WO2009065873A3 - Polyhedral oligomeric stannasilsesquioxanes as catalyst for polyurethane curing - Google Patents

Polyhedral oligomeric stannasilsesquioxanes as catalyst for polyurethane curing Download PDF

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Publication number
WO2009065873A3
WO2009065873A3 PCT/EP2008/065869 EP2008065869W WO2009065873A3 WO 2009065873 A3 WO2009065873 A3 WO 2009065873A3 EP 2008065869 W EP2008065869 W EP 2008065869W WO 2009065873 A3 WO2009065873 A3 WO 2009065873A3
Authority
WO
WIPO (PCT)
Prior art keywords
polyhedral oligomeric
coatings
stannasilsesquioxanes
catalyst
polyurethane curing
Prior art date
Application number
PCT/EP2008/065869
Other languages
French (fr)
Other versions
WO2009065873A2 (en
Inventor
Bir Darbar Mehta
Ali Malik Jamal Jaffar
Andreas Fechtenkoetter
Chih-Cheng Peng
Original Assignee
Basf Se
Bir Darbar Mehta
Ali Malik Jamal Jaffar
Andreas Fechtenkoetter
Chih-Cheng Peng
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Bir Darbar Mehta, Ali Malik Jamal Jaffar, Andreas Fechtenkoetter, Chih-Cheng Peng filed Critical Basf Se
Publication of WO2009065873A2 publication Critical patent/WO2009065873A2/en
Publication of WO2009065873A3 publication Critical patent/WO2009065873A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/045—Polysiloxanes containing less than 25 silicon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/58—Metal-containing linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/14—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms

Abstract

The invention relates to a curable composition comprising the following components: (A) at least one isocyanate, (B) at least one binder, and (C) at least one polyhedral oligomeric silsesquioxane, with the number of cages z per molecule being 2 or 3 and the number of tin atoms per molecule being at least one. Furthermore, the invention refers to a kit of parts comprising as components A), B), and C); to the use of the polyhedral oligomeric silsesquioxanes in coatings, lacquers, paintings, films and polymer compositions; to coatings obtainable by curing of these compositions; and to the use of polyhedral oligomeric silsesquioxanes containing at least one metal atom, in particular polyhedral oligomeric stannasilsesquioxane to increase the scratch resistance of coatings.
PCT/EP2008/065869 2007-11-21 2008-11-19 Polyhedral oligomeric stannasilsesquioxanes as catalyst for polyurethane curing WO2009065873A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07121179.1 2007-11-21
EP07121179 2007-11-21

Publications (2)

Publication Number Publication Date
WO2009065873A2 WO2009065873A2 (en) 2009-05-28
WO2009065873A3 true WO2009065873A3 (en) 2009-07-16

Family

ID=40383777

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/065869 WO2009065873A2 (en) 2007-11-21 2008-11-19 Polyhedral oligomeric stannasilsesquioxanes as catalyst for polyurethane curing

Country Status (1)

Country Link
WO (1) WO2009065873A2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102781994A (en) * 2009-12-21 2012-11-14 亨茨曼国际有限公司 A method to form a polyurethane material
CN107814936A (en) * 2017-11-02 2018-03-20 合众（佛山）化工有限公司 The low free monomer polyurethane curing agent that a kind of POSS is modified
CN107936814A (en) * 2017-11-02 2018-04-20 合众（佛山）化工有限公司 The net taste woodcare paint of high hardness polyurethane that a kind of POSS is modified

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9079828B2 (en) 2010-09-30 2015-07-14 Voco Gmbh Polymerizable compounds comprising a polyalicylic structure element
US8697769B2 (en) 2010-09-30 2014-04-15 Voco Gmbh Lacquer composition comprising a monomer with a polyalicyclic structure element
US9023916B2 (en) 2010-09-30 2015-05-05 Voco Gmbh Composite material comprising a monomer with a polyalicyclic structure element
US8915736B2 (en) 2010-09-30 2014-12-23 Voco Gmbh Composition comprising a monomer with a polyalicyclic structure element for filling and/or sealing a root canal
US8669302B2 (en) 2010-09-30 2014-03-11 Voco Gmbh Composite material comprising a monomer with a polyalicyclic structure element as a sealing material
EP2450025B1 (en) 2010-11-08 2012-11-28 VOCO GmbH Polymerisable phosphoric acid derivatives comprising a polyalicyclic structure element
EP2578200B1 (en) 2011-10-04 2018-03-28 VOCO GmbH Compounds for infiltrating and/or sealing of dental hard substance and method
DE102012001978A1 (en) 2012-02-02 2013-08-08 Voco Gmbh Dental composite materials containing tricyclic plasticizers
DE102012001979A1 (en) 2012-02-02 2013-08-08 Voco Gmbh A curable composition comprising plasticizer having a polyalicyclic structural element for use in the manufacture of dental materials
CN102773892B (en) * 2012-08-13 2014-03-26 山东农业大学 Preparation method of wood-organic-inorganic hybridized nano composite material based on doped nano POSS (Polyhedral Oligomeric Silsesquioxane)
EP2865704A1 (en) 2013-10-28 2015-04-29 Huntsman International Llc Synthesis and use of metallized polyhedral oligomeric silsesquioxane catalyst compositions
US11661533B2 (en) 2017-07-28 2023-05-30 Avery Dennison Corporation Pressure sensitive adhesives and articles with hyperbranched silsesquioxane core and methods of making the same
CN110358437B (en) * 2019-06-19 2021-05-28 广西邦格恩化工有限公司 High-performance environment-friendly water-based paint and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6936663B1 (en) * 2003-07-07 2005-08-30 Conano Corporation Powder coating compositions containing POSS compounds
WO2007041344A2 (en) * 2005-09-29 2007-04-12 Hybrid Plastics, Inc. Metallized nanostructured chemicals as cure promoters
WO2008144735A1 (en) * 2007-05-21 2008-11-27 Hybrid Plastics, Inc. Metallized polyhedral oligomeric silsesquioxanes as catalysts for polyurethanes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6936663B1 (en) * 2003-07-07 2005-08-30 Conano Corporation Powder coating compositions containing POSS compounds
WO2007041344A2 (en) * 2005-09-29 2007-04-12 Hybrid Plastics, Inc. Metallized nanostructured chemicals as cure promoters
WO2008144735A1 (en) * 2007-05-21 2008-11-27 Hybrid Plastics, Inc. Metallized polyhedral oligomeric silsesquioxanes as catalysts for polyurethanes

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ROBBERT DUCHATEAU*, TESSA W. DIJKSTRA, JOHN R. SEVERN, RUTGER A. VAN SANTEN AND ILIA V. KOROBKOV: "Synthesis and characterization of tin containing polyhedral oligometallasilsesquioxanes (POMSS)", DALTON TRANS., 2004, pages 2677 - 2682, XP002519736 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102781994A (en) * 2009-12-21 2012-11-14 亨茨曼国际有限公司 A method to form a polyurethane material
CN102781994B (en) * 2009-12-21 2014-05-07 亨茨曼国际有限公司 A method to form a polyurethane material
CN107814936A (en) * 2017-11-02 2018-03-20 合众（佛山）化工有限公司 The low free monomer polyurethane curing agent that a kind of POSS is modified
CN107936814A (en) * 2017-11-02 2018-04-20 合众（佛山）化工有限公司 The net taste woodcare paint of high hardness polyurethane that a kind of POSS is modified
CN107814936B (en) * 2017-11-02 2020-03-20 合众（佛山）化工有限公司 POSS (polyhedral oligomeric silsesquioxane) modified low-free monomer polyurethane curing agent

Also Published As

Publication number Publication date
WO2009065873A2 (en) 2009-05-28

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