CN104277518A - High-leveling abrasion-resistant ultraviolet-curable coating material for solid wood floors - Google Patents

High-leveling abrasion-resistant ultraviolet-curable coating material for solid wood floors Download PDF

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Publication number
CN104277518A
CN104277518A CN201410585520.3A CN201410585520A CN104277518A CN 104277518 A CN104277518 A CN 104277518A CN 201410585520 A CN201410585520 A CN 201410585520A CN 104277518 A CN104277518 A CN 104277518A
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CN
China
Prior art keywords
leveling
abrasion
resistant ultraviolet
floor board
wooden floor
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410585520.3A
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Chinese (zh)
Inventor
习小山
王军
黄波
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Chengdu Nashuo Technology Co Ltd
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Chengdu Nashuo Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Chengdu Nashuo Technology Co Ltd filed Critical Chengdu Nashuo Technology Co Ltd
Priority to CN201410585520.3A priority Critical patent/CN104277518A/en
Publication of CN104277518A publication Critical patent/CN104277518A/en
Pending legal-status Critical Current

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Abstract

The invention relates to the field of coating materials, and particularly relates to a high-leveling abrasion-resistant ultraviolet-curable coating material for solid wood floors. The high-leveling abrasion-resistant ultraviolet-curable coating material for solid wood floors is prepared from the following raw materials in percentage by mass: 30-45% of an aliphatic polyurethaneacrylate and difunctional polyurethaneacrylate oligomer mixture, 3-5% of ethyl cellulose, 3-5% of propylene glycol methyl ether acetate, 5-12% parts of an initiator, 1-3% of a surface additive, 5-10% of a cosolvent, 10-20% of a reactive diluent, 1-2% of nano-Ag Antimicrobial, and 10-30% of ethanol. The coating material disclosed by the invention also has excellent leveling property, friction resistance, scratch resistance. The other physical properties of the coating material disclosed by the invention are not affected, and the coating material even further has high aging resistance, adhesion, and cold and heat shock resistance, and can restrain dozens of types of bacteria such as various corrosive fungi and the like well.

Description

A kind of high-leveling for solid wooden floor board, abrasion-resistant ultraviolet-curing paint
Technical field
The present invention relates to paint field, particularly relate to a kind of high-leveling for solid wooden floor board, abrasion-resistant ultraviolet-curing paint.
Background technology
Ultraviolet-curing paint is since appearance, because it has the feature of 5E, i.e. efficient (Efficient), applicable wide (Enabling), economic (Economical), energy-conservation (Energy Saying), environmental friendliness (Environmental-friendly).In the prior art, ultraviolet-curing paint is widely used in and closely bound up field of living by people, to play the effect beautifying object and protection object.
Coating can not be corroded by available protecting wood floors, thus extends the work-ing life of wood floors, and wood floors seem more attractive in appearance under the covering with paint of coating in addition.But existing general wood floors coating effect is not good, levelling property, scratch resistance, scratch-resistant performance are general, have had influence on to coat process and result of use, and work-ing life also receives great impact.
Summary of the invention
The object of the invention is to address the deficiencies of the prior art, a kind of high-leveling for solid wooden floor board, abrasion-resistant ultraviolet-curing paint are provided, while the present invention possesses high-leveling, high abrasion wiping, high scratch resistance energy, also there is higher ageing resistance, sticking power, cold-and-heat resistent impact capacity.
For realizing the object of the invention, the technical solution used in the present invention is as follows:
For high-leveling, the abrasion-resistant ultraviolet-curing paint of solid wooden floor board, it is characterized in that: be prepared from by the raw material of following mass percent: aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixtures: 30% ~ 45%; Ethyl cellulose: 3% ~ 5%; 1-Methoxy-2-propyl acetate: 3% ~ 5%; Initiator: 5% ~ 12%; Surface modifier: 1% ~ 3%; Solubility promoter: 5% ~ 10%; Reactive thinner: 10% ~ 20%; Nano silver antimicrobials: 1% ~ 2%; Ethanol: 10% ~ 30%.
Further, described a kind of high-leveling for solid wooden floor board, abrasion-resistant ultraviolet-curing paint are prepared from by the raw material of following mass percent: aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixtures: 35%; Ethyl cellulose: 5%; 1-Methoxy-2-propyl acetate: 5%; Initiator: 8%; Surface modifier: 1.5%; Solubility promoter: 7.5%; Reactive thinner: 16.5%; Nano silver antimicrobials: 1.5%; Ethanol: 20%.
Further, described aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixtures, both mass ratioes are 1:2 ~ 3.
Further, described reactive thinner is hydroxy methacrylate and diacrylate ester mixture, and both mass ratioes are 1.5 ~ 2.5:1.
Further, described initiator is benzophenone, 1-hydroxycyclohexyl phenyl ketone or said mixture.
Further, described surface modifier is silicone based, organic fluorine class or said mixture.
Further, described solubility promoter is alcohol ether solvents.
The invention provides a kind of high-leveling for solid wooden floor board, abrasion-resistant ultraviolet-curing paint, beneficial effect is as follows:
What a kind of high-leveling for solid wooden floor board of the present invention, abrasion-resistant ultraviolet-curing paint not only can meet that coating has completely beautifies and defencive function; the present invention also has splendid levelling property, abrasion-resistant, scratch resistance performance; eliminate rapidly painting trace when coating uses, and protect wood floors not to be subject to the physical influence of external sharp instrument or friction.And other physical propertiess of the present invention are unaffected, there is higher ageing resistance, sticking power, cold-and-heat resistent impact capacity even further, can also well suppress tens kinds of bacteriums such as various corrodibility fungies.
Aliphatic polyurethane six acrylate that the present invention adopts and two functional group's urethane acrylate oligomer mixtures, there is the advantage that cost is low, hardness is high, chemical-resistant is good, surface cure performance is good, to the anti-microbial property of nano silver antimicrobials, there is good synergy again.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1:
Described a kind of high-leveling for solid wooden floor board, abrasion-resistant ultraviolet-curing paint are prepared from by the raw material of following mass percent:
Aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixtures: 36%; Ethyl cellulose: 5%; 1-Methoxy-2-propyl acetate: 4%; Benzophenone: 8%; Organic fluorine class: 1.5%; Glycol ether: 7.5%; Hydroxy methacrylate, diacrylate ester mixture: 16.5%; Nano silver antimicrobials: 1.5%; Ethanol: 20%.
Wherein, aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixture qualities are than being 1:2; Hydroxy methacrylate, diacrylate mixture quality are than being 2:1.
Embodiment 2:
Described a kind of high-leveling for solid wooden floor board, abrasion-resistant ultraviolet-curing paint are prepared from by the raw material of following mass percent:
Aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixtures: 40%; Ethyl cellulose: 4%; 1-Methoxy-2-propyl acetate: 3%; 1-hydroxycyclohexyl phenyl ketone: 12%; Silicone based: 2%; Glycol ether: 9%; Hydroxy methacrylate, diacrylate ester mixture: 15%; Nano silver antimicrobials: 1%; Ethanol: 14%.
Wherein, aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixture qualities are than being 1:2.5; Hydroxy methacrylate, diacrylate mixture quality are than being 2.5:1.
Embodiment 3:
Described a kind of high-leveling for solid wooden floor board, abrasion-resistant ultraviolet-curing paint are prepared from by the raw material of following mass percent:
Aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixtures: 38%; Ethyl cellulose: 3%; 1-Methoxy-2-propyl acetate: 5%; Benzophenone, 1-hydroxycyclohexyl phenyl ketone mixture: 12%; Silicone based, organic fluorine class mixture: 3%; Glycol ether: 10%; Hydroxy methacrylate, diacrylate ester mixture: 12%; Nano silver antimicrobials: 2%; Ethanol: 15%.
Wherein, aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixture qualities are than being 1:3; Benzophenone, 1-hydroxycyclohexyl phenyl ketone mixture quality are than being 2.2:1; Hydroxy methacrylate, diacrylate mixture quality are than being 1.8:1.

Claims (7)

1. for high-leveling, the abrasion-resistant ultraviolet-curing paint of solid wooden floor board, it is characterized in that: be prepared from by the raw material of following mass percent: aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixtures: 30% ~ 45%; Ethyl cellulose: 3% ~ 5%; Initiator: 5% ~ 12%; Surface modifier: 1% ~ 3%; Solubility promoter: 5% ~ 10%; Reactive thinner: 10% ~ 20%; Nano silver antimicrobials: 1% ~ 2%; Ethanol: 10% ~ 30%.
2. a kind of high-leveling for solid wooden floor board according to claim 1, abrasion-resistant ultraviolet-curing paint, is characterized in that: described a kind of high-leveling for solid wooden floor board, abrasion-resistant ultraviolet-curing paint are prepared from by the raw material of following mass percent: aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixtures: 40%; Ethyl cellulose: 5%; Initiator: 8%; Surface modifier: 1.5%; Solubility promoter: 7.5%; Reactive thinner: 16.5%; Nano silver antimicrobials: 1.5%; Ethanol: 20%.
3. a kind of high-leveling for solid wooden floor board according to claim 1 and 2, abrasion-resistant ultraviolet-curing paint, it is characterized in that: described aliphatic polyurethane six acrylate and two functional group's urethane acrylate oligomer mixtures, both mass ratioes are 1:2 ~ 3.
4. a kind of high-leveling for solid wooden floor board according to claim 1 and 2, abrasion-resistant ultraviolet-curing paint, is characterized in that: described reactive thinner is hydroxy methacrylate and diacrylate ester mixture, and both mass ratioes are 1.5 ~ 2.5:1.
5. a kind of high-leveling for solid wooden floor board according to claim 1 and 2, abrasion-resistant ultraviolet-curing paint, is characterized in that: described initiator is benzophenone, 1-hydroxycyclohexyl phenyl ketone or said mixture.
6. a kind of high-leveling for solid wooden floor board according to claim 1 and 2, abrasion-resistant ultraviolet-curing paint, is characterized in that: described surface modifier is silicone based, organic fluorine class or said mixture.
7. a kind of high-leveling for solid wooden floor board according to claim 1 and 2, abrasion-resistant ultraviolet-curing paint, is characterized in that: described solubility promoter is alcohol ether solvents.
CN201410585520.3A 2014-10-28 2014-10-28 High-leveling abrasion-resistant ultraviolet-curable coating material for solid wood floors Pending CN104277518A (en)

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CN201410585520.3A CN104277518A (en) 2014-10-28 2014-10-28 High-leveling abrasion-resistant ultraviolet-curable coating material for solid wood floors

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CN201410585520.3A CN104277518A (en) 2014-10-28 2014-10-28 High-leveling abrasion-resistant ultraviolet-curable coating material for solid wood floors

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109054676A (en) * 2018-08-02 2018-12-21 江苏双星彩塑新材料股份有限公司 A kind of antibacterial antiultraviolet fenestrated membrane
WO2020081253A1 (en) * 2018-10-15 2020-04-23 Metashield Llc Anti-fouling coatings

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002322432A (en) * 2001-02-26 2002-11-08 Daikin Ind Ltd Non-sticky abrasion-resistant coating composition and non-sticky abrasion-resistant coated article
CN1927971A (en) * 2006-09-18 2007-03-14 深圳清华大学研究院 Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof
CN102234479A (en) * 2010-04-20 2011-11-09 东莞市佩琦涂料有限公司 Ultraviolet-thermal curable coating
CN102850875A (en) * 2012-08-29 2013-01-02 郑州精益达汽车零部件有限公司 Automobile coating varnish, and preparation method and use method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002322432A (en) * 2001-02-26 2002-11-08 Daikin Ind Ltd Non-sticky abrasion-resistant coating composition and non-sticky abrasion-resistant coated article
CN1927971A (en) * 2006-09-18 2007-03-14 深圳清华大学研究院 Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof
CN102234479A (en) * 2010-04-20 2011-11-09 东莞市佩琦涂料有限公司 Ultraviolet-thermal curable coating
CN102850875A (en) * 2012-08-29 2013-01-02 郑州精益达汽车零部件有限公司 Automobile coating varnish, and preparation method and use method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109054676A (en) * 2018-08-02 2018-12-21 江苏双星彩塑新材料股份有限公司 A kind of antibacterial antiultraviolet fenestrated membrane
CN109054676B (en) * 2018-08-02 2022-07-22 江苏双星彩塑新材料股份有限公司 Bacteriostatic ultraviolet-proof window film
WO2020081253A1 (en) * 2018-10-15 2020-04-23 Metashield Llc Anti-fouling coatings
US11059990B2 (en) 2018-10-15 2021-07-13 Metashield Llc Anti-fouling coatings

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Application publication date: 20150114