CN101157813B - Electroplating effect imitated plastic paint and preparation method, diluent and process of using same - Google Patents
Electroplating effect imitated plastic paint and preparation method, diluent and process of using same Download PDFInfo
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- CN101157813B CN101157813B CN2007100770482A CN200710077048A CN101157813B CN 101157813 B CN101157813 B CN 101157813B CN 2007100770482 A CN2007100770482 A CN 2007100770482A CN 200710077048 A CN200710077048 A CN 200710077048A CN 101157813 B CN101157813 B CN 101157813B
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Abstract
The invention discloses a plastic paint with simulated electroplating effect. The composition and the weight ratio of the invention are as follows: 30 to 45 of acrylic resin with 50 percent of solid content and 70 to 90 DEG C of Tg, 20 to 30 of cellulose acetate butyrate with 20 percent of solid content, 8 to 12 of triad copolymer vinyl chloride-acetate resin with 30 percent of solid content, 6 to 10 of non-floating aluminum and silver pulp with an average diameter less than or equal to 20 Mum, 0.3 to 0.5 of dispersant, 0.2 to 0.4 of flatting agent, 0.4 to 0.6 anti-settling agent, 6.0 to 10.0 of toluene, 3.5 to 6.0 of ethyl acetate, 3.5 to 6.0 methy isobutyl ketone, 3.0 to 5.0 of isobutanol and 4.0 to 7.0 of glycol butyl ether. The special diluent of the invention, according to the weight ratio, is made from the following components evenly mixed: 20 of white gas, 10 of toluene, 22 of ethyl acetate, 15 of acetone, 25 of isobutanol and 8 of glycol butyl ether. The main paint which comprises the composition and the diluent are evenly mixed according to the ratio of 1: 2-3, then the mixture is used for spray coating; the metallic appearance of the paint film obtained is very close to the effect of the electroplating, and the paint film has good alcohol resistance with high hardness and strong wear resistance, and also has simple process. The aluminum and silver pulp used is a common type, the cost of which is only 5 percent to 10 percent of the simulated electroplating aluminum and silver pulp and about 2 percent of electrosilvering.
Description
Technical field
The present invention relates to a kind of plastic paint, especially relate to acrylic coating for plastics of a kind of imitative electroplating effect and preparation method thereof, the invention still further relates to the thinner of this plastic paint special use, and using method.
Background technology
The general acrylic coating for plastics that adopts of the surface protection of plastics such as the plastic casing of electric equipment products, plastic toy, auto parts machinery and decoration; wherein using maximum is aluminium powder paint; select different aluminium-silver slurrys for use; paint film can reach different metal effects, thereby satisfies different aesthetic requirements, realization individual decoration effect.The noblest beautiful electroplating effect true to nature that is to use the electrosilvering slurry to make, but electrosilvering slurry price is extremely expensive, has limited its widespread use, and, need first spray black priming paint when starching the electrosilvering plastic paint construction made from electrosilvering; Even use the imitative aluminium-silver slurry of electroplating, cost is also very high, uses to be restricted equally.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of acrylic coating for plastics that uses cheap common aluminium-silver slurry to reach imitative electroplating effect, and its manufacture method also is provided, and the special diluting agent that is used with this plastic paint, and the method for using.
For addressing the above problem, the invention provides a kind of plastic paint of imitative electroplating effect, it is characterized in that: its component and weight proportion are as follows:
Solids content is that 50% Tg is 70～90 ℃ acrylic resin 30-45
Solids content is 20% cellulose acetate butyrate 20-30
Solids content is 30% terpolymer vinyl chloride-vinyl acetate resin 8-12
The non-floating type aluminium-silver slurry 6-10 of median size≤20 μ m
Dispersion agent 0.3-0.5
Flow agent 0.2-0.4
Anti-settling agent 0.4-0.6
Toluene 6.0～10.0
Ethyl acetate 3.5～6.0
Methyl iso-butyl ketone (MIBK) 3.5～6.0
Isopropylcarbinol 3.0～5.0
Ethylene glycol monobutyl ether 4.0～7.0.
Further aluminium-silver slurry described in the technical scheme is preferably 1: 1 with toluene by weight ratio in the solvent.
Each component is preferably as follows weight proportion:
Solids content is that 50% Tg is 70～90 ℃ a acrylic resin 37
Solids content is 20% cellulose acetate butyrate 21
Solids content is 30% terpolymer vinyl chloride-vinyl acetate resin 10
The non-floating type aluminium-silver slurry 8.5 of median size≤20 μ m
Dispersion agent 0.4
Flow agent 0.3
Anti-settling agent 0.5
Toluene 8.5
Ethyl acetate 4.6
Methyl iso-butyl ketone (MIBK) 5.0
Isopropylcarbinol 3.0
Ethylene glycol monobutyl ether 4.1.
Described solids content is that 50% acrylic resin is to be that 25: 10: 15 butylacetate, butanone and the dissolving of ethylene glycol monobutyl ether mixing solutions forms with weight ratio.
Described solids content is that 20% cellulose acetate butyrate is to be that the mixed solvent dissolving of 20: 40: 20 butanone, butylacetate and ethylene glycol monobutyl ether forms with weight ratio;
Described solids content is that 30% terpolymer vinyl chloride-vinyl acetate resin is to be dissolved into the resin liquid that forms with butanone.
The brilliant white silver aluminium-silver slurry that the preferred content of aluminium powder of described aluminium-silver slurry is 65%, particle diameter is 8-15 μ m.
Described dispersion agent is the solution of 50% weight percentage of the unsaturated polycarboxylic acid polymkeric substance of lower molecular weight and the two mixture of organo-siloxane interpolymer, and wherein solvent is that weight ratio is 9: 1 the dimethylbenzene and the mixed solution of diisobutyl ketone;
Described flow agent is polyether-modified polydimethylsiloxane 12.5% solution, and wherein solvent is that weight ratio is 7: 2 the dimethylbenzene and the mixed solution of ethyleneglycol monophenylether; Described anti-settling agent is 20% dispersion liquid of polyamide wax.
The present invention also provides a kind of special diluting agent of plastic paint of imitative electroplating effect, it is characterized in that, is made of the component of following weight ratio:
White spirit 20
Toluene 10
Ethyl acetate 22
Acetone 15
Isopropylcarbinol 25
Ethylene glycol monobutyl ether 8.
The present invention also provides the method for the plastic paint that uses described imitative electroplating effect, it is characterized in that, plastic paint and the thinner that at first will imitate electroplating effect mix according to weight ratio 1: 2～3, carry out spraying application then, oven dry in 30 minutes promptly obtains the paint film of imitative electroplating effect through seasoning in 24 hours or 60～80 ℃ under the normal temperature;
Wherein,
Described thinner is made of the component of following weight proportion:
White spirit 20
Toluene 10
Ethyl acetate 22
Acetone 15
Isopropylcarbinol 25
Ethylene glycol monobutyl ether 8.
Imitative electroplating effect plastic paint beneficial effect by said components and weight proportion preparation is as follows:
The used cellulose acetate butyrate of the present invention has intensive to align effect to aluminium powder, make paint application after aluminium powder can align rapidly, like this, use the aluminium-silver slurry of common cheapness also can form metal sense intensive electroplating effect paint film; Because acrylic resin second-order transition temperature Tg is 70～90 ℃, makes paint film have higher hardness, ethanol-tolerant is good, and scoring resistance is good, and wear resistant is good; Owing to use vinyl chloride-vinyl acetate resin to cooperate with acrylic resin, increased sticking power to PVC, ABS and PC plastics, increase ply adhesion, make paint film have extraordinary alcohol resistance, the ethanol-tolerant wiping is above 500 times; The plastic paint of the imitative electroplating effect of the present invention has adopted non-floating type aluminium-silver slurry, has fabulous degree of staining, very strong opacifying power, coating metal is effective, select median size≤20 μ m, further select content of aluminium powder about 65%, the brilliant white silver of particle diameter 8-15 μ m in the technical scheme, narrow diameter distribution, aluminium powder particle diameter are little, can obtain the strong paint film of electroplating effect.
Toluene, ethyl acetate, methyl iso-butyl ketone (MIBK), isopropylcarbinol, the ethylene glycol monobutyl ether solvent of doing in component uses, these several solvent collocation are used and can be guaranteed that not only various resins are had solvency power preferably, simultaneously because their rate of volatilization is different, in the construction drying process, form good rate of volatilization gradient, guarantee progressively volatilization more uniformly of solvent, help forming good paint film.
The plastic paint of imitative electroplating effect of the present invention, used aluminium-silver slurry are common aluminium-silver slurry, and cost is imitative 5～10% of the aluminium-silver slurry of electroplating, and is about 2% of electrosilvering, has saved cost greatly.And use operation of the present invention simple, directly can be effective in frosting spraying, and need not to resemble electrosilvering starch first spray black priming paint.
In further technical scheme, adopt the equivalent solvent toluene when aluminium-silver slurry of the present invention is pre-dispersed, dispersion agent helps the aluminium powder dispersion and aligns, and prevents that paint film from growing dim; The flow agent back rapid levelling of coating surface and have smooth hand feeling that helps constructing; And anti-settling agent is selected 20% dispersion liquid of polyamide wax for use, can adopt the 6900-HV of Japanese Supreme Being Si Balong company, not only can prevent the sedimentation of aluminium powder in the storage process, also can prevent the aluminium powder rapid subsidence during construction, certain to aligning of aluminium powder simultaneously booster action.
The whole rate of volatilization of special diluting agent provided by the invention is very fast, and good rate of volatilization gradient is arranged, and helps paint film rapid drying and aluminium powder and aligns, thereby form the paint film that metal sense intensive is similar to electroplating effect.Wherein the use of ethylene glycol monobutyl ether also has the effect that prevents that the wet weather paint film from turning white.The solvent evaporates speed that solvency power is strong in the diluent formulation is very fast relatively, and end phenomenon appears stinging in the ABS that can prevent more weak plastic bottom material such as PS or be mixed with reclaimed materials when construction.
Preparation technology of the present invention, simple, the realization easily of using method.
Embodiment
Each component of the present invention is all selected currently available products for use, and the plastic paint master of imitative electroplating effect coats with lacquer each embodiment proportioning and sees Table shown in one:
Table one
| Sequence number | Material name | Producer and model | Embodiment 1 (Kg) | Embodiment 2 (Kg) | Embodiment 3 (Kg) |
| 1 | 50% acrylic resin | The BR113 of Mitsubishi | 30.0 | 37.0 | 40.0 |
| 2 | 20% cellulose acetate butyrate | Yi Shiman CAB381-20 | 25.0 | 21.0 | 20.0 |
| 3 | 30% terpolymer vinyl chloride-vinyl acetate resin | The triumphant E15/45M of Germany's prestige | 12.0 | 10.0 | 8.0 |
| 4 | Aluminium-silver slurry | The emerging ZX1065 of family | 6.0 | 8.5 | 9.2 |
| 5 | Dispersion agent | BYK-P104S | 0.3 | 0.4 | 0.5 |
| 6 | Flow agent | BYK306 | 0.2 | 0.3 | 0.4 |
| 7 | Anti-settling agent | 6900HV | 0.4 | 0.5 | 0.6 |
| 8 | Toluene | 6.0 | 8.5 | 9.2 | |
| 9 | Ethyl acetate | 5.0 | 4.6 | 4.0 | |
| 10 | Methyl iso-butyl ketone (MIBK) | 5.0 | 5.0 | 4.2 | |
| 11 | Isopropylcarbinol | 3.1 | 3.0 | 3.5 | |
| 12 | Ethylene glycol monobutyl ether | 6.0 | 4.1 | 5.0 |
[0057]Wherein, 50% acrylic resin can be selected solid resin for use, is that solid resin is dissolved into concentration expressed in percentage by weight is 50% resin liquid for the mixing solutions of 25: 10: 15 butylacetate, butanone and ethylene glycol monobutyl ether with weight ratio in advance with solid resin; Can select directly also that to contain admittedly be 50% resin liquid for use.Aforesaid propylene acid resin second-order transition temperature Tg is 70～90 ℃, has higher hardness, and ethanol-tolerant is good, and scoring resistance is good, if Tg crosses low then difference of hardness, ethanol-tolerant is bad, and scoring resistance is poor, the too high paint film cracking that then is prone to of Tg.
First before joining lacquer is that the mixing solutions of 20: 40: 20 butanone, butylacetate and ethylene glycol monobutyl ether dissolves cellulose acetate butyrate with weight ratio, obtains the resin liquid that the concentration expressed in percentage by weight shown in the table one is 20% cellulose acetate butyrate.
With butanone the terpolymer vinyl chloride-vinyl acetate resin is dissolved before joining lacquer, obtaining the weight percentage shown in the table one is that 30% resin liquid is standby.
Aluminium-silver slurry is non-floating type, selecting content of aluminium powder general on the market for use is 65% aluminium-silver slurry, the aluminium powder median size is generally more than 5 μ m in this aluminium-silver slurry, preferred median size 8～15 μ m of the present invention, size distribution is narrow more good more, the aluminium powder particle diameter is more little, aluminium powder is white more, the metal sense of aluminium powder own is strong more, and the paint film electroplating effect is true to nature more; As then the paint film electroplating effect is brighter to select the stronger tenderly white silver of metal sense, and then the paint film electroplating effect is more gloomy as the thin silver of choice criteria, should select different aluminium-silver slurrys for use according to the model effect.
Dispersion agent is selected the product B YK-P104S of German BYK company for use, and flow agent is selected the product B YK306 of German BYK company for use, and anti-settling agent adopts the 6900-HV of Japanese Supreme Being Si Balong company.
Below in conjunction with specific embodiment technical scheme of the present invention is described.
Embodiment 1
The plastic paint master lacquer of the imitative electroplating effect of preparation the present invention:
Get each component according to weight shown in the embodiment in the table one 1, the preparation method is according to following steps:
Step 1: aluminium-silver slurry pre-dispersed: get aluminium-silver slurry, toluene and dispersant, carry out stirring at low speed to there not being the aluminum particle that gathers, standby;
Step 2: with 50% acrylic resin, 20% cellulose acetate butyrate, 30% vinyl chloride-vinyl acetate resin, mix, add anti-settling agent then, high-speed stirring was disperseed 15 minutes again, add flow agent, ethyl acetate, methyl iso-butyl ketone (MIBK), isopropylcarbinol and ethylene glycol monobutyl ether then by weight, stir;
Step 3: pre-dispersed good aluminium-silver slurry in the above step 1 is joined under stirring at low speed in the paint vehicle that step 2 obtains, add and continue stirring at low speed 10～15 minutes, filter the plastic paint that promptly obtains imitative electroplating effect to being uniformly dispersed.
The thinner that preparation is special-purpose:
1. white spirit 20
2. toluene 10
3. ethyl acetate 22
4. acetone 15
5. isopropylcarbinol 25
6. ethylene glycol monobutyl ether 8
According to above-listed weight proportion, above-mentioned six kinds of solvents are joined in the proportion container, stirring at low speed 5～8 minutes, 400 mesh filter screens filter and package and promptly obtain special diluting agent.
The plastic paint master lacquer of the imitative electroplating effect of the present invention is mixed according to weight ratio with above-mentioned special diluting agent at 1: 3, spray, under the normal temperature through seasoning in 24 hours or 60～80 ℃ oven dry in 30 minutes, obtain paint film, performance test results (thickness 15-20 μ m) is shown in 1 corresponding data of embodiment in the table two.
Embodiment 2
Prepare the plastic paint master lacquer of imitative electroplating effect with specified embodiment 2 each composition weight, repetition embodiment 1 described method (only each composition weight changes) in the table one; The component, proportioning and the preparation method that repeat thinner among the embodiment 1 prepare thinner; To lead lacquer and mix at 1: 2.5 according to weight ratio with thinner, spraying then, with obtaining paint film after the embodiment 1 described method drying, performance test results (thickness 15-20 μ m) is shown in 2 corresponding datas of embodiment in the table two.
Embodiment 3
Prepare the plastic paint master lacquer of imitative electroplating effect with specified embodiment 2 each composition weight, repetition embodiment 1 described method (only each composition weight changes) in the table one; The component, proportioning and the preparation method that repeat thinner among the embodiment 1 prepare thinner; To lead lacquer and mix at 1: 2.0 according to weight ratio with thinner, spraying then, with obtaining paint film after the embodiment 1 described method drying, performance test results (thickness 15-20 μ m) is shown in 3 corresponding datas of embodiment in the table two.
Table two
| Sequence number | Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| 1 | Sticking power hundred lattice tests (%) | 100 | 100 | 100 |
| 2 | Hardness (pencil) | H | H | H |
| 3 | 95% alcohol wipe (〉=inferior) | 800 | 600 | 500 |
| 4 | The coating surface metal effect | Near electroplating effect | Electroplating effect is true to nature | Near electroplating effect |
Claims (9)
1. the plastic paint of an imitative electroplating effect is characterized in that, its component and weight proportion are as follows:
Solids content is that 50% Tg is 70～90 ℃ acrylic resin 30-45
Solids content is 20% cellulose acetate butyrate 20-30
Solids content is 30% terpolymer vinyl chloride-vinyl acetate resin 8-12
The non-floating type aluminium-silver slurry 6-10 of median size≤20 μ m
Dispersion agent 0.3-0.5
Flow agent 0.2-0.4
Anti-settling agent 0.4-0.6
Toluene 6.0～10.0
Ethyl acetate 3.5～6.0
Methyl iso-butyl ketone (MIBK) 3.5～6.0
Isopropylcarbinol 3.0～5.0
Ethylene glycol monobutyl ether 4.0～7.0.
2. the plastic paint of imitative electroplating effect according to claim 1 is characterized in that, described aluminium-silver slurry is 1: 1 with the toluene by weight ratio.
3. the plastic paint of imitative electroplating effect according to claim 1 is characterized in that, each component is according to following weight proportion:
Solids content is that 50% Tg is 70～90 ℃ a acrylic resin 37
Solids content is 20% cellulose acetate butyrate 21
Solids content is 30% terpolymer vinyl chloride-vinyl acetate resin 10
The non-floating type aluminium-silver slurry 8.5 of median size≤20 μ m
Dispersion agent 0.4
Flow agent 0.3
Anti-settling agent 0.5
Toluene 8.5
Ethyl acetate 4.6
Methyl iso-butyl ketone (MIBK) 5.0
Isopropylcarbinol 3.0
Ethylene glycol monobutyl ether 4.1.
4. according to the plastic paint of each described imitative electroplating effect of claim 1～3, it is characterized in that described solids content is that 50% acrylic resin is to be that 25: 10: 15 butylacetate, butanone and the dissolving of ethylene glycol monobutyl ether mixing solutions forms with weight ratio.
5. according to the plastic paint of each described imitative electroplating effect of claim 1～3, it is characterized in that described solids content is that 20% cellulose acetate butyrate is to be that the mixed solvent dissolving of 20: 40: 20 butanone, butylacetate and ethylene glycol monobutyl ether forms with weight ratio; Described solids content is that 30% terpolymer vinyl chloride-vinyl acetate resin is to be dissolved into the resin liquid that forms with butanone.
6. according to the plastic paint of each described imitative electroplating effect of claim 1～3, it is characterized in that the brilliant white silver aluminium-silver slurry that described aluminium-silver slurry aluminium powder content is 65%, particle diameter is 8-15 μ m.
7. according to the plastic paint of each described imitative electroplating effect of claim 1～3, it is characterized in that, described dispersion agent is the solution of 50% weight percentage of the unsaturated polycarboxylic acid polymkeric substance of lower molecular weight and the two mixture of organo-siloxane interpolymer, and wherein solvent is that weight ratio is 9: 1 the dimethylbenzene and the mixed solution of diisobutyl ketone; Described flow agent is polyether-modified polydimethylsiloxane 12.5% solution, and wherein solvent is that weight ratio is 7: 2 the dimethylbenzene and the mixed solution of ethyleneglycol monophenylether; Described anti-settling agent is 20% dispersion liquid of polyamide wax.
8. the special diluting agent of the plastic paint of the described imitative electroplating effect of claim 1 is characterized in that, is made of the component of following weight proportion:
White spirit 20
Toluene 10
Ethyl acetate 22
Acetone 15
Isopropylcarbinol 25
Ethylene glycol monobutyl ether 8.
9. use the method for the plastic paint of the described imitative electroplating effect of claim 1, it is characterized in that, plastic paint and the thinner that at first will imitate electroplating effect mix according to weight ratio 1: 2～3, carry out spraying application then, oven dry in 30 minutes promptly obtains the paint film of imitative electroplating effect through seasoning in 24 hours or 60～80 ℃ under the normal temperature; Wherein, described thinner is made of the component of following weight proportion:
White spirit 20
Toluene 10
Ethyl acetate 22
Acetone 15
Isopropylcarbinol 25
Ethylene glycol monobutyl ether 8.
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| CN101157813B true CN101157813B (en) | 2010-11-10 |
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| 潘承武、姚雅萍.铝塑板用金属亚光卷材面漆的研制.涂料工业35 1.2005,35(1),56-58. * |
| 苏海瑛.丙烯酸金属闪光漆的研制.涂料工业 2.2000,(2),16-17. |
| 苏海瑛.丙烯酸金属闪光漆的研制.涂料工业 2.2000,(2),16-17. * |
| 说明书第2页第2行－第3页倒数第8行，实施例2. |
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