CN104530962A - Waterborne UV wood paint coating and preparation method thereof - Google Patents
Waterborne UV wood paint coating and preparation method thereof Download PDFInfo
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- CN104530962A CN104530962A CN201410789849.1A CN201410789849A CN104530962A CN 104530962 A CN104530962 A CN 104530962A CN 201410789849 A CN201410789849 A CN 201410789849A CN 104530962 A CN104530962 A CN 104530962A
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- waterborne
- paint coating
- wood paint
- defoamer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention provides a waterborne UV wood paint coating and a preparation method thereof. The waterborne UV wood paint coating is mainly prepared from the following components in parts by weight: 30-60 parts of waterborne polyurethane acrylates resin, 30-50 parts of methacrylate-butyl acrylate copolymer, 1-2 parts of a photoinitiator, 0.3 part of a flatting agent, 0.5 part of a defoamer, 0.2 part of a dispersant, 10 parts of a cosolvent and 100-150 parts of deionized water. The waterborne UV wood paint coating is clear and transparent in appearance, distinct in film formation, high in solid content, good in fullness, high in film formation speed, good in paint film rigidity, good in wear resistance, good in adhesion and good in solvent resistance. In addition, the preparation method of the waterborne UV wood paint coating is simple to operate and is stable and controllable.
Description
Technical field
The present invention relates to technical field of coatings, especially relate to a kind of waterborne UV wood paint coating and preparation method thereof.
Background technology
In recent years, the UV coating (polyurethane ultraviolet curing coating) of environment-friendly high-efficiency is widely used at industry-by-industry, there is greatly the gesture replacing traditional PE, PU, NC, due to UV coating has can the feature such as actualizing technology approach many, wide application, safety, construction be relatively simple, very fast in developed country's development such as America and Europes in recent years, be popular.
Along with the enhancing of mankind's environmental consciousness, environmental regulation has been formulated in the discharge of various countries to VOC (volatile organic compounds) in succession, and it is increasingly strict to limit emission standard, is intended to the product innovation encouraging to promote the use of environmental protection, energy-saving and emission-reduction.Particularly this several years air PM2.5 concentration are more and more higher, environment is increasingly severe, government also increases and punishes control dynamics in environmental improvement, some areas enterprise VOC that kept under strict control discharges, therefore, in paint spraying field, the grade development and application of Environmentally friendly coatings of safety and the water-based of low VOC, powder and high solid is imperative.
The woodwork such as furniture, door and window curved surface is more, and major part needs spraying application just can complete coating process, and traditional oiliness UV paint exists many disadvantages, therefore will replace PE, PU, NC paint and then must overcome these difficult problems.
Summary of the invention
The technical problem to be solved in the present invention is, for the defect of prior art, provide a kind of waterborne UV wood paint coating and preparation method thereof, its film forming sharpness is high and solid containing high, fullness ratio is good, film forming speed is fast, and hardness of paint film, wear resistance, adhesive power and solvent resistance are good.
In order to solve the problems of the technologies described above, the invention provides a kind of waterborne UV wood paint coating, it is formulated by weight primarily of following composition:
Watersoluble polyurethane acrylic acid fat resin 30-60 part, methyl-acrylate-butyl acetate copolymer 30-50 part, light trigger 1-2 part, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, solubility promoter 10 parts, deionized water 100-150 part.
Further, in above-mentioned waterborne UV wood paint coating, described waterborne UV wood paint coating is preferably formulated by weight by following composition:
Watersoluble polyurethane acrylic acid fat resin 40-50 part, methyl-acrylate-butyl acetate copolymer 30-50 part, light trigger 1-2 part, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, stopping composition 10-20 part, solubility promoter 10 parts, deionized water 100-150 part.
Further, in above-mentioned waterborne UV wood paint coating, described waterborne UV wood paint coating is preferably formulated by weight by following composition:
Watersoluble polyurethane acrylic acid fat resin 40-60 part, methyl-acrylate-butyl acetate copolymer 30-50 part, light trigger 1-2 part, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, sub-powder and stopping composition 10-20 part, solubility promoter 10 parts, deionized water 100-150 part.
Further, in above-mentioned waterborne UV wood paint coating, described waterborne UV wood paint coating is preferably formulated by weight by following composition:
Watersoluble polyurethane acrylic acid fat resin 40-60 part, methyl-acrylate-butyl acetate copolymer 30-50 part, light trigger 1-2 part, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, solubility promoter 10 parts, deionized water 100-150 part.
Further, in above-mentioned waterborne UV wood paint coating, described light trigger is 2-hydroxy-2-methyl-1-phenyl-1-acetone.
Further, in above-mentioned waterborne UV wood paint coating, described flow agent is polyether silicones oxygen alkane, and described defoamer is modified organic silicon polyester, and described dispersion agent is polymer copolymerization body, and described stopping composition is talcum powder, transparent powder and zinc powder.
Separately, the present invention also provides a kind of preparation method of above-mentioned waterborne UV wood paint coating, said method comprising the steps of:
Step a: take raw material by the weight of above-mentioned each composition;
Step b: described watersoluble polyurethane acrylic acid fat resin is carried out mixing obtained mixture with methyl-acrylate-butyl acetate copolymer;
Step c: add light trigger, flow agent, dispersion agent, defoamer in mixture obtained above after, stirs 20 ~ 30 minutes;
Steps d: slowly added above-mentioned deionized water and solubility promoter in introversive above-mentioned stirring liquid in 1 ~ 3 minute, leaves standstill and is dispersed into stable emulsion, namely obtain described waterborne UV wood paint coating.
Further, in the preparation method of above-mentioned waterborne UV wood paint coating, described step c specifically comprises: add light trigger, flow agent, dispersion agent, defoamer and stopping composition in mixture obtained above after, stirs 20 ~ 30 minutes.
Further, in the preparation method of above-mentioned waterborne UV wood paint coating, described step c specifically comprises: add light trigger, flow agent, dispersion agent, defoamer, sub-powder and stopping composition in mixture obtained above after, stirs 20 ~ 30 minutes.
Further, in the preparation method of above-mentioned waterborne UV wood paint coating, the pureness specifications of described solubility promoter is analytical pure.
Further, in the preparation method of above-mentioned waterborne UV wood paint coating, described flow agent is polyether silicones oxygen alkane, and described defoamer is modified organic silicon polyester, and described dispersion agent is polymer copolymerization body, and described stopping composition is talcum powder, transparent powder and zinc powder.
The clear appearance of waterborne UV wood paint coating of the present invention is transparent, and film forming sharpness is high and solid containing high, and fullness ratio is good, film forming speed is fast, hardness of paint film, wear resistance, adhesive power and solvent resistance are good, and the preparation method of waterborne UV wood paint coating of the present invention is simple to operate, stablizes controlled.
Embodiment
Below in conjunction with specific embodiment, waterborne UV wood paint coating of the present invention and preparation method thereof is described.
Embodiment 1:
The present embodiment is water-based UV woodenware primer base, it is by formulated by weight by following composition: watersoluble polyurethane acrylic acid fat resin 30 parts, methyl-acrylate-butyl acetate copolymer 40 parts, light trigger 2 parts, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, stopping composition 15 parts, solubility promoter 10 parts, deionized water 100 parts, and the pureness specifications of described solubility promoter is analytical pure.
When preparing above-mentioned water-based UV woodenware primer base, first, raw material is taken by the weight of above-mentioned each composition; Again described watersoluble polyurethane acrylic acid fat resin is carried out mixing obtained mixture with methyl-acrylate-butyl acetate copolymer; Then, add light trigger, flow agent, dispersion agent, defoamer and stopping composition in mixture obtained above after, stir 20 ~ 30 minutes; Finally, slowly added above-mentioned deionized water and solubility promoter in 1 ~ 3 minute in introversive above-mentioned stirring liquid, leave standstill and be dispersed into stable emulsion, namely obtain described water-based UV woodenware primer base.
Embodiment 2:
The present embodiment is water-based UV woodenware matte topcoat paint, it is by formulated by weight by following composition: watersoluble polyurethane acrylic acid fat resin 40 parts, methyl-acrylate-butyl acetate copolymer 50 parts, light trigger 1.5 parts, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, sub-powder and stopping composition 20 parts, solubility promoter 10 parts, deionized water 150 parts, and the pureness specifications of described solubility promoter is analytical pure.
When preparing above-mentioned water-based UV woodenware primer base, first, raw material is taken by the weight of above-mentioned each composition; Again described watersoluble polyurethane acrylic acid fat resin is carried out mixing obtained mixture with methyl-acrylate-butyl acetate copolymer; Then, add light trigger, flow agent, dispersion agent, defoamer, sub-powder and stopping composition in mixture obtained above after, stir 20 ~ 30 minutes; Finally, slowly added above-mentioned deionized water and solubility promoter in 1 ~ 3 minute in introversive above-mentioned stirring liquid, leave standstill and be dispersed into stable emulsion, namely obtain described water-based UV woodenware matte topcoat paint.
Embodiment 3:
The present embodiment is water-based UV woodware high-gloss topcoat paint, it is by formulated by weight by following composition: watersoluble polyurethane acrylic acid fat resin 60 parts, methyl-acrylate-butyl acetate copolymer 30 parts, light trigger 1 part, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, solubility promoter 10 parts, deionized water 120 parts, and the pureness specifications of described solubility promoter is analytical pure.
When preparing above-mentioned water-based UV woodenware primer base, first, raw material is taken by the weight of above-mentioned each composition; Again described watersoluble polyurethane acrylic acid fat resin is carried out mixing obtained mixture with methyl-acrylate-butyl acetate copolymer; Then, add light trigger, flow agent, dispersion agent and defoamer in mixture obtained above after, stir 20 ~ 30 minutes; Finally, slowly added above-mentioned deionized water and solubility promoter in 1 ~ 3 minute in introversive above-mentioned stirring liquid, leave standstill and be dispersed into stable emulsion, namely obtain described water-based UV woodware high-gloss topcoat paint.
Waterborne UV wood paint coating of the present invention is water-soluble transparent glue, can be used for the woodworks such as timber, furniture, cabinet, stair, toy being covered with paint, lacquer, colour wash, etc. and protection.
The performance test results of embodiments of the invention 1, embodiment 2 and embodiment 3 is as following table:
As seen from the above table, the dry film performance of waterborne UV wood paint coating of the present invention is good, and curing speed is fast, and dope viscosity is low, admittedly containing moderate and can arbitrarily adjust, have good workability, can spray, roller coat, brushing.Sticking power is good, low smell, and skin irritation is low, and voc discharge meets national minimum standard, can replace the coating such as the conventional P U of current market and NC completely.
Compared to existing UV coating, waterborne UV wood paint coating of the present invention and preparation method thereof tool has the following advantages:
(1) cracking that the cure shrinkage that minimizing causes because using reactive thinner in a large number causes, distortion;
(2) good application property: the diluent water of available cheapness or thickening material control flow check sex change easily, makes coating may be used for various application mode, as roller coat. showering. and spraying etc.;
(3) viscosity need not be regulated for highly purified reactive thinner, decrease the problem such as toxicity and pungency;
(4) not containing volatilization organic solvent, do not fire not quick-fried, accumulating, produce all safer;
(5) easily film thickness can be controlled;
(6) equipment and container are easy to cleaning.
Compared to existing water-borne coatings, waterborne UV wood paint coating of the present invention and preparation method's tool have the following advantages:
1, solid containing high, can the fullness ratio such as conventional oil-based PU, PE be reached completely;
2, curing speed is fast: traditional water-miscible paint will reach to do solid work needs 12-48 hour, and water-based UV of the present invention paints to do from sudden strain of a muscle and does solid work also with regard to 1-2 hour.
3, paint film property is good: adopt UV crosslinking curing, quality of forming film is good.
To sum up, the clear appearance of waterborne UV wood paint coating of the present invention is transparent, film forming sharpness is high and solid containing high, fullness ratio is good, and in addition, waterborne UV wood paint coating of the present invention adopts UV curing mode, its film forming speed is fast, the all far super aqueous self-drying of hardness of paint film, wear resistance, adhesive power and solvent resistance and aqueous bi-component coating, the preparation method of another waterborne UV wood paint coating of the present invention is simple to operate, stablizes controlled.
The above embodiment only have expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (10)
1. a waterborne UV wood paint coating, is characterized in that, it is formulated by weight primarily of following composition:
Watersoluble polyurethane acrylic acid fat resin 30-60 part, methyl-acrylate-butyl acetate copolymer 30-50 part, light trigger 1-2 part, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, solubility promoter 10 parts, deionized water 100-150 part.
2. waterborne UV wood paint coating according to claim 1, is characterized in that, described waterborne UV wood paint coating is preferably formulated by weight by following composition:
Watersoluble polyurethane acrylic acid fat resin 40-50 part, methyl-acrylate-butyl acetate copolymer 30-50 part, light trigger 1-2 part, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, stopping composition 10-20 part, solubility promoter 10 parts, deionized water 100-150 part.
3. waterborne UV wood paint coating according to claim 1, is characterized in that, described waterborne UV wood paint coating is preferably formulated by weight by following composition:
Watersoluble polyurethane acrylic acid fat resin 40-60 part, methyl-acrylate-butyl acetate copolymer 30-50 part, light trigger 1-2 part, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, sub-powder and stopping composition 10-20 part, solubility promoter 10 parts, deionized water 100-150 part.
4. waterborne UV wood paint coating according to claim 1, is characterized in that, described waterborne UV wood paint coating is preferably formulated by weight by following composition:
Watersoluble polyurethane acrylic acid fat resin 40-60 part, methyl-acrylate-butyl acetate copolymer 30-50 part, light trigger 1-2 part, flow agent 0.3 part, defoamer 0.5 part, dispersion agent 0.2 part, solubility promoter 10 parts, deionized water 100-150 part.
5. the waterborne UV wood paint coating according to any one of Claims 1 to 4, is characterized in that, described light trigger is 2-hydroxy-2-methyl-1-phenyl-1-acetone.
6. the waterborne UV wood paint coating according to any one of Claims 1 to 4, it is characterized in that, described flow agent is polyether silicones oxygen alkane, and described defoamer is modified organic silicon polyester, described dispersion agent is polymer copolymerization body, and described stopping composition is talcum powder, transparent powder and zinc powder.
7. a preparation method for the waterborne UV wood paint coating as described in any one of claim 1 ~ 6, is characterized in that, said method comprising the steps of:
Step a: take raw material by the weight of above-mentioned each composition;
Step b: described watersoluble polyurethane acrylic acid fat resin is carried out mixing obtained mixture with methyl-acrylate-butyl acetate copolymer;
Step c: add light trigger, flow agent, dispersion agent, defoamer in mixture obtained above after, stirs 20 ~ 30 minutes;
Steps d: slowly added above-mentioned deionized water and solubility promoter in introversive above-mentioned stirring liquid in 1 ~ 3 minute, leaves standstill and is dispersed into stable emulsion, namely obtain described waterborne UV wood paint coating.
8. the preparation method of waterborne UV wood paint coating according to claim 7, it is characterized in that, described step c specifically comprises: add light trigger, flow agent, dispersion agent, defoamer and stopping composition in mixture obtained above after, stirs 20 ~ 30 minutes.
9. the preparation method of waterborne UV wood paint coating according to claim 7, it is characterized in that, described step c specifically comprises: add light trigger, flow agent, dispersion agent, defoamer, sub-powder and stopping composition in mixture obtained above after, stirs 20 ~ 30 minutes.
10. the preparation method of the waterborne UV wood paint coating according to any one of claim 7 ~ 9, is characterized in that, the pureness specifications of described solubility promoter is analytical pure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410789849.1A CN104530962A (en) | 2014-12-17 | 2014-12-17 | Waterborne UV wood paint coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410789849.1A CN104530962A (en) | 2014-12-17 | 2014-12-17 | Waterborne UV wood paint coating and preparation method thereof |
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| CN104530962A true CN104530962A (en) | 2015-04-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410789849.1A Pending CN104530962A (en) | 2014-12-17 | 2014-12-17 | Waterborne UV wood paint coating and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104946120A (en) * | 2015-06-29 | 2015-09-30 | 周建志 | Water-based wood paint and preparation method thereof |
| CN105368296A (en) * | 2015-11-05 | 2016-03-02 | 广西南宁桂变电气有限公司 | Woodenware furniture wear-resistant type coating for indoor decoration |
| CN106752541A (en) * | 2017-01-17 | 2017-05-31 | 中山市鑫峰光固化材料有限公司 | A kind of aqueous polyurethane ultraviolet-curing paint and preparation method thereof |
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| CN101481451A (en) * | 2009-01-23 | 2009-07-15 | 华南理工大学 | High solid content latent curing polyurethane acroleic acid hybrid emulsion |
| CN102206461A (en) * | 2010-03-31 | 2011-10-05 | 东莞市佩琦涂料有限公司 | Waterborne UV coating |
| CN102977739A (en) * | 2012-11-29 | 2013-03-20 | 广东汇龙涂料有限公司 | Ultraviolet (UV) curing electrostatic spraying transparent primer wood coating and construction method |
| CN103319666A (en) * | 2013-06-18 | 2013-09-25 | 华南理工大学 | Hyperbranched modified hydroxy acrylic resin aqueous dispersion, and preparation method and application thereof |
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2014
- 2014-12-17 CN CN201410789849.1A patent/CN104530962A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481451A (en) * | 2009-01-23 | 2009-07-15 | 华南理工大学 | High solid content latent curing polyurethane acroleic acid hybrid emulsion |
| CN102206461A (en) * | 2010-03-31 | 2011-10-05 | 东莞市佩琦涂料有限公司 | Waterborne UV coating |
| CN102977739A (en) * | 2012-11-29 | 2013-03-20 | 广东汇龙涂料有限公司 | Ultraviolet (UV) curing electrostatic spraying transparent primer wood coating and construction method |
| CN103319666A (en) * | 2013-06-18 | 2013-09-25 | 华南理工大学 | Hyperbranched modified hydroxy acrylic resin aqueous dispersion, and preparation method and application thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104946120A (en) * | 2015-06-29 | 2015-09-30 | 周建志 | Water-based wood paint and preparation method thereof |
| CN105368296A (en) * | 2015-11-05 | 2016-03-02 | 广西南宁桂变电气有限公司 | Woodenware furniture wear-resistant type coating for indoor decoration |
| CN106752541A (en) * | 2017-01-17 | 2017-05-31 | 中山市鑫峰光固化材料有限公司 | A kind of aqueous polyurethane ultraviolet-curing paint and preparation method thereof |
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Application publication date: 20150422 |