CN104293168A - VOC-free deodorization ultraviolet-curing coating for wood building material - Google Patents

VOC-free deodorization ultraviolet-curing coating for wood building material Download PDF

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Publication number
CN104293168A
CN104293168A CN201410584810.6A CN201410584810A CN104293168A CN 104293168 A CN104293168 A CN 104293168A CN 201410584810 A CN201410584810 A CN 201410584810A CN 104293168 A CN104293168 A CN 104293168A
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CN
China
Prior art keywords
building materials
voc
wooden building
curing paint
ultraviolet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410584810.6A
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Chinese (zh)
Inventor
习小山
王军
黄波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Nashuo Technology Co Ltd
Original Assignee
Chengdu Nashuo Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chengdu Nashuo Technology Co Ltd filed Critical Chengdu Nashuo Technology Co Ltd
Priority to CN201410584810.6A priority Critical patent/CN104293168A/en
Publication of CN104293168A publication Critical patent/CN104293168A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20—Diluents or solvents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to the field of coatings, in particular to a VOC-free deodorization ultraviolet-curing coating for a wood building material. The VOC-free deodorization ultraviolet-curing coating for the wood building material is prepared from the following raw materials in percentage by mass: 40-60 percent of the mixture of aliphatic polyurethane hexaacrylate and pure acrylic ester prepolymer, 3-5 percent of ethyl cellulose, 5-12 percent of an initiator, 1-3 percent of a surface additive, 5-10 percent of a solubilizing assistant, 1-2 percent of a nano-silver antibacterial agent and 10-30 percent of ethanol. The VOC-free deodorization ultraviolet-curing coating has a beautifying function and a protecting function, does not contain VOC, is more environment-friendly and healthy, and convenient to use by people.

Description

A kind of for wooden building materials not containing VOC, deodorizing ultraviolet-curing paint
Technical field
The present invention relates to paint field, particularly relate to a kind of for wooden building materials not containing VOC, deodorizing ultraviolet-curing paint.
Background technology
Ultraviolet-curing paint is since appearance, because it has the feature of 5E, i.e. efficient (Efficient), applicable wide (Enabling), economic (Economical), energy-conservation (Energy Saying), environmental friendliness (Environmental-friendly).In the prior art, ultraviolet-curing paint is widely used in and closely bound up field of living by people, to play the effect beautifying object and protection object.
Coating can not be corroded by the wooden building materials of available protecting, thus extends the work-ing life of wooden building materials, and wooden building materials seem more attractive in appearance under the covering with paint of coating in addition.Along with the progress in epoch, people pursue the in-built standard of environment protection health more, if therefore there is a kind of ultraviolet-curing paint being used in wooden building material surface not contain VOC material, will be applicable to very much promoting the use.
Summary of the invention
The object of the invention is to address the deficiencies of the prior art, there is provided a kind of for wooden building materials not containing VOC, deodorizing ultraviolet-curing paint, the present invention possesses except while VOC, deodorizing, also has higher salt fog resistance, ageing resistance, sticking power, cold-and-heat resistent impact capacity.
For realizing the object of the invention, the technical solution used in the present invention is as follows:
For wooden building materials not containing VOC, a deodorizing ultraviolet-curing paint, it is characterized in that: be prepared from by the raw material of following mass percent: aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture: 40% ~ 60%; Ethyl cellulose: 3% ~ 5%; Initiator: 5% ~ 12%; Surface modifier: 1% ~ 3%; Solubility promoter: 5% ~ 10%; Nano silver antimicrobials: 1% ~ 2%; Ethanol: 10 ~ 30%.
Further, described a kind of not being prepared from by the raw material of following mass percent containing VOC, deodorizing ultraviolet-curing paint for wooden building materials: aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture: 55%; Ethyl cellulose: 5%; Initiator: 8%; Surface modifier: 1.5%; Solubility promoter: 9%; Nano silver antimicrobials: 1.5%; Ethanol: 20%.
Further, described a kind of preparation method not containing VOC, deodorizing ultraviolet-curing paint for wooden building materials, comprises the following steps:
(1) aliphatic polyurethane six acrylate is mixed with initiator with pure acrylate pre-polymer mixture, mix placement 1 ~ 2 hour;
(2) by the mixing of materials that ethyl cellulose, surface modifier, solubility promoter and (1) step obtain, be warming up to 50 ~ 70 DEG C, stir 25 ~ 30 minutes under 1000 ~ 1200 revs/min, cool to less than 40 DEG C and add nano silver antimicrobials and ethanol again, to obtain final product.
Further, described aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture, both mass ratioes are 1:3 ~ 5.
Further, described initiator is benzophenone, 1-hydroxycyclohexyl phenyl ketone or said mixture.
Further, described surface modifier is silicone based, organic fluorine class or said mixture.
Further, described solubility promoter is alcohol ether solvents.
The invention provides a kind of for wooden building materials not containing VOC, deodorizing ultraviolet-curing paint, beneficial effect is as follows:
The present invention a kind of for wooden building materials not only can not meet that coating has completely containing VOC, deodorizing ultraviolet-curing paint beautify and defencive function, and the present invention is not containing VOC material, more environment protection health, is conducive to people and uses.The present invention also has splendid scratch resistance, weathering characteristics, protects wooden building materials not by the environmental influence that physical influence and the various weather of external sharp instrument or friction cause.
The present invention adopts ethyl cellulose and nano silver antimicrobials, when when indoor use, and damping further, deodorizing, and possess antibacterial ability.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1:
Described a kind of not being prepared from by the raw material of following mass percent containing VOC, deodorizing ultraviolet-curing paint for wooden building materials:
Aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture: 55%; Ethyl cellulose: 5%; Benzophenone: 8%; Organic fluorine class: 1.5%; Glycol ether: 9%; Nano silver antimicrobials: 1.5%; Ethanol: 20%.
Wherein, aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture mass ratio are 1:3.
Embodiment 2:
Described a kind of not being prepared from by the raw material of following mass percent containing VOC, deodorizing ultraviolet-curing paint for wooden building materials:
Aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture: 58%; Ethyl cellulose: 4%; 1-hydroxycyclohexyl phenyl ketone: 12%; Silicone based: 2%; Glycol ether: 9%; Nano silver antimicrobials: 1%; Ethanol: 14%.
Wherein, aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture mass ratio are 1:4.
Embodiment 3:
Described a kind of not being prepared from by the raw material of following mass percent containing VOC, deodorizing ultraviolet-curing paint for wooden building materials:
Aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture: 50%; Ethyl cellulose: 3%; Benzophenone, 1-hydroxycyclohexyl phenyl ketone mixture: 12%; Silicone based, organic fluorine class mixture: 3%; Glycol ether: 10%; Nano silver antimicrobials: 2%; Ethanol: 20%.
Wherein, aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture mass ratio are 1:5; Benzophenone, 1-hydroxycyclohexyl phenyl ketone mixture quality are than being 2.2:1.

Claims (7)

1. for wooden building materials not containing VOC, a deodorizing ultraviolet-curing paint, it is characterized in that: be prepared from by the raw material of following mass percent: aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture: 40% ~ 60%; Ethyl cellulose: 3% ~ 5%; Initiator: 5% ~ 12%; Surface modifier: 1% ~ 3%; Solubility promoter: 5% ~ 10%; Nano silver antimicrobials: 1% ~ 2%; Ethanol: 10 ~ 30%.
2. according to claim 1 a kind of for wooden building materials not containing VOC, deodorizing ultraviolet-curing paint, it is characterized in that: described a kind of not being prepared from by the raw material of following mass percent containing VOC, deodorizing ultraviolet-curing paint for wooden building materials: aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture: 55%; Ethyl cellulose: 5%; Initiator: 8%; Surface modifier: 1.5%; Solubility promoter: 9%; Nano silver antimicrobials: 1.5%; Ethanol: 20%.
3. according to claim 1 and 2 a kind of for wooden building materials not containing VOC, deodorizing ultraviolet-curing paint, it is characterized in that: described a kind of for wooden building materials not containing the preparation method of VOC, deodorizing ultraviolet-curing paint, comprise the following steps:
(1) aliphatic polyurethane six acrylate is mixed with initiator with pure acrylate pre-polymer mixture, mix placement 1 ~ 2 hour;
(2) by the mixing of materials that ethyl cellulose, surface modifier, solubility promoter and (1) step obtain, be warming up to 50 ~ 70 DEG C, stir 25 ~ 30 minutes under 1000 ~ 1200 revs/min, cool to less than 40 DEG C and add nano silver antimicrobials and ethanol again, to obtain final product.
4. according to claim 1 and 2 a kind of for wooden building materials not containing VOC, deodorizing ultraviolet-curing paint, it is characterized in that: described aliphatic polyurethane six acrylate and pure acrylate pre-polymer mixture, both mass ratioes are 1:3 ~ 5.
5. according to claim 1 and 2 a kind of for wooden building materials not containing VOC, deodorizing ultraviolet-curing paint, it is characterized in that: described initiator is benzophenone, 1-hydroxycyclohexyl phenyl ketone or said mixture.
6. according to claim 1 and 2 a kind of for wooden building materials not containing VOC, deodorizing ultraviolet-curing paint, it is characterized in that: described surface modifier is silicone based, organic fluorine class or said mixture.
7. according to claim 1 and 2 a kind of for wooden building materials not containing VOC, deodorizing ultraviolet-curing paint, it is characterized in that: described solubility promoter is alcohol ether solvents.
CN201410584810.6A 2014-10-28 2014-10-28 VOC-free deodorization ultraviolet-curing coating for wood building material Pending CN104293168A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410584810.6A CN104293168A (en) 2014-10-28 2014-10-28 VOC-free deodorization ultraviolet-curing coating for wood building material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410584810.6A CN104293168A (en) 2014-10-28 2014-10-28 VOC-free deodorization ultraviolet-curing coating for wood building material

Publications (1)

Publication Number Publication Date
CN104293168A true CN104293168A (en) 2015-01-21

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106085202A (en) * 2016-08-29 2016-11-09 佛山市高明区尚润盈科技有限公司 A kind of photochromic photocureable coating and preparation method thereof
CN106221555A (en) * 2016-08-29 2016-12-14 佛山市高明区尚润盈科技有限公司 A kind of antibiotic radiation proof photocureable coating and preparation method thereof
CN106221556A (en) * 2016-08-29 2016-12-14 佛山市高明区尚润盈科技有限公司 A kind of deodorization ultraviolet-curing paint and preparation method thereof
CN106349921A (en) * 2016-08-29 2017-01-25 佛山市高明区尚润盈科技有限公司 Antibacterial and deodorizing ultraviolet curing coating and preparing method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1927971A (en) * 2006-09-18 2007-03-14 深圳清华大学研究院 Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof
CN101210144A (en) * 2006-12-30 2008-07-02 比亚迪股份有限公司 Ultraviolet light solidifying matt coating and preparation method thereof
CN101654570A (en) * 2009-09-24 2010-02-24 中国海洋石油总公司 Water-based ultraviolet curing coating
CN102234480A (en) * 2010-04-20 2011-11-09 东莞市佩琦涂料有限公司 Ultraviolet light solidified antibiosis paint
JP2012229331A (en) * 2011-04-26 2012-11-22 Mitsubishi Rayon Co Ltd Active energy ray-curable composition and molding having curing film

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1927971A (en) * 2006-09-18 2007-03-14 深圳清华大学研究院 Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof
CN101210144A (en) * 2006-12-30 2008-07-02 比亚迪股份有限公司 Ultraviolet light solidifying matt coating and preparation method thereof
CN101654570A (en) * 2009-09-24 2010-02-24 中国海洋石油总公司 Water-based ultraviolet curing coating
CN102234480A (en) * 2010-04-20 2011-11-09 东莞市佩琦涂料有限公司 Ultraviolet light solidified antibiosis paint
JP2012229331A (en) * 2011-04-26 2012-11-22 Mitsubishi Rayon Co Ltd Active energy ray-curable composition and molding having curing film

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周诗彪等: "多官能度光固化聚氨酯丙烯酸酯", 《高分子研究与应用》, 30 November 2012 (2012-11-30), pages 158 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106085202A (en) * 2016-08-29 2016-11-09 佛山市高明区尚润盈科技有限公司 A kind of photochromic photocureable coating and preparation method thereof
CN106221555A (en) * 2016-08-29 2016-12-14 佛山市高明区尚润盈科技有限公司 A kind of antibiotic radiation proof photocureable coating and preparation method thereof
CN106221556A (en) * 2016-08-29 2016-12-14 佛山市高明区尚润盈科技有限公司 A kind of deodorization ultraviolet-curing paint and preparation method thereof
CN106349921A (en) * 2016-08-29 2017-01-25 佛山市高明区尚润盈科技有限公司 Antibacterial and deodorizing ultraviolet curing coating and preparing method thereof

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Application publication date: 20150121