CN100999639A - Water resin craft article colour drawing paint and preparation process thereof - Google Patents
Water resin craft article colour drawing paint and preparation process thereof Download PDFInfo
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- CN100999639A CN100999639A CN 200610123446 CN200610123446A CN100999639A CN 100999639 A CN100999639 A CN 100999639A CN 200610123446 CN200610123446 CN 200610123446 CN 200610123446 A CN200610123446 A CN 200610123446A CN 100999639 A CN100999639 A CN 100999639A
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Abstract
The present invention discloses one kind of water-base paint for color drawing of resin handicraft and its production process. The water-base resin paint has water soluble polypropylene resin as main material, pigment and metal complex dye as coloring material, n-butanol and Byk020 as defoaming agent, Byk301 as leveling agent, deionized water as diluent and water-base cross-linking agent, and is prepared into double component fast drying paint capable of curing at room temperature to form film. It has simple preparation process, and may be brushed to the surface of resin handicraft. It has the features of high brightness, bright color, high adhesion, etc. It may be also used in glass product surface and for decorating furniture.
Description
Technical field
The present invention relates to the coatings industry field, be specifically related to water resin craft article colour drawing paint and preparation method thereof.
Background technology
Artwork, general reference view and admire for people and the ornament of beautifying the environment, furnishings, finishing product etc.The raw material of manufacturing process product is a lot, and plastics, metal, timber, cement etc. are arranged.In plastic raw materials, occupy most ratios with the unsaturated polyester resin craft articles, since the nineties in last century, the Pearl River Delta just has thousands of family expenses resins to do the enterprise of artwork to the coastland of the Yangtze River Delta, it is to sell to foreign markets such as America, Europe, Asia that a considerable amount of products are arranged, as the furnishings of household and environment, ornament and red-letter day articles for use.
Yet interior architecture, finishing material and household supplies are the main sources that cause room air pollution.Like this, strengthen management, effectively improve IAQ (indoor air quality), become the common recognition of countries in the world building, finishing material.Member state and building products relevant law, management rules and administrative provisions are responsible for carrying out in European Union " management committee of parliament ", completely forbid in 2004 and produce and sell solvent based coating, change the use water-borne coatings into.In order to integrate with international standard, China will completely forbid the production and selling solvent based coating in 2008.
The coromandel laquer that China uses on the handicraft article made of unsaturated resin surface is solvent based coating basically, this kind solvent type coating itself is poisonous, can give out a large amount of objectionable impuritiess (as benzene, ketone, ether, lead, mercury etc.) injury HUMAN HEALTH in process of production and cause environmental pollution, cause considerable factory please less than the workman.Along with the domestic and international market is more and more stricter to the environmental requirement of artwork, the solvent based coating of using at the unsaturated polyester color drawing for curved surface of body must be replaced by water-borne coatings.
At present, enterprise is all competitively developing the environment protection health coating products, to improve the advantages for development of product on market.The artwork water-borne coatings that multiple brand has been arranged on the market, main base-material is acrylic resin, organic-silicon-modified resin, urethane resin etc., most of all have effect preferably on the resin craft surface, but surface drying speed is slower, and hardness of film is not ideal enough.In the coatings industry with the ratio of acrylate monomer synthetic resin paint also in continuous increase.Fields such as automobile decoration and maintenance, household electrical appliance, coiled material, machinery, timber, leather now have been widely used in.This class coating has the transparency height, look shallow, can reach the water-white degree; Fast light, weather-proof, protect light and protect that look good, outside durabitity is strong, and use temperature wide ranges.But aspect water resin craft article colour drawing paint, also do not use,, select suitable crosslinking agent extremely important because craft article colour drawing paint is done soon to coating and the having relatively high expectations of film performance.
Summary of the invention
The objective of the invention is to overcome the shortcoming of prior art, a kind of low production cost is provided, color is beautiful; color is various; the non-toxic water resin craft article colour drawing paint of excellent property, and can both play a good protection to workmen and construction environment, sterilization accomplished while constructing.
Another object of the present invention is to provide the preparation method of above-mentioned water resin craft article colour drawing paint.
Purpose of the present invention is achieved through the following technical solutions:
A kind of water resin craft article colour drawing paint, it is characterized in that in parts by weight, prescription comprises following component: 40～50 parts of water polyacrylic acids, the add-on of deionized water is 15～30 parts, 20～25 parts of water cross-linking agents, 3～5 parts of propyl carbinols, water-based pigment colour paste or water-based metal complex dyestuff solution are an amount of; Described water cross-linking agent is a biuret type polyisocyanates.
For the surface drying of accelerating coating with do solid work the time, it is linking agent that the present invention selects biuret type polyisocyanates.This linking agent can be by 3mol hexamethylene diisocyanate and the reaction of 1mol water, the biuret polyisocyanate with three-functionality-degree of generation.This compound has not yellowing preferably and good weatherability, can be supporting with polyester or polyacrylic ester, and preparation ambient cure coating.
The preparation method of water resin craft article colour drawing paint of the present invention comprises the steps:
(1) preparation of component one: earlier all water-and acrylates and propyl carbinol are mixed by prescription, add water-based pigment colour paste or water-based metal complex dyestuff solution then, add all deionized waters at last, make the component one of bi-component acrylic quick drying paint;
(2) component two is a water cross-linking agent, during application, component one and component two is mixed, and can obtain the colo(u)r coating of homogeneous.
With respect to prior art, the present invention has following advantage:
(1) the present invention's selection is that the polyacrylic ester of additive is main base-material with the edible ethanol; like this in construction process; coating of the present invention can play sterilization, disinfectant effect, can both play a good protection to workmen and construction environment, accomplishes the sterilization while constructing.
(2) after construction finished, filming to place under room temperature, ventilation condition got final product surface drying in 5 minutes, can do solid work in 1 hour.
(3) low production cost of the present invention, manufacture craft is simple, easy construction.
(4) coating brushing of the present invention is behind the unsaturated polyester surface, volatilization along with moisture, water-and acrylate forms the physical crosslinking by hydrogen bond except self, chemically crosslinked also takes place and improves film chemical resistant properties and anti-mechanical property in water cross-linking agent and vinylformic acid, after the completely solidified film forming of filming, film adhesive strong (1 grade), hardness height (3H), water-fast (not having peculiar in 72 hours), good weatherability.
Embodiment
In order to understand the present invention better, the invention will be further described below in conjunction with embodiment and accompanying drawing, but the scope of protection of present invention is not limited to the scope that embodiment represents.
Embodiment 1:
Take by weighing 40 parts of (weight percent, down with) water polyacrylic acids, 5 parts of propyl carbinols, 5 parts of water-based metal complex dyestuff solution (Guangdong Triratna chemical industry company limited provides for Red-10, solid content 30%), 30 parts of deionized waters, 20 parts of water cross-linking agents are stand-by.
Component one: at first 40 parts of water polyacrylic acids are dropped in the stirring tank, start stirrer, slowly add 5 parts of propyl carbinols then, after waiting to stir, added 30 parts of deionized water stir abouts 5 minutes, and then added 5 parts of Red-10 shaped metal complex dyestuff solution, stir about got final product in 5 minutes.
Component two: water cross-linking agent biuret type polyisocyanates.
Before coating application, take 2 20 parts of one 80 parts of components and components, fully mix, place a moment, can construct.This coating brushing on the resin craft of cleaning, is placed under room temperature, the ventilation condition and got final product surface drying in 5 minutes, can do solid work in 2.5 hours.After the completely solidified film forming of filming (indoor placement 24 hours), film adhesive is strong, hardness is high, water-tolerant, and good weatherability has glossiness height, characteristics such as beautiful in colour.Film concrete testing method and film performance such as following table 1:
Film performance and testing method in table 1 example 1
| Test event | Grade | Testing method |
| Sticking power | 1 grade | GB 1720-79 |
| Hardness | 3H | GB/T 6739-1996 |
| Water tolerance | There was not difference in 72 hours | GB/T 1733-93 |
Embodiment 2:
Take by weighing 40 parts of (weight percent, down with) water polyacrylic acids, 5 parts of propyl carbinols, 5 parts of water-based metal complex dyestuff solution (Guangdong Triratna chemical industry company limited provides for Blue-03, solid content 30%), 30 parts of deionized waters, 20 parts of water cross-linking agents are stand-by.
Component one: at first 40 parts of water polyacrylic acids are dropped in the stirring tank, start stirrer, slowly add 5 parts of propyl carbinols then, after waiting to stir, added 30 parts of deionized water stir abouts 5 minutes, and then added 5 parts of Blue-03 metallized dye solution, stir about got final product in 5 minutes.
Component two: water cross-linking agent biuret type polyisocyanates.
Before coating application, take 2 20 parts of one 80 parts of components and components, fully mix, place a moment, can construct.This coating brushing on the resin craft of cleaning, is placed under room temperature, the ventilation condition and got final product surface drying in 5 minutes, can do solid work in 2.5 hours.After the completely solidified film forming of filming (indoor placement 24 hours), film adhesive is strong, hardness is high, water-tolerant, and good weatherability has glossiness height, characteristics such as beautiful in colour.Film concrete testing method and film performance such as following table 2:
Film performance and testing method in table 2 example 2
| Test event | Grade | Testing method |
| Sticking power | 1 | GB 1720-79 |
| Hardness | 3H | GB/T 6739-1996 |
| Water tolerance | There was not difference in 72 hours | GB/T 1733-93 |
Embodiment 3:
Take by weighing 45 parts of (weight percents, water polyacrylic acid, 3 parts of propyl carbinols, 5 parts of water-based metal complex dyestuff solution (Red-10 down together), solid content 30%, Guangdong Triratna chemical industry company limited provides), 0.2 part of Byk020 defoamer (German BYK Chemie company produce), 24.3 parts of deionized waters, 22.5 parts of water cross-linking agents are stand-by.
Component one: at first 45 parts of water polyacrylic acids are dropped in the stirring tank, start stirrer, slowly add 3 parts of propyl carbinols then, after waiting to stir, added 24.3 parts of deionized water stir abouts 5 minutes, and then added 5 parts of Red-10 metallized dye solution, stir about got final product in 5 minutes.
Component two: water cross-linking agent biuret type polyisocyanates.
Before coating application, take 2 22.5 parts of one 77.5 parts of components and components, fully mix, place a moment, can construct.This coating brushing on the resin craft of cleaning, is placed under room temperature, the ventilation condition and got final product surface drying in 4 minutes, can do solid work in 2 hours.After the completely solidified film forming of filming (indoor placement 24 hours), film adhesive is strong, hardness is high, water-tolerant, and good weatherability has glossiness height, characteristics such as beautiful in colour.Film concrete testing method and film performance such as following table 3:
Film performance and testing method in table 3 example 3
| Test event | Grade | Testing method |
| Sticking power | 1 | GB 1720-79 |
| Hardness | 3H | GB/T 6739-1996 |
| Water tolerance | There was not difference in 72 hours | GB/T 1733-93 |
Embodiment 4:
Take by weighing 50 parts of water polyacrylic acids, 5 parts of propyl carbinols, 3 parts of water-based pigment colour paste (Red768, solid content 40%, sharp Dehua, Guangdong worker company limited provides), 16.5 parts of deionized waters, 25 parts of water cross-linking agents, 0.3 part of Byk020 defoamer (German BYK Chemie company produce), 0.2 part of Byk301 flow agent (German BYK Chemie company produce) are stand-by.
Component one: at first 50 parts of water polyacrylic acids are dropped in the stirring tank, start stirrer, slowly add 5 parts of propyl carbinols then, after waiting to stir, added 16.5 parts of deionized water stir abouts 5 minutes, then add 3 parts of Red768 water-based pigment colour pastes and part Byk020 defoamer, stir about 5 minutes; Add all residue Byk020 defoamers, Byk301 flow agent at last, stir about got final product in 5 minutes.
Component two: water cross-linking agent biuret type polyisocyanates.
Before coating application, take 2 25 parts of one 75 parts of components and components, fully mix, place a moment, can construct.This coating brushing on the resin craft of cleaning, is placed under room temperature, the ventilation condition and got final product surface drying in 3 minutes, can do solid work in 1.5 hours.After the completely solidified film forming of filming (indoor placement 24 hours), film adhesive is strong, hardness is high, water-tolerant, and good weatherability has glossiness height, characteristics such as beautiful in colour.Film concrete testing method and film performance such as following table 4:
Film performance and testing method in table 4 example 4
| Test event | Grade | Testing method |
| Sticking power | 1 | GB 1720-79 |
| Hardness | 3H | GB/T 6739-1996 |
| Water tolerance | There was not difference in 96 hours | GB/T 1733-93 |
Embodiment 5:
Take by weighing 50 parts of water polyacrylic acids, 2.5 parts of propyl carbinols, 7 parts of water-based pigment colour paste (Lemon548, solid content 50%, sharp Dehua, Guangdong worker company limited provides), 15 parts of deionized waters, 25 parts of water cross-linking agents, 0.3 part of Byk020 defoamer (German BYK Chemie company produce), 0.2 part of Byk301 flow agent (German BYK Chemie company produce) are stand-by.
Component one: at first 50 parts of water polyacrylic acids are dropped in the stirring tank, start stirrer, slowly add 2.5 parts of propyl carbinols then, after waiting to stir, added 15 parts of deionized water stir abouts 5 minutes, then add 7 parts of Lemon548 water-based pigment colour pastes and part Byk020 defoamer, stir about 5 minutes; Add all residue Byk020 defoamers, Byk301 flow agent at last, stir about got final product in 5 minutes.
Component two: water cross-linking agent biuret type polyisocyanates.
Before coating application, take 2 25 parts of one 75 parts of components and components, fully mix, place a moment, can construct.This coating brushing on the resin craft of cleaning, is placed under room temperature, the ventilation condition and got final product surface drying in 3 minutes, can do solid work in 1 hour.After the completely solidified film forming of filming (indoor placement 24 hours), film adhesive is strong, hardness is high, water-tolerant, and good weatherability has glossiness height, characteristics such as beautiful in colour.Film concrete testing method and film performance such as following table 5:
Film performance and testing method in table 5 example 5
| Test event | Grade | Testing method |
| Sticking power | 1 | GB 1720-79 |
| Hardness | 3H | GB/T 6739-1996 |
| Water tolerance | There was not difference in 96 hours | GB/T 1733-93 |
Embodiment 6:
Take by weighing 40 parts of (weight percent, down with) water polyacrylic acids, 5 parts of propyl carbinols, 5 parts of water-based metal complex dyestuff solution (Guangdong Triratna chemical industry company limited provides for Red-10, solid content 30%), 25 parts of deionized waters, 25 parts of water cross-linking agents are stand-by.
Component one: at first 40 parts of water polyacrylic acids are dropped in the stirring tank, start stirrer, slowly add 5 parts of propyl carbinols then, after waiting to stir, added 25 parts of deionized water stir abouts 5 minutes, and then added 5 parts of Red-10 metallized dye solution, stir about got final product in 5 minutes.
Component two: water cross-linking agent biuret type polyisocyanates.
Before coating application, take 2 25 parts of one 75 parts of components and components, fully mix, place a moment, can construct.This coating brushing on the resin craft of cleaning, is placed under room temperature, the ventilation condition and got final product surface drying in 5 minutes, can do solid work in 2.5 hours.After the completely solidified film forming of filming (indoor placement 24 hours), film adhesive is strong, hardness is high, water resistance is good, and good weatherability has glossiness height, characteristics such as beautiful in colour.Film concrete testing method and film performance such as following table 6:
Film performance and testing method in table 6 example 6
| Test event | Grade | Testing method |
| Sticking power | 1 | GB 1720-79 |
| Hardness | 2H | GB/T 6739-1996 |
| Water tolerance | There was not difference in 24 hours | GB/T 1733-93 |
Embodiment 7:
Take by weighing 50 parts of (weight percent, down with) water polyacrylic acids, 5 parts of propyl carbinols, 5 parts of water-based metal complex dyestuff solution (Guangdong Triratna chemical industry company limited provides for Red-10, solid content 30%), 20 parts of deionized waters, 20 parts of water cross-linking agents are stand-by.
Component one: at first 50 parts of water polyacrylic acids are dropped in the stirring tank, start stirrer, slowly add 5 parts of propyl carbinols then, after waiting to stir, added 20 parts of deionized water stir abouts 5 minutes, and then added 5 parts of Red-10 metallized dye solution, stir about got final product in 5 minutes.
Component two: water cross-linking agent biuret type polyisocyanates.
Before coating application, take 2 20 parts of one 80 parts of components and components, fully mix, place a moment, can construct.This coating brushing on the resin craft of cleaning, is placed under room temperature, the ventilation condition and got final product surface drying in 7 minutes, can do solid work in 2.5 hours.After the completely solidified film forming of filming (indoor placement 24 hours), film adhesive is strong, hardness is high, water-fast, and good weatherability has glossiness height, characteristics such as beautiful in colour.Film concrete testing method and film performance such as following table 5:
Film performance and testing method in table 7 example 7
| Test event | Grade | Testing method |
| Sticking power | 2 | GB 1720-79 |
| Hardness | 4H | GB/T 6739-1996 |
| Water tolerance | There was not difference in 72 hours | GB/T 1733-93 |
Claims (6)
1, a kind of water resin craft article colour drawing paint, it is characterized in that in parts by weight, prescription comprises following component: 40～50 parts of water polyacrylic acids, the add-on of deionized water is 15～30 parts, 20～25 parts of water cross-linking agents, 3～5 parts of propyl carbinols, water-based pigment colour paste or water-based metal complex dyestuff solution are an amount of; Described water cross-linking agent is a biuret type polyisocyanates.
2, water resin craft article colour drawing paint according to claim 1 is characterized in that described water-based pigment colour paste is Red768 type and Lemon548 type mill base; Described water-based metal complex dyestuff is Red-10 type and Blue-03 type dye.
3, water resin craft article colour drawing paint according to claim 1 and 2 is characterized in that in parts by weight, and prescription comprises that also 0～0.3 part of flow agent, described flow agent are Byk301 type flow agent.
4, water resin craft article colour drawing paint according to claim 1 and 2 is characterized in that in parts by weight, and prescription comprises that also 0～0.3 part of defoamer, described defoamer are Byk020 type defoamer.
5, the preparation method of the described water resin craft article colour drawing paint of claim 1 is characterized in that comprising the steps:
(1) preparation of component one: earlier all water-and acrylates and propyl carbinol are mixed by prescription, add water-based pigment colour paste or water-based metal complex dyestuff solution then, add all deionized waters at last, make the component one of bi-component acrylic quick drying paint;
(2) component two is a water cross-linking agent, during application, component one and component two is mixed, and can obtain the colo(u)r coating of homogeneous.
6, the lacquer preparation method of water resin craft article colour drawing according to claim 5 after it is characterized in that described step (1) water-and acrylate and propyl carbinol mixing, also comprises adding defoamer or flow agent.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610123446 CN100999639A (en) | 2006-11-10 | 2006-11-10 | Water resin craft article colour drawing paint and preparation process thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610123446 CN100999639A (en) | 2006-11-10 | 2006-11-10 | Water resin craft article colour drawing paint and preparation process thereof |
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| CN100999639A true CN100999639A (en) | 2007-07-18 |
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| CN 200610123446 Pending CN100999639A (en) | 2006-11-10 | 2006-11-10 | Water resin craft article colour drawing paint and preparation process thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880488A (en) * | 2010-07-16 | 2010-11-10 | 郑希林 | Gold glistening pigment and preparation method thereof |
| CN106280640A (en) * | 2016-08-31 | 2017-01-04 | 安徽阜南县万家和工艺品有限公司 | A kind of enhancement mode straw knitting coating additive |
| CN107151343A (en) * | 2017-05-18 | 2017-09-12 | 阜南县中泰工艺品有限公司 | A kind of method for lifting resin craft wearability |
| CN107629654A (en) * | 2017-09-29 | 2018-01-26 | 天长市墨缘玻璃建材有限公司 | A kind of base coat and its processing technology for coromandel laquer glass |
| CN107629506A (en) * | 2017-09-29 | 2018-01-26 | 天长市墨缘玻璃建材有限公司 | A kind of outdoor glass color-painting pigment and preparation method thereof |
| CN109235054A (en) * | 2017-06-13 | 2019-01-18 | 上海纳尔数码喷印材料股份有限公司 | A kind of preparation method of the aqueous air brushing textile cloth of light soft |
| CN111518412A (en) * | 2020-04-22 | 2020-08-11 | 窦敏辉 | Non-sulfonated aqueous metal complex dye with low heavy metal content |
| CN115991949A (en) * | 2022-12-14 | 2023-04-21 | 河源市云彩实业有限公司 | Transparent window color pigment and preparation method thereof |
-
2006
- 2006-11-10 CN CN 200610123446 patent/CN100999639A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880488A (en) * | 2010-07-16 | 2010-11-10 | 郑希林 | Gold glistening pigment and preparation method thereof |
| CN101880488B (en) * | 2010-07-16 | 2012-07-04 | 郑希林 | Gold glistening pigment and preparation method thereof |
| CN106280640A (en) * | 2016-08-31 | 2017-01-04 | 安徽阜南县万家和工艺品有限公司 | A kind of enhancement mode straw knitting coating additive |
| CN107151343A (en) * | 2017-05-18 | 2017-09-12 | 阜南县中泰工艺品有限公司 | A kind of method for lifting resin craft wearability |
| CN109235054A (en) * | 2017-06-13 | 2019-01-18 | 上海纳尔数码喷印材料股份有限公司 | A kind of preparation method of the aqueous air brushing textile cloth of light soft |
| CN107629654A (en) * | 2017-09-29 | 2018-01-26 | 天长市墨缘玻璃建材有限公司 | A kind of base coat and its processing technology for coromandel laquer glass |
| CN107629506A (en) * | 2017-09-29 | 2018-01-26 | 天长市墨缘玻璃建材有限公司 | A kind of outdoor glass color-painting pigment and preparation method thereof |
| CN111518412A (en) * | 2020-04-22 | 2020-08-11 | 窦敏辉 | Non-sulfonated aqueous metal complex dye with low heavy metal content |
| CN111518412B (en) * | 2020-04-22 | 2022-01-07 | 窦敏辉 | Non-sulfonated aqueous metal complex dye with low heavy metal content |
| CN115991949A (en) * | 2022-12-14 | 2023-04-21 | 河源市云彩实业有限公司 | Transparent window color pigment and preparation method thereof |
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