CN109485306A - The green woodcare paint face artificial board and preparation method thereof of anion can be discharged - Google Patents
The green woodcare paint face artificial board and preparation method thereof of anion can be discharged Download PDFInfo
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- CN109485306A CN109485306A CN201811159492.3A CN201811159492A CN109485306A CN 109485306 A CN109485306 A CN 109485306A CN 201811159492 A CN201811159492 A CN 201811159492A CN 109485306 A CN109485306 A CN 109485306A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses green woodcare paint face artificial boards that can discharge anion and preparation method thereof, belong to the technical field of Building decorating and repairs engineering, environment-friendly building materials.The preparation method that the green woodcare paint face artificial board of anion can be discharged is that raw material is carried out removal of impurities processing after pretreatment again, amorphous silica is processed as crystalline silica, ion inducing agent is then prepared, finally prepares wood-based plate.Wood-based plate energy-saving and environmental protection prepared by the present invention, conveniently, safely, can form complete anion layer in panel surface, just capable of releasing negative ion under natural conditions.
Description
Technical field
The invention belongs to the technical fields of Building decorating and repairs engineering, are related to environment-friendly building materials and its production technology, specifically
Say it is that one kind can discharge green woodcare paint face artificial board of anion and preparation method thereof.
Background technique
Conventionally produced decorative panel is due to that can seriously endanger the body of user containing harmful substances such as formaldehyde, VOC
Health, it is therefore desirable to reduce the introducing and discharge of harmful substance.At the same time, in order to meet people to high quality healthy living
The characteristics of pursuing, decorative panel and people's life is made full use of to be in close contact, so that it is had environment regulatory function is also industry research
Hot spot.
Currently, the content of negative oxygen ion has been taken as a major criterion of evaluation environment and air quality in air, it is empty
On the one hand adjustable positive and negative ion concentration ratio, another aspect can play the role of purifying air negative oxygen ion in gas again.Cause
This, anion burst size is to measure an important reference indicator of ecological board quality in wood-based plate.
In the prior art, negative ion releasing function is introduced in wood-based plate and be mainly the following method: (1) adding in substrate
Anion material (CN101269513B) is used during work;(2) addition is negative in facing and substrate bonding adhesive used
Anion material and adhesive are used together (CN104354399B) in bonding by ionic material (CN103909695A);
(3) increase by one layer of anion material film (CN105544919B) between facing and substrate;(4) negative in facing or middle addition
Ionic material (CN107938425A, CN106042569B).Wherein method (1) consumption anion material is larger, and method (2) is only fitted
For being applicable in adhesion technique, the part with negative ion releasing function of method (1) (2) (3) is not in ecological board surface layer, method
(4) better than first three methods from the structure of ecological board, and the following process of facing is flexible, is applicable to a variety of geometric forms
The outer packing of the furniture building materials ecological board of shape, the expansion of application are stronger.(note: anion material, which refers to, has release anion function
The material of energy)
But when there is the facing of negative ion releasing function using the production of technology disclosed in method 4, need by impregnation technology twice,
Such as given in the Chinese patent of Publication No. CN106042569B and make facing by the way of double-steeping technique,
Add anion inducing agent in impregnation technology twice, and anion material dosage is the 8% ~ 20% of adhesive dosage, bear from
Sub- materials'use amount is larger, and the heat pressing process time in later period is long;Simultaneously as the anion being added in impregnation technology twice lures
Hair agent be powdery, will cause be unevenly distributed, subsequent facing out-of-flatness, it is easy to crack the problems such as.To implement, implement the national new period
The Architecture Policies of " be applicable in, be economic, green, beauty ", are badly in need of proposing more advanced technical solution, guarantee plate environmental protection, simultaneously
The application of anion material is reduced, and can be avoided the above problem.
Summary of the invention
The purpose of the present invention, it is desirable to provide one kind can discharge green woodcare paint face artificial board and its preparation of anion
Method.Under conditions of harmful additive, complete anion layer is formed in panel surface, discharges anion.
To achieve the above object, used technical solution specifically includes that the present invention
A kind of preparation method for the green woodcare paint face artificial board that can discharge anion, including the following step successively carried out
It is rapid:
One, it pre-processes
Fibrous rich magnesium silicate, sulfate, rare earth ore are put into oxalic acid and are purified, wherein the rich magnesium silicate,
The mass ratio of sulfate, rare earth ore and oxalic acid is 1:0.2:2:3, and less than 8%, the purification time is not less than the concentration of the oxalic acid
8h obtains pure rich magnesium silicate, sulfate and rare earth ore to contamination precipitation;
Meanwhile unformed shape silica is heated to 300 DEG C, make wherein soluble silicon acid content be down to 30-40%, obtain crystal
Shape silica D;
Two, high temperature cleans
By pure rich magnesium silicate, sulfate and rare earth ore, high-temperature baking is carried out, grey materials A is obtained;
Three, material mixes
By south red agate, red jasper, strawberry crystalline substance, labradorite, color coloured glaze high-temperature baking together with grey materials A, mixture B is obtained,
Mixture B is tentatively ground, orange particle C is obtained;
Wherein, south red agate, red jasper, strawberry crystalline substance, labradorite, color coloured glaze and grey materials A mass ratio are 1:1:2:2:2:8;
Four, ion inducing agent is prepared
It is crushed after orange particle C and lenticular silica D are sufficiently mixed, particulate material E is obtained, by particulate material
E high-temperature baking obtains substance F;Wherein, the mass ratio of orange particle C and lenticular silica D are 5:2;
Substance F, defoaming agent, neutral solubization auxiliary agent and macromolecule polyurethane solution are mixed, the ion of white gum is obtained
Inducing agent G;Wherein, the mass ratio of the substance F, defoaming agent, neutral solubization auxiliary agent and macromolecule polyurethane solution is 1:
0.02:0.02:0.5;
Five, wood-based plate is prepared
Substrate base is successively carried out to levelling, polishing, spraying seal coat, spray paint, the obtained wood-based plate of cleaning finishing, wherein
It joined 2-6% ion inducing agent G in the finishing coat of spraying.
The bottom closing paint and finishing coat sprayed in this step is woodcare paint, and since woodcare paint paint has certain sticky spy
Property, therefore the different woodcare paint of density needs to consider the brushing surface and brushing technique and the brushing number of plies of woodcare paint, such as density
For the woodcare paint of 1:1.15 ~ 1.25, the anion inducing agent of addition is 2 ~ 2.5 %, makes every square metre when as finishing coat spraying
Brushing weight in 0.25KG or so, spraying is once advisable.
And density is the woodcare paint of 1:1.25 ~ 1.35, the anion inducing agent of addition is 2.5 ~ 3.5%, is sprayed as finishing coat
When, so that every square metre of brushing weight, in 0.40KG or so, spraying is once advisable.
In the woodcare paint that density is 1:1.35 ~ 1.5, the anion inducing agent of addition is 3.5 ~ 4.5 %, is sprayed as finishing coat
Tu Shi, so that every square metre of brushing weight, in 0.50KG or so, spraying is once advisable.
In the woodcare paint that density is 1:1.5 ~ 1.75, the anion inducing agent of addition is 4.5 ~ 6 %, is sprayed as finishing coat
When, so that every square metre of brushing weight, in 0.50KG or so, spraying is once advisable.
As restriction, to the high-temperature baking of pure rich magnesium silicate, sulfate and rare earth ore in the step 2
Condition are as follows: temperature is not less than 150 DEG C, and baking time is no less than for 24 hours.
It is limited as another kind, to south red agate, red jasper, strawberry crystalline substance, labradorite, color coloured glaze and ash in the step 3
The condition of color materials A high-temperature baking are as follows: heating temperature is not less than 700 DEG C, and baking time is no less than 6h.
As the third restriction, orange particle C and lenticular silica D are crushed in the step 4, crushed
It is crossed afterwards not less than 3000 meshes.
It is limited as the 4th kind, to the condition of particulate material E high-temperature baking in the step 4 are as follows: heating temperature is not low
In 500 DEG C, baking time is no less than 6h.
It is limited as the 5th kind, to the condition of particulate material E high-temperature baking in the step 4 are as follows: in the step 4
The condition that substance F, defoaming agent, neutral solubization auxiliary agent and macromolecule polyurethane solution are mixed are as follows: mixing speed is not low
In 800r/min, mixing time is no less than 2h.
As the restriction to step 5 of the present invention: described to be additionally provided between the step of spraying seal coat and spray paint
The step of spraying colored paint.
The present invention also provides one kind can discharge the green woodcare paint face artificial board of anion, according to it is above-mentioned can be with
The preparation method for discharging the green woodcare paint face artificial board of anion is prepared.
Beneficial effects of the present invention are as follows:
(1) preparation method that the present invention uses has carried out multiple purification, removal of impurities processing to ore, has eliminated 85% or more radiation
Property element and heavy metal element, the wood-based plate of preparation are safe and reliable;
(2) anion inducing agent used is liquid in the present invention, can be preferably in conjunction with all kinds of paint, sheet material;
(3) present invention will use after anion inducing agent and woodcare paint mixing, and inducing agent dosage is few, save the cost;
(4) production method that the present invention uses, color of paint are completely covered by anion inducing agent, do not need the programs such as foaming,
Construction efficiency is high;
(5) woodcare paint decoration panel produced by the present invention, is capable of forming complete anion layer, just releasably bear under natural conditions from
Son, and additive, based on natural ore powder, lacquer painting plate surface strength is higher, without adding harmful additive such as reinforcing agent.
In conclusion utilizing the green woodcare paint face artificial that can discharge anion made from production method of the invention
Plate is more energy efficient, environmentally friendly, conveniently, safely, and just capable of releasing negative ion in its natural state.
Specific embodiment
Below with reference to embodiment, the invention will be further described, it is understood by those skilled in the art that of the invention
It is not limited to following embodiment, any improvements and changes made on the basis of the specific embodiment of the invention are all in right of the present invention
It is required that protection within the scope of.
Embodiment 1 can discharge the preparation method of the green woodcare paint face artificial board of anion
The present embodiment is prepared in accordance with the following steps:
One, it pre-processes
It is to purify in 8% oxalic acid that 10kg rich magnesium silicate, 2kg sulfate, 20kg rare earth ore, which are put into the concentration that concentration is 30kg,
8h obtains pure rich magnesium silicate, sulfate, rare earth ore to contamination precipitation.
Unformed shape silica is warmed to 300 DEG C, make wherein soluble silicon acid content be down to 40%, obtain lenticular two
Silica D1.Silica has many advantages, such as that pH is neutral, nontoxic, suspension is good, strong adsorption at this time, it is often more important that have pair
Alpha-ray radioactive ray has good comprehensive.
Two, removal of impurities is handled
Pure rich magnesium silicate, sulfate, rare earth ore are toasted for 24 hours at 150 DEG C, obtain grey materials A.High-temperature baking can be gone
Except the radioactive element and heavy metal element in mineralising crystal, removal rate is up to 60%.
Three, material mixes
By 5kg south red agate, the red jasper of 5kg, 10kg strawberry crystalline substance, 10kg labradorite, 10kg coloured silk coloured glaze and 40kg grey materials A in
700 DEG C of baking 6h, can remove impurity, obtain substance B 1.Substance B 1 is tentatively ground using grinder, obtains orange particle
C1。
Four, ion inducing agent is prepared
It is crushed after the orange particle C1 of 50kg and 20kg lenticular silica D1 are sufficiently mixed, smashes it through 3000 mesh
Sieve, the particulate material E1 after must being sieved obtain substance F1 by particulate material E1 in 500 DEG C of high-temperature baking 6h.
80kg substance F1,1.6kg defoaming agent, 1.6kg neutrality solubization auxiliary agent and 40kg macromolecule polyurethane solution are mixed
Stirring is closed, mixing speed 800r/min obtains white gum ion inducing agent G1 after stirring 2h.
Five, wood-based plate is prepared
Substrate base is successively carried out to levelling, polishing, spraying seal coat, spray paint, the obtained wood-based plate of cleaning finishing, wherein
It joined 2.4% ion inducing agent G1 in the finishing coat of spraying.
The specific operation process of this step are as follows: substrate base treatment-scrapes one sandpapering of oil putty --- spraying first pass
Painting (seal coat) --- (colored paint does not require such as, this link can save second time paint of spraying according to production demand
Slightly) --- last is sprayed all over paint (finishing coat, this link add anion inducing agent) --- clear up finishing.
(1) Puttying: utilize the embedding criticize flat of putty whole at the incomplete place such as crack, nail hole of treated substrate base.
(2) dry sanding paper: after putty is completely dried, surface is tied using dry sanding paper.Should not be worn out by film when dry sanding paper, it protects
Corner has been protected, has been careful not to stay loose putty trace.It should clean up after having ground, and be cleaned the dust being scattered with damp cloth.
(3) spray bottom closing paint: this step sprays first pass woodcare paint, and tune will carefully examine Check after having sprayed, and sees that whether there is or not leakages to brush
Place.
(4) Puttying: after first pass paint parches, to bottom putty contraction place or having incomplete place, need to be careful with putty again
It criticizes and scrapes once.
(7) spray colored paint: this step sprays second time woodcare paint, mixes colours as needed, if necessary to keep log
Color does not need then to spray.When paying attention to after the completion of spraying using new sand paper, two sand paper opposite grindings must grind off coarse sand grains, prevent
Only destroy paint films.
(9) spray paint;This step sprays last all over woodcare paint, and joined 2.4% ion inducing agent in woodcare paint
G1.When spraying it is noted that paint do not flow do not fall, it is bright uniformly, color it is consistent.
Embodiment 2-7 can discharge the preparation method of the green woodcare paint face artificial board of anion
Embodiment 2-7 is respectively the preparation method that one kind can discharge the green woodcare paint face artificial board of anion, with implementation
The method of example 1 is essentially identical, the difference is that the technical parameter of preparation process is different, design parameter is as shown in table 1:
Effect example
Using the green woodcare paint face artificial board that anion can be discharged made from preparation method in embodiment 1 to 7 bear from
Sub- releasing effect is as shown in table 2:
Root bone requirements of the national standard (JCT 2040-2010 " anion function indoor decoration material "), anion correlation material
The material amount of inducing is 500/cm2;Anion burst size of the present invention reaches 1000/cm2 or more.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention
Within protection scope.
Claims (8)
1. the preparation method that one kind can discharge the green woodcare paint face artificial board of anion, it is characterised in that it includes successively
The following steps of progress:
One, it pre-processes
Fibrous rich magnesium silicate, sulfate, rare earth ore are put into oxalic acid and are purified, wherein the rich magnesium silicate,
The mass ratio of sulfate, rare earth ore and oxalic acid is 1:0.2:2:3, and less than 8%, the purification time is not less than the concentration of the oxalic acid
8h obtains pure rich magnesium silicate, sulfate and rare earth ore to contamination precipitation;
Meanwhile unformed shape silica is heated to 300 DEG C, make wherein soluble silicon acid content be down to 30-40%, obtain crystal
Shape silica D;
Two, high temperature cleans
By pure rich magnesium silicate, sulfate and rare earth ore, high-temperature baking is carried out, grey materials A is obtained;
Three, material mixes
By south red agate, red jasper, strawberry crystalline substance, labradorite, color coloured glaze high-temperature baking together with grey materials A, mixture B is obtained,
Mixture B is tentatively ground, orange particle C is obtained;
Wherein, south red agate, red jasper, strawberry crystalline substance, labradorite, color coloured glaze and grey materials A mass ratio are 1:1:2:2:2:8;
Four, ion inducing agent is prepared
It is crushed after orange particle C and lenticular silica D are sufficiently mixed, particulate material E is obtained, by particulate material
E high-temperature baking obtains substance F;Wherein, the mass ratio of orange particle C and lenticular silica D are 5:2;
Substance F, defoaming agent, neutral solubization auxiliary agent and macromolecule polyurethane solution are mixed, the ion of white gum is obtained
Inducing agent G;Wherein, the mass ratio of the substance F, defoaming agent, neutral solubization auxiliary agent and macromolecule polyurethane solution is 1:
0.02:0.02:0.5;
Five, wood-based plate is prepared
Substrate base is successively carried out to levelling, polishing, spraying seal coat, spray paint, the obtained wood-based plate of cleaning finishing, wherein
It joined 2-6% ion inducing agent G in the finishing coat of spraying.
2. the preparation method of the green woodcare paint face artificial board according to claim 1 that can discharge anion, special
Sign is, to the condition of the high-temperature baking of pure rich magnesium silicate, sulfate and rare earth ore in the step 2 are as follows: temperature
Not less than 150 DEG C, baking time is no less than for 24 hours.
3. the preparation method of the green woodcare paint face artificial board according to claim 1 or 2 that anion can be discharged,
It is characterized in that, south red agate, red jasper, strawberry crystalline substance, labradorite, color coloured glaze and grey materials A high temperature is dried in the step 3
Roasting condition are as follows: heating temperature is not less than 700 DEG C, and baking time is no less than 6h.
4. the preparation method of the green woodcare paint face artificial board according to claim 1 or 2 that anion can be discharged,
It is characterized in that: orange particle C and lenticular silica D being crushed in the step 4, smashed it through not less than 3000
Mesh.
5. the preparation method of the green woodcare paint face artificial board according to claim 1 or 2 that anion can be discharged,
It is characterized in that, to the condition of particulate material E high-temperature baking in the step 4 are as follows: heating temperature is not less than 500 DEG C, when baking
Between no less than 6h.
6. the preparation method of the green woodcare paint face artificial board according to claim 1 or 2 that anion can be discharged,
It is characterized in that, substance F, defoaming agent, neutral solubization auxiliary agent and macromolecule polyurethane solution is mixed in the step 4
Condition are as follows: mixing speed is not less than 800r/min, and mixing time is no less than 2h.
7. the preparation method of the green woodcare paint face artificial board according to claim 1 that can discharge anion, special
The step of sign is, is additionally provided with spraying colored paint in the step 5 between the step of spraying seal coat and spray paint.
8. the green woodcare paint face artificial board that one kind can discharge anion, it is characterised in that: appoint in -7 according to claim 1
The green woodcare paint face artificial board preparation method of anion can be discharged by anticipating described in a claim is prepared.
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CN110237662A (en) * | 2019-07-08 | 2019-09-17 | 石家庄常宏建筑装饰工程有限公司 | The plate aldehyde remover and preparation method thereof of anion can be discharged |
CN110396324A (en) * | 2019-09-12 | 2019-11-01 | 河北森雅环保新材料科技有限公司 | The production method for inducing the water paint and its functional powders and auxiliary agent of negative oxygen ion |
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Application publication date: 20190319 |