CN107227110A - A kind of high-performance vacuum coating UV finish paints - Google Patents

A kind of high-performance vacuum coating UV finish paints Download PDF

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Publication number
CN107227110A
CN107227110A CN201710507881.XA CN201710507881A CN107227110A CN 107227110 A CN107227110 A CN 107227110A CN 201710507881 A CN201710507881 A CN 201710507881A CN 107227110 A CN107227110 A CN 107227110A
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CN
China
Prior art keywords
parts
resin
vacuum coating
activated monomer
matrix resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710507881.XA
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Chinese (zh)
Inventor
李文彪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taicang Meihang Coatings Co Ltd
Original Assignee
Taicang Meihang Coatings Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taicang Meihang Coatings Co Ltd filed Critical Taicang Meihang Coatings Co Ltd
Priority to CN201710507881.XA priority Critical patent/CN107227110A/en
Publication of CN107227110A publication Critical patent/CN107227110A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of high-performance vacuum coating UV finish paints, including:Matrix resin, compounding resin, activated monomer, light trigger, auxiliary agent group and adhesion promoter are closed and formed, wherein, described matrix resin is 33 40 parts, described compounding resin is 20 30 parts, and described activated monomer is 15 22 parts, and described light trigger is 10 15 parts, described auxiliary agent is 58 parts, adhesion promoter is 13 parts, and described matrix resin is urethane acrylate, and described compounding resin is combined by negative resin and positive resin.By the above-mentioned means, the present invention can strengthen the adhesive force between priming paint and plastic basis material and the coat of metal, there is high activity, high glaze, less flexible, high rigidity, while also increasing the aesthetics of product surface.

Description

A kind of high-performance vacuum coating UV finish paints
Technical field
The present invention relates to paint field, more particularly to a kind of high-performance vacuum coating UV finish paints.
Background technology
Traditional solvent-borne vacuum metallizing coating species is more, using wide, but it has many birth defects, such as coating institute It is difficult to reconcile containing solvent, low boiling, the solvent of high volatile will upset coating surface in coating drying process because quickly volatilizing Planarization, there is pin hole and surface defect in cured film, and remain in the coating high volatile solvent during vacuum coating It can escape, coating quality will be caused to reduce, adhesive force, brightness deterioration;Solvent based coating contains substantial amounts of volatile component, right Environment is unfavorable;In addition, also there is curing efficiency bottom in solvent based coating, the disadvantage such as energy consumption height.
Disadvantages mentioned above has a strong impact on application of the solvent based coating in vacuum coating technology, the appearance of ultraviolet-curing paint Solvent based coating problems faced is solved well, with prominent advantage, thus is widely used vacuum coating technology In, and gradually substitute traditional solvent-borne coating.
The content of the invention
The present invention solves the technical problem of a kind of high-performance vacuum coating UV finish paints are provided, can strengthen priming paint with Adhesive force between plastic basis material and the coat of metal, has the advantages that high activity, high glaze, less flexible, high rigidity, while also increasing The aesthetics of product surface.
In order to solve the above technical problems, one aspect of the present invention is:A kind of high-performance vacuum coating is provided UV finish paints, it is characterised in that including:Matrix resin, compounding resin, activated monomer, light trigger, auxiliary agent group and adhesive force promote Agent is closed and formed, wherein, described matrix resin is 33-40 parts, and described compounding resin is 20-30 parts, described activated monomer For 15-22 parts, described light trigger is 10-15 parts, and described auxiliary agent is 5-8 parts, and adhesion promoter is 1-3 parts, described Matrix resin be urethane acrylate, described compounding resin combines by negative resin and positive resin.
In a preferred embodiment of the present invention, described matrix resin is 38 parts, and described compounding resin is 25 parts, institute The activated monomer stated is 15 parts, and described light trigger is 12 parts, and described auxiliary agent is 6 parts, and adhesion promoter is 1 part.
In a preferred embodiment of the present invention, described activated monomer is the acrylic acid list of the multiple functional radical of two functional groups Body, described light trigger is cation light initiator, and described auxiliary agent is levelling agent and anti-sagging agent.
In a preferred embodiment of the present invention, according to certain proportioning, first by 33-40 parts of matrix resin, 20-30 parts Compounding resin and the mixing of 15-22 part of activated monomer, be sufficiently stirred for, 10-15 parts light-initiated added after stirring 45 minutes Agent, 5-8 parts of auxiliary agent and 1-3 parts of adhesion promoter, were again stirring for after 45 minutes, standstill seal 12 hours, you can obtain Described high-performance vacuum coating UV finish paints.
The beneficial effects of the invention are as follows:Adhesive force between present invention enhancing priming paint and plastic basis material and the coat of metal, has The advantages of high activity, high glaze, less flexible, high rigidity, while also increasing the aesthetics of product surface.
Embodiment
Presently preferred embodiments of the present invention is described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that apparent clearly being defined so as to be made to protection scope of the present invention.
Embodiment 1
A kind of high-performance vacuum coating UV finish paints, it is characterised in that including:Matrix resin, compounding resin, activated monomer, light draw Hair agent, auxiliary agent group and adhesion promoter, which are closed, to be formed, wherein, described matrix resin is 33-40 parts, and described compounding resin is 20-30 parts, described activated monomer is 15-22 parts, and described light trigger is 10-15 parts, and described auxiliary agent is 5-8 parts, attached Adhesion promoter is 1-3 parts, and described matrix resin is urethane acrylate, and described compounding resin is by negative resin and Yang Shu Fat is combined.
Further illustrate, described matrix resin is 38 parts, described compounding resin is 25 parts, and described activated monomer is 15 parts, described light trigger is 12 parts, and described auxiliary agent is 6 parts, and adhesion promoter is 1 part.
Further illustrate, described activated monomer is the acrylic monomers of the multiple functional radical of two functional groups, described light draws Hair agent is cation light initiator, and described auxiliary agent is levelling agent and anti-sagging agent.
Further illustrate, according to certain proportioning, first by 33-40 parts of matrix resin, 20-30 parts of compounding resin and 15-22 parts of activated monomer mixing, is sufficiently stirred for, stirring added after 45 minutes 10-15 parts of light trigger, 5-8 parts help Agent and 1-3 parts of adhesion promoter, were again stirring for after 45 minutes, standstill seal 12 hours, you can obtain described high-performance Vacuum coating UV finish paints.
Further illustrating, described urethane acrylate(PUA)Molecule in contain acrylic-functional and amino Formic acid ester bond, the adhesive after solidification has the high-wearing feature of polyurethane, adhesion, pliability, high-peeling strength and excellent Resistance to low temperature and polyacrylate remarkable optical property and weatherability, are a kind of radiation curing materials of high comprehensive performance Material.
Embodiment 2
A kind of high-performance vacuum coating UV finish paints, it is characterised in that including:Matrix resin, compounding resin, activated monomer, light draw Hair agent, auxiliary agent group and adhesion promoter, which are closed, to be formed, wherein, described matrix resin is 33-40 parts, and described compounding resin is 20-30 parts, described activated monomer is 15-22 parts, and described light trigger is 10-15 parts, and described auxiliary agent is 5-8 parts, attached Adhesion promoter is 1-3 parts, and described matrix resin is urethane acrylate, and described compounding resin is by negative resin and Yang Shu Fat is combined.
Further illustrate, described matrix resin is 35 parts, described compounding resin is 28 parts, and described activated monomer is 18 parts, described light trigger is 10 parts, and described auxiliary agent is 7 parts, and adhesion promoter is 1 part.
Further illustrate, described activated monomer is the acrylic monomers of the multiple functional radical of two functional groups, described light draws Hair agent is cation light initiator, and described auxiliary agent is levelling agent and anti-sagging agent.
Further illustrate, according to certain proportioning, first by 33-40 parts of matrix resin, 20-30 parts of compounding resin and 15-22 parts of activated monomer mixing, is sufficiently stirred for, stirring added after 45 minutes 10-15 parts of light trigger, 5-8 parts help Agent and 1-3 parts of adhesion promoter, were again stirring for after 45 minutes, standstill seal 12 hours, you can obtain described high-performance Vacuum coating UV finish paints.
Further illustrating, described urethane acrylate(PUA)Molecule in contain acrylic-functional and amino Formic acid ester bond, the adhesive after solidification has the high-wearing feature of polyurethane, adhesion, pliability, high-peeling strength and excellent Resistance to low temperature and polyacrylate remarkable optical property and weatherability, are a kind of radiation curing materials of high comprehensive performance Material.
Embodiment 3
A kind of high-performance vacuum coating UV finish paints, it is characterised in that including:Matrix resin, compounding resin, activated monomer, light draw Hair agent, auxiliary agent group and adhesion promoter, which are closed, to be formed, wherein, described matrix resin is 33-40 parts, and described compounding resin is 20-30 parts, described activated monomer is 15-22 parts, and described light trigger is 10-15 parts, and described auxiliary agent is 5-8 parts, attached Adhesion promoter is 1-3 parts, and described matrix resin is urethane acrylate, and described compounding resin is by negative resin and Yang Shu Fat is combined.
Further illustrate, described matrix resin is 33 parts, described compounding resin is 30 parts, and described activated monomer is 15 parts, described light trigger is 11 parts, and described auxiliary agent is 8 parts, and adhesion promoter is 3 parts.
Further illustrate, described activated monomer is the acrylic monomers of the multiple functional radical of two functional groups, described light draws Hair agent is cation light initiator, and described auxiliary agent is levelling agent and anti-sagging agent.
Further illustrate, according to certain proportioning, first by 33-40 parts of matrix resin, 20-30 parts of compounding resin and 15-22 parts of activated monomer mixing, is sufficiently stirred for, stirring added after 45 minutes 10-15 parts of light trigger, 5-8 parts help Agent and 1-3 parts of adhesion promoter, were again stirring for after 45 minutes, standstill seal 12 hours, you can obtain described high-performance Vacuum coating UV finish paints.
Further illustrating, described urethane acrylate(PUA)Molecule in contain acrylic-functional and amino Formic acid ester bond, the adhesive after solidification has the high-wearing feature of polyurethane, adhesion, pliability, high-peeling strength and excellent Resistance to low temperature and polyacrylate remarkable optical property and weatherability, are a kind of radiation curing materials of high comprehensive performance Material.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, is included within the scope of the present invention.

Claims (4)

1. a kind of high-performance vacuum coating UV finish paints, it is characterised in that including:Matrix resin, compounding resin, activated monomer, light Initiator, auxiliary agent group and adhesion promoter are closed and formed, wherein, described matrix resin is 33-40 parts, described compounding resin For 20-30 parts, described activated monomer is 15-22 points, and described light trigger is 10-15 parts, and described auxiliary agent is 5-8 parts, Adhesion promoter is 1-3 parts, and described matrix resin is urethane acrylate, and described compounding resin is by negative resin and sun Resin combination is formed.
2. a kind of high-performance vacuum coating UV finish paints according to claim 1, it is characterised in that:Described matrix resin is 38 parts, described compounding resin is 25 parts, and described activated monomer is 15 parts, and described light trigger is 12 parts, and described helps Agent is 6 parts, and adhesion promoter is 1 part.
3. a kind of high-performance vacuum coating UV finish paints according to claim 1, it is characterised in that:Described activated monomer is The acrylic monomers of the multiple functional radical of two functional groups, described light trigger is cation light initiator, and described auxiliary agent is stream Flat agent and anti-sagging agent.
4. a kind of high-performance vacuum coating UV finish paints according to claim 1, it is characterised in that:According to certain proportioning, First 33-40 parts of matrix resin, 20-30 parts of compounding resin and 15-22 parts of activated monomer are mixed, is sufficiently stirred for, stirs 10-15 parts of light trigger, 5-8 parts of auxiliary agent and 1-3 parts of adhesion promoter is added after 45 minutes, 45 points are again stirring for Zhong Hou, standstill seal 12 hours, you can obtain described high-performance vacuum coating UV finish paints.
CN201710507881.XA 2017-06-28 2017-06-28 A kind of high-performance vacuum coating UV finish paints Pending CN107227110A (en)

Priority Applications (1)

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CN201710507881.XA CN107227110A (en) 2017-06-28 2017-06-28 A kind of high-performance vacuum coating UV finish paints

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Application Number Priority Date Filing Date Title
CN201710507881.XA CN107227110A (en) 2017-06-28 2017-06-28 A kind of high-performance vacuum coating UV finish paints

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108822721A (en) * 2018-07-13 2018-11-16 安徽康瑞高科新材料技术工程有限公司 A kind of vacuum coating UV coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101157808A (en) * 2007-11-01 2008-04-09 凌云剑 Highly wearable vacuum coating ultraviolet curing coatings
CN101280154A (en) * 2007-04-06 2008-10-08 上海海优威电子技术有限公司 Ultraviolet curing vacuum metallizing coating
CN104530924A (en) * 2014-12-22 2015-04-22 湖州南浔双林振森实木加工厂 Ultraviolet curing coating and preparation method thereof
CN105131797A (en) * 2015-09-22 2015-12-09 太仓市金鹿电镀有限公司 Plastic electroplating technology for automobile trim strips

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280154A (en) * 2007-04-06 2008-10-08 上海海优威电子技术有限公司 Ultraviolet curing vacuum metallizing coating
CN101157808A (en) * 2007-11-01 2008-04-09 凌云剑 Highly wearable vacuum coating ultraviolet curing coatings
CN104530924A (en) * 2014-12-22 2015-04-22 湖州南浔双林振森实木加工厂 Ultraviolet curing coating and preparation method thereof
CN105131797A (en) * 2015-09-22 2015-12-09 太仓市金鹿电镀有限公司 Plastic electroplating technology for automobile trim strips

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108822721A (en) * 2018-07-13 2018-11-16 安徽康瑞高科新材料技术工程有限公司 A kind of vacuum coating UV coating and preparation method thereof

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Application publication date: 20171003