyl)-2-hydroxy-2-methyl-1-acetone, 1-[4-(2-hydroxyl second
Epoxide) phenyl]-2-hydroxy-2-methyl-1-acetone, 2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-
In morpholinyl-1-acetone, 2-benzyl-2-dimethylamino-1-(4-morpholino phenyl)-1-butanone one
Plant or multiple；Anthraquinone light trigger is the one in 2-tert-butyl group anthraquinone, 1-chloroanthraquinone, 2-amyl anthraquinone
Or it is multiple；Thioxanthone photo initiator be 2,4-dimethyl thioxanthone, 2,4-diethyl thioxanthone,
2-isopropyl thioxanthone, 4-isopropyl thioxanthone, 2-chloro thioxanthone, 2,4-diisopropyl sulfur
One or more in miscellaneous anthrone；Benzophenone light trigger be benzophenone, 4-chlorobenzophenone, to first
Base benzophenone, 4-benzoyl-4 ' one or more in-dimethyl diphenyl sulfide；Acylphosphanes aoxidizes
Compound light trigger is 2,4,6-trimethyl benzoyl diphenyl base phosphine oxide, double (2,4,6-trimethylbenzene
Formoxyl)-phenyl phosphine oxide, two (2,6-dimethylbenzoyl)-2,4,4-tri-methyl-amyl oxidation
One or more in phosphine, 2,4,6-trimethylbenzoyl phenyl ethyoxyl phosphine oxide；Benzoate light
Initiator is methyl benzoylbenzoate, methyl o-benzoylbenzoate or their mixture.
Auxiliary agent is that the levelling agent of Bi Ke chemical company of Germany is (such as BYK306, BYK358 or their mixing
Thing), Germany Bi Ke chemical company defoamer (such as BYK052, BYK055 or their mixture) and
/ or Bi Ke chemical company of Germany wetting dispersing agent (such as Disperbyk 103, Disperbyk 163 or
Their mixture).
Pigment is the inorganic pigments such as titanium dioxide, carbon black or ferrum oxide；Phthalocyanine blue, phthalein mountain valley with clumps of trees and bamboo chrome yellow green, brown or
Bright red organic pigment such as grade；Bronze (copper powder), argentum powder (aluminium powder), pearl essence, fluorescent material, illusion-colour face
The special effect pigments such as material or reflective pigment.
Filler is the powder body materials such as Pulvis Talci, calcium carbonate, barium sulfate or flatting silica.Color essence is oiliness color essence
Or aqueous color essence.
Radiation curing colored bottom enamelled coating B, radiation curing colour-wash or ink layer C, transparent clear D
Thickness be 0～200um, aqueous inorganic gel layer E and aqueous photo-catalytic sterilization, sterilizing, anti-soil
The thickness of layer F is 0～50um.
The mode of application includes roller coat, showering, dip-coating, sprays or brush.
Decorative panel matrix A includes oriented wood chipboard, orientation stalk board, wood wool board, compressed straw slab or bamboo filament plate.
Radiation curing uses ultraviolet light polymerization or electronic beam curing.
Inspection: inspection makes radiation curable coating and/or ink, the radiation curing colour 3D orientation of production
Particieboard base, orientation straw base, wood wool board base, compressed straw slab base, bamboo filament plate base decorative panel are the most qualified.
Pasting protective film: color at the radiation curing through checking qualified radiation curable coating and/or ink, production
Color 3D oriented wood chipboard base, orientation straw base, wood wool board base, compressed straw slab base, bamboo filament plate base decorative panel table
Face patch polypropylene or polyethylene etc. are for protection surface, it is to avoid scratching, abrasive thin film, to surface
Coating be protected by.
Packaging: specification and requirement according to product are to finished product packing.
It is pointed out that the content that a kind of radiation curable coating decorative panel above for the present invention includes
Can individually implement, or the enforcement that combines in every way, and these variant are all in the present invention
Protection domain within.
Last it is noted that above example is only in order to illustrate technical scheme, rather than to it
Limit.Although the present invention being described in detail with reference to previous embodiment, the ordinary skill of this area
Personnel it is understood that the technical scheme described in foregoing embodiments still can be modified by it, or
Person carries out equivalent to wherein portion of techniques feature；And these amendments or replacement, do not make corresponding skill
The essence of art scheme departs from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (10)
1. a radiation curable coating decorative panel, including a decorative panel matrix (A), it is characterised in that institute
State matrix (A) surface be coated with successively radiation curing colored bottom enamelled coating (B), radiation curing colour-wash or
Ink layer (C).
A kind of radiation curable coating decorative panel the most according to claim 1, it is characterised in that described
Radiation curing colour-wash or ink layer (C) surface are also coated with transparent clear (D).
A kind of radiation curable coating decorative panel the most according to claim 1, it is characterised in that described
Radiation curing colour-wash or ink layer (C) surface are also coated with aqueous inorganic gel layer (E) and aqueous
Photo-catalytic sterilization, sterilizing, anti-soil layer (F).
A kind of radiation curable coating decorative panel the most according to claim 2, it is characterised in that described
Transparent clear (D) surface is also coated with aqueous inorganic gel layer (E) and aqueous photo-catalytic sterilization, goes out
Bacterium, anti-soil layer (F).
A kind of radiation curable coating decorative panel the most according to claim 1, it is characterised in that described
Radiation curing colour-wash or ink layer (C) surface are also coated with aqueous photo-catalytic sterilization, sterilizing, anti-soil
Layer (F).
A kind of radiation curable coating decorative panel the most according to claim 2, it is characterised in that described
Transparent clear (D) surface is also coated with aqueous photo-catalytic sterilization, sterilizing, anti-soil layer (F).
7. according to a kind of radiation curable coating decorative panel described in claim 2 or 4, it is characterised in that
Radiation curing coloured substrate used by described radiation curing colored bottom enamelled coating (B) is by acrylic ester prepolymer
10～80%, acrylate monomer 10～60%, light trigger 3～12%, auxiliary agent 0～2%, pigment 1～
50% and filler 0～30%, color essence 0～50% formed；Described radiation curing colour-wash, ink layer (C)
Used radiation curing colour-wash, ink by acrylic ester prepolymer 10～80%, acrylate monomer
10～60%, light trigger 3～6%, auxiliary agent 0～2%, pigment 1～50% and filler 0～30%, color essence 0～
50% is formed；Radiation curing clear varnish used by described radiation curing transparent clear (D) is by propylene
Acid esters prepolymer 10～80%, acrylate monomer 10～60%, light trigger 3～6%, auxiliary agent 0～2%
Formed with filler 0～50%.
A kind of radiation curable coating decorative panel the most according to claim 4, it is characterised in that described
Radiation curing colored bottom enamelled coating (B), radiation curing colour-wash or ink layer (C), transparent clear (D)
Thickness be 0～200um, described aqueous inorganic gel layer (E) and aqueous photo-catalytic sterilization, sterilizing,
The thickness of anti-soil layer (F) is 0～50um.
9. according to a kind of radiation curable coating decorative panel described in claim 1-4, it is characterised in that
The mode of described application includes roller coat, showering, dip-coating, sprays or brush.
10. according to a kind of radiation curable coating decorative panel described in claim 1-4, it is characterised in that
Described decorative panel matrix (A) includes oriented wood chipboard, orientation stalk board, wood wool board, compressed straw slab, bamboo wood
In conjunction with or bamboo filament plate.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2015108449032 | 2015-11-30 | ||
| CN201510844903 | 2015-11-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106013672A true CN106013672A (en) | 2016-10-12 |
Family
ID=57090636
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610392649.1A Pending CN106013672A (en) | 2015-11-30 | 2016-06-06 | Radiation curable coating decorative board |
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| CN105882042A (en) * | 2015-12-24 | 2016-08-24 | 陈伟 | A radiation-cured decorative panel with self-cleaning, antibacterial and bactericidal functions |
| CN110003715A (en) * | 2019-03-27 | 2019-07-12 | 临沂青松油墨厂 | A kind of Polywoven Bag printing alcohol-soluble ink and preparation method thereof |
| CN115537067A (en) * | 2022-08-29 | 2022-12-30 | 佛山市东鹏陶瓷发展有限公司 | High-hardness antifouling UV decorative plate and preparation method thereof |
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| CN110003715B (en) * | 2019-03-27 | 2021-08-10 | 山东华诺日化有限公司 | Alcohol-soluble ink for printing plastic woven bags and preparation method thereof |
| CN115537067A (en) * | 2022-08-29 | 2022-12-30 | 佛山市东鹏陶瓷发展有限公司 | High-hardness antifouling UV decorative plate and preparation method thereof |
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Application publication date: 20161012 |