CN104387948A - Vacuum plating under-coating paint as well as application and preparation method of vacuum platable hard thin film for IML prepared from vacuum plating under-coating paint - Google Patents
Vacuum plating under-coating paint as well as application and preparation method of vacuum platable hard thin film for IML prepared from vacuum plating under-coating paint Download PDFInfo
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- CN104387948A CN104387948A CN201410714421.0A CN201410714421A CN104387948A CN 104387948 A CN104387948 A CN 104387948A CN 201410714421 A CN201410714421 A CN 201410714421A CN 104387948 A CN104387948 A CN 104387948A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
- C08J2475/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a vacuum plating under-coating paint as well as a preparation method and an application of a vacuum platable PET hard thin film for IML. The vacuum plating under-coating paint is prepared from the following components: 10-30 parts of polyurethane acrylate, 5-10 parts of epoxy acrylate, 5-10 parts of modified acrylate, 0.5-2 parts of flatting agent, 1-2 parts of photoinitiator and 50-70 parts of organic solvent. The vacuum plating under-coating paint for a PET substrate is produced by evenly mixing a reactive diluent, the flatting agent and the organic solvent together, next, adding the polyurethane acrylate, the epoxy acrylate and the modified acrylate and mixing evenly, and then adding the photoinitiator at the final stage for dispersing evenly; the vacuum plating under-coating paint is applicable to preparing the vacuum platable PET hard thin film for the IML; the cost can be effectively reduced; the obtained vacuum platable PET hard thin film for the IML has certain forming tensile properties, and the outer layer of the hard thin film has high hardness and high wear resistance, while the inner layer of the same has excellent adhesion to a metal coating and a screen printing ink layer, and furthermore, the metal coating is excellent in glossiness.
Description
Technical field
The present invention relates to a kind of coating, particularly a kind of UV photocuring Vacuum Deposition bottom-coating for PET base material and preparation method thereof and application.
The present invention relates to a kind of film, particularly a kind ofly coated the Vacuum Deposition hardening film for IML technology prepared by PET base material by above-mentioned coating.
Background technology
The distinguishing feature of in-mode inserts injection moulding (IML) technique is: surface hardening film wear resisting property is given prominence to, and printed layers is clipped in the middle, and can prevent product surface from being scratched, and the bright-coloured of color can be kept for a long time not easily to fade.Day by day lightening along with consumption electronic products, the plurality of advantages of IML technology makes it to be particularly suitable for the plastic prods such as 3C, household electrical appliances, auto parts, the instrument of particularly popular at present phone housing and various household electrical appliances and operating panel etc.
Along with the development of IML technology, the demand of thin-film material has not only been confined to the transparent hard film of high printing opacity, some have the thin-film material of unique additional function also to arise at the historic moment.Vacuum Deposition film is exactly one of them, from the angle used, IML Vacuum Deposition film requires in optical grade PET base material, carry out two-sided stiffened process, outside requires that high rigidity and high-wear resistance scratch to avoid product, inner face requires to have plating property on ink printing and metal, resultant metal gloss is given by printed patterns and metal cladding, reach unique transparent metal effect, have shaping tensile property simultaneously and can be injection molded into various three-dimensional contouring, this technique is applicable to manufacturing high-grade 3C and casing of domestic electrical equipment very much.
Traditional Vacuum Deposition bottom-coating is used for PC, PMMA, ABS and compound plastic board usually through spraying coating process, baking-curing, and construction thickness 10 ~ 30 μm is to ensure plating property on the metal that substrate surface is smooth and excellent.Current Vacuum Deposition bottom-coating is not used for PET base material, and spraying coating process coating consumption is large, and production cost is high, and PET base material surface finish is good, only need be coated with very shallow layer and can ensure that substrate surface is smooth and keep excellent sticking power to metal plating.In sum, a kind of two-sided PET cured film of market in urgent need, coated on one side high rigidity hardening coat (taking charge of patent " a kind of UV photo-cured coating for IML and preparation method thereof and application " see me) ensures high rigidity and wear resistance, another side coating is used for the Vacuum Deposition bottom-coating of PET film base material, and its coating has plating property on excellent levelling property, enough ink adhesions and metal, this film has the market requirement that certain shaping tensile property can meet IML technology diversification day by day.
Summary of the invention
Primary and foremost purpose of the present invention is to overcome the shortcoming of prior art with not enough, fills up gaps in market, provide a kind of Vacuum Deposition bottom-coating for PET base material and for IML can Vacuum Deposition transparent film.
Another object of the present invention is to provide the preparation method of the described Vacuum Deposition bottom-coating for PET base material.
Another object of the present invention be to provide described can the preparation method of Vacuum Deposition film.
Object of the present invention is achieved through the following technical solutions: a kind of Vacuum Deposition bottom-coating, comprises following composition according to the mass fraction: urethane acrylate 10 ~ 30 parts, epoxy acrylate 5 ~ 10 parts, modification acrylate 5 ~ 10 parts, reactive thinner 5 ~ 10 parts, flow agent 0.5 ~ 2 part, light trigger 1 ~ 2 part, organic solvent 50 ~ 70 parts;
Described urethane acrylate is the low functionality of 2 ~ 4 and the high-functionality polyurethane acrylic collocation of 6 ~ 15, and low functionality urethane acrylate is preferably at least one in large Japanese ink chemistry UA-711BT-1, UA-510-2, Changxing chemistry DR-U010, DR-U150 and Bayer VP LS2220, XP2491; High-functionality polyurethane acrylic is preferably at least one in Changxing chemistry 6161-100,6195-100, DR-U116 and cyanogen special EB1259, EB1290N, EB8602, EB8415;
Described epoxy acrylate is modified epoxy acrylic ester, be preferably Changxing chemistry 6215-100,6233, at least one in DR-G991 and cyanogen special EB3300, EB3703, EB9636;
Described acrylate is modification acrylate, in order to strengthen the sticking power of coating to PET base material and metal plating, be preferably Changxing chemistry 6063-1,6070,6071, at least one in 6071-2 and BASF PA9039, PA9083;
Described reactive thinner is 2 ~ 4 functionality acrylate reactive thinners, is preferably at least one in DSM AgiSyn2836, AgiSyn2884, Changxing chemistry EM231, EM235;
Described flow agent is at least one in polyacrylate(s) flow agent; Be more preferably at least one in Bi Ke chemistry BYK-352, BYK-358N, BYK-390, enlightening height Flow300, Flow370, BASF Efka FL3740, Efka FL3785;
Described light trigger is preferably at least one in alpha-alcohol ketone photoinitiator, alpha-amino group ketone-type photoinitiators and acylphosphine oxide photoinitiator; Be more preferably at least one in vapour Bagong department Darocur 1173 light trigger, BASF Irgacure 2959 light trigger, BASF Irgacure 184 light trigger, BASF Irgacure2022 light trigger, BASF Irgacure 907 light trigger and BASF Lucirin TPO photoinitiator;
Described machine solvent is at least one in ketone and esters solvent, for the resin in diluted formulations and auxiliary agent, improves the workability of coating;
Described ketone be preferably acetone, butanone and methyl iso-butyl ketone (MIBK) and at least one;
Described ester is preferably at least one in ethyl acetate and butylacetate;
The preparation method of the described UV photocuring Vacuum Deposition bottom-coating for PET base material, comprises following steps:
(1) 5 ~ 10 mass parts reactive thinners, 0.5 ~ 2 mass parts flow agent are mixed with 50 ~ 70 mass parts organic solvents;
(2) add the mixing of 10 ~ 30 mass parts aliphatic urethane acrylates, 5 ~ 10 mass parts epoxy acrylates and 5 ~ 10 mass parts modification acrylates in the mixture obtained toward step (1), be uniformly dispersed; Then add 1 ~ 2 mass parts light trigger, mixing, obtains the UV photocuring Vacuum Deposition bottom-coating for IML; This coating needs sealing, keeps in Dark Place.
Described UV photocuring Vacuum Deposition bottom-coating is applied to preparation IML with can Vacuum Deposition hardening film, can adopt a mouthful die coating method, air knife method, reverse rolling method, spray method, the methods such as the skill in using a kitchen knife in cookery, woodburytype and spin application method of scraping are prepared.
IML is with can the preparation method of Vacuum Deposition hardening film, and comprise the steps: the UV photo-cured coating being used for IML to coat optical grade PET base material, obtain wet film, then dry, UV irradiates solidification, and obtaining IML use can Vacuum Deposition hardening film;
Described PET base material thickness is preferably 100 μm, 125 μm and 188 μm;
The thickness of described wet film is preferably 5 ~ 20 μm;
Described drying temperature is preferably 50 ~ 100 DEG C;
Described UV luminous energy is 200 ~ 800mJ/cm
2be more preferably 300 ~ 400mJ/cm
2;
Described IML, with being preferably 2 ~ 10 μm by Vacuum Deposition hardening film thickness, is more preferably 3 ~ 6 μm.
By described IML with can the IML that obtains of the preparation method of Vacuum Deposition PET hardening film with can Vacuum Deposition PET hardening film.
The present invention has following advantage and effect relative to prior art:
(1) in the formula of the UV photo-cured coating for IML provided by the invention, use aliphatic urethane acrylate, be aided with modification acrylate, thus give utilize above-mentioned UV photo-cured coating to prepare coating to the sticking power of PET base material and vacuum metallization coating and screen printing ink excellence.
(2) IML Vacuum Deposition hardening film provided by the invention has certain shaping tensile property, and has excellent sticking power to PET base material, metal plating and screen printing ink; Product after metallizing coating has excellent metalluster and unique transparent metal effect, and metal plating remains on part innerside not easily scratch and save finish paint spray procedure; Adopt the coating mode of production to reduce coating consumption, reduce raw materials cost; Adopt UV photocuring to enhance productivity, reduce production cost.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited thereto.
Embodiment 1
Preparation for the Vacuum Deposition bottom-coating of IML:
(1) by 50g organic solvent (acetone/butyl acetate=1: 1), 10g reactive thinner (DSM AgiSyn2836), 2g flow agent (BYK-352) mix;
(2) add 25g urethane acrylate (large Japanese ink chemistry UA-711BT-1/ Changxing chemistry 6195-100=2: 1), 6g epoxy acrylate (the special EB3300 of cyanogen), 5g modification acrylate (BASF PA9083) in the mixture obtained to step (1), high-speed stirring is uniformly dispersed;
(3) add 2g light trigger (vapour Bagong department Darocur 1173/ BASF Lucirin TPO=2: 1) in the mixture obtained to step (2), be uniformly dispersed, filter, obtain the Vacuum Deposition bottom-coating for PET base material.
Embodiment 2
Preparation for the Vacuum Deposition bottom-coating of IML:
(1) by 70g organic solvent (ethyl acetate/methyl iso-butyl ketone (MIBK)=1: 1), 5g reactive thinner (Changxing chemistry EM231), 0.5g flow agent (BYK-358N) mix;
(2) add 10g urethane acrylate (Bayer XP2491/ cyanogen special EB1290N=3: 2), 8g epoxy acrylate (Changxing chemistry DR-G991), 5g modification acrylate (Changxing chemistry 6071-2) in the mixture obtained to step (1), high-speed stirring is uniformly dispersed;
(3) add 1g light trigger (BASF Irgacure 184/ BASF Irgacure 907=2: 1) in the mixture obtained to step (2), be uniformly dispersed, filter, obtain the Vacuum Deposition bottom-coating for PET base material.
Embodiment 3
Preparation for the Vacuum Deposition bottom-coating of IML:
(1) by 60g organic solvent (butanone/butylacetate=2: 1), 8g reactive thinner (Changxing chemistry EM235), 1g flow agent (enlightening height FLow370) mix;
(2) add 15g urethane acrylate (Changxing chemistry DR-U150/ cyanogen special EB8602=2: 1), 5g epoxy acrylate (the special EB3703 of cyanogen), 10g modification acrylate (Changxing chemistry 6070) in the mixture obtained to step (1), high-speed stirring is uniformly dispersed;
(3) add 1.5g light trigger (BASF Irgacure 184/ BASF Lucirin TPO=2: 1) in the mixture obtained to step (2), be uniformly dispersed, filter, obtain the Vacuum Deposition bottom-coating for PET base material.
Comparative example 1
(1) by 60g organic solvent (butanone/butylacetate=2: 1), 8g reactive thinner (Changxing chemistry EM235), 1g flow agent (enlightening height FLow370) mix;
(2) add 25g urethane acrylate (Changxing chemistry DR-U150/ cyanogen special EB8602=2: 1) in the mixture obtained to step (1), 5g epoxy acrylate (the special EB3703 of cyanogen), high-speed stirring be uniformly dispersed;
(3) add 1.5g light trigger (BASF Irgacure 184/ BASF Lucirin TPO=2: 1) in the mixture obtained to step (2), be uniformly dispersed, filter, obtain the Vacuum Deposition bottom-coating for PET base material.
Effect example
Can the preparation of Vacuum Deposition PET hardening film: coat in the PET film (another side has been coated with high rigidity coating) of area A 4 paper size by coating 2 ~ 5g line rod, 50 ~ 100 DEG C of heat drying 1 ~ 2min, UV solidify energy 300 ~ 500mJ/cm
2, the build of solidification 2 ~ 5 μm.That is prepared by the coating by embodiment 1 ~ 3 and comparative example 1 can Vacuum Deposition PET hardening film over-all properties evaluate, see table 1.
Table 1 can Vacuum Deposition PET hardening film comprehensive performance evaluation
Note: the method detecting thickness is shown in JIS C-2318; The method detecting transmittance is shown in JIS K-7105; The method detecting mist degree is shown in JIS K-7105; The method detecting cupping is shown in GB 9753-2007-T; The method detecting sticking power is shown in JIS K-5600; The detection method of wet-hot aging performance is for testing transmittance and mist degree in humidity 90%, temperature 80 DEG C effect after 240 hours; The detection method of water boiling resistance performance is boiling water boiling 1h, dries up rear test transmittance and mist degree.
The coating performance data of embodiment 1 ~ 3 as can be seen from table 1, use through the different urethane acrylates of formulation optimization, epoxy acrylate and modification acrylate collocation, hardening film optical grade PET base material, metal plating and ink for screen printing layer to excellent adhesive attraction simultaneously can be prepared, and there is shaping tensile property, the service requirements of multiple different downstreams processing procedure can be met.
According to embodiment 3 and comparative example 1, after removing modification acrylate, the sticking power of coating to PET base material declines to some extent, to the sticking power degradation of metal plating and silk-screen mirror-like silver ink, illustrate that the sticking power aspect of hardening coat to metal plating and mirror-like silver ink that be added in of modification acrylate plays vital effect.
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from spirit of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (9)
1. a Vacuum Deposition bottom-coating, is characterized in that comprising following composition according to the mass fraction: urethane acrylate 10 ~ 30 parts, epoxy acrylate 5 ~ 10 parts, modification acrylate 5 ~ 10 parts, reactive thinner 5 ~ 10 parts, flow agent 0.5 ~ 2 part, light trigger 1 ~ 2 part, organic solvent 50 ~ 70 parts.
2. Vacuum Deposition bottom-coating according to claim 1, is characterized in that:
Described aliphatic urethane acrylate is the low functionality of 2 ~ 4 and the high functionality aliphatic urethane acrylate collocation of 6 ~ 15;
Described epoxy acrylate is modified epoxy acrylic ester;
Described acrylate is modification acrylate;
Described flow agent is polyacrylate(s) class flow agent;
Described light trigger is at least one in alpha-alcohol ketone photoinitiator, alpha-amino group ketone-type photoinitiators and acylphosphine oxide photoinitiator;
Described organic solvent is at least two kinds in ketone and esters solvent.
3. Vacuum Deposition bottom-coating according to claim 1, it is characterized in that: described epoxy acrylate is modified epoxy acrylic ester, described reactive thinner is 2 ~ 4 functionality acryllic acid ester activated diluting agents.
4. Vacuum Deposition bottom-coating according to claim 2, is characterized in that: described flow agent is at least one in polyacrylate(s) flow agent;
Described ketone is at least one in acetone, methyl iso-butyl ketone (MIBK) and butanone;
Described ester is at least one in ethyl acetate and butylacetate.
5. the preparation method of Vacuum Deposition bottom-coating described in any one of Claims 1 to 4, is characterized in that comprising following steps:
(1) 5 ~ 10 mass parts reactive thinners, 0.5 ~ 2 mass parts flow agent are mixed with 50 ~ 70 mass parts organic solvents;
(2) add the mixing of 10 ~ 30 mass parts aliphatic urethane acrylates, 5 ~ 10 mass parts epoxy acrylates and 5 ~ 10 mass parts modification acrylates in the mixture obtained toward step (1), be uniformly dispersed; Then add 1 ~ 2 mass parts light trigger, mixing, obtains the UV photocuring Vacuum Deposition bottom-coating for IML; This coating needs sealing, keeps in Dark Place.
6. Vacuum Deposition bottom-coating described in any one of Claims 1 to 4 at preparation IML with can application in Vacuum Deposition PET hardening film.
7. an IML is with can the preparation method of Vacuum Deposition PET hardening film, it is characterized in that comprising the steps: that the Vacuum Deposition bottom-coating being used for IML by described in any one of Claims 1 to 4 is coated with, obtain wet film, then heat drying, UV photocuring, obtaining IML use can Vacuum Deposition hardening film.
8. IML with can the preparation method of Vacuum Deposition PET hardening film, is characterized in that as recited in claim 7:
Described PET base material thickness is 100 μm, 125 μm and 188 μm;
The thickness of described wet film is 5 ~ 20 μm;
Described drying temperature is 50 ~ 100 DEG C;
Described UV luminous energy is 200 ~ 800mJ/cm
2;
Described IML is with can Vacuum Deposition hardening film thickness be 2 ~ 10 μm.
9. IML is with can a Vacuum Deposition PET hardening film, it is characterized in that adopting if described IML arbitrary in claim 7 or 8 is with can the preparation method of Vacuum Deposition PET hardening film obtain.
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|---|---|---|---|
| CN201410714421.0A CN104387948A (en) | 2014-12-01 | 2014-12-01 | Vacuum plating under-coating paint as well as application and preparation method of vacuum platable hard thin film for IML prepared from vacuum plating under-coating paint |
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| CN201410714421.0A CN104387948A (en) | 2014-12-01 | 2014-12-01 | Vacuum plating under-coating paint as well as application and preparation method of vacuum platable hard thin film for IML prepared from vacuum plating under-coating paint |
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| CN104927621A (en) * | 2015-05-31 | 2015-09-23 | 湖南省金海科技有限公司 | Low-energy curing UV coating system for PET plastic vacuum coating spraying process |
| CN105038574A (en) * | 2015-08-26 | 2015-11-11 | 太仓市金新涂料有限公司 | Acid and alkali resistant UV curing coating |
| CN110437688A (en) * | 2018-05-02 | 2019-11-12 | 温州酷乐餐桌用品有限公司 | A kind of technique improving printed matter wash durability |
| CN110527334A (en) * | 2019-09-11 | 2019-12-03 | 南京工程学院 | A kind of vacuum visible light room temperature curing composite membrane and preparation method based on carbon quantum dot |
| CN111234684A (en) * | 2020-01-21 | 2020-06-05 | 江门市恒之光环保新材料有限公司 | Steel wool-resistant super-wear-resistant resin |
| CN111234689A (en) * | 2020-04-03 | 2020-06-05 | 江西省赐彩新材料科技有限公司 | Ultraviolet curing primer for optical coating and preparation and application thereof |
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| CN115160853A (en) * | 2022-06-20 | 2022-10-11 | 广东希贵光固化材料有限公司 | Ultraviolet photocuring printing coating |
| CN115991954A (en) * | 2022-12-30 | 2023-04-21 | 三棵树(上海)新材料研究有限公司 | High-adhesion UV (ultraviolet) coating on PET (polyethylene terephthalate) film, preparation method of high-adhesion UV coating and preparation method of film material |
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Application publication date: 20150304 |