CN102234480A - Ultraviolet light solidified antibiosis paint - Google Patents
Ultraviolet light solidified antibiosis paint Download PDFInfo
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- CN102234480A CN102234480A CN2010101563547A CN201010156354A CN102234480A CN 102234480 A CN102234480 A CN 102234480A CN 2010101563547 A CN2010101563547 A CN 2010101563547A CN 201010156354 A CN201010156354 A CN 201010156354A CN 102234480 A CN102234480 A CN 102234480A
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- aliphatic urethane
- curing antibiotic
- inert solvent
- curing
- urethane acrylates
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Abstract
The invention relates to the paint field, specifically to an ultraviolet light solidified antibiosis paint, which is made from the following raw materials of: by weight, 19-25% of aliphatic polyurethane acrylate, 5-12.5% of epoxy acrylate, 8-15% of an active diluent, 0.5-2% of a sliver-nanoparticles antimicrobial agent, 1.5-4% of a photoinitiator, 0.1-0.2% of a levelling agent and 47.85-65.9% of an inert solvent. The ultraviolet light solidified antibiosis paint provided by the invention has antibiosis capability and simultaneously has no impact on the performance index of the paint itself.
Description
Technical field
The present invention relates to paint field, be specifically related to a kind of coating that can antimicrobial relies on ultraviolet light polymerization.
Background technology
Ultraviolet-curing paint has the characteristics of 5E, i.e. Efficient (efficiently), Enabling (being suitable for wide), Economical (economy), Energy saying (energy-conservation), Environmental-friendly (environmental friendliness).In the prior art, the ultraviolet-curing paint closely bound up field that has been widely used in by people and lived, as be used in the shell of article such as mobile phone, computer, digital camera, toy for children, to play the effect that beautifies object and protection object.And these daily necessities are often contacted by people, if the coating on their surfaces does not have antibacterial ability, people are easy to be subjected to be bonded at the infection of the bacterium and the germ of coating surface so.For the infection of the bacterium and the germ that prevent to be bonded at coating surface, we need a kind of ultraviolet-curing paint with antibacterial.
Summary of the invention
The objective of the invention is to address the deficiencies of the prior art, a kind of UV curing antibiotic coating is provided, when the present invention has antibacterial ability, also can not influence resistance to soiling, salt fog resistance, ageing resistance, wear resistance, anti scuffing ability, sticking power, cold-and-heat resistent impact capacity that coating itself has.
The objective of the invention is to realize by following scheme:
A kind of UV curing antibiotic coating is characterized in that: described UV curing antibiotic coating is formed by the feedstock production of following mass percent:
Aliphatic urethane acrylate 19-25%
Epoxy acrylate 5-12.5%
Reactive thinner 8-15%
Nano silver antimicrobials 0.5-2%
Light trigger 1.5-4%
Flow agent 0.1-0.2%
Inert solvent 47.85-65.9%.
Described UV curing antibiotic coating is formed by the feedstock production of following mass percent:
Aliphatic urethane acrylate 19.55-19.8%
Epoxy acrylate 12.5%
Reactive thinner 15%
Nano silver antimicrobials 0.5-1%
Light trigger 2%
Flow agent 0.2%
Inert solvent 50%.
Described aliphatic urethane acrylate is made up of six sense aliphatic urethane acrylates and the two sense aliphatic urethane acrylates that contain 15%PGDA; Described reactive thinner is made up of Viscoat 295 and tripropylene glycol diacrylate; Described light trigger is made up of 1-hydroxyl-ring ethyl-phenyl ketone and 2.4.6 diphenyl phosphate oxidation.
Described six sense aliphatic urethane acrylates are 15 with the mass ratio that contains the two sense aliphatic urethane acrylates of 15%PGDA: 4.55-4.8; The mass ratio of described Viscoat 295 and tripropylene glycol diacrylate is 1: 1; The mass ratio of described 1-hydroxyl-ring ethyl-phenyl ketone and 2.4.6 diphenyl phosphate oxidation is 3: 1.
Described epoxy acrylate is an aliphatic epoxy acrylate.
Described flow agent is siliceous flow agent.
Described inert solvent is made up of diacetone alcohol, butyl ester and ethyl ester.
In described inert solvent, the mass ratio of diacetone alcohol, butyl ester and ethyl ester is 2: 5: 3.
The invention has the advantages that: UV curing antibiotic coating of the present invention not only can satisfy the function of beautifying object and protection object that coating has fully; can also the good restraining intestinal bacteria, tens kinds of bacteriums such as staphylococcus, make people really away from bacterium and germ.In addition, the present invention is when having antibacterial effect, and his all performance index are all unaffected, even has better resistance to soiling, salt fog resistance, ageing resistance, wear resistance, anti scuffing ability, sticking power and cold-and-heat resistent impact property.
The present invention selects two kinds of reactive thinners, i.e. Viscoat 295 and tripropylene glycol diacrylate for use.Viscoat 295 can provide reasonable hardness and curing speed to composition, and tripropylene glycol diacrylate has good flexibility, can reduce composition viscosity, well adhere to promoter action in addition, two kinds of reactive thinners are used the performance that the cost of both having controlled composition does not also influence integral formula.
The present invention selects two kinds of light triggers for use, be 1-hydroxyl-ring ethyl-phenyl ketone and 2.4.6 diphenyl phosphate oxidation, because the absorption peak of 1-hydroxyl-ring ethyl-phenyl ketone is at 325-330nm, wave band is shorter, in coating, play good light-initiated effect, and 2.4.6 diphenyl phosphate oxidation absorption peak is at 350-400nm, wave band is bigger, have good deep layer and solidify effect, the effect that has bleaching simultaneously, both are used in combination and make the present invention have good light-initiated effect and deep layer solidification effect simultaneously, make that curing is more complete.
The present invention selects two kinds of aliphatic urethane acrylates for use, i.e. six sense aliphatic urethane acrylates and contain the two sense aliphatic urethane acrylates of 15%PGDA, six sense aliphatic urethane acrylates have hardness height, chemical-resistant is good, surface cure is effective advantage, but its water tolerance is relatively poor, and the flexibility of two sense aliphatic urethane acrylates that contains 15%PGDA is good, water tolerance outstanding, both are used in combination and have both strengthened water tolerance, not only to the anti-microbial property of nano silver antimicrobials but also have good synergy.
Embodiment
The present invention will be further described below in conjunction with embodiment.
Embodiment 1: UV curing antibiotic coating is formed by the feedstock production of following mass percent:
Six sense aliphatic urethane acrylates 15%
The two sense aliphatic urethane acrylates 4% that contain 15%PGDA
Aliphatic epoxy acrylate 5%
Viscoat 295 4%
Tripropylene glycol diacrylate 4%
Nano silver antimicrobials 0.5%
1-hydroxyl-ring ethyl-phenyl ketone 1.125%
2.4.6 diphenyl phosphate oxidation 0.375%
Siliceous flow agent 0.1%
Inert solvent 65.9%.
Wherein, inert solvent is made up of diacetone alcohol, butyl ester and ethyl ester, and the mass ratio of diacetone alcohol, butyl ester and ethyl ester is 2: 5: 3.
Embodiment 2: UV curing antibiotic coating is formed by the feedstock production of following mass percent:
Six sense aliphatic urethane acrylates 15%
The two sense aliphatic urethane acrylates 10% that contain 15%PGDA
Aliphatic epoxy acrylate 9%
Viscoat 295 6%
Tripropylene glycol diacrylate 6%
Nano silver antimicrobials 2%
1-hydroxyl-ring ethyl-phenyl ketone 3%
2.4.6 diphenyl phosphate oxidation 1%
Siliceous flow agent 0.15%
Inert solvent 47.85%.
Wherein, inert solvent is made up of diacetone alcohol, butyl ester and ethyl ester, and the mass ratio of diacetone alcohol, butyl ester and ethyl ester is 2: 5: 3.
Embodiment 3: UV curing antibiotic coating is formed by the feedstock production of following mass percent:
Six sense aliphatic urethane acrylates 15%
The two sense aliphatic urethane acrylates 4.8% that contain 15%PGDA
Aliphatic epoxy acrylate 12.5%
Viscoat 295 7.5%
Tripropylene glycol diacrylate 7.5%
Nano silver antimicrobials 0.5%
1-hydroxyl-ring ethyl-phenyl ketone 1.5%
2.4.6 diphenyl phosphate oxidation 0.5%
Siliceous flow agent 0.2%
Inert solvent 50%.
Wherein, inert solvent is made up of diacetone alcohol, butyl ester and ethyl ester, and the mass ratio of diacetone alcohol, butyl ester and ethyl ester is 2: 5: 3.
Embodiment 4: UV curing antibiotic coating is formed by the feedstock production of following mass percent:
Six sense aliphatic urethane acrylates 15%
The two sense aliphatic urethane acrylates 4.3% that contain 15%PGDA
Aliphatic epoxy acrylate 12.5%
Viscoat 295 7.5%
Tripropylene glycol diacrylate 7.5%
Nano silver antimicrobials 1%
1-hydroxyl-ring ethyl-phenyl ketone 1.5%
2.4.6 diphenyl phosphate oxidation 0.5%
Siliceous flow agent 0.2%
Inert solvent 50%.
Wherein, inert solvent is made up of diacetone alcohol, butyl ester and ethyl ester, and the mass ratio of diacetone alcohol, butyl ester and ethyl ester is 2: 5: 3.
Embodiment 5: UV curing antibiotic coating is formed by the feedstock production of following mass percent:
Six sense aliphatic urethane acrylates 15%
The two sense aliphatic urethane acrylates 4.55% that contain 15%PGDA
Aliphatic epoxy acrylate 12.5%
Viscoat 295 7.5%
Tripropylene glycol diacrylate 7.5%
Nano silver antimicrobials 0.75%
1-hydroxyl-ring ethyl-phenyl ketone 1.5%
2.4.6 diphenyl phosphate oxidation 0.5%
Siliceous flow agent 0.2%
Inert solvent 50%.
Wherein, inert solvent is made up of diacetone alcohol, butyl ester and ethyl ester, and the mass ratio of diacetone alcohol, butyl ester and ethyl ester is 2: 5: 3.
Embodiment 6: preparation method and step that UV curing antibiotic coating of the present invention is concrete are as follows:
1, light trigger in the adding prescription and inert solvent stir and make it not have particulate state in container;
2, aliphatic urethane acrylate and reactive thinner stir in the interpolation prescription;
3, the epoxy acrylate that adds in the prescription stirs;
4, flow agent, nano silver antimicrobials stir in the interpolation prescription;
5, add remaining inert solvent in the prescription at last, filter then, pack.
Table 1 is the technical indicator behind the UV curing antibiotic coating film-forming that processes according to the method for embodiment 6 according to each components contents among the embodiment 1-5.
Table 1
Table 2 is the production company and the product code name of each raw material among the embodiment 1-5.
Table 2
The coating component | Business Name | The product code name |
Six sense aliphatic urethane acrylates | Changxing company | 6145-100 |
The two sense aliphatic urethane acrylates that contain 15%PGDA | UCB. S.A. (BE) Bruxelles Belgium | Ebceryl4883 |
Epoxy acrylate | UCB. S.A. (BE) Bruxelles Belgium | LR-8765 |
Viscoat 295 | Changxing company | TMPTA |
Tripropylene glycol diacrylate | Changxing company | HDDA |
Nano silver antimicrobials | The positive company in Shanghai, Shanghai | AG-WB3000 |
1-hydroxyl-ring ethyl-phenyl ketone | Vapour Bagong department | 184 |
2.4.6 diphenyl phosphate oxidation | Vapour Bagong department | TPO |
Siliceous flow agent | Dow Corning Corporation | DC57 |
Claims (8)
1. UV curing antibiotic coating, it is characterized in that: described UV curing antibiotic coating is formed by the feedstock production of following mass percent:
Aliphatic urethane acrylate 19-25%
Epoxy acrylate 5-12.5%
Reactive thinner 8-15%
Nano silver antimicrobials 0.5-2%
Light trigger 1.5-4%
Flow agent 0.1-0.2%
Inert solvent 47.85-65.9%.
2. according to the described UV curing antibiotic coating of claim 1, it is characterized in that: described UV curing antibiotic coating is formed by the feedstock production of following mass percent:
Aliphatic urethane acrylate 19.55-19.8%
Epoxy acrylate 12.5%
Reactive thinner 15%
Nano silver antimicrobials 0.5-1%
Light trigger 2%
Flow agent 0.2%
Inert solvent 50%.
3. according to claim 1 or 2 described UV curing antibiotic coatings, it is characterized in that: described aliphatic urethane acrylate is made up of six sense aliphatic urethane acrylates and the two sense aliphatic urethane acrylates that contain 15%PGDA; Described reactive thinner is made up of Viscoat 295 and tripropylene glycol diacrylate; Described light trigger is made up of 1-hydroxyl-ring ethyl-phenyl ketone and 2.4.6 diphenyl phosphate oxidation.
4. according to the described UV curing antibiotic coating of claim 3, it is characterized in that: described six sense aliphatic urethane acrylates are 15 with the mass ratio that contains the two sense aliphatic urethane acrylates of 15%PGDA: 4.55-4.8; The mass ratio of described Viscoat 295 and tripropylene glycol diacrylate is 1: 1; The mass ratio of described 1-hydroxyl-ring ethyl-phenyl ketone and 2.4.6 diphenyl phosphate oxidation is 3: 1.
5. according to claim 1 or 2 described UV curing antibiotic coatings, it is characterized in that: described epoxy acrylate is an aliphatic epoxy acrylate.
6. according to claim 1 or 2 described UV curing antibiotic coatings, it is characterized in that: described flow agent is siliceous flow agent.
7. according to claim 1 or 2 described UV curing antibiotic coatings, it is characterized in that: described inert solvent is made up of diacetone alcohol, butyl ester and ethyl ester.
8. according to the described UV curing antibiotic coating of claim 7, it is characterized in that: in described inert solvent, the mass ratio of diacetone alcohol, butyl ester and ethyl ester is 2: 5: 3.
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CN2010101563547A CN102234480A (en) | 2010-04-20 | 2010-04-20 | Ultraviolet light solidified antibiosis paint |
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Application publication date: 20111109 |