CN101157808A - Highly wearable vacuum coating ultraviolet curing coatings - Google Patents
Highly wearable vacuum coating ultraviolet curing coatings Download PDFInfo
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- CN101157808A CN101157808A CNA2007100360219A CN200710036021A CN101157808A CN 101157808 A CN101157808 A CN 101157808A CN A2007100360219 A CNA2007100360219 A CN A2007100360219A CN 200710036021 A CN200710036021 A CN 200710036021A CN 101157808 A CN101157808 A CN 101157808A
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- acrylate
- vacuum coating
- ultraviolet curing
- curing coatings
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- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 36
- 238000001771 vacuum deposition Methods 0.000 title claims abstract description 30
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 35
- 239000000178 monomer Substances 0.000 claims abstract description 28
- 239000011248 coating agent Substances 0.000 claims abstract description 19
- 125000000524 functional group Chemical group 0.000 claims abstract description 15
- 229920002635 polyurethane Polymers 0.000 claims abstract description 14
- 239000004814 polyurethane Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 6
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 6
- 229940043265 methyl isobutyl ketone Drugs 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- 239000002318 adhesion promoter Substances 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 3
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 claims description 3
- GZBSIABKXVPBFY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GZBSIABKXVPBFY-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 3
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 3
- -1 hydroxy-cyclohexyl (methyl) acrylate Chemical compound 0.000 claims description 3
- 229940091853 isobornyl acrylate Drugs 0.000 claims description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- BNJGYHUCRJBAOR-UHFFFAOYSA-N 2,3-diethoxypent-2-ene Chemical group C(C)OC(=C(CC)OCC)C BNJGYHUCRJBAOR-UHFFFAOYSA-N 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 2
- NSFGOWGWLHAJPC-UHFFFAOYSA-N COCOC.C(C=C)(=O)O Chemical compound COCOC.C(C=C)(=O)O NSFGOWGWLHAJPC-UHFFFAOYSA-N 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 235000019439 ethyl acetate Nutrition 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 239000005543 nano-size silicon particle Substances 0.000 claims description 2
- WKGDNXBDNLZSKC-UHFFFAOYSA-N oxido(phenyl)phosphanium Chemical compound O=[PH2]c1ccccc1 WKGDNXBDNLZSKC-UHFFFAOYSA-N 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 7
- 238000004383 yellowing Methods 0.000 abstract description 5
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- 238000005382 thermal cycling Methods 0.000 abstract 1
- 238000001723 curing Methods 0.000 description 21
- 239000003973 paint Substances 0.000 description 21
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 14
- 238000007747 plating Methods 0.000 description 9
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000004925 Acrylic resin Substances 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 5
- 229920000178 Acrylic resin Polymers 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000003678 scratch resistant effect Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Abstract
The invention relates to the electronic application-coating field, in particular to uv-curing coating with high wearing resistance and vacuum coating. The compositions and contents of the invention are: 10 wt percent to 30 wt percent of difunctional group polyurethane acrylate, 10 wt percent to 40 wt percent of high functional group polyurethane acrylate, 5 wt percent to 20 wt percent of high functional group acrylate monomer, 0 wt percent to 15 wt percent of monofunctional group acrylate monomer, 1 wt percent to 10 wt percent of acid adhesive promoter, 1 wt percent to 6 wt percent of photoinitiator, 0 wt percent to 5 wt percent of nano wearing resistance materials, 0.1 wt percent to 2 wt percent of additive and 10 wt percent to 50 wt percent of solvent. The invention is designed for providing surface protection for vacuum coating parts of electric products such as mobile phone, MP3, and digital camera, etc., and is characterized by good surface effect, good performances of ultrawear-resistance, high temperature and humidity resistance, anti-cold thermal cycling and anti-yellowing, etc., wherein, RCA wear can be up to more than 1500 times, which can effectively improve the service life of electric products. The invention effectively enhances the adhesion and wearing resistant performance of the uv-curing and vacuum coating dope, solves the matching problem of the bottom and surface lacquer of the uv-curing and vacuum coating dope, and has broad university.
Description
Technical field
The invention belongs to paint field, particularly in workpiece surface a kind of ultraviolet-curing paint that uses after the vacuum plating metallization.
Background technology
Through 40 years of development, radiation curing technology be widely used global every field and industry.Ultraviolet-curing paint (being called for short UV coating) has advantages such as VOC content is low, curing speed fast, the good combination property of filming, and has obtained develop rapidly in China.Plastic basis material is handled by vacuum plating, can make workpiece obtain the metalluster and the mirror effect of height.Ultraviolet-curing vacuum coating coating generally adopts the mode application of spraying, and curing speed is fast, and is simple to operate, and easy construction is widely used.Generally be applied to the application of body surfaces such as computer peripheral device, Communication Equipment, audio-visual equipment, consumption electronic products, auto-parts and opto-electronics, toy, makeup and various plastic cement, metal, bamboo woodenware.Because the singularity of ultraviolet-curing vacuum coating coating, the metal-plated rete is in the centre of vacuum plating priming paint and finish paint, ultraviolet-curing paint is because of fast setting, shrinkage ratio is bigger, general ultraviolet-cured coatings adhering on metal is difficult, and for the ultraviolet-curing vacuum coating finish paint, should satisfy has excellent sticking power on the metal-plated rete, can not influence the metal-plated rete again to vacuum plating priming paint sticking power, so the vacuum plating finish paint is required quite harsh.Wherein Chinese patent CN1281011A application is " at the bottom of the ultraviolet-curing vacuum coating, finish paint ", it is matrix resin that finish paint adopts polyester acrylate and phenolic aldehyde epoxy acrylate, solved the sticking power problem of ultraviolet-curing vacuum coating finish paint, but because hardness is low, wear resisting property and anti-pollution characteristic are poor, it is matrix resin that the urethane resin of epoxy acrylic resin and 2 functional groups is adopted in Chinese patent CN1803942A application " ultraviolet-curing paint that is used for metal plating surface protection ", the compound resin that collocation thermoplastic acrylic resin and cellulosic resin are formed, improved the hardness of coating by the rigid structure in the increase coating system, but because the epoxy acrylic resin wear resisting property is poor, filming yellowing resistance can be poor, do not satisfy the needs of current electronic product far away to coating requirements at the higher level, particularly high-wear resistance.Thereby limited the application of ultraviolet-curing vacuum coating coating.
Summary of the invention
The purpose of this invention is to provide a kind of scratch-resistant performance that can improve workpiece surface widely, and the finish paint of gained has high rigidity, excellent ring is surveyed the highly wearable vacuum coating ultraviolet curing coatings of performance and anti-yellowing property.
Technical scheme of the present invention is:
The highly wearable vacuum coating ultraviolet curing coatings that is used for electronic product of the present invention, it is formed and weight percent is:
Two functional polyurethane acrylate 10-30%
High functional polyurethane acrylate 10-40%
The high acrylate monomer 5-20% of functional group
Simple function group acrylate monomer 0-15%
Peracidity adhesion promoter 1-10%
Light trigger 1-6%
Nano wearproof material 0-5%
Auxiliary agent 0.1-2%
Solvent 10-50%
Two functional polyurethane acrylate of the present invention are meant aliphatic two functional polyurethane acrylic ester prepolymers, as 6070,6071,6072,6075 of Changxing chemical company, and the RESIN 5704 of the special company of U.S.'s cyanogen etc.
High functional polyurethane acrylate of the present invention is meant the polyurethane prepolymer of functionality between 6～15,6144-100,6145-100 as Changxing chemical company, CHO31, EB1290, the EB5129 of the special company of U.S.'s cyanogen, the CN9006 of Sartomer company, CN9010, PRO30000, PRO8122A, the UV-7600B of Japanese synthetic chemistry, UV-7605B, UV7640B etc.
High functional group of the present invention acrylate monomer is meant acrylate monomer---the four-functional group propenoic acid ester monomer of 4～6 functional groups: (alkoxylate) tetramethylol methane tetraacrylate; Five functional group's acrylate monomers: dipentaerythrityl ether five acrylate; Six functional groups acrylate monomer: dipentaerythrityl ether six acrylate (DPHA).
Monofunctional acrylate monomer of the present invention is meant ethoxy ethoxy ethyl propylene acid esters, (methyl) iso-bornyl acrylate, tetrahydrofuran (THF) (methyl) acrylate, hydroxy-cyclohexyl (methyl) acrylate, vinyl pyrrolidone, ring TriMethylolPropane(TMP) methylal acrylate.
Acid adhesion promoter of the present invention contains the Acrylic Acid Monomer or the acrylic polymer of phosphoric acid modification.The CD9050 of Sartomer company, CD9051, cyanogen spy's EB168, EB170, the PHOTOMER4703 that section is peaceful.
Described light trigger is the non-yellow stain type light trigger, as a kind of or mixture in 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxyl-cyclohexyl-phenyl ketone, two (2,4,6-Three methyl Benzene formyl) phenyl phosphine oxide.
Nano wearproof material of the present invention is meant nano aluminium oxide, nano silicon.NANOBYK-3601, NANOBYK-3602, NANOBYK-3610, NANOBYK-3650 as Bi Ke company.
Described auxiliary agent comprises flow agent, defoamer, wetting dispersing agent; Wherein the consumption of flow agent is the 0-1% of coating total amount, and the consumption of defoamer is the 0-0.5% of coating total amount, and the consumption of wetting dispersing agent is the 0-0.5% of coating total amount; Described flow agent, defoamer, wetting dispersing agent use together or use separately.
Described flow agent is meant BYK 306, BYK 307, BYK 333, BYK 358, BYK 371, BYK UV3500, BYK UV3530, EFKA 3031, TEGO 432, TEGO 450, EFKA 3883, EFKA 3277, EFKA 3777 etc.Can select wherein one or more mixture.
Described defoamer is meant BYK 055, BYK 066, EFKA 2721, DEUCHEM 2700, TEGO920 etc.Can select wherein one or more mixture.
Described wetting dispersing agent is meant one or more the mixture of BYK 161, BYK 163, BYK 164, EFKA 4800, EFKA4010 etc.
Solvent of the present invention is one or more the mixture in vinyl acetic monomer, N-BUTYL ACETATE, butanone, methyl iso-butyl ketone (MIBK), Virahol, propyl carbinol, diacetone alcohol, propylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol ether acetate, the propylene-glycol ethyl ether acetic ester.
The preparation method of highly wearable vacuum coating ultraviolet curing coatings of the present invention is:
(1) with high functional group aliphatic urethane acrylate resin 50 ℃ of preheatings 1 hour, with 1/2 the amount solvent in reactor fully the dissolving;
(2) add high monomer, simple function group monomer, two functional polyurethane acrylate and light triggers in reactor, 50 ℃ were stirred 30 minutes;
(3) add flow agent, defoamer and rest parts solvent, high-speed stirring filtered and packaged with 400 order filter clothes after 30 minutes.
The coating that is used for the vacuum coating surface protection of the present invention is transparent or semitransparent glue, and solid content is 40～70%, and room temperature lucifuge period of storage is 1 year, and solidifying required energy is 800～1200mj/m
2, the production efficiency height.
The present invention is based on high-functionality polyurethane acrylic resin and high functional group acrylate monomer, collocation part two functional polyurethane acrylate resins and high property adhesion promoter, improve the sticking power of finish paint to the metal-plated rete, and the shrinking percentage that can acrylate monomer produces when solidifying of the high official of the monofunctional acrylate monomer balance of suitably introducing partially rigid, carry out surface enhancing with the nano wearproof material that does not influence glossiness in right amount; Significantly improved the RCA wear hardness of finish paint, added a certain amount of light trigger, surperficial auxiliary agent and thinner again, improved execution of coating performance and surface effect, made the demand that satisfies high-grade electronic product.
The obtained beneficial effect of the present invention is: paint spraying of the present invention is behind workpiece surface; the scratch-resistant performance of workpiece surface has raising significantly; the RCA that films abrasion after the curing reach as high as (load 175 grams) more than 1500 times; have excellent high temperature resistance high humidity, cold-and-heat resistent impact, salt spray resistance, anti-makeup performance, anti-artificial hand perspiration, the aging resistance of anti-UV simultaneously, improve the decoration and protection effect of product surface greatly.
Have good protection effect and high wear resisting property by filming of making of ultraviolet-curing paint of the present invention.Resulting finish paint has high abrasion, high rigidity, excellent ring is surveyed characteristics such as performance and anti-yellowing property, this coating not only with metal plating sticking power excellence, well weather resistance, Tu Chu abrasion resistance properties especially.It is bad to have overcome existing vacuum coating surface protective coating wear resistance, and the shortcoming that protective capability is relatively poor has reached the ornamental and protective value requirement on consumption electronic product surfaces such as mobile phone, digital camera.Characteristics such as it is simple to have construction simultaneously, and easy to operate, suitability is wide.
In sum; the present invention is directed to the vacuum plating workpiece surface protection of electronic products such as mobile phone, MP3, digital camera; have characteristics such as good, super wear-resisting, the high-temp resisting high-humidity resisting of surface effect, cold-and-heat resistent circulation, anti-yellowing property excellence; wherein the highest can the reaching more than 1500 times of RCA abrasion effectively improved the work-ing life of electronic product.The present invention efficiently solves ultraviolet-curing vacuum coating ADHESION OF PAINTS power and wear resisting property, has solved the end, the finish paint corresponding problem of ultraviolet-curing vacuum coating coating, has versatility widely.
Embodiment
Following examples are intended to illustrate the present invention rather than with further qualification of the present invention.
Embodiment 1
Changxing 6071 10.0wt%
The synthetic 7605B 20.0wt% of Japan
DPHA 15.0wt％
Iso-bornyl acrylate 4.0wt%
CD 9051 8.0wt％
1-hydroxyl-cyclohexyl-phenyl ketone 4.0wt%
NANOBYK-3601 2.0wt％
BYK 333 0.1wt％
BYK 066 0.1wt％
Vinyl acetic monomer 21.8wt%
Butanone 10.0wt%
Ethylene glycol ether acetate 5.0wt%
Embodiment 2
Changxing 6075 20.0wt%
Special 5704 10.0wt% of cyanogen
The synthetic 7640B 10.0wt% of Japan
DPHA 10.0wt％
Special EB 168 1.0wt% of cyanogen
1-hydroxyl-cyclohexyl-phenyl ketone 4.0wt%
NANOBYK-3610 4.0wt％
BYK 307 0.5wt％
BYK 066 0.2wt％
BYK 164 0.3wt％
Vinyl acetic monomer 15.0wt%
Butanone 20.0wt%
Propylene-glycol ethyl ether 5.0wt%
Embodiment 3
Changxing 6071 20.0wt%
The special EB1290 25.0wt% of cyanogen
Tetramethylol methane tetraacrylate 10.0wt%
CD 9051 2.0wt％
2-hydroxy-2-methyl-1-phenyl-acetone 3.0wt%
NANOBYK-3610 5.0wt％
TEGO 432 0.2wt％
TEGO 920 0.2wt％
Vinyl acetic monomer 14.6wt%
N-BUTYL ACETATE 15.0wt%
Methyl iso-butyl ketone (MIBK) 5.0wt%
Embodiment 4
Special 5704 10.0wt% of cyanogen
PRO30000 20.0wt％
DPHA 10.0wt％
Vinyl pyrrolidone 15.0wt%
PHOTOMER 4703 2.0wt％
1-hydroxyl-cyclohexyl-phenyl ketone 4.0wt%
BYK 3777 0.2wt％
BYK UV3500 0.3wt％
DEUCHEM 2700 0.1wt％
EFKA 2721 0.2wt％
Vinyl acetic monomer 13.2wt%
N-BUTYL ACETATE 20.0wt%
Ethylene glycol ether acetate 5.0wt%
The vacuum coating ultraviolet curing coatings of above embodiment is sprayed on the ABS base material of vacuum plating, 60 ℃ infrared levelling 3-5 minute, effect is as follows behind the ultraviolet light polymerization:
| Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Testing method |
| Hardness | 2H | 2H | 2H | 2H | GB/T 6739-96 |
| Sticking power | 100/100 | 100/100 | 100/100 | 100/100 | GB/T 9286-88 |
| The RCA abrasion | 1200 times | 1100 times | 1500 times | 1000 times | The wear-resisting tester of Noman RCA (load 175g) |
| Cold-resistant thermal shocking | By | By | By | By | -40℃×1h～70℃×1h |
| High-temp resisting high-humidity resisting | By | By | By | By | 75℃×95％RH，48h |
| The salt spray resistance test | By | By | By | By | 35 ℃ * 85%RH, Ph=6.5-7.2,5% NaCl |
| Artificial perspiration resistance's liquid | By | By | By | By | Neutral solution, 5 days |
| The sunblock lotion test | OK | OK | OK | OK | 85℃×95％RH，120h |
| The QUV burn-in test | OK | OK | OK | OK | 12 cycles: 1 cycle=4h UV shines (UV-A, 340nm, 60 ℃)+4h wet environment (50 ℃) |
Illustrate: film thickness: 10 microns, ultraviolet photoetching energy: 1000mj/m
2
Claims (10)
1. a highly wearable vacuum coating ultraviolet curing coatings is characterized in that containing following component, and the weight percent of each component is:
Two functional polyurethane acrylate 10-30%
High functional polyurethane acrylate 10-40%
The high acrylate monomer 5-20% of functional group
Simple function group acrylate monomer 0-15%
Acid adhesion promoter 1-10%
Light trigger 1-6%
Nano wearproof material 0-5%
Auxiliary agent 0.1-2%
Solvent 10-50%
2. a kind of highly wearable vacuum coating ultraviolet curing coatings according to claim 1 is characterized in that, described two functional polyurethane acrylate are meant that functional group is 2 aliphatic urethane acrylate prepolymer.
3. a kind of highly wearable vacuum coating ultraviolet curing coatings according to claim 1 is characterized in that, described high functional polyurethane acrylate is meant that functionality is at 6～15 aliphatic urethane acrylate prepolymer.
4. a kind of highly wearable vacuum coating ultraviolet curing coatings according to claim 1 is characterized in that, described high functional group acrylate monomer is meant the acrylate monomer of 4～6 functional groups.
5. a kind of highly wearable vacuum coating ultraviolet curing coatings according to claim 1, it is characterized in that described high functional group acrylate monomer is: (alkoxylate) tetramethylol methane tetraacrylate, dipentaerythrityl ether five acrylate or dipentaerythrityl ether six acrylate (DPHA); Described simple function group acrylate monomer is meant ethoxy ethoxy ethyl propylene acid esters, (methyl) iso-bornyl acrylate, tetrahydrofuran (THF) (methyl) acrylate, hydroxy-cyclohexyl (methyl) acrylate, vinyl pyrrolidone or ring TriMethylolPropane(TMP) methylal acrylate.
6. a kind of highly wearable vacuum coating ultraviolet curing coatings according to claim 1 is characterized in that, the per-cent that the nano wearproof material accounts for the coating total amount is 1-5%.
7. a kind of highly wearable vacuum coating ultraviolet curing coatings according to claim 1 is characterized in that, described acid adhesion promoter contains the Acrylic Acid Monomer or the acrylic polymer of phosphoric acid modification.
8. a kind of highly wearable vacuum coating ultraviolet curing coatings according to claim 1, it is characterized in that, described light trigger is meant a kind of or mixture in 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxyl-cyclohexyl-phenyl ketone, two (2,4,6-Three methyl Benzene formyl) phenyl phosphine oxide.
9. a kind of highly wearable vacuum coating ultraviolet curing coatings according to claim 1 is characterized in that, described nano wearproof material is meant nano aluminium oxide or nano silicon.
10. a kind of highly wearable vacuum coating ultraviolet curing coatings according to claim 1 is characterized in that described auxiliary agent comprises flow agent, defoamer, wetting dispersing agent; Wherein the consumption of flow agent is the 0.1-1% of coating total amount, and the consumption of defoamer is the 0.1-0.5% of coating total amount; Described flow agent, defoamer use together or use separately; Described solvent is one or more the mixture in vinyl acetic monomer, N-BUTYL ACETATE, butanone, methyl iso-butyl ketone (MIBK), Virahol, propyl carbinol, diacetone alcohol, propylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol ether acetate, the propylene-glycol ethyl ether acetic ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100360219A CN100567413C (en) | 2007-11-01 | 2007-11-01 | Highly wearable vacuum coating ultraviolet curing coatings |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100360219A CN100567413C (en) | 2007-11-01 | 2007-11-01 | Highly wearable vacuum coating ultraviolet curing coatings |
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| Publication Number | Publication Date |
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| CN101157808A true CN101157808A (en) | 2008-04-09 |
| CN100567413C CN100567413C (en) | 2009-12-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2007100360219A Active CN100567413C (en) | 2007-11-01 | 2007-11-01 | Highly wearable vacuum coating ultraviolet curing coatings |
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| CN100567413C (en) | 2009-12-09 |
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