CN105385284B - A kind of aqueous UV base coat and preparation method thereof - Google Patents
A kind of aqueous UV base coat and preparation method thereof Download PDFInfo
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- CN105385284B CN105385284B CN201511018722.0A CN201511018722A CN105385284B CN 105385284 B CN105385284 B CN 105385284B CN 201511018722 A CN201511018722 A CN 201511018722A CN 105385284 B CN105385284 B CN 105385284B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Polymers & Plastics (AREA)
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Abstract
The invention discloses a kind of aqueous UV base coat, including following components and its weight percent content：Aqueous acrylic emulsion 50 70%, mass percent concentration is 35% alkali soluble resins solution 0 30%, the water-base resin 10 20% with activity double key, coalescents 0 2%, defoamer 0.1 0.5%, moistening flatting agent 0.1% 1.5%, deionized water 0 30%.It is main to be prepared using progressively material additive process present invention also offers a kind of preparation method of aqueous UV base coat.Activity double key in the aqueous UV base coat prepared using the invention, ultraviolet light-initiated radical polymerization is participated in the glossy solidification process in UV faces, so as to form riveting formula structure between base oil and UV faces oil, strengthen adhesive force of the UV faces oil in base oil, and then strengthen adhesive force of the UV gloss oil in printing paper.
Description
Technical field
The invention belongs to polymeric material field, more particularly to a kind of aqueous UV base coat and preparation method thereof.
Background technology
UV gloss oil is due to the good performance such as its glossiness is high, abrasion resistance is good, and in use almost zero
Discharge, is the optimal selection currently on the market after paper printing in Lacquer finish product.But UV gloss oil is attached from being gone up in off-set oil ink
Put forth effort poor, ply adhesion need to be improved with one layer of base oil.
But the using effect of country UV base oils is very poor at present, when causing ply adhesion that paper can be subject to cross ink to dust
Loose etc. the influence of the depth of ink colors, paper fibre, product Lacquer finish defect rate are higher.In addition, UV printing finishing oil into
This is higher, and glazing cost must be further increased after the base oil of one layer of higher price before face oil is crossed.
Patent CN 101967323A are disclosed and are only existed thing between a kind of preparation method of aqueous UV base coat, and UV faces oil
Reason interaction, i.e., adhered to using intermolecular Van der Waals force, provides crosslinking without the double bond of reactivity, adhesive force is not
By force.
The content of the invention
The purpose of the present invention, is exactly to solve the above-mentioned problems and provides a kind of aqueous UV base coat, the aqueous UV base coat
In activity double key, ultraviolet light-initiated radical polymerization is participated in the glossy solidification process in UV faces, so that in base oil and UV faces
Riveting formula structure is formed between oil, strengthens adhesive force of the UV faces oil in base oil, and then it is attached in printing paper to strengthen UV gloss oil
Put forth effort.
Another object of the present invention, which also resides in, provides a kind of preparation method of aqueous UV base coat.
To achieve the above object, technical scheme is implemented as follows：
A kind of aqueous UV base coat of the present invention, including following components and its weight percent content：
The sum of percentage by weight of above-mentioned raw materials is 100%；
The water-base resin with activity double key, the quantity of its activity double key account for all chemical bond quantity of the water-base resin
Percentage be 5-10%.
A kind of above-mentioned aqueous UV base coat, wherein, it by glass transition temperature is -20-5 that the aqueous acrylic emulsion, which is,
DEG C aqueous acrylic emulsion A and glass transition temperature be that 50-80 DEG C of aqueous acrylic emulsion B is mixed.
A kind of above-mentioned aqueous UV base coat, wherein, the aqueous acrylic emulsion A is by the raw material of following percentage by weight
It is polymerized：
Alkali soluble resins:5.0-20.0%；
Mass percent concentration is 25% ammonium hydroxide:2.0-8.0%；
Initiator:0.1-1.0%；
Styrene:5.0-18.0%；
Butyl acrylate:15.0-38.0%；
Acrylic acid:0-2.0%；
Hydroxy-ethyl acrylate:0-5.0%；
Deionized water:50.0-60.0%；
The sum of percentage by weight of above-mentioned raw materials is 100%.
A kind of above-mentioned aqueous UV base coat, wherein, the aqueous acrylic emulsion B is by the original of following percentage by weight
Material is polymerized：
Alkali soluble resins:5.0-20.0%；
Mass percent concentration is 25% ammonium hydroxide:2.0-8.0%；
Initiator:0.1-1.0%；
Styrene:0-40.0%；
Methyl methacrylate:0-40.0%；
Butyl acrylate:0-10.0%；
Acrylic acid:0-2%；
Hydroxy-ethyl acrylate:0-5%；
Deionized water:50-60%；
The sum of percentage by weight of above-mentioned raw materials is 100%.
A kind of above-mentioned aqueous UV base coat, wherein, the mass percent concentration be 35% alkali soluble resins solution in,
As 50-130 DEG C of the glass transition temperature of the alkali soluble resins of solute, molecular weight 2000-20000, acid number 150-
300mgKOH/g, the lye as solvent are the ammonium hydroxide that mass percent concentration is 25%.
A kind of above-mentioned aqueous UV base coat, wherein, the water-base resin with activity double key, including with activity double key
Water-based emulsion or alkali solubility macromolecule oligomer with activity double key.
A kind of above-mentioned aqueous UV base coat, wherein, the water-based emulsion with activity double key is selected from styrene-butadiene latex or carboxylic
Base styrene-butadiene latex；The alkali solubility macromolecule oligomer with activity double key is selected from polyethyleneglycol diacrylate, polyurethane
Polyurethane aqueous dispersion body acrylic resin modified or with activity double key.
Present invention also offers a kind of preparation method of the aqueous UV base coat with excellent adhesive attraction, comprise the following steps：
Step 1：Prepare raw material according to following components and its weight percent content：Aqueous acrylic emulsion 50.0-
70.0%, mass percent concentration is 35% alkali soluble resins solution 0-30%, the water-base resin 10- with activity double key
20%, coalescents 0-2%, defoamer 0.1-0.5%, moistening flatting agent 0.1-1.5%, deionized water 0-30%；
Step 2：First aqueous acrylic emulsion is poured into a clean container under the mixing speed of 500-800r/min, according to
The secondary alkali soluble resins solution, the water-base resin with activity double key, defoamer for adding mass percent concentration and being 35%,
0.5-1h is stirred under the mixing speed of 800-1200r/min；
Step 3：Coalescents, moistening flatting agent and deionized water is slowly added dropwise successively again, in turning for 300-500r/min
The lower stirring defoaming of speed, 200 mesh filter and package, up to aqueous UV base coat finished product.
Beneficial effects of the present invention are as follows：
1. mixed emulsion can be adjusted by adjusting the ratio of aqueous acrylic emulsion A and aqueous acrylic emulsion B
The various performances such as resistance to blocking, pliability are to meet the various performance requirements of process.
2. the effect of the water-base resin with activity double key is to make water borne base and UV by the glossy curing reaction of scope of participants
The link of covalent bond is produced between top layer, there is provided good combination power, forms riveting formula structure between base oil and UV faces oil, so that
Improve adhesive force.
3. material provided by the invention has excellent adhesion property.It is made after aqueous UV base coat finished product, passes through GB/T
Method as defined in 9286-1998 carries out adhesive force test, and obtained result is 0-1 grades.
Embodiment
Below in conjunction with a comparative example and four embodiments, the invention will be further described.
Raw materials used model and producer are as shown in the table in embodiment：
Comparative example is commercially available material with remaining raw material used in embodiment.
Comparative example 1
First the aqueous acrylic emulsion B of 56% aqueous acrylic emulsion A and 14% is mixed, 500-800r/min's
The aqueous acrylic emulsion mixed is poured into a clean container under mixing speed, sequentially add 15% mass percent it is dense
The alkali soluble resins solution, 0.5% defoamer and 1.5% moistening flatting agent for 35% are spent, in stirring for 800-1200r/min
Mix and stir 0.5-1h under speed；2% diethylene glycol monobutyl ether coalescents and 11% deionized water is slowly added dropwise successively again,
Defoaming is stirred under the rotating speed of 300-500r/min, 200 mesh filter and package, up to aqueous UV base coat finished product.
Embodiment 1
First the aqueous acrylic emulsion B of 40% aqueous acrylic emulsion A and 15% is mixed, 500-800r/min's
The aqueous acrylic emulsion mixed is poured into a clean container under mixing speed, sequentially add 15% mass percent it is dense
The alkali soluble resins solution for 35%, 16% SQS2-07,0.5% defoamer and 1.5% moistening flatting agent are spent,
0.5-1h is stirred under the mixing speed of 800-1200r/min；2% diethylene glycol monobutyl ether coalescents are slowly added dropwise successively again
Deionized water with 10%, stirs defoaming, 200 mesh filter and package, up to aqueous UV base coat under the rotating speed of 300-500r/min
Finished product.
Embodiment 2
First the aqueous acrylic emulsion B of 40% aqueous acrylic emulsion A and 28% is mixed, 500-800r/min's
The aqueous acrylic emulsion mixed is poured into a clean container under mixing speed, sequentially adds 10% mass percent concentration
For 35% alkali soluble resins solution, 8% polyethyleneglycol diacrylate, 0.5% defoamer and 1.5% wetting levelling
Agent, 0.5-1h is stirred under the mixing speed of 800-1200r/min；Be slowly added dropwise successively again 2% diethylene glycol monobutyl ether into
Film auxiliary agent and 10% deionized water, stir defoaming under the rotating speed of 300-500r/min, and 200 mesh filter and package, up to water-based
UV base oil finished products.
Embodiment 3
First the aqueous acrylic emulsion B of 40% aqueous acrylic emulsion A and 15% is mixed, 500-800r/min's
The aqueous acrylic emulsion mixed is poured into a clean container under mixing speed, sequentially adds 15% mass percent concentration
For 35% alkali soluble resins solution, 16% butadiene-styrene latex, 0.5% defoamer and 1.5% moistening flatting agent, in 800-
0.5-1h is stirred under the mixing speed of 1200r/min；Be slowly added dropwise successively again 2% diethylene glycol monobutyl ether coalescents and
10% deionized water, stirs defoaming under the rotating speed of 300-500r/min, and 200 mesh filter and package, up to aqueous UV base coat into
Product.
Embodiment 4
First the aqueous acrylic emulsion B of 40% aqueous acrylic emulsion A and 28% is mixed, 500-800r/min's
The aqueous acrylic emulsion mixed is poured into a clean container under mixing speed, sequentially adds 10% mass percent concentration
Alkali soluble resins solution, 8% ethoxyquin trimethylolpropane tris propylene, 0.5% defoamer for 35% and 1.5%
Moistening flatting agent, 0.5-1h is stirred under the mixing speed of 800-1200r/min；2% diethylene glycol is slowly added dropwise successively again
Monobutyl ether coalescents and 10% deionized water, stir defoaming under the rotating speed of 300-500r/min, and 200 mesh filter and package,
Up to aqueous UV base coat finished product.
Product obtained in comparative example 1, and embodiment 1-4 is carried out according to method as defined in GB/T 9286-1998
Adhesive force is tested.Art post paperboard is printed using 200 grams of five colors, on different aqueous UV base coats, the adhesive force test knot of UV faces oil
Fruit see the table below：
| Project | Adhesive force is graded |
| Comparative example 1 | 2 |
| Embodiment 1 | 1 |
| Embodiment 2 | 0 |
| Embodiment 3 | 1 |
| Embodiment 4 | 0 |
By upper table, it is clear that the more traditional water-based gloss oil increase of the aqueous UV base coat of the present invention is with active double
The water-base resin of key, is tested by adhesive force, and adhesive force significantly improves.
Meanwhile the activity double key in aqueous UV base coat of the invention, participation ultraviolet light draws in the glossy solidification process in UV faces
The radical polymerization of hair, so as to form riveting formula structure between base oil and UV faces oil, strengthens adhesive force of the UV faces oil in base oil,
And then strengthen adhesive force of the UV gloss oil in printing paper.
Above example is used for illustrative purposes only, rather than limitation of the present invention, the technology people in relation to technical field
Member, without departing from the spirit and scope of the present invention, can also make various conversion or modification, therefore all equivalent
Technical solution should also belong to scope of the invention, should be limited by each claim.
Claims (3)
1. a kind of water-based UV base oils, it is characterised in that including following components and its weight percent content：
Aqueous acrylic emulsion：50.0-70.0%；
Mass percent concentration is 35% alkali soluble resins solution：0-30%；
Water-base resin with activity double key：10-20%；
Coalescents：0-2% ；
Defoamer：0.1-0.5%；
Moistening flatting agent：0.1-1.5%；
Deionized water：0-30%；
The sum of percentage by weight of above-mentioned raw materials is 100%；
The water-base resin with activity double key, the quantity of its activity double key account for the hundred of all chemical bond quantity of the water-base resin
It is 5-10% to divide ratio；
The water-base resin with activity double key is the water-based emulsion with activity double key；It is described water-based with activity double key
Lotion is selected from styrene-butadiene latex or carboxylic styrene butadiene latex；
The aqueous acrylic emulsion is by aqueous acrylic emulsion A of the glass transition temperature for -20~5 DEG C and vitrifying
Transition temperature is that 50~80 DEG C of aqueous acrylic emulsion B is mixed；
The aqueous acrylic emulsion A is formed by the polymerizable raw material of following percentage by weight：
Alkali soluble resins:5.0-20.0%；
Mass percent concentration is 25% ammonium hydroxide:2.0-8.0%；
Initiator:0.1-1.0%；
Styrene:5.0-18.0%；
Butyl acrylate:15.0-38.0%；
Acrylic acid:0-2.0%；
Hydroxy-ethyl acrylate:0-5.0%；
Deionized water:50.0-60.0%；
The sum of percentage by weight of above-mentioned raw materials is 100%；
The aqueous acrylic emulsion B is formed by the polymerizable raw material of following percentage by weight：
Alkali soluble resins:5.0-20.0%；
Mass percent concentration is 25% ammonium hydroxide:2.0-8.0%；
Initiator:0.1-1.0%；
Styrene:0-40.0%；
Methyl methacrylate:0-40.0%；
Butyl acrylate:0-10.0%；
Acrylic acid:0-2%；
Hydroxy-ethyl acrylate:0-5%；
Deionized water:50-60%；
The sum of percentage by weight of above-mentioned raw materials is 100%.
2. a kind of water-based UV base oils as claimed in claim 1, it is characterised in that the mass percent concentration is 35%
In alkali soluble resins solution, as 50-130 DEG C of the glass transition temperature of the alkali soluble resins of solute, molecular weight 2000-
20000, acid number 150-300mgKOH/g, the lye as solvent are the ammonium hydroxide that mass percent concentration is 25%.
3. a kind of preparation method of water-based UV base oils, comprises the following steps：
Step 1：Prepare raw material according to following components and its weight percent content：
Aqueous acrylic emulsion：50.0-70.0%；
Mass percent concentration is 35% alkali soluble resins solution：0-30%,
Water-base resin with activity double key：10-20%,
Coalescents：0-2%,
Defoamer：0.1-0.5%,
Moistening flatting agent：0.1-1.5%,
Deionized water：0-30%；
The sum of percentage by weight of above-mentioned raw materials is 100%；
The water-base resin with activity double key, the quantity of its activity double key account for the hundred of all chemical bond quantity of the water-base resin
It is 5-10% to divide ratio；
The water-base resin with activity double key is the water-based emulsion with activity double key；It is described water-based with activity double key
Lotion is selected from styrene-butadiene latex or carboxylic styrene butadiene latex；
The aqueous acrylic emulsion is by aqueous acrylic emulsion A of the glass transition temperature for -20~5 DEG C and vitrifying
Transition temperature is that 50~80 DEG C of aqueous acrylic emulsion B is mixed；
The aqueous acrylic emulsion A is formed by the polymerizable raw material of following percentage by weight：
Alkali soluble resins:5.0-20.0%；
Mass percent concentration is 25% ammonium hydroxide:2.0-8.0%；
Initiator:0.1-1.0%；
Styrene:5.0-18.0%；
Butyl acrylate:15.0-38.0%；
Acrylic acid:0-2.0%；
Hydroxy-ethyl acrylate:0-5.0%；
Deionized water:50.0-60.0%；
The sum of percentage by weight of above-mentioned raw materials is 100%；
The aqueous acrylic emulsion B is formed by the polymerizable raw material of following percentage by weight：
Alkali soluble resins:5.0-20.0%；
Mass percent concentration is 25% ammonium hydroxide:2.0-8.0%；
Initiator:0.1-1.0%；
Styrene:0-40.0%；
Methyl methacrylate:0-40.0%；
Butyl acrylate:0-10.0%；
Acrylic acid:0-2%；
Hydroxy-ethyl acrylate:0-5%；
Deionized water:50-60%；
The sum of percentage by weight of above-mentioned raw materials is 100%；
Step 2：First aqueous acrylic emulsion is poured into a clean container under the mixing speed of 500-800r/min, is added successively
Enter alkali soluble resins solution, the water-base resin with activity double key, defoamer that mass percent concentration is 35%, in 800-
0.5-1h is stirred under the mixing speed of 1200r/min；
Step 3：Coalescents, moistening flatting agent and deionized water is slowly added dropwise successively again, under the rotating speed of 300-500r/min
Stirring defoaming, 200 mesh filter and package, up to aqueous UV base coat finished product.
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| CN107652771A (en) * | 2016-07-25 | 2018-02-02 | 洋紫荆油墨（浙江）有限公司 | A kind of online water-based base oil composition of high adhesion force and its manufacture method |
| CN110965387A (en) * | 2019-11-27 | 2020-04-07 | 苏州三帆包装材料有限公司 | Label with high water-resistant strength and processing method thereof |
| CN116265537A (en) * | 2021-12-17 | 2023-06-20 | 深圳市裕同包装科技股份有限公司 | Aqueous base oil, method for producing same, and printed matter |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1544754A (en) * | 2003-11-27 | 2004-11-10 | 惠州市华阳化工有限公司 | Base oil for paper |
| CN101275005A (en) * | 2008-05-14 | 2008-10-01 | 恒昌涂料（惠阳）有限公司 | Preparation for acroleic acid emulsion having nucleocapsid structure, acroleic acid emulsion and water-based gloss oil therefrom |
| CN102964981A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | Water-based UV (Ultraviolet) tin printing gloss oil and method for preparing same |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5880356A (en) * | 1981-11-09 | 1983-05-14 | Toray Ind Inc | Coating composition |
| JPS6114267A (en) * | 1984-06-29 | 1986-01-22 | Showa Denko Kk | Water-and oil-repellent paint |
| CN101503580B (en) * | 2009-03-06 | 2011-02-09 | 恒昌涂料（惠阳）有限公司 | Ultraviolet light curing oil polish and preparation thereof |
| CN101967323B (en) * | 2010-09-29 | 2012-10-10 | 苏州凯康化工科技有限公司 | Aqueous UV base coat and preparation method thereof |
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- 2015-12-30 CN CN201511018722.0A patent/CN105385284B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1544754A (en) * | 2003-11-27 | 2004-11-10 | 惠州市华阳化工有限公司 | Base oil for paper |
| CN101275005A (en) * | 2008-05-14 | 2008-10-01 | 恒昌涂料（惠阳）有限公司 | Preparation for acroleic acid emulsion having nucleocapsid structure, acroleic acid emulsion and water-based gloss oil therefrom |
| CN102964981A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | Water-based UV (Ultraviolet) tin printing gloss oil and method for preparing same |
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