CN110511663B - Printable hardened film formula suitable for oil-water dual-purpose ink and printing film - Google Patents
Printable hardened film formula suitable for oil-water dual-purpose ink and printing film Download PDFInfo
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- CN110511663B CN110511663B CN201910843083.3A CN201910843083A CN110511663B CN 110511663 B CN110511663 B CN 110511663B CN 201910843083 A CN201910843083 A CN 201910843083A CN 110511663 B CN110511663 B CN 110511663B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5209—Coatings prepared by radiation-curing, e.g. using photopolymerisable compositions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B41M5/5281—Polyurethanes or polyureas
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
- C08J2463/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
- C08J2475/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
- C08J2483/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a printable hardening film formula suitable for oil-water dual-purpose ink, which comprises the following components in parts by weight: 30-80 parts of urethane acrylate prepolymer, 5-30 parts of diluent monomer, 0.5-10 parts of photoinitiator, 10-70 parts of antifogging resin, 0.1-10 parts of sulfosuccinate surfactant and 10-90 parts of solvent; wherein, the antifogging resin comprises a resin containing hydroxyl, amino and carboxyl. The invention also claims a printing film which comprises a substrate layer and a functional coating, wherein the functional coating is prepared by the formula of the printable hardening film suitable for the oil-water dual-purpose ink. The formula of the printable hardening film effectively solves the problem of adhesion of oil-based ink and water-based ink, and has the performances of scraping resistance and hardness.
Description
Technical Field
The invention relates to a hardened film formula, in particular to a printable hardened film formula suitable for oil-water dual-purpose ink and a printing film.
Background
The printing film refers to a plastic film coated on the surface of a product. The current common printing film is only suitable for printing of oil-based ink or water-based ink, and is difficult to be suitable for both oil-based ink and water-based ink.
And the prior bottom coating printable film does not have the performances of scratch resistance and hardness, and if the surface of the film is abraded in the using process, the appearance and the performance of the subsequent printing ink are influenced. The components in the existing printing film formula are mainly high molecular polymers, and are mainly suitable for oily ink.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide a printable hardened film formula suitable for oil-water dual-purpose ink and a printing film.
The first purpose of the invention is to provide a printable hardening film formula suitable for oil-water dual-purpose ink, which comprises the following components in parts by weight:
30-80 parts of urethane acrylate prepolymer, 5-30 parts of diluent monomer, 0.5-10 parts of photoinitiator, 10-70 parts of antifogging resin, 0.1-10 parts of sulfosuccinate surfactant and 10-90 parts of solvent; wherein, the antifogging resin comprises a resin containing hydroxyl, amino and carboxyl.
Further, the polyurethane acrylate prepolymer is selected from aliphatic polyurethane acrylate or a mixture of polyurethane and polyacrylate, the molecular weight of the aliphatic polyurethane acrylate is 5000-100 g/mol, the molecular weight of the polyurethane is 5000-100 g/mol, and the molecular weight of the polyacrylate is 5000-100 g/mol.
Further, the polyurethane acrylate prepolymer is selected from aliphatic polyurethane acrylate, and the aliphatic polyurethane acrylate is one or more of LM302, UH312, UH322, LM601 and LM 4312.
Further, the diluent monomer is an acrylate monomer.
Further, the acrylate monomer is an aliphatic acrylate monomer containing 4-10 carbon atoms and/or a functional monomer, and the functional monomer is selected from hydroxyethyl acrylate, hydroxypropyl acrylate or glycidyl acrylate.
Further, the photoinitiator is selected from a cleavage type initiator and/or a hydrogen abstraction type initiator.
Further, the cracking type initiator is one or more of 1173, 184, 907, 369, 1490 and 1700 photoinitiators.
Further, the hydrogen abstraction initiator is one or more of Benzophenone (BP), 4-methylbenzophenone and 2,4, 6-trimethylbenzophenone.
Further, the antifogging resin is at least two of a carboxylated epoxy acrylate resin, a fluorinated epoxy resin, an aminosilicone resin and a styrene maleic anhydride resin, and must contain the aminosilicone resin.
Further, the sulfosuccinate surfactant is one or more of a sodium salt of di-n-hexyl sulfosuccinate, a sodium salt of bis (2-ethylbutyl) sulfosuccinate, a sodium salt of bis (2-methylpentyl) sulfosuccinate and a sodium salt of bis (4-methyl-2-pentyl) sulfosuccinate.
Further, the solvent is selected from one or more of propanol, isopropanol, isobutanol, n-butanol, acetone, butanone, cyclohexanone, methyl isobutyl ketone, isophorone, ethyl acetate, butyl acetate, toluene, xylene, propylene glycol methyl ether and dipropylene glycol methyl ether.
In the present application, the amount of the antifogging resin in the appropriate range, which is outside the range of the amount of the present invention, affects the adhesion of the oil-based ink and the hardness and abrasion resistance of the coating, and less than the range of the amount of the present invention, affects the adhesion of the water-based ink. In the antifogging resin, -OH or-NH2The addition of the (B) can reduce the hardness and the wear resistance of the coating, and the multiple functions of hardening and printing are realized by optimizing the formula proportion. And due to the introduction of-OH, an adhesion condition is provided for the water-based ink.
The second purpose of the invention is to provide a printing film, which comprises a substrate layer and a functional coating layer, wherein the functional coating layer is prepared by the formula of the printable hardening film suitable for the oil-water dual-purpose ink.
By the scheme, the invention at least has the following advantages:
today's printed films are primed films and do not have other properties. The printing film prepared by the formula of the printable hardening film suitable for the oil-water dual-purpose ink enables the current printing film to have the performances of scraping resistance and hardness, and effectively solves the adhesion problem of the oil-based ink and the water-based ink. When the surface of the printing film is printed by the oil-based ink, the oil-based ink can be well attached, and hydroxyl groups introduced into the formula provide good attachment conditions for the attachment of the water-based ink.
The foregoing is a summary of the present invention, and in order to provide a clear understanding of the technical means of the present invention and to be implemented in accordance with the present specification, the following is a preferred embodiment of the present invention and is described in detail below.
Detailed Description
The following examples are given to further illustrate the embodiments of the present invention. The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
Example 1
The formula of the printable hardened film suitable for the oil-water dual-purpose ink comprises the following components in parts by weight:
30 parts of a polyurethane acrylate prepolymer, wherein the polyurethane acrylate prepolymer is LM 302;
5 parts of a diluent monomer, wherein the diluent monomer comprises 1 part of butyl acrylate, 2 parts of hydroxypropyl acrylate and 2 parts of perfluorobutyl acrylate;
1173 photoinitiator 0.5 part;
10 parts of antifogging resin, wherein the antifogging resin comprises 5 parts of amino silicone resin and 5 parts of carboxylated epoxy acrylate resin;
1 part of di-n-hexyl sulfosuccinate sodium salt;
30 parts of solvent, wherein the solvent is selected from one or more of propanol, isopropanol, isobutanol, n-butanol, acetone, butanone, cyclohexanone, methyl isobutyl ketone, isophorone, ethyl acetate, butyl acetate, toluene, xylene, propylene glycol methyl ether and dipropylene glycol methyl ether.
Example 2
The formula of the printable hardened film suitable for the oil-water dual-purpose ink comprises the following components in parts by weight:
40 parts of urethane acrylate prepolymer, wherein each 20 parts of the urethane acrylate prepolymer comprises LM601 and LM 302;
10 parts of a diluent monomer, wherein the diluent monomer comprises 2 parts of octyl acrylate and 8 parts of glycidyl acrylate;
907 parts of a photoinitiator;
30 parts of antifogging resin, wherein the antifogging resin comprises 10 parts of amino silicone resin, carboxylated epoxy acrylate resin and fluorinated epoxy resin;
3 parts of bis (2-methylpentyl) sulfosuccinate sodium salt;
30 parts of solvent, wherein the solvent is selected from one or more of propanol, isopropanol, isobutanol, n-butanol, acetone, butanone, cyclohexanone, methyl isobutyl ketone, isophorone, ethyl acetate, butyl acetate, toluene, xylene, propylene glycol methyl ether and dipropylene glycol methyl ether.
Example 3
The formula of the printable hardened film suitable for the oil-water dual-purpose ink comprises the following components in parts by weight:
55 parts of a polyurethane acrylate prepolymer, wherein the polyurethane acrylate prepolymer is LM 4312;
15 parts of a diluent monomer comprising 7 parts of nonyl acrylic acid and 8 parts of hydroxypropyl acrylate;
5 parts of BP photoinitiator;
40 parts of antifogging resin, including 10 parts of amino silicone resin, 20 parts of fluorinated epoxy resin and 10 parts of styrene maleic anhydride resin;
5 parts of sodium bis (2-ethylbutyl) sulfosuccinate;
30 parts of solvent, wherein the solvent is selected from one or more of propanol, isopropanol, isobutanol, n-butanol, acetone, butanone, cyclohexanone, methyl isobutyl ketone, isophorone, ethyl acetate, butyl acetate, toluene, xylene, propylene glycol methyl ether and dipropylene glycol methyl ether.
Example 4
The formula of the printable hardened film suitable for the oil-water dual-purpose ink comprises the following components in parts by weight:
55 parts of a polyurethane acrylate prepolymer, wherein the polyurethane acrylate prepolymer is LM 302;
25 parts of a diluent monomer which is hydroxyethyl acrylate;
8 parts of 4-methylbenzophenone photoinitiator;
55 parts of antifogging resin, including 25 parts of amino silicone resin and 30 parts of carboxylated epoxy acrylate resin;
7 parts of di-n-hexyl sulfosuccinate sodium salt;
30 parts of solvent, wherein the solvent is selected from one or more of propanol, isopropanol, isobutanol, n-butanol, acetone, butanone, cyclohexanone, methyl isobutyl ketone, isophorone, ethyl acetate, butyl acetate, toluene, xylene, propylene glycol methyl ether and dipropylene glycol methyl ether.
Example 5
The formula of the printable hardened film suitable for the oil-water dual-purpose ink comprises the following components in parts by weight:
80 parts of urethane acrylate prepolymer, including 40 parts of each of LM302 and LM4312,
30 parts of a diluent monomer, including 15 parts of each of glycidyl acrylate and hydroxyethyl acrylate;
10 parts of 2,4, 6-trimethylbenzophenone photoinitiator;
70 parts of antifogging resin, including 30 parts of amino silicone resin, 10 parts of carboxylated epoxy acrylate resin and 30 parts of styrene maleic anhydride resin;
10 parts of di-n-hexyl sulfosuccinate sodium salt;
30 parts of solvent, wherein the solvent is selected from one or more of propanol, isopropanol, isobutanol, n-butanol, acetone, butanone, cyclohexanone, methyl isobutyl ketone, isophorone, ethyl acetate, butyl acetate, toluene, xylene, propylene glycol methyl ether and dipropylene glycol methyl ether.
Example 6
The printing films prepared by the printable hardened film formulations suitable for the oil-water dual-purpose ink in the embodiments 1 to 5 are coated on the surface of the PET substrate layer, and after UV curing, a functional coating is formed on the surface of the PET substrate layer, so that the printing films are obtained.
The printed films prepared separately above showed good adhesion to both oil-based inks and water-based inks, and the results are shown in table 1.
TABLE 1 Properties of different printed films
| Performance of | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 |
| Water drop angle | 55-60° | 38-45° | 40-50° | 25-30° | 35° |
| Dyne value | 34 | 38-40 | 36-38 | 48 | 44 |
| Attachment grid | 5B | 5B | 5B | 5B | 5B |
| Baige boiled adhesive | 5B | 5B | 5B | 3B | 4B |
| Hardness of | 500g×2H | 750g×1H | 500g×2H | 500g×1H | 500g×1H |
| Abrasion resistant (500g) | 500 round trip | 400 round trip | 400 round trip | 250 go back and forth | 300 back and forth |
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, it should be noted that, for those skilled in the art, many modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.
Claims (7)
1. A printable hardening film suitable for oil-water dual-purpose ink is characterized by comprising the following components in parts by weight:
30-80 parts of urethane acrylate prepolymer, 5-30 parts of diluent monomer, 0.5-10 parts of photoinitiator, 10-70 parts of antifogging resin, 0.1-10 parts of sulfosuccinate surfactant and 10-90 parts of solvent; wherein the antifogging resin comprises a resin containing hydroxyl, amino and carboxyl;
the antifogging resin is at least two of carboxylated epoxy acrylate resin, fluorinated epoxy resin, amino silicone resin and styrene maleic anhydride resin, and the antifogging resin must contain the amino silicone resin;
the sulfosuccinate surfactant is one or more of a sodium salt of di-n-hexyl sulfosuccinate, a sodium salt of bis (2-ethylbutyl) sulfosuccinate, a sodium salt of bis (2-methylpentyl) sulfosuccinate and a sodium salt of bis (4-methyl-2-pentyl) sulfosuccinate.
2. The printable curing film suitable for oil and water ink according to claim 1, wherein: the polyurethane acrylate prepolymer is selected from aliphatic polyurethane acrylate or a mixture of polyurethane and polyacrylate, the molecular weight of the aliphatic polyurethane acrylate is 5000-5000 g/mol, the molecular weight of the polyurethane is 100-5000g/mol, and the molecular weight of the polyacrylate is 100-5000 g/mol.
3. The printable curing film suitable for oil and water ink according to claim 1, wherein: the polyurethane acrylate prepolymer is selected from aliphatic polyurethane acrylate, and the aliphatic polyurethane acrylate is one or more of LM302, UH312, UH322, LM601 and LM 4312.
4. The printable curing film suitable for oil and water ink according to claim 1, wherein: the diluent monomer is an acrylate monomer.
5. The printable curing film suitable for oil and water ink according to claim 4, wherein: the acrylate monomer is an aliphatic acrylate monomer containing 4-10 carbon atoms and/or a functional monomer, and the functional monomer is selected from hydroxyethyl acrylate, hydroxypropyl acrylate or glycidyl acrylate.
6. The printable curing film suitable for oil and water ink according to claim 1, wherein: the photoinitiator is selected from a cracking type initiator and/or a hydrogen abstraction type initiator.
7. A printed film, characterized by: comprising a substrate layer and a functional coating layer made of a printable hardened film suitable for oil-and-water dual-purpose ink according to any one of claims 1 to 6.
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| CN201910843083.3A CN110511663B (en) | 2019-09-06 | 2019-09-06 | Printable hardened film formula suitable for oil-water dual-purpose ink and printing film |
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| CN201910843083.3A CN110511663B (en) | 2019-09-06 | 2019-09-06 | Printable hardened film formula suitable for oil-water dual-purpose ink and printing film |
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| CN110511663B true CN110511663B (en) | 2021-09-10 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1265408A (en) * | 2000-03-30 | 2000-09-06 | 吉林大学 | Hydrophilic antifogging and antifrosting anti-friction coating and its application |
| CN103305078A (en) * | 2013-06-26 | 2013-09-18 | 中国科学院化学研究所 | Hydrophobic material and application thereof in preparation of offset print printing plates |
| CN103540255A (en) * | 2013-09-27 | 2014-01-29 | 上海维凯化学品有限公司 | Ultraviolet curable anti-fingerprint coating composition with printability |
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- 2019-09-06 CN CN201910843083.3A patent/CN110511663B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1265408A (en) * | 2000-03-30 | 2000-09-06 | 吉林大学 | Hydrophilic antifogging and antifrosting anti-friction coating and its application |
| CN103305078A (en) * | 2013-06-26 | 2013-09-18 | 中国科学院化学研究所 | Hydrophobic material and application thereof in preparation of offset print printing plates |
| CN103540255A (en) * | 2013-09-27 | 2014-01-29 | 上海维凯化学品有限公司 | Ultraviolet curable anti-fingerprint coating composition with printability |
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Address after: 215400 No.5, Hubin Road, Xinhu Town, Shuangfeng town, Taicang City, Suzhou City, Jiangsu Province Applicant after: Jiangsu Huangguan New Material Technology Co.,Ltd. Address before: 215416 No.8, Xinhu Jianyuan Road, Shuangfeng town, Taicang City, Suzhou City, Jiangsu Province Applicant before: CROWN (TAICANG) ADHESIVE PRODUCTS Co.,Ltd. |
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| CB02 | Change of applicant information | ||
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