CN106243990A - A kind of ultraviolet light polymerization transfer coatings compositions - Google Patents
A kind of ultraviolet light polymerization transfer coatings compositions Download PDFInfo
- Publication number
- CN106243990A CN106243990A CN201610760580.3A CN201610760580A CN106243990A CN 106243990 A CN106243990 A CN 106243990A CN 201610760580 A CN201610760580 A CN 201610760580A CN 106243990 A CN106243990 A CN 106243990A
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- CN
- China
- Prior art keywords
- ultraviolet light
- acrylate
- transfer coatings
- light polymerization
- coatings compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The present invention relates to a kind of ultraviolet light polymerization transfer coatings compositions.This coating composition is made up of according to each component of percentage by weight following: chlorination modified acrylate 10 15 parts, acrylate copolymer 15 40 parts, acrylate monomer 5 25 parts, light trigger 3 10 parts, solvent 35 55 parts, auxiliary agent 0.5 3 parts.Above-mentioned substance is prepared by mixing into coating at certain temperature and mixing speed, is then applied to base material and uses ultraviolet radiation-curable simultaneously, the coating of densification can be formed.Coating prepared by the present invention, solidification temperature is lower, and increases significantly in terms of antistatic and anti-soil, it is possible to better meet the market demand, therefore possesses higher promotional value.
Description
Technical field
The present invention relates to a kind of conventional coating, the preparation of a kind of chemistry painting industry compositions using ultraviolet light polymerization
Method.
Background technology
Ultraviolet refers to the general name that electromagnetic spectrum medium wavelength radiates from 10nm-400nm, it is impossible to cause the vision of people.
The ultraviolet wavelength of industrial application is based on 200nm-400nm.Irradiate, with ultraviolet light, the coating carrying out solidifying and be referred to as ultraviolet light
Solidification transfer coatings, namely after coating is coated with by dip-coating, showering, paint, the method such as spin coating, even vacuum painting is coated with, then through ultraviolet
Line irradiates and film-forming.This technique functions comes from the international coatings market of the seventies, is a kind of brand-new coating paint-on technique.
In 20 end of the centurys, ultraviolet-curing paint comes into vogue in the ground such as west, Japan, is applied to mobile phone, DVD, walkman shell the earliest
External coating process, its application now further expanded to the household appliance technical field such as cosmetics, television set and computer later.
Ultraviolet-curing paint quickly grows, and due to the coating after solidification, to have the scratch resistance of excellence, high rigidity, richness good etc. excellent
Point, and possess efficiently at the aspect such as economy and environment, the advantage such as energy-saving and environmental protection, therefore the type coating is used in building, physical culture
Product, telecommunications, packaging material and automobile component are obtained for and are widely applied.
The invention discloses a kind of ultraviolet light polymerization transfer coatings compositions, this coating composition is by chlorination modified propylene
Acid ester resin, acrylate copolymer, acrylate list, light trigger, solvent and auxiliary agent composition.With the ultraviolet mentioned on market
Photocuring transfer coatings is compared, and coating curing temperatures of the present invention is lower, and increases significantly in terms of antistatic and anti-soil,
The market demand can be better met, therefore possess higher promotional value.
Summary of the invention
The invention aims to solve above-mentioned deficiency and provide a kind of new have on antistatic and stain resistance prominent
Go out the preparation method of the ultraviolet light polymerization transfer coatings compositions of performance.
In order to achieve the above object, the compositions of the present invention includes following composition:
Chlorination modified acrylate 10-15 part,
Acrylate copolymer 15-40 part,
Acrylate monomer 5-25 part,
Light trigger 3-10 part,
Solvent 35-55 part,
Auxiliary agent 0.5-3 part.
Wherein, described chlorination modified acrylate is chloride polyurethane acrylate resin, chloride polyacrylic acid
In ester resin, chloride Epocryl two or three, described acrylate copolymer be official's degree be the fat of 2-7
Fat race urethane methacylate resins, described acrylate monomer is trimethylolpropane trimethacrylate, three hydroxyl first
Base propane trimethyl acrylic ester, ethoxyquin trimethylolpropane trimethacrylate, the third oxidation trimethylolpropane tris acrylic acid
Two or more in ester, described light trigger is benzophenone, and described organic solvent is normal propyl alcohol, isopropanol, positive fourth
Two or more in alcohol, ethyl acetate, n-butyl acetate, propylene glycol monomethyl ether, propylene-glycol ethyl ether, described auxiliary agent is defoamer
And levelling agent.
Paint solidification temperature prepared by the method is lower, and increases significantly in terms of antistatic and anti-soil, it is possible to
Better meet the market demand, therefore possess higher promotional value.
Detailed description of the invention
Embodiment 1
Chlorination modified acrylate 20kg and acrylate copolymer 20kg is put in reactor, then in reactor
Add organic solvent 65kg, be heated to 75 DEG C, open stirring, make the resin in reactor all dissolve, backward reactor in
Add acrylate monomer 15kg, add light trigger 7kg, add auxiliary agent 1.2kg simultaneously, continue stirring and make system dispersion all
Even, system stops heating the most afterwards and stirring makes reactor naturally cool to room temperature, obtains final coating products.
The each component related to consists of:
Embodiment 2
Chlorination modified acrylate 30kg and acrylate copolymer 20kg is put in reactor, then in reactor
Add organic solvent 75kg, be heated to 80 DEG C, open stirring, make the resin in reactor all dissolve, backward reactor in
Add acrylate monomer 25kg, add light trigger 11kg, add auxiliary agent 1.9kg simultaneously, continue stirring and make system disperse
Uniformly, system stops heating the most afterwards and stirring makes reactor naturally cool to room temperature, obtains final coating products.
The each component related to consists of:
It should be noted that being above the specific embodiment to the present invention describes, but the invention is not limited in above-mentioned specific
Embodiment, related personnel can make various adjustment within the scope of the claims, and this has no effect in the essence of the present invention
Hold.
Claims (8)
1. a ultraviolet light polymerization transfer coatings compositions, it is characterised in that said composition by following according to percentage by weight
Each component forms:
Chlorination modified acrylate 10-15 part,
Acrylate copolymer 15-40 part,
Acrylate monomer 5-25 part,
Light trigger 3-10 part,
Solvent 35-55 part,
Auxiliary agent 0.5-3 part.
A kind of ultraviolet light polymerization transfer coatings compositions, it is characterised in that described is chlorination modified
Acrylate is chloride polyurethane acrylate resin, chloride polyacrylate resin, chloride Epocryl
In two or three.
A kind of ultraviolet light polymerization transfer coatings compositions, it is characterised in that described acrylate
Copolymer be official's degree be the aliphatic polyurethane methacrylate resin of 2-7.
A kind of ultraviolet light polymerization transfer coatings compositions, it is characterised in that described acrylate
Monomer is trimethylolpropane trimethacrylate, trimethylol-propane trimethacrylate, ethoxyquin trimethylolpropane tris
Two or more in acrylate, the third oxidation trimethylolpropane trimethacrylate.
A kind of ultraviolet light polymerization transfer coatings compositions, it is characterised in that described light trigger
For benzophenone.
A kind of ultraviolet light polymerization transfer coatings compositions, it is characterised in that described organic solvent
For two kinds in normal propyl alcohol, isopropanol, n-butyl alcohol, ethyl acetate, n-butyl acetate, propylene glycol monomethyl ether, propylene-glycol ethyl ether or many
Kind.
A kind of ultraviolet light polymerization transfer coatings compositions, it is characterised in that described auxiliary agent is for disappearing
Infusion and levelling agent.
A kind of ultraviolet light polymerization transfer coatings compositions, it is characterised in that preparation process is first will
Chlorination modified acrylate and acrylate copolymer put in reactor, then add organic solvent in reactor and add
Heat to 40-90 DEG C, is opened stirring, is made the resin in reactor all dissolve, backward reactor in add acrylate monomer,
Adding light trigger, add auxiliary agent simultaneously, continue stirring and make system be uniformly dispersed, system stops heating the most afterwards and stirring makes
Reactor naturally cools to room temperature, obtains final coating products.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610760580.3A CN106243990A (en) | 2016-08-31 | 2016-08-31 | A kind of ultraviolet light polymerization transfer coatings compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610760580.3A CN106243990A (en) | 2016-08-31 | 2016-08-31 | A kind of ultraviolet light polymerization transfer coatings compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106243990A true CN106243990A (en) | 2016-12-21 |
Family
ID=57596922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610760580.3A Pending CN106243990A (en) | 2016-08-31 | 2016-08-31 | A kind of ultraviolet light polymerization transfer coatings compositions |
Country Status (1)
| Country | Link |
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| CN (1) | CN106243990A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107974151A (en) * | 2017-11-15 | 2018-05-01 | 深圳雅联实业有限公司 | A kind of UV coating of resistance to highly basic, strong acid |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050165125A1 (en) * | 2002-03-22 | 2005-07-28 | Takeshi Tsunoda | Uv-curable coating composition and coated articles |
| CN101260253A (en) * | 2008-04-22 | 2008-09-10 | 惠州市长润发涂料有限公司 | Ultraviolet solidifying protection paint applied for polyester substrate surface |
| CN102070984A (en) * | 2010-12-31 | 2011-05-25 | 上海参爱贸易有限公司 | Stain-resisting ultraviolet curing painting |
| CN103540255A (en) * | 2013-09-27 | 2014-01-29 | 上海维凯化学品有限公司 | Ultraviolet curable anti-fingerprint coating composition with printability |
| CN103555156A (en) * | 2013-09-27 | 2014-02-05 | 上海维凯化学品有限公司 | Ultraviolet-curable anti-fingerprint antistatic paint composition |
-
2016
- 2016-08-31 CN CN201610760580.3A patent/CN106243990A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050165125A1 (en) * | 2002-03-22 | 2005-07-28 | Takeshi Tsunoda | Uv-curable coating composition and coated articles |
| CN101260253A (en) * | 2008-04-22 | 2008-09-10 | 惠州市长润发涂料有限公司 | Ultraviolet solidifying protection paint applied for polyester substrate surface |
| CN102070984A (en) * | 2010-12-31 | 2011-05-25 | 上海参爱贸易有限公司 | Stain-resisting ultraviolet curing painting |
| CN103540255A (en) * | 2013-09-27 | 2014-01-29 | 上海维凯化学品有限公司 | Ultraviolet curable anti-fingerprint coating composition with printability |
| CN103555156A (en) * | 2013-09-27 | 2014-02-05 | 上海维凯化学品有限公司 | Ultraviolet-curable anti-fingerprint antistatic paint composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107974151A (en) * | 2017-11-15 | 2018-05-01 | 深圳雅联实业有限公司 | A kind of UV coating of resistance to highly basic, strong acid |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161221 |
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