CN104479444A - Boiling-resistant mirror resin and preparation method thereof - Google Patents
Boiling-resistant mirror resin and preparation method thereof Download PDFInfo
- Publication number
- CN104479444A CN104479444A CN201410730609.4A CN201410730609A CN104479444A CN 104479444 A CN104479444 A CN 104479444A CN 201410730609 A CN201410730609 A CN 201410730609A CN 104479444 A CN104479444 A CN 104479444A
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- CN
- China
- Prior art keywords
- minute surface
- surface resin
- water boiling
- boiling resistance
- solidifying agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
Abstract
The invention discloses boiling-resistant mirror resin and a preparation method thereof. The boiling-resistant mirror resin is prepared from the following raw materials in parts by mass: 30-50 parts of common mirror resin, 10-25 parts of a curing agent, 1-2 parts of a catalyst and 20-35 parts of a diluent. The preparation method of the boiling-resistant mirror resin comprises the following steps: adding the diluents into a mixing cylinder, adding the common mirror resin, the curing agent and the catalyst and uniformly mixing at room temperature. Boiling-resistant mirror ink is prepared by mixing the boiling-resistant mirror resin and mirror silver slurry at a mass ratio of 1:(1.5-2). The mirror ink obtained by the mirror resin has good mirror effect and relatively strong boiling resistance, after the ink is boiled for 1 hour, the adhesion of the ink to a glass substrate or a metal substrate can still reach Level 0.
Description
Technical field
The present invention relates to a kind of water boiling resistance minute surface resin and preparation method thereof.
Background technology
Ink with mirror effect is a kind of ink with special decorative effect, and bulk composition is aluminium-silver slurry and resin, constructs on smooth, transparent base material.After film forming, paint film has the light reflection of height, and from front, ink has the effect of similar mirror.Common ink with mirror effect is under some particular surroundingss, and under such as boiling water exists, coating structure can be destroyed, and thus causes ink loss of gloss and loss of adhesion.
Therefore, study a kind of water boiling resistance minute surface resin and ink with mirror effect necessary.
Summary of the invention
The object of the present invention is to provide a kind of water boiling resistance minute surface resin and preparation method thereof.
The technical solution used in the present invention is:
A kind of water boiling resistance minute surface resin, it is made up of the raw material of following mass parts: the common minute surface resin of 30-50 part, the solidifying agent of 10-25 part, the catalyzer of 1-2 part, the thinner of 20-35 part.
Described common minute surface resin is nitrocellulose resin solution or cellulose acetate butyrate solution, and solid content is between 5%-15%.
Described solidifying agent is organosilicon solidifying agent or amino resin curing agents.
The general formula of described organosilicon solidifying agent is YSiX
3, Y is selected from alkyl, thiazolinyl or end with Cl, NH
2, SH, epoxy, N
3, (methyl) acryloxy, isocyanate group alkyl; X is selected from Cl, OMe, OEt, OC
2h
4oCH
3, OSiMe
3, OAc.
Described organosilicon solidifying agent is at least one in Union carbide A-162, ethyl triethoxysilane, vinyl triacetyl oxosilane, methyl tributanoximo silane, tetraethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, 3-glycydoxy triethoxyl silane, β-(3,4-epoxycyclohexyl) ethyl trimethoxy silane.
Described amino resin curing agents be melamine class aminoresin, benzene for aminoresin, methyl-etherified melamine class aminoresin, butyl ether melamine class aminoresin, methyl-etherified benzene at least one in aminoresin, the etherification benzene substituted aminoresin of fourth.
When described solidifying agent is organosilicon, catalyzer is selected from least one in carboxylic acid, sulfonic acid,-sulfinic acid, thionothiolic acid; When described solidifying agent is aminoresin, catalyzer is carboxylic acid.
Described thinner is selected from the one in vinyl acetic monomer, N-BUTYL ACETATE, glycol methyl ether acetate, propylene glycol monomethyl ether, butyl glycol ether, dimethylbenzene, pimelinketone, isophorone.
A preparation method for water boiling resistance minute surface resin, step is as follows: in mixed cylinder, add thinner, then adds common minute surface resin, solidifying agent, catalyzer, mixes under room temperature.
A kind of water boiling resistance ink with mirror effect, it is that to be starched according to mass ratio by described water boiling resistance minute surface resin and mirror-like silver be 1:(1.5-2) be mixed.
The invention has the beneficial effects as follows: the ink with mirror effect mirror effect that the present invention obtains is good; Water boiling resistance ability is comparatively strong, still can reach 0 grade after poach 1h to the sticking power of glass baseplate or metal base.
Embodiment
A kind of water boiling resistance minute surface resin, it is made up of the raw material of following mass parts: the common minute surface resin of 30-50 part, the solidifying agent of 10-25 part, the catalyzer of 1-2 part, the thinner of 20-35 part.
Described common minute surface resin is nitrocellulose resin solution or cellulose acetate butyrate solution, and solid content is between 5%-15%;
Preferably, described common minute surface resin is cellulose acetate butyrate (model is CAB381-20) solution; Or be cellulose acetate butyrate solution, wherein, the nitrogen content of cellulose acetate butyrate is at 10.7%-11.2%, and viscosity is more than falling ball viscosity second;
Further preferred, be cellulose acetate butyrate solution, wherein, the nitrogen content of cellulose acetate butyrate is at 10.7%-11.2%, and viscosity is more than falling ball viscosity second.
Described solidifying agent is organosilicon solidifying agent or amino resin curing agents.
The general formula of described organosilicon solidifying agent is YSiX
3, Y is selected from alkyl, thiazolinyl or end with Cl, NH
2, SH, epoxy, N
3, (methyl) acryloxy, isocyanate group alkyl; X is selected from Cl, OMe, OEt, OC
2h
4oCH
3, OSiMe
3, OAc.
Preferably, described organosilicon solidifying agent is at least one in Union carbide A-162, ethyl triethoxysilane, vinyl triacetyl oxosilane, methyl tributanoximo silane, tetraethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, 3-glycydoxy triethoxyl silane, β-(3,4-epoxycyclohexyl) ethyl trimethoxy silane.
Described amino resin curing agents be melamine class aminoresin, benzene for aminoresin, methyl-etherified melamine class aminoresin, butyl ether melamine class aminoresin, methyl-etherified benzene at least one in aminoresin, the etherification benzene substituted aminoresin of fourth.
When described solidifying agent is organosilicon, catalyzer is selected from least one in carboxylic acid, sulfonic acid,-sulfinic acid, thionothiolic acid; When described solidifying agent is aminoresin, catalyzer is carboxylic acid.
Preferably, when described solidifying agent is organosilicon, catalyzer is selected from the one in acetic acid, butyric acid, succinic acid, oxalic acid, phenylformic acid, p-methyl benzenesulfonic acid; When described solidifying agent is aminoresin, catalyzer is selected from the one in acetic acid, butyric acid, succinic acid, oxalic acid, phenylformic acid.
Described thinner is selected from the one in vinyl acetic monomer, N-BUTYL ACETATE, glycol methyl ether acetate, propylene glycol monomethyl ether, butyl glycol ether, dimethylbenzene, pimelinketone, isophorone.
A preparation method for water boiling resistance minute surface resin, step is as follows: in mixed cylinder, add thinner, then adds common minute surface resin, solidifying agent, catalyzer, mixes under room temperature.
A kind of water boiling resistance ink with mirror effect, it is that to be starched according to mass ratio by described water boiling resistance minute surface resin and mirror-like silver be 1:(1.5-2) be mixed.
Below in conjunction with specific embodiment, the present invention is described further:
embodiment 1:
A kind of water boiling resistance minute surface resin, its table composed as follows of filling a prescription:
table 1: the formula composition of water boiling resistance minute surface resin
The composition of ink with mirror effect and preparation in present case: the minute surface resin in the present embodiment gets 40 parts, 60 parts of mirror-like silvers slurries mix and obtain ink with mirror effect, and on a glass, paint film is at 180 DEG C of baking 10min for ink silk screen printing.
Testing inspection:
embodiment 2:
A kind of water boiling resistance minute surface resin, its table composed as follows of filling a prescription:
table 2: the formula composition of water boiling resistance minute surface resin
The composition of ink with mirror effect and preparation in present case: the minute surface resin in the present embodiment gets 40 parts, 60 parts of mirror-like silvers slurries mix and obtain ink with mirror effect, and on a glass, paint film just can obtain the ink with mirror effect of water boiling resistance at 180 DEG C of baking 10min to ink silk screen printing.
Testing inspection:
embodiment 3:
A kind of water boiling resistance minute surface resin, its table composed as follows of filling a prescription:
table 3: the formula composition of water boiling resistance minute surface resin
The composition of ink with mirror effect and preparation in the present embodiment: the minute surface resin in the present embodiment gets 40 parts, 60 parts of mirror-like silvers slurries mix and obtain ink with mirror effect, and on stainless steel, paint film just can obtain the minute surface of water boiling resistance at 180 DEG C of baking 10min to ink silk screen printing
Testing inspection:
Claims (10)
1. a water boiling resistance minute surface resin, is characterized in that: it is made up of the raw material of following mass parts: the common minute surface resin of 30-50 part, the solidifying agent of 10-25 part, the catalyzer of 1-2 part, the thinner of 20-35 part.
2. a kind of water boiling resistance minute surface resin according to claim 1, is characterized in that: described common minute surface resin is nitrocellulose resin solution or cellulose acetate butyrate solution, and solid content is between 5%-15%.
3. a kind of water boiling resistance minute surface resin according to claim 1, is characterized in that: described solidifying agent is organosilicon solidifying agent or amino resin curing agents.
4. a kind of water boiling resistance minute surface resin according to claim 3, is characterized in that: the general formula of described organosilicon solidifying agent is YSiX
3, Y is selected from alkyl, thiazolinyl or end with Cl, NH
2, SH, epoxy, N
3, (methyl) acryloxy, isocyanate group alkyl; X is selected from Cl, OMe, OEt, OC
2h
4oCH
3, OSiMe
3, OAc.
5. a kind of water boiling resistance minute surface resin according to claim 3, is characterized in that: described organosilicon solidifying agent is at least one in Union carbide A-162, ethyl triethoxysilane, vinyl triacetyl oxosilane, methyl tributanoximo silane, tetraethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, 3-glycydoxy triethoxyl silane, β-(3,4-epoxycyclohexyl) ethyl trimethoxy silane.
6. a kind of water boiling resistance minute surface resin according to claim 3, is characterized in that: described amino resin curing agents be melamine class aminoresin, benzene for aminoresin, methyl-etherified melamine class aminoresin, butyl ether melamine class aminoresin, methyl-etherified benzene at least one in aminoresin, the etherification benzene substituted aminoresin of fourth.
7. a kind of water boiling resistance minute surface resin according to claim 3, it is characterized in that: when described solidifying agent is organosilicon, catalyzer is selected from least one in carboxylic acid, sulfonic acid,-sulfinic acid, thionothiolic acid; When described solidifying agent is aminoresin, catalyzer is carboxylic acid.
8. a kind of water boiling resistance minute surface resin according to claim 1, is characterized in that: described thinner is selected from the one in vinyl acetic monomer, N-BUTYL ACETATE, glycol methyl ether acetate, propylene glycol monomethyl ether, butyl glycol ether, dimethylbenzene, pimelinketone, isophorone.
9. the preparation method of a kind of water boiling resistance minute surface resin according to claim 1, is characterized in that: step is as follows: in mixed cylinder, add thinner, then adds common minute surface resin, solidifying agent, catalyzer, mix under room temperature.
10. a water boiling resistance ink with mirror effect, is characterized in that: it is that to be starched according to mass ratio by water boiling resistance minute surface resin according to claim 1 and mirror-like silver be 1:(1.5-2) be mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410730609.4A CN104479444B (en) | 2014-12-05 | 2014-12-05 | Boiling-resistant mirror resin and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410730609.4A CN104479444B (en) | 2014-12-05 | 2014-12-05 | Boiling-resistant mirror resin and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104479444A true CN104479444A (en) | 2015-04-01 |
| CN104479444B CN104479444B (en) | 2017-04-19 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410730609.4A Active CN104479444B (en) | 2014-12-05 | 2014-12-05 | Boiling-resistant mirror resin and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038397A (en) * | 2015-07-08 | 2015-11-11 | 合肥旭阳铝颜料有限公司 | Ultrasonic cleaning resistant mirror ink for mobile phone lens |
| CN105153800A (en) * | 2015-07-08 | 2015-12-16 | 合肥旭阳铝颜料有限公司 | One-component mirror surface sliver ink |
| CN105691074A (en) * | 2016-02-18 | 2016-06-22 | 钟治超 | Pattern laser etching process for surface of TPU rubber product |
| CN109763349A (en) * | 2019-01-22 | 2019-05-17 | 华大化学(安徽)有限公司 | A kind of middle hard synthetic leather bloom bright face mirror face resin and its preparation method and application |
| CN109836754A (en) * | 2019-01-17 | 2019-06-04 | 广州致辉精化股份有限公司 | A kind of PC mirror surface resin of solvent resistant water boiling resistance and preparation method thereof |
| CN111484767A (en) * | 2019-01-26 | 2020-08-04 | 深圳市和泰辉科技有限公司 | Single-component mirror ink and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1541642A1 (en) * | 2003-12-05 | 2005-06-15 | Rohm And Haas Company | Markable powder coating comprising a magnetic interference pigment |
| CN102533014A (en) * | 2012-02-16 | 2012-07-04 | 上海天地涂料有限公司 | Mirror silver coating, mirror silver resin forming mirror silver coating, and preparation methods for mirror silver coating and mirror silver resin |
| CN103951789A (en) * | 2014-04-04 | 2014-07-30 | 广州伊德尔化学科技有限公司 | High-temperature-resistant mirror silver resin and preparation method thereof |
-
2014
- 2014-12-05 CN CN201410730609.4A patent/CN104479444B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1541642A1 (en) * | 2003-12-05 | 2005-06-15 | Rohm And Haas Company | Markable powder coating comprising a magnetic interference pigment |
| CN102533014A (en) * | 2012-02-16 | 2012-07-04 | 上海天地涂料有限公司 | Mirror silver coating, mirror silver resin forming mirror silver coating, and preparation methods for mirror silver coating and mirror silver resin |
| CN103951789A (en) * | 2014-04-04 | 2014-07-30 | 广州伊德尔化学科技有限公司 | High-temperature-resistant mirror silver resin and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038397A (en) * | 2015-07-08 | 2015-11-11 | 合肥旭阳铝颜料有限公司 | Ultrasonic cleaning resistant mirror ink for mobile phone lens |
| CN105153800A (en) * | 2015-07-08 | 2015-12-16 | 合肥旭阳铝颜料有限公司 | One-component mirror surface sliver ink |
| CN105691074A (en) * | 2016-02-18 | 2016-06-22 | 钟治超 | Pattern laser etching process for surface of TPU rubber product |
| CN105691074B (en) * | 2016-02-18 | 2018-12-28 | 徐州千百度鞋业有限公司 | The laser carving pattern process of TPU rubber material product surface |
| CN109836754A (en) * | 2019-01-17 | 2019-06-04 | 广州致辉精化股份有限公司 | A kind of PC mirror surface resin of solvent resistant water boiling resistance and preparation method thereof |
| CN109836754B (en) * | 2019-01-17 | 2021-08-10 | 广州致辉精化股份有限公司 | Solvent-resistant and boiling-resistant PC mirror resin and preparation method thereof |
| CN109763349A (en) * | 2019-01-22 | 2019-05-17 | 华大化学(安徽)有限公司 | A kind of middle hard synthetic leather bloom bright face mirror face resin and its preparation method and application |
| CN111484767A (en) * | 2019-01-26 | 2020-08-04 | 深圳市和泰辉科技有限公司 | Single-component mirror ink and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN104479444B (en) | 2017-04-19 |
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