CN105400385A - Photocuring abrasion-resistant coating having antibacterial performance and preparation method thereof - Google Patents
Photocuring abrasion-resistant coating having antibacterial performance and preparation method thereof Download PDFInfo
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- CN105400385A CN105400385A CN201510867167.2A CN201510867167A CN105400385A CN 105400385 A CN105400385 A CN 105400385A CN 201510867167 A CN201510867167 A CN 201510867167A CN 105400385 A CN105400385 A CN 105400385A
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Abstract
The invention provides a photocuring abrasion-resistant coating having an antibacterial performance. The photocuring abrasion-resistant coating comprises, by mass parts, 50-60 parts of oligomer, 5-6 parts of crosslinking agent, 10-15 parts of reactive diluent, 6-8 parts of photoinitiator, 0.8-1.5 parts of antifoaming agent, 1-1.5 parts of flatting agent, 1-1.2 parts of matting agent, 0.5-1 part of slip agent, 0.8-1.2 parts of wetting agent, 10-15 parts of solvent, 0.5-1 part of cellulose, 3-5 parts of abrasion-resistant additive, 3-5 parts of antibacterial agent and 0.8-1 part of preservative, wherein the oligomer is mixed solution of polysilicone emulsion and epoxy acrylate.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of photocuring wear-resistant paint with anti-microbial property and preparation method thereof.
Background technology
Photo-cured coating be a kind of novel receive UV-irradiation after, physicochemical change can be there is in the short period of time and the coating solidified.With traditional seasoning or by thermofixation coating compared with, photo-cured coating not only has the advantage that curing speed is fast, excellent performance, base material are applied widely, and solidification process does not need additional heat, energy-conserving and environment-protective simultaneously, therefore, the application of photo-cured coating is more and more wider in the last few years.
Also there are some different problems in current photo-cured coating, existing photo-cured coating can produce string stress after photocuring, thus cause class coating material to enbrittle, impact resistance and wear resisting property poor.Therefore, coating be made to have better application characteristic, need the wear resisting property improving coating further.
In addition, coating is easy breed bacteria, mould often, makes coatingsurface generation mildew affect effect attractive in appearance, needs coating to have the effect of Antimicrobial preservative, but adding of antiseptic-germicide, the wear resisting property of coating can be reduced further.
Summary of the invention
Main purpose of the present invention is to provide a kind of photo-cured coating having antimicrobial characteristic and high-wearing feature concurrently.
For reaching above object, the invention provides a kind of photocuring wear-resistant paint with anti-microbial property, comprise following component, the content of each component represents with mass parts: 50 ~ 60 parts of oligopolymers, 5 ~ 6 parts of linking agents, 10 ~ 15 portions of reactive thinners, 6 ~ 8 parts of light triggers, 0.8 ~ 1.5 part of defoamer, 1 ~ 1.5 part of flow agent, 1 ~ 1.2 part of matting agent, 0.5 ~ 1 part of surface slip agent, 0.8 ~ 1.2 part of wetting agent, 10 ~ 15 parts of solvents, 0.5 ~ 1 part of Mierocrystalline cellulose, 3 ~ 5 parts of antiwear assistants, 3 ~ 5 portions of antiseptic-germicides, 0.8 ~ 1 portion of sanitas.
Preferably, described oligopolymer is the mixed solution of silicone emulsion and epoxy acrylate, and wherein said silicone emulsion is 1: 4 with the mixed volume ratio of described epoxy acrylate.Described silicone select following one or more: aminoethyl vinyl silicone, aminoethyl imido propyl group silicone.Utilize silicone emulsion to carry out the mixed and modified snappiness increasing epoxy acrylate to epoxy acrylate, thus improve galled spots and the wear resistance of film.
Preferably, described linking agent is bisphenol-A-polyoxyethylene polyoxypropylene ether.Described reactive thinner is cyclohexanediol diacrylate.Described light trigger is 4-(2-methylol acryloxy) methyl benzophenone.Described defoamer is vinyl trifluoropropyl siloxane.Described flow agent is 3-methyl methacrylate base ethyl diethoxy silane.Described matting agent is Viscoat 295.Described surface slip agent is Union carbide A-162.Described wetting agent is the different monooctyl ester of polymethyl acrylic acid.Described solvent is propyl carbinol.Described Mierocrystalline cellulose is hydroxypropyl carboxyethyl cellulose.
Preferably, described antiwear assistant is aluminum isopropylate and titanium tetraisopropylate, and the volume ratio of described aluminum isopropylate and described titanium tetraisopropylate is 1: 1.Select organo-metallic titanium salt and aluminium salt to be antiwear assistant, organic metal salt is hydrolyzed rear generation nano-metal-oxide particle in a solvent, can increase the wear resisting property of film.
Preferably, described antiseptic-germicide is dodecylamino pyridinium salt organic antibacterial agent, and described sanitas is 2-hydroxyethyl-4-isothiazoline-3-ketone.Select organic antibacterial agent and anticorrosive agent fully can ensure its dispersion in resin matrix, give the anti-corrosive antibacterial performance of coating excellence.
The present invention also provides a kind of method preparing described photocuring wear-resistant paint, comprises the following steps:
(1) 50 ~ 60 parts of oligopolymers, 5 ~ 6 parts of linking agents, 10 ~ 15 parts of reactive thinners, 10 ~ 15 solvents and 0.5 ~ 1 part of Mierocrystalline cellulose are put into whipping appts, after stirring, obtain mixture;
(2) 6 ~ 8 parts of light triggers, 0.8 ~ 1.5 part of defoamer, 1 ~ 1.5 part of flow agent, 1 ~ 1.2 part of matting agent, 0.5 ~ 1 part of surface slip agent, 0.8 ~ 1.2 part of wetting agent, 0.8 ~ 1 portion of sanitas are added under whipped state the described mixture in step (1);
(3) 3 ~ 5 parts of antiwear assistants and 3 ~ 5 parts of antiseptic-germicides are added in the mixture that step (2) obtains, after stirring, obtain described photocuring wear-resistant paint.
Preferably, in step (1), after each component adds whipping appts, under the rotating speed of 1000r/min, 20min is stirred.In step (2), after each component is added described mixture, under the rotating speed of 1000r/min, stir 30min.In step (3), each component is added after in the mixture that step (2) obtains, under the rotating speed of 1200r/min, stir 30min namely obtain described photocuring wear-resistant paint.
The UV Curable Abrasion Resistant Coatings with anti-microbial property provided by the invention has following beneficial effect:
1. emulsion of the present invention is the mixed solution of silicone emulsion and epoxy acrylate, and the introducing of silicone improves galled spots and the wear resistance of film on the one hand, and another aspect is also conducive to the cohesive strength improving film.
2. the present invention has screened organo-metallic titanium salt and aluminium salt as antiwear assistant, further increases film wear resisting property.
3. the present invention has screened sanitas and the Antibacterial accessory ingredient that 2-hydroxyethyl-4-isothiazoline-3-ketone and dodecylamino pyridinium salt are coating, select organic anti-corrosive agent and Antibacterial accessory ingredient fully can ensure its dispersion in resin matrix, decrease sanitas and antiseptic-germicide to the impact of film wear resistance, also give the anti-corrosive antibacterial performance of coating excellence simultaneously.
Embodiment
Below describe and realize the present invention for disclosing the present invention to enable those skilled in the art.Preferred embodiment in below describing only as an example, it may occur to persons skilled in the art that other apparent modification.
The epoxy acrylate that following examples adopt originates from the wooden Chemical Co., Ltd. in Shanghai three; Silicone emulsion originates from Dow corning company; Bisphenol-A-polyoxyethylene polyoxypropylene ether originates from Shang Haiyu and rises Chemical Co., Ltd.; Cyclohexanediol diacrylate originates from Zeon Corp; 4-(2-methylol acryloxy) methyl benzophenone originates from the farsighted chemical (Shanghai) Co., Ltd. of sky, and the raw material of other components and chemical reagent are commercial.
Embodiment 1
(1), take 40 parts of epoxy acrylates, 10 parts of aminoethyl vinyl silicone emulsions, 5 parts of bisphenol-A-polyoxyethylene polyoxypropylene ethers, 10 parts of reactive thinners, 10 parts of solvents and 0.5 part of Mierocrystalline cellulose are put in stirred pot, under the rotating speed of 1000r/min, stir 20min, obtain mixture; (2), then take 6 parts of light triggers according to mass ratio, 1.2 portions of defoamers, 1.5 portions of flow agents, 1.1 portions of matting agents, 0.8 portion of surface slip agent, 1.1 portions of wetting agents, 0.8 portion of sanitas add in the mixture of step (1) under whipped state, under the rotating speed of 1000r/min, stir 30min; (3), finally measure 3.0 parts of antiwear assistants, 4.0 parts of antiseptic-germicides join in the mixture of step (2), in stirred pot, under 1200r/min, stir 30min can obtain photocuring hydridization wear-resistant paint.
Embodiment 2
(1), take 44 parts of epoxy acrylates, 11 parts of aminoethyl vinyl silicone emulsions, 5 parts of bisphenol-A-polyoxyethylene polyoxypropylene ethers, 15 parts of reactive thinners, 12 parts of solvents and 0.7 part of Mierocrystalline cellulose are put in stirred pot, under the rotating speed of 1000r/min, stir 20min, obtain mixture; (2), then take 6.5 parts of light triggers according to mass ratio, 1.0 portions of defoamers, 1.3 portions of flow agents, 1.0 portions of matting agents, 0.6 portion of surface slip agent, 1.0 portions of wetting agents, 0.9 portion of sanitas add in the mixture of step (1) under whipped state, under the rotating speed of 1000r/min, stir 30min; (3), finally measure 4.0 parts of antiwear assistants, 3.5 parts of antiseptic-germicides join in the mixture of step (2), in stirred pot, under 1200r/min, stir 30min can obtain photocuring hydridization wear-resistant paint.
Embodiment 3
(1), take 48 parts of epoxy acrylates, 12 parts of aminoethyl vinyl silicone emulsions, 5 parts of bisphenol-A-polyoxyethylene polyoxypropylene ethers, 10 parts of reactive thinners, 15 parts of solvents and 1.0 parts of Mierocrystalline celluloses are put in stirred pot, under the rotating speed of 1000r/min, stir 20min, obtain mixture; (2), then take 7.0 parts of light triggers according to mass ratio, 1.5 portions of defoamers, 1.4 portions of flow agents, 1.2 portions of matting agents, 1.0 portions of surface slip agents, 1.2 portions of wetting agents, 0.9 portion of sanitas add in the mixture of step (1) under whipped state, under the rotating speed of 1000r/min, stir 30min; (3), finally measure 2.5 parts of antiwear assistants, 3.0 parts of antiseptic-germicides join in the mixture of step (2), in stirred pot, under 1200r/min, stir 30min can obtain photocuring hydridization wear-resistant paint.
Embodiment 4
(1), take 44 parts of epoxy acrylates, 11 parts of aminoethyl vinyl silicone emulsions, 5.5 parts of bisphenol-A-polyoxyethylene polyoxypropylene ethers, 15 parts of reactive thinners, 14 parts of solvents and 0.9 part of Mierocrystalline cellulose are put in stirred pot, under the rotating speed of 1000r/min, stir 20min, obtain mixture; (2), then take 7.5 parts of light triggers according to mass ratio, 1.1 portions of defoamers, 1.0 portions of flow agents, 1.0 portions of matting agents, 0.5 portion of surface slip agent, 0.8 portion of wetting agent, 1 portion of sanitas add in the mixture of step (1) under whipped state, under the rotating speed of 1000r/min, stir 30min; (3), finally measure 3.5 parts of antiwear assistants, 4.5 parts of antiseptic-germicides join in the mixture of step (2), in stirred pot, under 1200r/min, stir 30min can obtain photocuring hydridization wear-resistant paint.
Comparative example 1
(1), take 50 parts of epoxy acrylates, 5 parts of bisphenol-A-polyoxyethylene polyoxypropylene ethers, 10 parts of reactive thinners, 10 parts of solvents and 0.5 part of Mierocrystalline cellulose are put in stirred pot, under the rotating speed of 1000r/min, stir 20min, obtain mixture; (2), then take 6 parts of light triggers according to mass ratio, 1.2 portions of defoamers, 1.5 portions of flow agents, 1.1 portions of matting agents, 0.8 portion of surface slip agent, 1.1 portions of wetting agents, 0.8 portion of sanitas add in the mixture of step (1) under whipped state, under the rotating speed of 1000r/min, stir 30min; (3), finally measure 3.0 parts of antiwear assistants, 4.0 parts of antiseptic-germicides join in the mixture of step (2), in stirred pot, under 1200r/min, stir 30min can obtain photocuring hydridization wear-resistant paint.
Comparative example 2
(1), take 44 parts of epoxy acrylates, 11 parts of aminoethyl vinyl silicone emulsions, 5 parts of bisphenol-A-polyoxyethylene polyoxypropylene ethers, 15 parts of reactive thinners, 12 parts of solvents and 0.7 part of Mierocrystalline cellulose are put in stirred pot, under the rotating speed of 1000r/min, stir 20min, obtain mixture; (2), then take 6.5 parts of light triggers according to mass ratio, 1.0 portions of defoamers, 1.3 portions of flow agents, 1.0 portions of matting agents, 0.6 portion of surface slip agent, 1.0 portions of wetting agents, 0.9 portion of sanitas add in the mixture of step (1) under whipped state, under the rotating speed of 1000r/min, stir 30min; (3), finally measuring 4.0 parts of antiwear assistants joins in the mixture of step (2), stirs 30min and can obtain photocuring hydridization wear-resistant paint in stirred pot under 1200r/min.
Spray on PC base material by the photocuring wear-resistant paint that above each embodiment and comparative example obtain, test the performance of film after film-forming, wherein cohesive strength is according to GB9153-88 standard testing; Wear resisting property is according to ASTMF2357-04 (RCA is wear-resisting) standard testing; The anti-microbial property test of film adopts JISZ2801 standard testing,
Be tested bacterial classification with intestinal bacteria, shown in test result following table.
Can find with comparing of comparative example 1 from embodiment 1, after mixing silicone in emulsion, not only significantly can improve the wear resistance of film, also improve the cohesive strength of film to a certain extent.Can find with comparing of comparative example 2 from embodiment 1, add the antimicrobial efficiency that antiseptic-germicide drastically increases film, the wear resistance of film is not had an impact adding of antiseptic-germicide simultaneously.
More than show and describe ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; the just principle of the present invention described in above-described embodiment and specification sheets; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements all fall in claimed scope of the present invention.The protection domain of application claims is defined by appending claims and equivalent thereof.
Claims (8)
1. one kind has the photocuring wear-resistant paint of anti-microbial property, it is characterized in that, comprise following component, the content of each component represents with mass parts: 50 ~ 60 parts of oligopolymers, 5 ~ 6 parts of linking agents, 10 ~ 15 portions of reactive thinners, 6 ~ 8 parts of light triggers, 0.8 ~ 1.5 part of defoamer, 1 ~ 1.5 part of flow agent, 1 ~ 1.2 part of matting agent, 0.5 ~ 1 part of surface slip agent, 0.8 ~ 1.2 part of wetting agent, 10 ~ 15 parts of solvents, 0.5 ~ 1 part of Mierocrystalline cellulose, 3 ~ 5 parts of antiwear assistants, 3 ~ 5 portions of antiseptic-germicides, 0.8 ~ 1 portion of sanitas.
2. photocuring wear-resistant paint according to claim 1, is characterized in that, described oligopolymer is the mixed solution of silicone emulsion and epoxy acrylate.
3. photocuring wear-resistant paint according to claim 2, is characterized in that, described silicone emulsion select following one or more: aminoethyl vinyl silicone emulsion, aminoethyl imido propyl group silicone emulsion.
4. photocuring wear-resistant paint according to claim 3, is characterized in that, described silicone emulsion is 1: 4 with the mixed volume ratio of described epoxy acrylate.
5. photocuring wear-resistant paint according to claim 2, is characterized in that, described antiwear assistant is aluminum isopropylate and titanium tetraisopropylate, and the volume ratio of described aluminum isopropylate and described titanium tetraisopropylate is 1: 1.
6. photocuring wear-resistant paint according to claim 2, is characterized in that, described antiseptic-germicide is dodecylamino pyridinium salt organic antibacterial agent, and described sanitas is 2-hydroxyethyl-4-isothiazoline-3-ketone.
7. according to the arbitrary described photocuring wear-resistant paint of claim 1-6, it is characterized in that, described linking agent is bisphenol-A-polyoxyethylene polyoxypropylene ether, described reactive thinner is cyclohexanediol diacrylate, described light trigger is 4-(2-methylol acryloxy) methyl benzophenone, described defoamer is vinyl trifluoropropyl siloxane, described flow agent is 3-methyl methacrylate base ethyl diethoxy silane, described matting agent is Viscoat 295, described surface slip agent is Union carbide A-162, described wetting agent is the different monooctyl ester of polymethyl acrylic acid, described solvent is propyl carbinol, described Mierocrystalline cellulose is hydroxypropyl carboxyethyl cellulose.
8. prepare a method for the arbitrary described photocuring wear-resistant paint of claim 1-7, it is characterized in that, comprise the following steps:
(1) 50 ~ 60 parts of oligopolymers, 5 ~ 6 parts of linking agents, 10 ~ 15 parts of reactive thinners, 10 ~ 15 solvents and 0.5 ~ 1 part of Mierocrystalline cellulose are put into whipping appts, after stirring, obtain mixture;
(2) 6 ~ 8 parts of light triggers, 0.8 ~ 1.5 part of defoamer, 1 ~ 1.5 part of flow agent, 1 ~ 1.2 part of matting agent, 0.5 ~ 1 part of surface slip agent, 0.8 ~ 1.2 part of wetting agent, 0.8 ~ 1 portion of sanitas are added under whipped state the described mixture in step (1);
(3) 3 ~ 5 parts of antiwear assistants and 3 ~ 5 parts of antiseptic-germicides are added in the mixture that step (2) obtains, after stirring, obtain described photocuring wear-resistant paint.
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| CN201510867167.2A CN105400385B (en) | 2015-11-27 | 2015-11-27 | A kind of photocuring wear-resistant paint and preparation method thereof with anti-microbial property |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109401612A (en) * | 2018-11-02 | 2019-03-01 | 华容县恒兴建材有限公司 | Wear-resisting optical curing of UV coating |
| CN111100536A (en) * | 2018-10-25 | 2020-05-05 | 宁波其兰文化发展有限公司 | Anti-aging ultraviolet curing composite conductive coating and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1754929A (en) * | 2004-09-29 | 2006-04-05 | 上海保诺杰企业发展有限公司 | UV cured protective coating of reflective film |
| CN1927971A (en) * | 2006-09-18 | 2007-03-14 | 深圳清华大学研究院 | Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof |
| JP2008063437A (en) * | 2006-09-07 | 2008-03-21 | Sk Kaken Co Ltd | Coating composition and coating method |
| CN101423678A (en) * | 2008-10-29 | 2009-05-06 | 国家纳米科学中心 | Light curing nano composite coating |
| CN102234480A (en) * | 2010-04-20 | 2011-11-09 | 东莞市佩琦涂料有限公司 | Ultraviolet light solidified antibiosis paint |
| CN104910758A (en) * | 2015-05-11 | 2015-09-16 | 广德美涂士化工有限公司 | High-strength antibacterial ultraviolet-curable coating |
-
2015
- 2015-11-27 CN CN201510867167.2A patent/CN105400385B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1754929A (en) * | 2004-09-29 | 2006-04-05 | 上海保诺杰企业发展有限公司 | UV cured protective coating of reflective film |
| JP2008063437A (en) * | 2006-09-07 | 2008-03-21 | Sk Kaken Co Ltd | Coating composition and coating method |
| CN1927971A (en) * | 2006-09-18 | 2007-03-14 | 深圳清华大学研究院 | Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof |
| CN101423678A (en) * | 2008-10-29 | 2009-05-06 | 国家纳米科学中心 | Light curing nano composite coating |
| CN102234480A (en) * | 2010-04-20 | 2011-11-09 | 东莞市佩琦涂料有限公司 | Ultraviolet light solidified antibiosis paint |
| CN104910758A (en) * | 2015-05-11 | 2015-09-16 | 广德美涂士化工有限公司 | High-strength antibacterial ultraviolet-curable coating |
Non-Patent Citations (1)
| Title |
|---|
| 樊武厚等: "助剂对水性聚氨酯涂膜耐磨性的影响", 《皮革与科学工程》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111100536A (en) * | 2018-10-25 | 2020-05-05 | 宁波其兰文化发展有限公司 | Anti-aging ultraviolet curing composite conductive coating and preparation method thereof |
| CN109401612A (en) * | 2018-11-02 | 2019-03-01 | 华容县恒兴建材有限公司 | Wear-resisting optical curing of UV coating |
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| CN105400385B (en) | 2019-02-15 |
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Effective date of registration: 20211227 Address after: 212426 No. 19, Fenggang village, Huangmei Town, Jurong City, Zhenjiang City, Jiangsu Province Patentee after: JIANGSU HIMONIA TECHNOLOGY Co.,Ltd. Address before: 42 Wentao Road, Xiangshan Industrial Zone, Ningbo, Zhejiang 315708 Patentee before: NINGBO SHUANGREN NEW MATERIAL CO.,LTD. |