CN1840595A - Aqueous wood paint and method for preparing same - Google Patents
Aqueous wood paint and method for preparing same Download PDFInfo
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- CN1840595A CN1840595A CN 200510065482 CN200510065482A CN1840595A CN 1840595 A CN1840595 A CN 1840595A CN 200510065482 CN200510065482 CN 200510065482 CN 200510065482 A CN200510065482 A CN 200510065482A CN 1840595 A CN1840595 A CN 1840595A
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Abstract
The invention discloses a water-based woodenware paint comprising the following constituents: core-shell type water-based propylene acid polyurethane emulsion 50-90%, pigment 0-20%, filling material 1-20%, anion generating material 1-10%, other auxiliary agent 1-10%, and deionized water 1-20%.
Description
Technical field
The present invention relates to a kind of house fitting-up and paint and preparation method thereof, the spraying water-based property of especially a kind of furniture wood lacquer and preparation method thereof.
Background technology
Traditional wood lacquer is generally solvent-borne type paint, the polyurethane paint that uses in a large number up till now from early stage phenolic paint, alkyd paint, pyroxylin(e)finish, all contain a large amount of volatile organic solvents, in coating material production and use, discharge a large amount of harmful organic compound (VOC).Along with various countries' environmental regulation to the restriction of VOC and to the attention day by day of environmental protection, the solvent-borne type wood lacquer is subjected to unprecedented challenge.Thus, aqueous woodware paint arises at the historic moment, and becomes the focus of numerous R﹠D institutions and the research and development of coating material production enterprise.
As woodwork coating, should meet following several primary condition: good beautify, decoration functions; Compliance with environmental protection requirements has the excellent protection function; Has the workability that adapts to multiple constructional method; Have good matching capacity and economy.Above-mentioned these problems, be aqueous woodware paint research and development the problem that must consider and face.At present the most of aqueous woodware paints that use all contain toxic gas after tested, and part content severe overweight, and brushing is on buildings, woodwork top layer, and that can give people healthyly brings bigger infringement.By disclosed relevant aqueous wooden ware paint formula as can be known, its poor performance, when Toxic matter reduced, the temperature tolerance of paint film, tack and hardness etc. decreased.
Summary of the invention
Order of the present invention is to provide a kind of and can purifies air, and compliance with environmental protection requirements is to nontoxic aqueous woodware paint of HUMAN HEALTH and preparation method thereof.
For achieving the above object, the invention discloses following technical scheme, a kind of aqueous woodware paint, comprise following component (weight percent): nuclear-shell mould water soluble acrylic acid polyaminoester emulsion 50～90%, pigment 0～20%, filler 1～20%, anion-generating material 1～10%, other auxiliary agent 1～10%, deionized water 1～20%.
Aqueous woodware paint of the present invention, with nuclear-shell mould acroleic acid polyurethane polymer emulsion is base-material, cooperate with face, filler, anion-generating material and other auxiliary agent to form, a kind of aqueous woodware paint of the present invention has taken into full account wood structure and characteristic, has considered the basic demand that wood lacquer is covered with paint, lacquer, colour wash, etc.So, this aqueous woodware paint fast drying, easy construction, paint film mechanical property excellence, strong adhesion can be widely used in the covering with paint and the protection of wooden articles.
Concrete composition of the used constituent of the present invention and consumption are as follows:
Nuclear-shell mould acroleic acid polyurethane polymer emulsion solid is divided into 30～45%, and the consumption of this emulsion in aqueous woodware paint is 50～90%, and optimum amount is 70～90%.
Pigment can be Rutile type Titanium Dioxide, carbon black, phthalein cyanogen indigo plant, red iron oxide, iron oxide black, iron oxide yellow, red, lemon yellow etc.
Filler is talcum powder, light calcium carbonate, kaolin, zinc sulfide white etc.
Anion-generating material is the tourmaline powder through rare-earth activated processing, and its particle size range is 2000～12500 orders, and the consumption in wood lacquer is 1～10%, can select different meshes and consumption according to different needs.
The present invention is adjuvant used to be comprised:
Thickening material can singlely be selected for use or compound propylene soda acid swelling type and the polyurethane associative thickener selected for use, preferentially selects associative thickener in the present invention for use.As the peaceful Thickener 631 of section, Thickener 642, Thicklevelling 632, Thicklevelling HAS 625,, DSX-1550, DSX 3075 etc.
Defoamer is generally selected the organic silicon modified by polyether class, as section peaceful Dehydran 1293, FoamStarA32, FoamStar A34 etc.
It is the salt of vinyl monomer and copolymers of unsaturated carboxylic acids that dispersion agent is generally selected for use, as the peaceful Hydropalat 5040 of section, Hydropalat 34, Hydropalat 875 etc.
The pH regulator agent is the volatility organic amine.For example: monoethanolamine, AMP-95, N, N-dimethylethanolamine etc.
A kind of aqueous woodware paint of the present invention prepares according to following steps:
(1) add the accurately deionized water of metering of warp in the paint container, wetting agent and defoamer stirred 10～15 minutes with adjustable high-speed dispersion machine (down together), and rotating speed is 400～500rpm.
(2) press formula rate and add nuclear-core-shell polymers emulsion, stirred 10～15 minutes, rotating speed is 500～600rpm.
(3) press formula rate and add extender paste and rare-earth activated negative ion generation powder slurry, stirred rotating speed 500～600rpm 15～30 minutes.
(4) add thickening material, flow agent stirred 5～10 minutes, and rotating speed is 800～1000rpm.
(5) with 400 purpose screen filtrations, packing promptly obtains needed aqueous woodware paint with negative ion releasing function.
Beneficial effect of the present invention is at high glass transition temperature acrylic ester emulsion or polyaminoester emulsion ornamental bad, shortcomings such as paint film is easy to crack, selected a kind of core-shell type aqueous acroleic acid polyurethane dispersion, and in the process of paint, add a kind of anion-generating material, mix with pigment, filler, siccative and other auxiliary agent, process through operations such as dispersion, grindings, this lacquer not only can reduce the discharging of toxic substance, and can discharge a large amount of negative ions, play the effect that purifies air, strengthens HUMAN HEALTH.
Embodiment
In order better to set forth the present invention, enumerate following example and illustrated, but example is not a limitation of the present invention.
1 one kinds of aqueous woodware paints of embodiment comprise following component (numerical value is weight percentage):
Component title weight percent %
Nuclear-shell acroleic acid polyurethane emulsion 70
Titanium dioxide R706 10
Talcum powder 1250 orders 5
Light calcium carbonate 800 orders 5
Rare-earth activated negative ion powder 1250 orders 2
Thickening material DSX-1550 0.4
Defoamer FoamStar A34 0.6
Dispersion agent Hydropalat 5,040 0.4
PH regulator agent AMP95 0.2
Deionized water 6.4
100
The preparation method: 1. add the accurately deionized water of metering of warp in the paint container, defoamer and dispersion agent stirred 10～15 minutes with adjustable high-speed dispersion machine (down together), and rotating speed is 400～500rpm.2. press formula rate and add nuclear-shell acroleic acid polyurethane emulsion, stirred 10～15 minutes, rotating speed is 500～600rpm.3. press formula rate and add titanium dioxide, talcum powder, light calcium carbonate extender paste and rare-earth activated anion-generating material powder slurry, stirred rotating speed 500～600rpm 15～30 minutes.
(4) add thickening material, flow agent and pH regulator agent were stirred 5～10 minutes, and rotating speed is 800～1000rpm.
(5) with 400 purpose screen filtrations, packing promptly obtains needed aqueous woodware paint with negative ion releasing function.
2 one kinds of aqueous woodware paints of embodiment comprise following component:
Component title weight percent %
Nuclear-shell acroleic acid polyurethane emulsion 55
Titanium dioxide R244 15
Talcum powder 1250 orders 5
Light calcium carbonate 800 orders 5
Rare-earth activated negative ion powder 4000 orders 5
Thickening material Thickener 631 0.4
Defoamer FoamStar A32 0.4
Dispersion agent Hydropalat 140 0.6
PH regulator agent AMP95 0.2
Deionized water 13.4
100
The preparation method is with embodiment 1
3 one kinds of aqueous woodware paints of example comprise following several component:
Component title weight percent %
Nuclear-shell acroleic acid polyurethane emulsion 65
Titanium dioxide R706 15
Rare-earth activated negative ion powder 10000 orders 10
Thickening material DSX-3075 0.6
Defoamer FoamStar A34 0.4
Dispersion agent Hydropalat 875 0.6
PH regulator agent AMP95 0.2
Deionized water 8.2
100
The preparation method is with embodiment 1
Claims (5)
1, a kind of aqueous woodware paint comprises following component (weight percent): core-shell type water soluble acrylic acid polyaminoester emulsion 50～90%, pigment 0～20%, filler 1～20%, anion-generating material 1～10%, other auxiliary agent 1～10%, deionized water 1～20%; Its preparation method comprises the steps:
(1) add the accurately deionized water of metering of warp in the paint container, wetting agent and defoamer stirred 10～15 minutes with adjustable high-speed dispersion machine (down together), and rotating speed is 400～500rpm;
(2) press formula rate and add the core-shell type polymer emulsion, stirred 10～15 minutes, rotating speed is 500～600rpm;
(3) press formula rate and add extender paste and rare-earth activated negative ion generation powder slurry, stirred rotating speed 500～600rpm 15～30 minutes;
(4) add thickening material, flow agent stirred 5～10 minutes, and rotating speed is 800～1000rpm;
(5) with 400 purpose screen filtrations, packing promptly obtains needed aqueous woodware paint with negative ion releasing function.
2, core-shell type water soluble acrylic acid polyaminoester emulsion according to claim 1, it is characterized in that: the solid of this emulsion is divided into 30～45%, and the optimum amount in woodenware is 70～90%.
3, pigment according to claim 1 is characterized in that: used pigment is Rutile type Titanium Dioxide or carbon black or phthalein cyanogen indigo plant or red iron oxide or iron oxide black or iron oxide yellow or red or lemon yellow.
4, filler according to claim 1 is characterized in that: used filler is talcum powder or light calcium carbonate or kaolin or zinc sulfide white.
5, anion-generating material according to claim 1 is characterized in that: used anion material is the tourmaline powder through rare-earth activated processing, and its particle size range is 2000～12500 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510065482 CN1840595A (en) | 2005-04-01 | 2005-04-01 | Aqueous wood paint and method for preparing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510065482 CN1840595A (en) | 2005-04-01 | 2005-04-01 | Aqueous wood paint and method for preparing same |
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| CN1840595A true CN1840595A (en) | 2006-10-04 |
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| CN 200510065482 Pending CN1840595A (en) | 2005-04-01 | 2005-04-01 | Aqueous wood paint and method for preparing same |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974277A (en) * | 2010-10-29 | 2011-02-16 | 浙江菲达中科精细化学品有限公司 | White waterborne wood base coat for medium density fiberboard and preparation technology thereof |
| CN102134434A (en) * | 2011-03-08 | 2011-07-27 | 三棵树涂料股份有限公司 | High-performance water-based white sealing primer |
| CN102260446A (en) * | 2011-04-29 | 2011-11-30 | 广州立邦涂料有限公司 | Hydrophobic single-component polyurethane lawn paint and preparing method thereof |
| CN104119800A (en) * | 2014-07-15 | 2014-10-29 | 三棵树涂料股份有限公司 | Special-effect heath indoor wall aqueous paint composition and preparation method thereof |
| CN104629576A (en) * | 2015-01-19 | 2015-05-20 | 安徽嘉年华漆业有限公司 | High-performance water-based wood coating |
| CN104629574A (en) * | 2015-01-19 | 2015-05-20 | 安徽嘉年华漆业有限公司 | High-water-resistance antibacterial waterborne woodware coating |
| CN105255354A (en) * | 2015-10-08 | 2016-01-20 | 江苏华夏制漆科技有限公司 | Butanone-resistant water-borne acrylic polyurethane paint and preparing method thereof |
| CN105462477A (en) * | 2015-12-15 | 2016-04-06 | 沪宝新材料科技（上海）股份有限公司 | Water-borne wood paint capable of releasing negative ions and production process thereof |
| CN105131804B (en) * | 2015-10-08 | 2017-06-06 | 杨年富 | UV anion waterborne radiation curable coatings |
| CN106891405A (en) * | 2017-01-19 | 2017-06-27 | 苏州正泽木业有限公司 | A kind of processing method of anion timber and the timber |
| CN108102484A (en) * | 2018-01-05 | 2018-06-01 | 吕跃文 | Single-component water-based forest negative oxygen ion woodcare paint and preparation method thereof |
| CN109485306A (en) * | 2018-09-30 | 2019-03-19 | 石家庄常宏建筑装饰工程有限公司 | The green woodcare paint face artificial board and preparation method thereof of anion can be discharged |
| CN113122084A (en) * | 2020-01-11 | 2021-07-16 | 中科(深圳)微能量科学技术研究院有限公司 | Water-based air purification paint and preparation method thereof |
| CN114085577A (en) * | 2021-12-23 | 2022-02-25 | 东莞市涂芭新材料有限公司 | Water-based antiviral negative oxygen ion woodenware coating and preparation method thereof |
| CN114456672A (en) * | 2022-01-19 | 2022-05-10 | 三棵树(上海)新材料研究有限公司 | High-adhesion water-based single-component wood coating for multiple substrates and preparation method thereof |
-
2005
- 2005-04-01 CN CN 200510065482 patent/CN1840595A/en active Pending
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974277B (en) * | 2010-10-29 | 2013-01-16 | 浙江菲达中科精细化学品有限公司 | White waterborne wood base coat for medium density fiberboard and preparation technology thereof |
| CN101974277A (en) * | 2010-10-29 | 2011-02-16 | 浙江菲达中科精细化学品有限公司 | White waterborne wood base coat for medium density fiberboard and preparation technology thereof |
| CN102134434A (en) * | 2011-03-08 | 2011-07-27 | 三棵树涂料股份有限公司 | High-performance water-based white sealing primer |
| CN102260446A (en) * | 2011-04-29 | 2011-11-30 | 广州立邦涂料有限公司 | Hydrophobic single-component polyurethane lawn paint and preparing method thereof |
| CN104119800B (en) * | 2014-07-15 | 2017-12-08 | 三棵树涂料股份有限公司 | Water-based coating compositions of special efficacy health indoor wall and preparation method thereof |
| CN104119800A (en) * | 2014-07-15 | 2014-10-29 | 三棵树涂料股份有限公司 | Special-effect heath indoor wall aqueous paint composition and preparation method thereof |
| CN104629576A (en) * | 2015-01-19 | 2015-05-20 | 安徽嘉年华漆业有限公司 | High-performance water-based wood coating |
| CN104629574A (en) * | 2015-01-19 | 2015-05-20 | 安徽嘉年华漆业有限公司 | High-water-resistance antibacterial waterborne woodware coating |
| CN105255354A (en) * | 2015-10-08 | 2016-01-20 | 江苏华夏制漆科技有限公司 | Butanone-resistant water-borne acrylic polyurethane paint and preparing method thereof |
| CN105131804B (en) * | 2015-10-08 | 2017-06-06 | 杨年富 | UV anion waterborne radiation curable coatings |
| CN105462477A (en) * | 2015-12-15 | 2016-04-06 | 沪宝新材料科技（上海）股份有限公司 | Water-borne wood paint capable of releasing negative ions and production process thereof |
| CN106891405A (en) * | 2017-01-19 | 2017-06-27 | 苏州正泽木业有限公司 | A kind of processing method of anion timber and the timber |
| CN108102484A (en) * | 2018-01-05 | 2018-06-01 | 吕跃文 | Single-component water-based forest negative oxygen ion woodcare paint and preparation method thereof |
| CN109485306A (en) * | 2018-09-30 | 2019-03-19 | 石家庄常宏建筑装饰工程有限公司 | The green woodcare paint face artificial board and preparation method thereof of anion can be discharged |
| CN113122084A (en) * | 2020-01-11 | 2021-07-16 | 中科(深圳)微能量科学技术研究院有限公司 | Water-based air purification paint and preparation method thereof |
| CN114085577A (en) * | 2021-12-23 | 2022-02-25 | 东莞市涂芭新材料有限公司 | Water-based antiviral negative oxygen ion woodenware coating and preparation method thereof |
| CN114456672A (en) * | 2022-01-19 | 2022-05-10 | 三棵树(上海)新材料研究有限公司 | High-adhesion water-based single-component wood coating for multiple substrates and preparation method thereof |
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