CN106905838A - A kind of LED curable water-bornes UV furniture house ornamentation paints and preparation method thereof - Google Patents

A kind of LED curable water-bornes UV furniture house ornamentation paints and preparation method thereof Download PDF

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Publication number
CN106905838A
CN106905838A CN201710154906.2A CN201710154906A CN106905838A CN 106905838 A CN106905838 A CN 106905838A CN 201710154906 A CN201710154906 A CN 201710154906A CN 106905838 A CN106905838 A CN 106905838A
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water
coating
led
curable water
led curable
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谭昊涯
李京
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Zhuhai Dongcheng Light Curing New Materials Ltd By Share Ltd
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Zhuhai Dongcheng Light Curing New Materials Ltd By Share Ltd
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Priority to CN201710154906.2A priority Critical patent/CN106905838A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/061Special surface effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/06Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/58No clear coat specified
    • B05D7/584No clear coat specified at least some layers being let to dry, at least partially, before applying the next layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The present invention discloses a kind of LED curable water-bornes UV furniture house ornamentation paints, including:It is attached to furniture house ornamentation surface and the coating I solidified by LED curable water-borne UV adhesion primers;It is attached to the surface of coating I and the coating II solidified by LED curable water-borne UV colouring agents;It is attached to the surface of coating II and the coating III solidified by LED curable water-borne UV protective topcoats.The paint hardness of paint film is high, richness is good, adhesive force is excellent, wearability and anti-stain characteristic can strong, in bright gay color, color inhibitions; with solidifying in good decorative effect and defencive function, and preparation, convenient, speed is fast, and production efficiency is high; energy consumption is low, green pollution-free.

Description

A kind of LED curable water-bornes UV furniture house ornamentation paints and preparation method thereof
Technical field
The invention belongs to furniture house ornamentation decoration material field, and in particular to a kind of LED curable water-bornes UV furniture house ornamentation paints and Its preparation method.
Background technology
Traditional paint is mostly one-component coating, two-component coating and baking-type coating, their slow drying speeds, production effect Rate is low, and containing a large amount of volatile organic solvents, easily environment is polluted.With the raising of people's environmental consciousness, as ring The water paint of guarantor's type paint is widely used, particularly the field such as finishing, construction material, furniture application indoors.However, existing water Property paint deficiency is still present in the application, such as weatherability is poor, hardness is low, drying time is long, low production efficiency, it is ornamental not enough Enrich.LED curable water-borne paints are expected to have the technical characterstic and water that LED curing rates are fast, energy consumption is low, paint film property is excellent concurrently Property paint is environment friendly and pollution-free, the low advantage of cost.
The content of the invention
It is an object of the invention to provide a kind of LED curable water-bornes UV furniture house ornamentation paints and preparation method thereof.The paint paint film Hardness is high, richness is good, adhesive force is excellent, wearability and anti-stain characteristic can strong, in bright gay color, color inhibition, with good dress Decorations effect and defencive function, and solidify convenient, speed in preparation soon, production efficiency is high, and energy consumption is low, green pollution-free.
Specifically, a kind of LED curable water-bornes UV furniture house ornamentation paints, it is characterised in that including:It is attached to furniture house ornamentation table Face and the coating I solidified by LED curable water-borne UV adhesion primers;It is attached to the surface of coating I and by LED curable water-bornes UV The coating II of toner solidification;It is attached to the surface of coating II and the coating solidified by LED curable water-borne UV protective topcoats Ⅲ。
Described LED curable water-borne UV adhesion primers, by weight percentage, comprising:Water-and acrylate prepolymer 10- 70%th, water-soluble active monomer 10-60%, light trigger 1-5%, aqueous promoter 0-5%, filler 0-50% and water 0-50%.
Described LED curable water-borne UV colouring agents, by weight percentage, comprising:Water-and acrylate prepolymer 10- 70%th, water-soluble active monomer 10-60%, light trigger 1-5%, aqueous promoter 0-5%, pigment 0-30% and water 0-30%.
Described LED curable water-borne UV protective topcoats, by weight percentage, comprising:Water-and acrylate prepolymer 10- 70%th, water-soluble active monomer 10-60%, light trigger 1-5%, aqueous promoter 0-5%, filler 0-50% and water 0-50%.
As optimal technical scheme, in above-mentioned LED curable water-bornes UV adhesion primers, UV colouring agents and UV protective topcoats, Described water-and acrylate prepolymer is selected from aqueous polyurethane acrylate, waterborne epoxy acrylate, waterborne polyester propylene At least one in acid esters, aqueous amino acrylates, aqueous acrylamide acidifying polyacrylate and water-borne acrylate copolymer.
Described water-soluble active monomer preferably is selected from propoxyl group trimethylolpropane trimethacrylate (PO3- TMPTA), first Base hydroxypropyl acrylate (HPMA), ethoxylated trimethylolpropane triacrylate (EOn- TMPTA, n=3,6,9,15, 20), hydroxy-ethyl acrylate (HEA), methacrylic acid (MAA), pure acrylic acid (AA), hydroxyethyl methacrylate (HEMA) and third At least one in olefin(e) acid hydroxypropyl acrylate (HPA).
Described light trigger is preferably mercaptan, Ciba 1173, Ciba 184, Ciba 369, Ciba 907, Ciba 819th, one or more the combination in Ciba 651, TPO, ITX.
Described aqueous promoter can be levelling agent, wetting dispersing agent, photosensitivity promotor, adhesion promoter, defoamer, Polymerization inhibitor, delustering agent, one or more combination of anti-settling agent.
Described pigment can be the one kind or two in carbon black, titanium dioxide, pearly-lustre silver powder, pearly-lustre bronze, iron oxide red, phthalocyanine blue Plant the combination of the above.
Described filler preferably is selected from talcum powder, flatting silica, aerosil, anti-scratch wax powder, calcium carbonate, barium sulfate, stone At least one in Ying Fen, kaolin, bentonite.
In above-mentioned LED curable water-bornes UV furniture house ornamentation paints, the thickness of coating I, II and III can be identical, also can be different, excellent Elect 10-200um, more preferably 10-120um as.With 60 ° of Grossmeters, the coating gloss metering of coating III is preferably 10-120 ° It is adjustable.
The preparation method of LED curable water-bornes UV furniture house ornamentation paints of the invention, comprises the following steps:
1) cleaning furniture house ornamentation surface;
2) in furniture house ornamentation external coating LED curable water-borne UV adhesion primers;
3) first time LED solidifications, form coating I;
4) in the external coating LED curable water-borne UV colouring agents of coating I;
5) second LED solidification, forms coating II;
6) in the external coating LED curable water-borne UV protective topcoats of coating II, infrared levelling or natural levelling;
7) third time LED solidifications, form coating III.
In above-mentioned preparation process, described application can be carried out using usual manner as known in the art, such as blade coating, spray Painting, dip-coating, brushing, roller coat, showering etc., this is to those skilled in the art easily to determine.
The LED curable water-borne UV adhesion primers of application, UV colouring agents and UV protective topcoats have good sound to LED light source The wavelength of Ying Xing, applicable LED can be 420nm, 405nm, 390nm, 385nm, 380nm, 375nm, 370nm, 365nm, One kind in 360nm.Specific photocuring operating process is to those skilled in the art easily to determine.Preferably, institute The LED solidifications stated use 1-6 branch power to be irradiated for the LED lamp tube of 0.01-5KW, irradiation speed 1-100m/min.
Step 6) in, the temperature of described infrared levelling is preferably 20-150 DEG C, and flow time is preferably 0.1-10min.
In addition to above-mentioned steps 1-7, the preparation method of LED curable water-bornes UV furniture house ornamentation paints of the invention can also be optional Ground includes the conventional steps such as packaging (specification and requirement according to product are packed to finished product).
LED curable water-bornes UV furniture house ornamentation paints of the invention have that hardness of paint film is high, richness is good, wearability and dirt-resistant Performance is strong, decorative effect and the features such as excellent defencive function, fully meets the use requirement of building trade furniture upholstery, and Preparation technology production efficiency is high, energy consumption is low, green non-pollution.
Specific embodiment
The present invention is described in further detail below in conjunction with specific embodiment, but should not be construed as protecting the present invention Protect the limitation of scope.
Prepare embodiment
The White LED curable water-borne UV furniture house ornamentation paints of embodiment 1.
From the glued board of specification 1.2m × 2.44m × 6mm, in one layer of LED curable water-bornes UV of its surface roller coating after cleaning Adhesion primer, it is the solidification of 15m/min to enter after drying equipped with 2 power 300W, the LED of wavelength 365nm and irradiation speed Machine, it is the coating I of 20um that thickness is formed after solidification.In I surface roller coating of coating, one layer of LED curable water-borne UV white color agents, do Enter after dry equipped with 3 power 1KW, the LED of wavelength 395nm and irradiation speed is the curing of 15m/min, formed after solidification Thickness is the coating II of 25um.It it is 80 DEG C in temperature again in II surface roller coating of coating, one layer of LED curable water-borne UV protective topcoat Levelling 60s under infrared levelling line, subsequently into equipped with 5 power 2KW, the LED of wavelength 365nm and irradiation speed be 15m/ The curing of min, it is the coating III of 30um that thickness is formed after solidification.Obtain final product White LED curable water-borne UV furniture house ornamentation decorative panels.
Wherein, the percentage by weight composition of LED curable water-bornes UV adhesion primers is:Aqueous polyurethane acrylate 56%, Hydroxy propyl methacrylate 27.5%, mercaptan 3%, Ciba 1,173 1%, levelling agent (BYK-333) 0.5%, adhesive force promote Agent (phosphate CN9051) 1.5%, defoamer (BYK-018) 0.5%, water 10%.
The percentage by weight of LED curable water-borne UV white color agents is constituted:Waterborne polyester acrylate 35%, aqueous ammonia Base acrylate 20%, propoxyl group trimethylolpropane trimethacrylate 20%, mercaptan 3%, TPO 2%, levelling agent (BYK- 380) 0.5%, photosensitivity promotor (reactive amines P-1114) 1%, titanium dioxide 13%, polymerization inhibitor (hydroquinones) 0.5%, water 5%.
The percentage by weight of LED curable water-borne UV protective topcoats is constituted:Waterborne epoxy acrylate 29%, aqueous poly- ammonia Ester acrylate 36%, hydroxy-ethyl acrylate 19%, mercaptan 4%, levelling agent (BYK-381) 0.5%, defoamer (BYK-022) 0.5%th, adhesion promoter (phosphate CN9051) 1%, talcum powder 10%.
The red LED curable water-borne UV furniture house ornamentation paints of embodiment 2.
It is the solid wood of 1.0m × 2.5m × 10mm from specification, in one layer of LED curable water-bornes UV of its surface showering after cleaning Adhesion primer, subsequently into equipped with 2 power 1KW, the LED of wavelength 385nm and irradiation speed for 15m/min curing, It is the coating I of 80um that thickness is formed after solidification.In I surface showering of coating, one layer of LED curable water-borne UV red stain, Ran Houjin Enter equipped with 3 power 3KW, the LED of wavelength 420nm and irradiation speed is the curing of 15m/min, thickness is formed after solidification is The coating II of 50um.Again in II surface showering of coating, one layer of LED curable water-borne UV protective topcoat, in the infrared stream that temperature is 80 DEG C Levelling 60s under horizontal line, subsequently into equipped with 5 power 5KW, the LED of wavelength 405nm and irradiation speed consolidating for 15m/min Change machine, it is the coating III of 40um that thickness is formed after solidification.Obtain final product red LED curable water-borne UV furniture house ornamentation decorative panels.
Wherein, the percentage by weight composition of LED curable water-bornes UV adhesion primers is:Aqueous acrylamide is acidified polyacrylate 63%th, hydroxyethyl methacrylate 30.5%, mercaptan 4%, wetting dispersing agent (DISPERBYK-180) 0.5%, adhesive force promote Agent (hydroxy acrylate) 1%, defoamer (BYK-028) 1%.
The percentage by weight of LED curable water-borne UV colouring agents is constituted:Waterborne polyester acrylate 35%, water soluble acrylic acid Ester copolymer 20%, hydroxypropyl acrylate 21%, mercaptan 2%, TPO3%, levelling agent (BYK-337) 0.5%, photosensitivity promotor (reactive amines P-1114) 1%, iron oxide red 17%, defoamer (BYK-093) 0.5%.
The percentage by weight of LED curable water-borne UV protective topcoats is constituted:Aqueous amino acrylates 21%, aqueous poly- ammonia Ester acrylate 35%, hydroxy propyl methacrylate 12%, ethoxyquin trimethylolpropane trimethacrylate (EO3-TMPTA) 16%th, Ciba184 2%, mercaptan 2%, levelling agent (BYK-387) 0.5%, defoamer (BYK-1610) 0.5%, stabilizer are (right Hydroxyanisol) 1%, flatting silica (OK500) 10%.
The pearly-lustre of embodiment 3. silver LED curable water-borne UV furniture lacquers
It is three offset plates of 1.2m × 2.4m × 12mm from specification, in one layer of LED curable water-borne of its surface spraying after cleaning UV adhesion primers, subsequently into equipped with the solidification that 2 power 0.5KW, the LED of wavelength 395nm and irradiation speed are 15m/min Machine, it is the coating I of 28um that thickness is formed after solidification.In I surface spraying of coating, one layer of LED curable water-borne UV pearly-lustres silver colouring agent, Subsequently into equipped with the curing that 3 power 3KW, the LED of wavelength 420nm and irradiation speed are 12m/min, formed after solidification Thickness is the coating II of 32um.It it is 80 DEG C in temperature again in II surface spraying of coating, one layer of LED curable water-borne UV protective topcoat Levelling 60s under infrared levelling line, subsequently into equipped with 5 power 5KW, the LED of wavelength 365nm and irradiation speed be 15m/ The curing of min, it is the coating III of 30um that thickness is formed after solidification.Obtain final product pearly-lustre silver LED curable water-borne UV furniture house ornamentation decoration Plate.
Wherein, the percentage by weight composition of LED curable water-bornes UV adhesion primers is:Aqueous polyurethane acrylate 40%, Aqueous acrylamide acidifying polyacrylate 25.5%, ethoxylated trimethylolpropane triacrylate (EO6- TMPTA) 27.5%, Mercaptan 4%, levelling agent (BYK-3500) 0.5%, adhesion promoter (phosphate CN9051) 1.5%, defoamer (BYK- 080A) 1%.
The percentage by weight of LED curable water-borne UV colouring agents is constituted:Waterborne polyester acrylate 32%, water-base epoxy third Olefin(e) acid ester 23%, hydroxy-ethyl acrylate 14%, pure acrylic acid 12%, mercaptan 1%, TPO 3%, levelling agent (BYK-3530) 0.5%th, photosensitivity promotor (reactive amines P-1114) 2%, pearly-lustre silver powder 12%, adhesion promoter (phosphate CN9051) 0.5%.
The percentage by weight of LED curable water-borne UV protective topcoats is constituted:Waterborne epoxy acrylate 20%, waterborne polyester Acrylate 34%, ethoxylated trimethylolpropane triacrylate (EO15- TMPTA) 14%, third oxidation trihydroxy methyl third Alkane triacrylate 17%, mercaptan 4%, levelling agent (BYK-333) 0.5%, defoamer (BYK-1615) 0.5%, polymerization inhibitor are (right Benzenediol) 1%, calcium carbonate 9%.
Performance characterization
With reference to corresponding examination criteria, to three kinds of LED curable water-borne UV furniture house ornamentation decorative panels obtained in above-described embodiment 1-3 Performance detection is carried out, detection project includes hardness of paint film, outward appearance, adhesive force, water resistance, wearability, stain resistance, washability Property and yellowing resistance.
Testing result is as shown in Table 1 below.
Table 1
The hardness of paint film that can be seen that LED curable water-bornes UV furniture house ornamentation paints of the invention by the testing result of table 1 is high, Richness is good, and adhesive force is strong, and water resistance, wearability, anti-stain characteristic energy, abrasion resistance and yellowing resistance are excellent, decorative effect and Defencive function is good, fully meets the use requirement of building trade furniture upholstery, and preparation technology production efficiency is high, energy consumption Low, green non-pollution.

Claims (10)

1. a kind of LED curable water-bornes UV furniture house ornamentation paints, it is characterised in that including:It is attached to furniture house ornamentation surface and is consolidated by LED Change the coating I of aqueous UV adhesion primers solidification;It is attached to the surface of coating I and by the solidification of LED curable water-borne UV colouring agents Into coating II;It is attached to the surface of coating II and the coating III solidified by LED curable water-borne UV protective topcoats;
Described LED curable water-borne UV adhesion primers, by weight percentage, comprising:Water-and acrylate prepolymer 10-70%, Water-soluble active monomer 10-60%, light trigger 1-5%, aqueous promoter 0-5%, filler 0-50% and water 0-50%;
Described LED curable water-borne UV colouring agents, by weight percentage, comprising:Water-and acrylate prepolymer 10-70%, water Insoluble active monomer 10-60%, light trigger 1-5%, aqueous promoter 0-5%, pigment 0-30% and water 0-30%;
Described LED curable water-borne UV protective topcoats, by weight percentage, comprising:Water-and acrylate prepolymer 10-70%, Water-soluble active monomer 10-60%, light trigger 1-5%, aqueous promoter 0-5%, filler 0-50% and water 0-50%.
2. LED curable water-bornes UV furniture house ornamentation paints according to claim 1, it is characterised in that:It is attached in LED curable water-bornes UV In priming paint, UV colouring agents and UV protective topcoats, described water-and acrylate prepolymer be selected from aqueous polyurethane acrylate, Waterborne epoxy acrylate, waterborne polyester acrylate, aqueous amino acrylates, aqueous acrylamide acidifying polyacrylate and water At least one in property acrylate copolymer.
3. LED curable water-bornes UV furniture house ornamentation paints according to claim 1, it is characterised in that:Described water-soluble active Monomer is selected from propoxyl group trimethylolpropane trimethacrylate(PO3-TMPTA), hydroxy propyl methacrylate(HPMA), ethyoxyl Change trimethylolpropane trimethacrylate (EOn- TMPTA, n=3,6,9,15,20), hydroxy-ethyl acrylate(HEA), metering system Acid(MAA), pure acrylic acid(AA), hydroxyethyl methacrylate(HEMA)And hydroxypropyl acrylate(HPA)In at least one.
4. LED curable water-bornes UV furniture house ornamentation paints according to claim 1, it is characterised in that:Described light trigger is One kind in mercaptan, Ciba 1173, Ciba 184, Ciba 369, Ciba 907, Ciba 819, Ciba 651, TPO, ITX or Two or more combinations.
5. LED curable water-bornes UV furniture house ornamentation paints according to claim 1, it is characterised in that:Described aqueous promoter is Levelling agent, wetting dispersing agent, photosensitivity promotor, adhesion promoter, defoamer, polymerization inhibitor, delustering agent, one kind of anti-settling agent or Two or more combinations.
6. LED curable water-bornes UV furniture house ornamentation paints according to claim 1, it is characterised in that:Described pigment be carbon black, One or more combination in titanium dioxide, pearly-lustre silver powder, pearly-lustre bronze, iron oxide red, phthalocyanine blue;Described filler is selected to be slided In stone flour, flatting silica, aerosil, anti-scratch wax powder, calcium carbonate, barium sulfate, silica flour, kaolin, bentonite at least It is a kind of.
7. LED curable water-borne UV furniture house ornamentation paints according to any one of claim 1-6, it is characterised in that:Coating I, II and III thickness is preferably 10-200 um, more preferably 10-120 um independently of one another.
8. the preparation method of the LED curable water-borne UV furniture house ornamentation paints any one of claim 1-7, including following step Suddenly:
1)Cleaning furniture house ornamentation surface;
2)In furniture house ornamentation external coating LED curable water-borne UV adhesion primers;
3)First time LED solidifies, and forms coating I;
4)In the external coating LED curable water-borne UV colouring agents of coating I;
5)Second LED solidification, forms coating II;
6)In the external coating LED curable water-borne UV protective topcoats of coating II, infrared levelling or natural levelling;
7)Third time LED solidifies, and forms coating III.
9. preparation method according to claim 8, it is characterised in that:For solidify LED wavelength be 420nm, One kind in 405nm, 390nm, 385nm, 380nm, 375nm, 370nm, 365nm, 360nm.
10. preparation method according to claim 8, it is characterised in that:Step 6)In, the temperature of described infrared levelling is 20-150 DEG C, flow time is 0.1-10 min.
CN201710154906.2A 2017-03-16 2017-03-16 A kind of LED curable water-bornes UV furniture house ornamentation paints and preparation method thereof Pending CN106905838A (en)

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CN108977053A (en) * 2018-07-26 2018-12-11 北京小米移动软件有限公司 Composite coating material and its preparation method and application
CN109233605A (en) * 2018-10-10 2019-01-18 安徽科纳家居饰材有限公司 A kind of aqueous UV coatings for furniture and preparation method thereof
CN109517525A (en) * 2018-09-30 2019-03-26 佛山阳光逸采涂料科技有限公司 A kind of UV LED UV-curable waterborne ecological vegetable oil and preparation method thereof
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CN116060276A (en) * 2023-02-21 2023-05-05 小森新材料科技有限公司 Facing technology for artificial board surface 3D display Kong Muwen paint surface numerical control color matching decoration
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* Cited by examiner, † Cited by third party
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CN108410347B (en) * 2018-04-22 2020-10-02 湖州吉复新型材料科技有限公司 Water-based UV (ultraviolet) coating for LED (light-emitting diode) light source
CN108410347A (en) * 2018-04-22 2018-08-17 湖州吉复新型材料科技有限公司 A kind of LED light source waterborne UV coating
CN108753119A (en) * 2018-06-21 2018-11-06 恒昌涂料(惠阳)有限公司 A kind of high covering LED solidification based white primer and preparation method thereof
CN108977053A (en) * 2018-07-26 2018-12-11 北京小米移动软件有限公司 Composite coating material and its preparation method and application
CN109517525A (en) * 2018-09-30 2019-03-26 佛山阳光逸采涂料科技有限公司 A kind of UV LED UV-curable waterborne ecological vegetable oil and preparation method thereof
CN109517525B (en) * 2018-09-30 2020-12-08 佛山阳光逸采涂料科技有限公司 UV LED water-based ultraviolet-curing ecological vegetable oil and preparation method thereof
CN109233605A (en) * 2018-10-10 2019-01-18 安徽科纳家居饰材有限公司 A kind of aqueous UV coatings for furniture and preparation method thereof
CN109825118A (en) * 2019-03-06 2019-05-31 上海君子兰新材料股份有限公司 A kind of solvent-free white paint of LED-UV photocuring
CN110698971A (en) * 2019-09-12 2020-01-17 湖南松井新材料股份有限公司 Water-based UV (ultraviolet) dirt-resistant self-cleaning coating and preparation method and application thereof
CN110698971B (en) * 2019-09-12 2021-09-17 湖南松井新材料股份有限公司 Water-based UV (ultraviolet) dirt-resistant self-cleaning coating and preparation method and application thereof
CN111286262A (en) * 2020-03-27 2020-06-16 吴月成 Environment-friendly energy-saving water-based transparent gloss finish paint sprayed on light-emitting diode (LED) photocuring woodware
CN115926608B (en) * 2022-04-24 2024-01-05 苏州悦路医用材料有限公司 High-cleanliness heat-resistant cutting die and preparation method thereof
CN116060276A (en) * 2023-02-21 2023-05-05 小森新材料科技有限公司 Facing technology for artificial board surface 3D display Kong Muwen paint surface numerical control color matching decoration
CN116060276B (en) * 2023-02-21 2023-11-10 小森新材料科技有限公司 Facing technology for artificial board surface 3D display Kong Muwen paint surface numerical control color matching decoration

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Application publication date: 20170630