CN102533014A - Mirror silver coating, mirror silver resin forming mirror silver coating, and preparation methods for mirror silver coating and mirror silver resin - Google Patents
Mirror silver coating, mirror silver resin forming mirror silver coating, and preparation methods for mirror silver coating and mirror silver resin Download PDFInfo
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- CN102533014A CN102533014A CN201210035652XA CN201210035652A CN102533014A CN 102533014 A CN102533014 A CN 102533014A CN 201210035652X A CN201210035652X A CN 201210035652XA CN 201210035652 A CN201210035652 A CN 201210035652A CN 102533014 A CN102533014 A CN 102533014A
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Abstract
The invention relates to a formula of a mirror silver coating, a mirror silver resin forming the mirror silver coating, and the preparation methods for the mirror silver coating and the mirror silver resin. According to the formula, the mirror silver coating consists of the following components in part by mass: 2 to 20 parts of mirror silver resin, 5 to 30 parts of butanol, 5 to 20 parts of isopropanol, 20 to 55 parts of acetic ether, 10 to 20 parts of butyl acetate, 5 to 30 parts of propylene glycol methyl ether acetate, and 0.5 to 3 parts of electroplating silver slurry; the mirror silver coating is high in decoration; compared with the conventional cyanogen-containing electroplating, the method for electroplating by using the mirror silver coating has the advantage that environment is polluted slightly; the selected raw materials have special structures and are low in cost, the mirror silver coating can replace a foreign product completely due to the performance, and the price of the mirror silver coating is more than 50 percent lower than that of an imported product; and the mirror silver coating has a super electroplating effect, is high in adhesion, and can meet the characteristics of a wet to wet spraying process; and a paint film can be machined and cut.
Description
Technical field
The present invention relates to a kind of coating, be specifically related to a kind of minute surface silver coating, also relate to the constituent minute surface silver resin for preparing this minute surface silver coating, the invention still further relates to the preparation method of minute surface silver coating and constituent minute surface silver resin, belong to the technical field of coating.
Background technology
Electrosilvering (minute surface silver) is a kind of very special metallic pigment, has galvanized effect, therefore on market, often it is called by " electrosilvering ".Vacuum aluminum-coated metallic pigment are through the production of special vacuum aluminum plating process, compare the suspension-s that this pigment is made up of very smooth and extremely thin flakey aluminium flake with the aluminium pigment of producing with traditional method (like ball milled).This pigment has high reflecting effect, and its " radially than " is that the ratio of average particle diameter and its thickness is much bigger relatively.
The present domestic sophisticated minute surface silver coating product that still do not have; The product that is mostly U.S. PPG company, German Lankwitzer Lackfabrik company or Taiwan-owned enterprise that present minute surface silver coating uses; Valuable product, and can not satisfy wet spraying requirement of bumping wet technology on the market.Domestic existing production minute surface silver coating is mainly selected the isocyanate resin and the Hydroxylated acrylic resin like soluble cotton, cellulose acetate butyrate (CAB), thermoplastic acrylic and heat curing-type of self-drying type for use; The compactness of paint film is poor; Can lose mirror effect behind the Lacquer finish, Lacquer finish does not then lose the paint film provide protection.
Summary of the invention:
One of technical problem to be solved by this invention is to provide a kind of minute surface silver coating, and this minute surface silver coating is applicable to surfacecti proteon and other applications that needs mirror effect of automobile light metal wheel hub surface high-decoration.
Two of technical problem to be solved by this invention is to prepare the used constituent minute surface silver resin of above-mentioned minute surface silver coating.
Three of technical problem to be solved by this invention is to provide the preparation method of above-mentioned constituent minute surface silver resin.
Four of technical problem to be solved by this invention is to provide the preparation method of above-mentioned minute surface silver coating.
As the minute surface silver coating of first aspect present invention, form by the component of following mass parts:
Minute surface silver resin 2-20 part;
Butanols 5-30 part;
Virahol 5-20 part;
Vinyl acetic monomer 20-55 part;
N-BUTYL ACETATE 10-20 part;
1-Methoxy-2-propyl acetate 5-30 part;
Electrosilvering slurry 0.5-3 part.
The component of preferred mass part of above-mentioned minute surface silver coating is formed:
8 parts of minute surface silver resins;
15 parts in butanols;
8 parts of Virahols;
43.5 parts of vinyl acetic monomers;
15 parts of N-BUTYL ACETATEs;
9 parts of 1-Methoxy-2-propyl acetates;
1.5 parts in electrosilvering slurry.
Constituent minute surface silver resin as second aspect present invention is made up of the component of following mass parts:
Polyvinyl butyral acetal 5-20 part;
Butanols 30-60 part;
YLENE 10-30 part;
N-BUTYL ACETATE 10-30 part.
Preparing method as the constituent minute surface silver resin of third aspect present invention is characterized in that this preparation method may further comprise the steps:
According to turnout, select to disperse equipment and instruments such as cylinder and dispersion machine, select the power of machine, power is high more in principle, is easy to material dispersed more, and guarantees that it is clean, trouble free.
(1) butanols is added in the paint cylinder, rotating speed is transferred to 200r/min, under the whipped state, add polyvinyl butyral acetal, dissolving evenly;
(2) adding is sequentially added into YLENE and N-BUTYL ACETATE under the whipped state, after reinforced the completion, continues stirring 10min;
(3) sampling, by the technical indicator test performance qualified after, filter discharging.
Preparing method as the minute surface silver coating of fourth aspect present invention is characterized in that this preparation method may further comprise the steps:
According to turnout, select to disperse equipment and instruments such as cylinder and dispersion machine, select the power of machine, power is high more in principle, is easy to material dispersed more, and guarantees that it is clean, trouble free.
(1) at room temperature, butanols and Virahol are added in the paint cylinder, rotating speed is transferred to 200r/min, under the whipped state, add the minute surface silver resin, dissolving is even, and it is for use to get homogeneous solution A;
(2) get among step (1) the gained homogeneous solution A, whipped state is adding vinyl acetic monomer and N-BUTYL ACETATE down, after reinforced the completion, continues to stir 10min, gets homogeneous solution B;
(3) in step (2) gained homogeneous solution B, whipped state is the adding 1-Methoxy-2-propyl acetate down, after reinforced the completion, continues to stir 5min, gets homogeneous solution C;
(4) stirring velocity is transferred to 100r/min, in the homogeneous solution C of step (3) gained, slowly add the electrosilvering slurry, the reinforced continued of accomplishing stirs 20min, with the coating-4 viscosity meter test, is controlled under the viscosity of prescription regulation, promptly makes the minute surface silver coating.
In a preferred embodiment of the present invention, said electrosilvering slurry is the Decomet 2008/10 electrosilvering slurry of German Shu Lunke company.
Minute surface silver coating of the present invention has following characteristic:
1. anti-lost silver is effective;
2. supporting sticking power is good, can with epoxy polyester powder, epoxy in be coated with, the supporting use of alcohol acids, acrylic acid or the like baking colored paint;
3. can be used with the thermoset acrylics coating varnish, can dry the back cover liquid varnish by minute surface silver, also wettable wet (Wet to Wet) spraying liquid coating varnish that bumps also can be dried the back cover transparent powder;
4. after the oven dry of minute surface silver, can carry out machining, bright of turning does not have and collapses the lacquer phenomenon;
5. mirror effect is splendid;
6. powder of the qualified end of matching performance, coating varnish, anti-neutral salt spray can reach 400h;
Minute surface silver coating prescription of the present invention is selected homemade minute surface silver resin for use, and price is lower more than 70% than the electrosilvering resin of buying on the market.This minute surface silver resin is selected polyvinyl butyral acetal (polyvinyl Butyral for use; Be abbreviated as PVB) be principal constituent; PVB belongs to thermoplastic resin, second-order transition temperature higher (between 66-84 ℃), and its characteristics are itself to contain a lot of hydroxyls; Can produce the reaction (cross linking reaction) of building bridge to promote performances such as chemical proofing and hardness of film with some thermosetting resins (thermosetting resin); And having the excellent high transparent of filming, elasticity, toughness, anti-highly basic, oil-proofness and pliability are with the low temperature shock-resistance; Because it has special chemical structure, so glass, metal, pottery, plastics, leather and timber etc. are all had the very strong associativity of adhering to.
In order fully to represent the mirror effect of minute surface silver lacquer, should satisfy following condition:
1) base material has smooth, smooth and clean surface.The surface is smooth more, and mirror effect is good more.First priming is wanted on surface for injustice, so that surfacing.Generally can give being coated with one deck varnish, as to metal sense have relatively high expectations, also can give being coated with one deck black primer.
2) film thickness will approach, greatly about 5 μ m.Because minute surface silver is complete " non-floating " metallic pigment, they are arranged in the bottom of base material, and blocked up paint film weakens because of the refraction of light, and then can influence the mirror effect of coating.
3) coating will have enough flowabilities.For the aluminium flake that makes the minute surface Silver pigments is better arranged, hope that paint film can be good at shrinking when solvent evaporates, the rheological of coating plays a part very big here.For pigment particles and base material are arranged in parallel, must be noted that control viscosity.Select allotment solvent composition and low-down resin solids, can reach the result of hope.
4) base material should not possess absorptivity or absorptivity is very low.Because the aluminium flake of electrosilvering slurry is very thin, has absorbefacient base material and can cause the irregular of pigment orientation, and then influence the mirror effect of coating.Have absorbefacient base material if must select for use, should on substrate surface, feel secure earlier.
5) addition of electrosilvering slurry: at 1-6%, actual amount is please tested voluntarily according to the formula system suggestion.Generally speaking, lower pigment addition often can obtain mirror effect preferably, because the aluminium flake of electrosilvering is very thin, too high pigment addition can cause the accumulation of aluminium flake and then cause the aluminium flake irregular alignment, has influenced mirror effect on the contrary.Certainly low excessively pigment addition also can influence mirror effect because of hiding lack.Consider the expensive price of electrosilvering slurry simultaneously, addition is no more than 3% in principle.
6) to note the control of the air pressure and the coating cloud of spray gun during spraying application.Generally speaking, the air pressure of spray gun is lower than the common aluminium powder paint of spray.
7) the electrosilvering slurry should add in the final stage of paint manufacturing process, and adopts low speed, low-shearing power hybrid mode preparation coating.
The general selective volatilization property of solvent faster, but too fast evaporable solvent composition is unfavorable for the outward appearance of electrosilvering lacquer, because there is not time enough well to arrange by aluminium flake.Alcoholic solvent will avoid the use of in principle, must use also should be limited on the very small addition.But consider that polyvinyl butyral acetal and alcoholic solvent compatibility are good, when design minute surface silver prescription, must adjust the blend proportion of alcoholic solvent.
Embodiment
In order to make technique means of the present invention, creation characteristic, to reach purpose and effect and be easy to understand and understand,, further set forth the present invention below in conjunction with specific embodiment.
One, the preparation of minute surface silver resin
The prescription of the minute surface silver resin of each embodiment preparation is seen table 1:
Table 1: the prescription quality umber of minute surface silver resin is in mass fraction
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Polyvinyl butyral acetal | 10 | 5 | 13 | 16 | 20 |
| Butanols | 50 | 60 | 45 | 40 | 30 |
| YLENE | 20 | 20 | 30 | 19 | 20 |
| N-BUTYL ACETATE | 20 | 15 | 12 | 25 | 30 |
(2) preparation process
According to turnout, select to disperse equipment and instruments such as cylinder and dispersion machine, select the power of machine, power is high more in principle, is easy to material dispersed more, and guarantees that it is clean, trouble free.
(1) butanols is added in the paint cylinder, rotating speed is transferred to 200r/min, under the whipped state, add polyvinyl butyral acetal, dissolving evenly;
(2) adding is sequentially added into YLENE and N-BUTYL ACETATE under the whipped state, after reinforced the completion, continues stirring 10min;
(3) sampling, by the technical indicator test performance qualified after, filter discharging.
The minute surface silver resin performance index that each embodiment obtains are seen table 2.
Table 2: minute surface silver resin inspection technology index
Two, the making of minute surface silver coating
Embodiment 6
(1) formulation for coating material
The minute surface silver resin 8kg of embodiment 1 preparation;
Butanols 15kg;
Virahol 8kg;
Vinyl acetic monomer 43.5kg;
N-BUTYL ACETATE 15kg;
1-Methoxy-2-propyl acetate 9kg;
Electrosilvering slurry 1.5kg.
(2) preparation process
According to turnout, select to disperse equipment and instruments such as cylinder and dispersion machine, select the power of machine, power is high more in principle, is easy to material dispersed more, and guarantees that it is clean, trouble free.
(1) at room temperature, in butanols and Virahol adding paint cylinder, rotating speed is transferred to 200r/min, under the whipped state, add the minute surface silver resin of embodiment 1 preparation, dissolving is even, and it is for use to get homogeneous solution A;
(2) get among step (1) the gained homogeneous solution A, whipped state is adding vinyl acetic monomer and N-BUTYL ACETATE down, after reinforced the completion, continues to stir 10min, gets homogeneous solution B;
(3) in step (2) gained homogeneous solution B, whipped state is the adding 1-Methoxy-2-propyl acetate down, after reinforced the completion, continues to stir 5min, gets homogeneous solution C;
(4) stirring velocity is transferred to 100r/min, in the homogeneous solution C of step (3) gained, slowly add the electrosilvering slurry, the reinforced continued of accomplishing stirs 20min, with the coating-4 viscosity meter test, is controlled under the viscosity of prescription regulation, promptly makes the minute surface silver coating.
Embodiment 7
(1) formulation for coating material
The minute surface silver resin 4kg of embodiment 2 preparations;
Butanols 12kg;
Virahol 6kg;
Vinyl acetic monomer 50kg;
N-BUTYL ACETATE 17.8kg;
1-Methoxy-2-propyl acetate 9kg;
Electrosilvering slurry 1.2kg.
(2) preparation process
According to turnout, select to disperse equipment and instruments such as cylinder and dispersion machine, select the power of machine, power is high more in principle, is easy to material dispersed more, and guarantees that it is clean, trouble free.
(1) at room temperature, butanols and Virahol are added in the paint cylinder.Rotating speed is transferred to 200r/min, under the whipped state, add the minute surface silver resin of embodiment 2 preparations, dissolving is even, and it is for use to get homogeneous solution A;
(2) get among step (1) the gained homogeneous solution A, whipped state is adding vinyl acetic monomer and N-BUTYL ACETATE down, after reinforced the completion, continues to stir 10min, gets homogeneous solution B;
(3) in step (2) gained homogeneous solution B, whipped state is the adding 1-Methoxy-2-propyl acetate down, after reinforced the completion, continues to stir 5min, gets homogeneous solution C;
(4) stirring velocity is transferred to 100r/min, in the homogeneous solution C of step (3) gained, slowly add the electrosilvering slurry, the reinforced continued of accomplishing stirs 20min, with the coating-4 viscosity meter test, is controlled under the viscosity of prescription regulation, promptly makes the minute surface silver coating.
Embodiment 8
(1) formulation for coating material
The minute surface silver resin 10kg of embodiment 3 preparations;
Butanols 10kg;
Virahol 6kg;
Vinyl acetic monomer 54kg;
N-BUTYL ACETATE 12.5kg;
1-Methoxy-2-propyl acetate 5kg;
Electrosilvering slurry 2.5kg.
(2) preparation process
According to turnout, select to disperse equipment and instruments such as cylinder and dispersion machine, select the power of machine, power is high more in principle, is easy to material dispersed more, and guarantees that it is clean, trouble free.
(1) at room temperature, butanols and Virahol are added in the paint cylinder.Rotating speed is transferred to 200r/min, under the whipped state, add the minute surface silver resin of embodiment 3 preparations, dissolving is even, and it is for use to get homogeneous solution A;
(2) get among step (1) the gained homogeneous solution A, whipped state is adding vinyl acetic monomer and N-BUTYL ACETATE down, after reinforced the completion, continues to stir 10min, gets homogeneous solution B;
(3) in step (2) gained homogeneous solution B, whipped state is the adding 1-Methoxy-2-propyl acetate down, after reinforced the completion, continues to stir 5min, gets homogeneous solution C;
(4) stirring velocity is transferred to 100r/min, in the homogeneous solution C of step (3) gained, slowly add the electrosilvering slurry, the reinforced continued of accomplishing stirs 20min, with the coating-4 viscosity meter test, is controlled under the viscosity of prescription regulation, promptly makes the minute surface silver coating.
Embodiment 9
(1) formulation for coating material
The minute surface silver resin 6kg of embodiment 4 preparations;
Butanols 20kg;
Virahol 10kg;
Vinyl acetic monomer 22kg;
N-BUTYL ACETATE 11kg;
1-Methoxy-2-propyl acetate 30kg;
Electrosilvering slurry 1.0kg.
(2) preparation process
According to turnout, select to disperse equipment and instruments such as cylinder and dispersion machine, select the power of machine, power is high more in principle, is easy to material dispersed more, and guarantees that it is clean, trouble free.
(1) at room temperature, butanols and Virahol are added in the paint cylinder.Rotating speed is transferred to 200r/min, under the whipped state, add the minute surface silver resin of embodiment 4 preparations, dissolving is even, and it is for use to get homogeneous solution A;
(2) get among step (1) the gained homogeneous solution A, whipped state is adding vinyl acetic monomer and N-BUTYL ACETATE down, after reinforced the completion, continues to stir 10min, gets homogeneous solution B;
(3) in step (2) gained homogeneous solution B, whipped state is the adding 1-Methoxy-2-propyl acetate down, after reinforced the completion, continues to stir 5min, gets homogeneous solution C;
(4) stirring velocity is transferred to 100r/min, in the homogeneous solution C of step (3) gained, slowly add the electrosilvering slurry, the reinforced continued of accomplishing stirs 20min, with the coating-4 viscosity meter test, is controlled under the viscosity of prescription regulation, promptly makes the minute surface silver coating.
Embodiment 10
(1) formulation for coating material
The minute surface silver resin 13kg of embodiment 5 preparations;
Butanols 8kg;
Virahol 15kg;
Vinyl acetic monomer 30kg;
N-BUTYL ACETATE 19kg;
1-Methoxy-2-propyl acetate 13kg;
Electrosilvering slurry 2kg.
(2) preparation process
According to turnout, select to disperse equipment and instruments such as cylinder and dispersion machine, select the power of machine, power is high more in principle, is easy to material dispersed more, and guarantees that it is clean, trouble free.
(1) at room temperature, butanols and Virahol are added in the paint cylinder.Rotating speed is transferred to 200r/min, under the whipped state, add the minute surface silver resin of embodiment 5 preparations, dissolving is even, and it is for use to get homogeneous solution A;
(2) get among step (1) the gained homogeneous solution A, whipped state is adding vinyl acetic monomer and N-BUTYL ACETATE down, after reinforced the completion, continues to stir 10min, gets homogeneous solution B;
(3) in step (2) gained homogeneous solution B, whipped state is the adding 1-Methoxy-2-propyl acetate down, after reinforced the completion, continues to stir 5min, gets homogeneous solution C;
(4) stirring velocity is transferred to 100r/min, in the homogeneous solution C of step (3) gained, slowly add the electrosilvering slurry, the reinforced continued of accomplishing stirs 20min, with the coating-4 viscosity meter test, is controlled under the viscosity of prescription regulation, promptly makes the minute surface silver coating.
The performance index of the minute surface silver coating of each embodiment preparation
More than show and described ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; The present invention is not restricted to the described embodiments; That describes in the foregoing description and the specification sheets just explains principle of the present invention; The present invention also has various changes and modifications under the prerequisite that does not break away from spirit and scope of the invention, and these variations and improvement all fall in the scope of requirement protection of the present invention.The scope that the present invention requires to protect is defined by appending claims and equivalent thereof.
Claims (5)
1. a minute surface silver coating is characterized in that, should be made up of the component of following mass parts:
Minute surface silver resin 2-20 part;
Butanols 5-30 part;
Virahol 5-20 part;
Vinyl acetic monomer 20-55 part;
N-BUTYL ACETATE 10-20 part;
1-Methoxy-2-propyl acetate 5-30 part;
Electrosilvering slurry 0.5-3 part.
2. minute surface silver coating according to claim 1 is characterized in that, is made up of the component of following mass parts:
8 parts of minute surface silver resins;
15 parts in butanols;
8 parts of Virahols;
43.5 parts of vinyl acetic monomers;
15 parts of N-BUTYL ACETATEs;
9 parts of 1-Methoxy-2-propyl acetates;
1.5 parts in electrosilvering slurry.
3. a constituent minute surface silver resin for preparing claim 1 or 2 described minute surface silver coatings is characterized in that, is made up of the component of following mass parts:
Polyvinyl butyral acetal 5-20 part;
Butanols 30-60 part;
YLENE 10-30 part;
N-BUTYL ACETATE 10-30 part.
4. the preparation method of the described constituent minute surface of claim 3 silver resin is characterized in that, is made up of following steps below this preparation method:
(1) butanols is added in the paint cylinder, rotating speed is transferred to 200r/min, under the whipped state, add polyvinyl butyral acetal, dissolving evenly;
(2) adding is sequentially added into YLENE and N-BUTYL ACETATE under the whipped state, after reinforced the completion, continues stirring 10min;
(3) sampling, by the technical indicator test performance qualified after, filter discharging.
5. the preparation method of each described minute surface silver coating of claim 1-2 is characterized in that, this preparation method may further comprise the steps:
(1) at room temperature, butanols and Virahol are added in the paint cylinder.Rotating speed is transferred to 200r/min, under the whipped state, add the minute surface silver resin, dissolving is even, and it is for use to get homogeneous solution A;
(2) get among step (1) the gained homogeneous solution A, whipped state is adding vinyl acetic monomer and N-BUTYL ACETATE down, after reinforced the completion, continues to stir 10min, gets homogeneous solution B;
(3) in step (2) gained homogeneous solution B, whipped state is the adding 1-Methoxy-2-propyl acetate down, after reinforced the completion, continues to stir 5min, gets homogeneous solution C;
(4) stirring velocity is transferred to 100r/min, in the homogeneous solution C of step (3) gained, slowly add the electrosilvering slurry, the reinforced continued of accomplishing stirs 20min, with the coating-4 viscosity meter test, is controlled under the viscosity of prescription regulation, promptly makes the minute surface silver coating.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210035652XA CN102533014A (en) | 2012-02-16 | 2012-02-16 | Mirror silver coating, mirror silver resin forming mirror silver coating, and preparation methods for mirror silver coating and mirror silver resin |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210035652XA CN102533014A (en) | 2012-02-16 | 2012-02-16 | Mirror silver coating, mirror silver resin forming mirror silver coating, and preparation methods for mirror silver coating and mirror silver resin |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102745016A (en) * | 2012-07-24 | 2012-10-24 | 福建申利卡铝业发展有限公司 | Manufacture technology of vacuum-electroplated glossy face light ring |
| CN103483960A (en) * | 2013-09-30 | 2014-01-01 | 东来涂料技术（上海）有限公司 | Automotive upholstery paint with electroplating effect and preparation method of paint |
| CN104479444A (en) * | 2014-12-05 | 2015-04-01 | 广州致辉精化股份有限公司 | Boiling-resistant mirror resin and preparation method thereof |
| CN105669906A (en) * | 2016-03-09 | 2016-06-15 | 广州伊德尔化学科技有限公司 | Alcohol washing-resistant high temperature resistant mirror-like silver resin and preparation method thereof |
| CN106068468A (en) * | 2013-12-30 | 2016-11-02 | 艾利丹尼森公司 | The open pearl method of high reflectance and material |
| CN106675263A (en) * | 2016-12-22 | 2017-05-17 | 东来涂料技术（上海）有限公司 | Special effect paint containing rainbow effect pigment paste and preparation method thereof |
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| CN107141857A (en) * | 2017-05-22 | 2017-09-08 | 上海天地涂料有限公司 | A kind of minute surface silver resin and preparation method thereof |
| CN107245262A (en) * | 2017-05-26 | 2017-10-13 | 上海天地涂料有限公司 | A kind of minute surface silver coating and preparation method thereof |
| CN114163885A (en) * | 2021-12-23 | 2022-03-11 | 深圳邦荣汽车用品有限公司 | Electrosilvering paint, preparation method and application |
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| CN102745016B (en) * | 2012-07-24 | 2015-11-18 | 福建申利卡铝业发展有限公司 | The manufacture craft of vacuum plating bright lightweight circle |
| CN102745016A (en) * | 2012-07-24 | 2012-10-24 | 福建申利卡铝业发展有限公司 | Manufacture technology of vacuum-electroplated glossy face light ring |
| CN103483960B (en) * | 2013-09-30 | 2016-12-07 | 东来涂料技术（上海）有限公司 | A kind of automotive upholstery coating with electroplating effect and preparation method thereof |
| CN103483960A (en) * | 2013-09-30 | 2014-01-01 | 东来涂料技术（上海）有限公司 | Automotive upholstery paint with electroplating effect and preparation method of paint |
| CN106068468A (en) * | 2013-12-30 | 2016-11-02 | 艾利丹尼森公司 | The open pearl method of high reflectance and material |
| CN104479444A (en) * | 2014-12-05 | 2015-04-01 | 广州致辉精化股份有限公司 | Boiling-resistant mirror resin and preparation method thereof |
| CN105669906A (en) * | 2016-03-09 | 2016-06-15 | 广州伊德尔化学科技有限公司 | Alcohol washing-resistant high temperature resistant mirror-like silver resin and preparation method thereof |
| CN105669906B (en) * | 2016-03-09 | 2017-11-21 | 广州伊德尔化学科技有限公司 | A kind of resistance to alcohol is washed, High temperature resistance mirror-like silver resin and preparation method thereof |
| CN106675263A (en) * | 2016-12-22 | 2017-05-17 | 东来涂料技术（上海）有限公司 | Special effect paint containing rainbow effect pigment paste and preparation method thereof |
| CN106700876A (en) * | 2016-12-23 | 2017-05-24 | 安徽康瑞高科新材料技术工程有限公司 | Water-boiling-resisting mirror-surface silver baking finish capable of being recoated and preparation method of water-boiling-resisting mirror-surface silver baking finish |
| CN107141857A (en) * | 2017-05-22 | 2017-09-08 | 上海天地涂料有限公司 | A kind of minute surface silver resin and preparation method thereof |
| CN107245262A (en) * | 2017-05-26 | 2017-10-13 | 上海天地涂料有限公司 | A kind of minute surface silver coating and preparation method thereof |
| CN114163885A (en) * | 2021-12-23 | 2022-03-11 | 深圳邦荣汽车用品有限公司 | Electrosilvering paint, preparation method and application |
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Application publication date: 20120704 |