CN105482689A - Peelable blue plastic and preparation method thereof - Google Patents
Peelable blue plastic and preparation method thereof Download PDFInfo
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- CN105482689A CN105482689A CN201610038540.8A CN201610038540A CN105482689A CN 105482689 A CN105482689 A CN 105482689A CN 201610038540 A CN201610038540 A CN 201610038540A CN 105482689 A CN105482689 A CN 105482689A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Polymers & Plastics (AREA)
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Abstract
The invention discloses a peelable blue plastic and a preparation method thereof. The peelable blue plastic comprises the following components in parts by weight: 60-150 parts of UV curing resin A, 60-150 parts of UV curing resin B, 0.05-0.1 part of a leveling agent, 1-10 parts of a wetting agent, 0.2-1 part of a defoamer, 1-10 parts of UV color paste, 3-5 parts of a photoinitiator A and 3-5 parts of a photoinitiator B. After coating, through irradiation of a 365 nm UV LED lamp, the peelable blue plastic coating is high in curing ability, good in binding force, easy to peel, complete in peeling, and free of residue; the peelable blue plastic can be applied to insulation protection, moisture and pollution prevention and anti-scratch protection of materials of PET, ITO conductive films, ITO glass, mobile glass, tempered glass windows and the like.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of peelable blue glue and preparation method thereof.
Background technology
In recent years, the fast development of digital product has driven the fast development of touch-screen industry.High performance touch-screen preparation technology needs to have the ink of resistance erosion function or " peelable blue gel ", " surface protective glue " of metallic surface processing protection.When manufacturing printed board, on plate, some part often will adopt adhesive to hide, in order to avoid poured by tin during scolding tin, the such as plate face of golden finger, interface card, carbonaceous conductive button and larger area, these all need optionally scolding tin and multiple scolding tin continuously, as the hybrid precast of SMD, Reflow Soldering craft and automatic and other soldering tin techniques etc.Use for reference the protected mode of peelable blue gel in PCB industry printed circuit board technology, adopt printing peelable glue to avoid touch-screen to sustain damage in the mill, enhance productivity and product quality.Usually; peelable glue is a kind of single component touch-screen special isolation protection pliability ink; color is blue glutinous thick liquid, and the peelable glue coating after high temperature resistant is more prone to peel off, and toughness also can be strengthened; can peel off easily with hand or instrument after application; and do not have residue at material surface or polluting material, do not need secondary cleaning, have that sticking power is good, cull, endurance (acid-basicity) are unexcellent; the advantages such as level and smooth light is easily shelled, easy to operate.Be mainly used in the insulation plated film flow process of transparent ITO conductive glass, ito thin film, PET film in touch-screen, by silk screen printing in PET film and glass, play in process of production after baking film forming and prevent the effect that material is contaminated or scratch, on the touchscreen, before line bonding, available simple and easy method is taken off, and once peels off clean.
Current peelable blue glue generally heats and is cured more than 100 DEG C, and solidification value is high, and general peelable blue glue equally also lifetime is long, stripping process exist loaded down with trivial details, have the problems such as residual.
Based on above background, need development one fast setting, the good non-scale of bonding force can to come off, have and peel off easy, complete, do not flow high temperature resistant peelable blue glue of the good peeling effect such as residual stain and preparation method thereof.
Summary of the invention
In order to overcome the deficiencies in the prior art, the object of the present invention is to provide a kind of there is fast setting, the peelable blue glue with Noctilucent visual ability and preparation method thereof.The peelable blue glue prepared is high temperature resistant, and peeling effect is good.
Technical scheme of the present invention is specifically described as follows
A kind of peelable blue glue, calculates by weight, its raw material composition and content as follows:
Wherein:
The structural formula of described UV cured resin A is as follows:
Wherein: m is the integer within the scope of 1-30; N is the integer within the scope of 1-30;
Described UV cured resin B is toughened resin;
Described UV mill base is the blue F4049 of mill base;
Described light trigger A is selected from one or more in BASF Irgacure1173, Irgacure184D, IrgacureTPO, Irgacure369, Irgacure651, Irgacure379, Irgacure819, Irgacure907 or macromolecular photoinitiator EsacureKIP150;
Described photoinitiator b is selected from one or more in BASF BASF light trigger Irgacure2959, IRGACURE500 or IRGACURE819DW.
In the present invention, described UV cured resin A calculates by weight, its raw material composition and content as follows:
Described UV cured resin A is prepared as follows:
Methyl Hydrogen Polysiloxane Fluid and ethoxylated trimethylolpropane triacrylate are joined in reaction vessel in proportion; add stopper again; pass into shielding gas; stir and heat, being warming up to 60 ~ 80 DEG C, adding catalyzer; stir lower constant temperature 3 ~ 5h; stop heating, treat that temperature drops to room temperature, obtain UV cured resin A.
In the present invention, described UV cured resin B is selected from one or more in epoxy acrylate, urethane acrylate, polyester acrylate or polyether acrylate.
In the present invention, described flow agent is selected from one or more in enlightening height TegoGlide410, German BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348; Described wetting agent be selected from the NP-100 of LG-DOW company or German BYK333 flow agent one or both; Described defoamer is selected from one or more in German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038.
The present invention also provides a kind of preparation method of peelable blue glue, and concrete steps are as follows:
According to formula, wetting agent, flow agent, defoamer and UV mill base is added in the high speed dispersor controlling rotating speed 300-1400r/min, after disperseing 15-20min under 600-800r/min rotating speed, rotating speed is down to 300r/min, add UV cured resin A, UV cured resin B and light trigger A, photoinitiator b, continue dispersion 50-100min, mix, namely obtain peelable blue glue.
Useful achievement of the present invention is as follows:
The peelable blue glue of one of the present invention, owing to containing numerous crosslinkable acrylate structural after the peelable blue glue curing of coating of one of the present invention, can realize fast setting under the UV-LED light source irradiation of 365nm.
The peelable blue glue of gained of the present invention, adopt the NDJ-1 rotational viscosimeter that Shanghai sharp bearing device Manufacturing Co., Ltd provides, pass through GB/T2794-2013, " the mensuration list cylinder rotary viscosimeter method of tackiness agent viscosity ", detect under the condition of room temperature 25 DEG C, its viscosity is 30000-40000mPa.s.
Further, carry out the fineness test of peelable blue glue by GB/T6753.1-2007 standard " mensuration of colored paint, varnish and printing-ink mesh-of-grind ", recording fineness is :≤5 μm.
Further, through the surface of the slide glass of the peelable blue glue of 365nmUV-LED light irradiation precoating after the peelable blue glue film of gained of the present invention, according to the fingers-touch method (surface of the peelable blue glue of the cured for some time that press...withes one's finger, using tack-free as completely crued standard, when solidifying completely with peelable blue glue, the shortest time used characterizes), after testing, the set time of the peelable blue glue of quick-drying of the present invention is 1-5s.
Further, peelable blue glue of the present invention, UV cured resin A molecular structure as main film forming substance is organosilicon structures, there is very low surface energy, reduce the interaction between film and base material, make it to embody better from separability, stripping strength adopt Shenzhen newly to think carefully the CMT5104 electronic tension tester of company at room temperature carries out the stripping test of 180 ° by GB/T2790-1995 standard " tackiness agent 180 ° of peeling strength test methods ", draw speed 50mm/min; Recording stripping strength is 0.21 ~ 0.25kN/m;
Further, peelable blue glue prepared by the present invention adds UV mill base, makes it have noctilucence characteristic.
In sum, the peelable blue glue of one of the present invention, has curing speed and have noctilucence effect faster after film.Preparation method's technique of the present invention is simple, easy to control, technology maturation, fast, efficient, and be suitable for suitability for industrialized production.
Embodiment
Below by embodiment, the present invention is described in further detail, but do not limit the present invention.
In the raw material that various embodiments of the present invention are used except the special producer that shows and specification, other raw materials are commercially available, and specification is chemical pure.
The model of the various equipment that the present invention is used and the information of manufacturer as follows:
GFJ-0.4 type high speed dispersor, Shanghai Xin Nuo plant and instrument company limited produces.
Embodiment 1
A kind of peelable blue glue, calculates by weight, its raw material composition and content as follows:
Wherein: described UV cured resin A calculates by weight, its composition and content as follows:
Described UV cured resin A carries out as follows:
10 parts of Methyl Hydrogen Polysiloxane Fluids and 10 parts of ethoxylated trimethylolpropane triacrylates are joined in the there-necked flask of 500ml; add the hydroquinone of polymerization retarder of 0.01 part again; pass into shielding gas; stir and heat, being warming up to 60 DEG C, adding the complex compound of 0.03 part of Platinic chloride; stir lower constant temperature 3h; stop heating, treat that flask temperature drops to room temperature, obtain UV cured resin A.
Described UV cured resin B is toughened resin, as epoxy acrylate, urethane acrylate in mass ratio 1:1 composition mixture;
Described flow agent is enlightening height TegoGlide410;
Described UV wetting agent is the NP-100 of LG-DOW company;
The yellowish green MG-1 that described UV mill base provides for Dongguan City Chun Liang process materials company limited;
Described defoamer is the mixture of German BYK-035, BYK-037 1:1 in mass ratio;
Described light trigger A be BASF Irgacure1173, Irgacure184D, IrgacureTPO in mass ratio 1:1:2 composition mixture;
Described photoinitiator b be BASF BASF light trigger Irgacure2959, IRGACURE500 in mass ratio 1:1 composition mixture;
In the present embodiment, a kind of preparation method of peelable blue glue, specifically comprises the steps:
According to formula, 1 part of wetting agent, 0.05 part of flow agent, 0.2 part of defoamer and 1 part of UV mill base is added in the GFJ-0.4 type high speed dispersor (Shanghai Xin Nuo plant and instrument company limited) controlling rotating speed 300r/min, after disperseing 15min under 600r/min rotating speed, rotating speed is down to 300r/min, add 60 parts of UV cured resin A, 60 parts of UV cured resin B, 3 parts of light trigger A and 3 part photoinitiator bs, continue dispersion 50min, mix, namely obtain peelable blue glue.
The peelable blue glue of the present embodiment gained, adopt the NDJ-1 rotational viscosimeter that Shanghai sharp bearing device Manufacturing Co., Ltd provides, by GB/T2794-2013, " the mensuration list cylinder rotary viscosimeter method of tackiness agent viscosity ", detect under the condition of room temperature 25 DEG C, its viscosity is 30000mPa.s.
The peelable blue glue of the present embodiment gained, carry out the fineness test of peelable blue glue by GB/T6753.1-2007 standard " mensuration of colored paint, varnish and printing-ink mesh-of-grind ", recording fineness is: 3.5 μm.
Through the surface of the slide glass of the peelable blue glue of 365nmUV-LED light irradiation precoating after the peelable blue glue film of the present embodiment gained, according to the fingers-touch method (surface of the peelable blue glue of the cured for some time that press...withes one's finger, using tack-free as completely crued standard, when solidifying completely with peelable blue glue, the shortest time used characterizes), after testing, the set time of the peelable blue glue of quick-drying of the present invention is 1s.
Further, the peelable blue glue of one of the present embodiment, UV cured resin A molecular structure as main film forming substance is organosilicon structures, there is very low surface energy, reduce the interaction between film and base material, make it to embody better rippability, the CMT5104 electronic tension tester that stripping strength adopts Shenzhen newly to think carefully company at room temperature carries out the stripping test of 180 ° by GB/T2790-1995 standard " tackiness agent 180 ° of peeling strength test methods ", draw speed 50mm/min; Recording stripping strength is 0.25kN/m;
Fast setting performance after the peelable blue glue film of above the present embodiment gained, peeling effect is good.
Embodiment 2
A kind of peelable blue glue, calculates by weight, its raw material composition and content as follows:
Wherein: described UV cured resin A calculates by weight, its composition and content as follows:
Described UV cured resin A carries out as follows:
20 parts of Methyl Hydrogen Polysiloxane Fluids and 20 parts of ethoxylated trimethylolpropane triacrylates are joined in the there-necked flask of 500ml; add the hydroquinone of polymerization retarder of 0.02 part again; pass into shielding gas; stir and heat, being warming up to 80 DEG C, adding the complex compound of 0.05 part of Platinic chloride; stir lower constant temperature 5h; stop heating, treat that flask temperature drops to room temperature, obtain UV cured resin A.
Described UV cured resin B is toughened resin, as epoxy acrylate, urethane acrylate in mass ratio 2:1 composition mixture;
Described flow agent be German BYK-345, BYK-346 in mass ratio 1:1 composition mixture;
Described UV wetting agent is German BYK333;
The sky blue UV mill base that described hard iron light Materials Co., Ltd of Foshan City provides;
Described defoamer is German BYK Bi Ke BYK-024, BYK-025, BYK-035 is the mixture of 1:1:1 composition in mass ratio;
Described light trigger A be BASF Irgacure184D, IrgacureTPO, Irgacure369, Irgacure819 in mass ratio 1:1:1:1 composition mixture;
Described photoinitiator b be BASF BASF light trigger Irgacure2959, IRGACURE500 in mass ratio 1:2 composition mixture;
A preparation method for peelable blue glue, specifically comprises the steps:
According to formula, 10 parts of wetting agents, 0.1 part of flow agent, 1 part of defoamer and 10 parts of UV mill bases are added in the GFJ-0.4 type high speed dispersor (Shanghai Xin Nuo plant and instrument company limited) controlling rotating speed 1400r/min, after disperseing 20min under 800r/min rotating speed, rotating speed is down to 300r/min, add 150 parts of UV cured resin A, 150 parts of UV cured resin B, 5 parts of light trigger A, 5 parts of photoinitiator bs, continue dispersion 100min, mix, namely obtain peelable blue glue.
The peelable blue glue of the present embodiment gained, adopt the NDJ-1 rotational viscosimeter that Shanghai sharp bearing device Manufacturing Co., Ltd provides, by GB/T2794-2013, " the mensuration list cylinder rotary viscosimeter method of tackiness agent viscosity ", detect under the condition of room temperature 25 DEG C, its viscosity is 40000mPa.s.
The peelable blue glue of the present embodiment gained, carry out the fineness test of peelable blue glue by GB/T6753.1-2007 standard " mensuration of colored paint, varnish and printing-ink mesh-of-grind ", recording fineness is 4.5 μm.
Through the surface of the slide glass of the peelable blue glue of 365nmUV-LED light irradiation precoating after the peelable blue glue film of the present embodiment gained, according to the fingers-touch method (surface of the peelable blue glue of the cured for some time that press...withes one's finger, using tack-free as completely crued standard, when solidifying completely with peelable blue glue, the shortest time used characterizes), after testing, the set time of the peelable blue glue of quick-drying of the present invention is 5s.
The CMT5104 electronic tension tester that stripping strength adopts Shenzhen newly to think carefully company at room temperature carries out the stripping test of 180 ° by GB/T2790-1995 standard " tackiness agent 180 ° of peeling strength test methods ", draw speed 50mm/min; Recording stripping strength is 0.21kN/m;
Fast setting performance after the peelable blue glue film of above the present embodiment gained, peeling effect is good.
In sum, what peelable blue glue of the present invention adopted is UV curing formula, and the high speed curable of UV improves its curing speed, only has 1-5s; Peelable blue glue has noctilucence characteristic.UV cured resin A molecular structure as main film forming substance is organosilicon structures, has very low surface energy, reduces the interaction between film and base material, makes it to embody better from separability, and stripping strength is 0.21 ~ 0.25kN/m.After 365nmUV-LED light irradiation, have quick setting capabilities after this is high temperature resistant peelable blue glue film, the good non-scale of bonding force comes off, it is easy, complete to peel off, and does not flow residual stain.
Above said content be only the present invention conceive under basic explanation, and according to any equivalent transformation that technical scheme of the present invention is done, all should protection scope of the present invention be belonged to.
Claims (6)
1. a peelable blue glue, is characterized in that, calculate by weight, its raw material composition and content as follows:
Wherein: the structural formula of described UV cured resin A is as follows:
Wherein: m is the integer within the scope of 1-30; N is the integer within the scope of 1-30;
Described UV cured resin B is toughened resin;
Described UV mill base is the blue F4049 of mill base;
Described light trigger A is selected from one or more in BASF Irgacure1173, Irgacure184D, IrgacureTPO, Irgacure369, Irgacure651, Irgacure379, Irgacure819, Irgacure907 or macromolecular photoinitiator EsacureKIP150;
Described photoinitiator b is selected from one or more in BASF BASF light trigger Irgacure2959, IRGACURE500 or IRGACURE819DW.
2. peelable blue glue according to claim 1, it is characterized in that, its viscosity under the condition of room temperature 25 DEG C is 30000-40000mPa.s, fineness Wei≤5 μm, set time is 1-5s, and the stripping strength recorded when draw speed 50mm/min is 0.21 ~ 0.25kN/m.
3. peelable blue glue according to claim 1, is characterized in that, described UV cured resin A calculates by weight, its raw material composition and content as follows:
Described UV cured resin A is prepared as follows:
Methyl Hydrogen Polysiloxane Fluid and ethoxylated trimethylolpropane triacrylate are joined in reaction vessel in proportion; add stopper again; pass into shielding gas; stir and heat, being warming up to 60 ~ 80 DEG C, adding catalyzer; stir lower constant temperature 3 ~ 5h; stop heating, treat that temperature drops to room temperature, obtain UV cured resin A.
4. peelable blue glue according to claim 1, is characterized in that, described UV cured resin B is selected from one or more in epoxy acrylate, urethane acrylate, polyester acrylate or polyether acrylate.
5. peelable blue glue according to claim 1, it is characterized in that, described flow agent is selected from one or more in enlightening height TegoGlide410, German BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348; Described wetting agent be selected from the NP-100 of LG-DOW company or German BYK333 flow agent one or both; Described defoamer is selected from one or more in German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038.
6. a preparation method for peelable blue glue, it is characterized in that, concrete steps are as follows:
According to formula, wetting agent, flow agent, defoamer and UV mill base is added in the high speed dispersor controlling rotating speed 300-1400r/min, after disperseing 15-20min under 600-800r/min rotating speed, rotating speed is down to 300r/min, add UV cured resin A, UV cured resin B and light trigger A, photoinitiator b, continue dispersion 50-100min, mix, namely obtain peelable blue glue.
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| CN201610038540.8A CN105482689B (en) | 2016-01-20 | 2016-01-20 | Peelable blue glue and preparation method thereof |
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| CN201610038540.8A CN105482689B (en) | 2016-01-20 | 2016-01-20 | Peelable blue glue and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111139015A (en) * | 2019-12-31 | 2020-05-12 | 天津久日新材料股份有限公司 | Environment-friendly UV LED (ultraviolet light emitting diode) curing peelable blue glue and preparation method thereof |
| CN113667394A (en) * | 2021-08-16 | 2021-11-19 | 广东希贵光固化材料有限公司 | Temporary protective coating for UV (ultraviolet) light stripping and application thereof |
| CN114729181A (en) * | 2019-12-20 | 2022-07-08 | Dic株式会社 | Aqueous urethane resin dispersion, synthetic leather, and method for producing synthetic leather |
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| CN105176449A (en) * | 2015-07-24 | 2015-12-23 | 中山市伯伦克专用化学产品有限公司 | UV-curing peelable blue glue and preparation method therefor |
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| JP2000345109A (en) * | 1999-06-02 | 2000-12-12 | Mitsuo Oyanagi | Peelable coating material having excellent appearance and peeling properties |
| CN103031053A (en) * | 2013-01-06 | 2013-04-10 | 北京海斯迪克新材料有限公司 | UV-cured peelable blue gel for temporary protection of touch screen and preparation method thereof |
| CN105176449A (en) * | 2015-07-24 | 2015-12-23 | 中山市伯伦克专用化学产品有限公司 | UV-curing peelable blue glue and preparation method therefor |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114729181A (en) * | 2019-12-20 | 2022-07-08 | Dic株式会社 | Aqueous urethane resin dispersion, synthetic leather, and method for producing synthetic leather |
| CN111139015A (en) * | 2019-12-31 | 2020-05-12 | 天津久日新材料股份有限公司 | Environment-friendly UV LED (ultraviolet light emitting diode) curing peelable blue glue and preparation method thereof |
| CN113667394A (en) * | 2021-08-16 | 2021-11-19 | 广东希贵光固化材料有限公司 | Temporary protective coating for UV (ultraviolet) light stripping and application thereof |
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| CN105482689B (en) | 2017-11-07 |
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