CN111807702A - Method for manufacturing glazed tile with glazed three-dimensional effect - Google Patents
Method for manufacturing glazed tile with glazed three-dimensional effect Download PDFInfo
- Publication number
- CN111807702A CN111807702A CN202010779596.5A CN202010779596A CN111807702A CN 111807702 A CN111807702 A CN 111807702A CN 202010779596 A CN202010779596 A CN 202010779596A CN 111807702 A CN111807702 A CN 111807702A
- Authority
- CN
- China
- Prior art keywords
- parts
- glazed
- mixture
- powder
- frit particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
The invention discloses a method for manufacturing glazed tiles with glazed three-dimensional effect, which belongs to the technical field of ceramic building materials and comprises the following operation processes: step S1: preparing frit particles, mixing various frit particles, adding water into the mixture, and uniformly mixing and stirring to obtain a mixture, wherein the weight ratio of the mixture to the water is 1: 0.55; step S2: and putting the mixture into a ball mill for ball milling treatment. According to the invention, through the mutual matching of the materials such as the designed black talc, the inorganic nano material, the silver powder, the sulfate, the carbonic acid compound, the sepiolite, the calcined talcum powder, the fly ash and the grinding aid, the formation of pinholes, bubbles and holes can be avoided to a large extent under the condition that the particle size of the frit particles is relatively large, and the frit particles cannot be easily sucked away by negative pressure air flow on a preheating belt in a kiln due to the relatively large particle size of the frit particles, so that the decorative effect of the glaze surface stereoscopic effect can be improved to a certain extent.
Description
Technical Field
The invention belongs to the technical field of ceramic building materials, and particularly relates to a method for manufacturing glazed tiles with a glazed three-dimensional effect.
Background
The glazed tile is a glazed tile which is formed by firing the surface of the tile at high temperature and high pressure, and consists of an adobe and a glazed surface, wherein the main body of the glazed tile is formed by argil and china clay, the back fired by the argil is red, and the back fired by the china clay is grey white. The glazed tile may have various patterns and figures, and has color and pattern more than polished tile, and the surface has glaze material and thus less wear resistance than polished tile.
With the fusion of various tile process technologies and the use of new effect materials, various tile products with special decorative effects are continuously emerging. Consumers are also more and more in demand for ceramic tile products with different concave-convex three-dimensional surfaces, the ceramic tile three-dimensional decoration effect in the existing market is that frit particles with certain thickness are paved on the surface of a blank body through a cloth mode, the frit particles are matched with sizing materials to be fixed, the three-dimensional qualitative effect is completed after high-temperature calcination, but some problems exist, when the frit particles are large in size, pinholes, air bubbles, holes and other adverse phenomena are easily generated, when the size of the frit particles is small, the frit particles are easily sucked away by negative pressure air flow on a preheating zone in a kiln, so that arrangement of the frit particles is changed, the three-dimensional effect is influenced, and therefore, the method for manufacturing the glazed tile with the glaze three-dimensional effect is urgently needed in the market at the present stage to solve the problems.
Disclosure of Invention
The invention aims to: in order to solve the three-dimensional decoration effect of the ceramic tile in the existing market, frit particles with certain thickness are mostly laid on the surface of a blank body in a material distribution mode, and are matched with a sizing material for fixing, the three-dimensional qualitative effect is completed after high-temperature calcination, but some problems exist, when the mesh of the frit particles is large, adverse phenomena such as pinholes, air bubbles, holes and the like are easily generated, and when the mesh of the frit particles is small, the frit particles are easily absorbed by negative pressure air flow on a preheating belt in a kiln, so that the arrangement of the frit particles is changed, and the three-dimensional effect is influenced.
In order to achieve the purpose, the invention adopts the following technical scheme:
a method of manufacturing a glazed tile having a glazed three-dimensional effect, comprising the following operational procedures:
step S1: preparing frit particles, mixing various frit particle ingredients, adding water into the mixture, mixing and stirring uniformly to obtain a mixture, wherein the weight ratio of the mixture to the water is 1: 0.55;
step S2: putting the mixture into a ball mill for ball milling treatment, and then sieving to obtain slurry with the particle fineness of 180 meshes;
step S3: filter-pressing the slurry to dewater to obtain mud cakes with the water content of 9 percent, coarsely refining the mud cakes by a mud refining machine, and then aging to prepare the mud cakes into particles for later use;
step S4: secondly, spraying a layer of water repellent on the surface of the porcelain tile green body layer or the surface of the glaze layer, then paving the frit particles prepared in the step S1 with a certain thickness on the surface of the water repellent, and finally spraying a layer of frit particle fixing adhesive;
step S5: drying and firing the ceramic tile green body to obtain the glazed tile with high-strength three-dimensional effect.
As a further description of the above technical solution:
the frit particle ingredient comprises the following raw materials in parts by weight:
18-25 parts of feldspar powder, 35-55 parts of black talc, 10-19 parts of diatomite, 2.4-5 parts of inorganic nano material, 0.1-0.7 part of silver powder, 2-8 parts of carbonate, 1-5 parts of sulfate, 22-28 parts of spherical titanium alloy metal powder, 20-25 parts of sepiolite, 15-20 parts of nano iron oxide, 9-10 parts of cohesive soil, 5-10 parts of calcined talcum powder, 6-19 parts of magnesia, 1-3 parts of fly ash, 1.5-6 parts of limestone, 11-18 parts of grinding aid and 6-17 parts of magnesium chloride solution.
As a further description of the above technical solution:
the feldspar powder is formed by mixing albite powder and potassium feldspar powder, and the weight ratio of the albite powder to the potassium feldspar powder is 1: 9. .
As a further description of the above technical solution:
the particle fineness obtained in the step S5 is 190-220 meshes, the water content of the mud cake obtained in the step S3 is 9%, the drying temperature in the step S3 is 40-50 ℃, the drying humidity is 60-70%, and the drying time under the conditions is 10-12 h.
As a further description of the above technical solution:
the spherical titanium alloy metal powder comprises 90% of titanium, 6% of aluminum and 4% of vanadium by mass, and the average grain size is 15-53 mu m.
As a further description of the above technical solution:
the grinding aid is polyacrylamide, the molecular weight of the grinding aid is 2000 ten thousand, and the solid content of the grinding aid is 95%.
In summary, due to the adoption of the technical scheme, the invention has the beneficial effects that:
1. according to the invention, through the mutual matching of the materials such as the designed black talc, the inorganic nano material, the silver powder, the sulfate, the carbonate compound, the sepiolite, the calcined talcum powder, the fly ash and the grinding aid, the formation of pinholes, bubbles and holes can be avoided to a large extent under the condition that the particle size of the frit particles is relatively large, and the frit particles cannot be easily sucked away by negative pressure airflow on a preheating belt in a kiln due to the relatively large particle size of the frit particles, so that the decorative effect of the glaze surface stereoscopic effect can be improved to a certain extent.
2. In the invention, through the designed feldspar powder and black talc, the main components of the albite powder and the black talc are SiO2 and Al2O3, and the albite powder and the black talc also contain partial alkali oxides such as Na2O, K2O and the like, the content of the introduced SiO2 and Al2O3 is correspondingly increased, the substances are continuously fused in a high-temperature liquid phase at high temperature, the viscosity of the liquid phase is improved, the resistance of pore expansion is increased, the pore diameter of the formed pore is reduced, through the designed diatomite, the diatomite is used as a matrix of a frit particle ingredient, the diatomite has larger specific surface area, small contractibility and large pores, is beneficial to the fusion of the feldspar powder and the black talc, through the designed inorganic nano material and silver powder, and through the high-temperature compounding of the inorganic nano material and the silver powder, a smooth and high-brightness nano glaze film layer can be obtained, the temperature resistance is high, the acid and alkali resistance is good, and a certain antibacterial effect is achieved, through the designed carbonic acid compound and sulfate, the sprayed magnesium chloride solution can help substances such as carbonic compound, sulfate and the like in the ingredients to be completely decomposed before vitrification of the ingredients, the magnesium chloride solution is prepared from anhydrous magnesium chloride, in the blank firing process, chemical reaction is firstly carried out to generate basic magnesium chloride, and the generated basic magnesium chloride then reacts with substances such as carbonic compound, sulfate and the like in the blank, so that the substances such as carbonic compound, sulfate and the like which are difficult to decompose can generate gas to be decomposed below the temperature required by vitrification of the ingredients, the generated gas smoothly permeates the ingredients to be discharged, and pores are prevented from being formed on a glaze surface.
3. According to the invention, through the designed spherical titanium alloy metal powder, the mass fraction of titanium in the spherical titanium alloy metal powder is 90%, the mass fraction of aluminum is 6%, the mass fraction of vanadium is 4%, the average particle size is 15 μm, the spherical titanium alloy metal powder treated by the soaking solution can improve the fluidity of the ingredients, is beneficial to the precipitation of crystals in the sintering process, greatly improves the color and luster of a metallic luster glaze surface, enhances the anti-cracking performance, the apparent porosity, the wear resistance and other performances of the glaze surface through the designed sepiolite, has high strength, good acid-base resistance and wear resistance, reduces the thermal expansion coefficient, enhances the thermal stability, ensures that the fired glaze surface has few pinholes, is fine and fine, has good glossiness, greatly improves the glaze hardness, and can effectively reduce the viscosity of a glaze layer in the glaze surface calcination process through the designed nano iron oxide, the defects of pores and the like on the surface of a glaze body are reduced, the clay is designed, the clay refers to the soil with more clay particles and smaller water permeability, the compacted clay has good water stability, higher strength, large capillary action, fine particles, more and smaller pores and weak water permeability, has expansion and contraction characteristics, and the mechanical property changes along with the water content, and the magnesium soil and the fly ash which are designed provide Mg and can react with the fly ash to form cordierite, so that the thermal shock resistance of a glaze layer is improved, and mullite can be generated in the firing process, so that the breaking strength and the thermal shock resistance of the glaze layer are improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be described below clearly and completely in connection with the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a technical scheme that: a method of manufacturing a glazed tile having a glazed three-dimensional effect, comprising the following operational procedures:
step S1: preparing frit particles, mixing various frit particle ingredients, adding water into the mixture, mixing and stirring uniformly to obtain a mixture, wherein the weight ratio of the mixture to the water is 1: 0.55;
step S2: putting the mixture into a ball mill for ball milling treatment, and then sieving to obtain slurry with the particle fineness of 180 meshes;
step S3: filter-pressing the slurry to dewater to obtain mud cakes with the water content of 9 percent, coarsely refining the mud cakes by a mud refining machine, and then aging to prepare the mud cakes into particles for later use;
step S4: secondly, spraying a layer of water repellent on the surface of the porcelain tile green body layer or the surface of the glaze layer, then paving the frit particles prepared in the step S1 with a certain thickness on the surface of the water repellent, and finally spraying a layer of frit particle fixing adhesive;
step S5: drying and firing the ceramic tile green body to obtain the glazed tile with high-strength three-dimensional effect.
Specifically, the frit particle ingredients comprise the following raw materials in parts by weight:
18-25 parts of feldspar powder, 35-55 parts of black talc, 10-19 parts of diatomite, 2.4-5 parts of inorganic nano material, 0.1-0.7 part of silver powder, 2-8 parts of carbonate, 1-5 parts of sulfate, 22-28 parts of spherical titanium alloy metal powder, 20-25 parts of sepiolite, 15-20 parts of nano iron oxide, 9-10 parts of cohesive soil, 5-10 parts of calcined talcum powder, 6-19 parts of magnesia, 1-3 parts of fly ash, 1.5-6 parts of limestone, 11-18 parts of grinding aid and 6-17 parts of magnesium chloride solution.
Specifically, the feldspar powder is formed by mixing the albite powder and the potash feldspar powder, the weight ratio of the albite powder to the potash feldspar powder is 1:9, the albite powder and the black talc in the feldspar powder are designed, the albite powder and the black talc are mainly composed of SiO2 and Al2O3, and also contain partial alkali oxides such as Na2O and K2O, the content of the introduced SiO2 and Al2O3 is correspondingly increased, the substances are continuously melted in a high-temperature liquid phase at high temperature, the viscosity of the liquid phase is improved, the resistance of pore expansion is increased, the pore diameter of a formed pore is reduced, the sprayed magnesium chloride solution can help the substances such as carbonic compound and sulfate in the ingredients to be completely decomposed before the ingredients are vitrified, the magnesium chloride solution is prepared from anhydrous magnesium chloride, and during blank firing, a chemical reaction is firstly generated to generate basic magnesium chloride, the generated basic magnesium chloride reacts with substances such as carbonic acid compounds, sulfate and the like in the blank, so that the substances such as carbonic acid compounds, sulfate and the like which are difficult to decompose can generate gas to be decomposed below the temperature required by vitrification of ingredients, the generated gas smoothly permeates the ingredients to be discharged, and pores are prevented from being formed on the glaze surface.
Specifically, the particle fineness obtained in the step S5 is 190-220 meshes, the water content of the mud cake obtained in the step S3 is 9%, the drying temperature in the step S3 is 40-50 ℃, the drying humidity is 60-70%, and the drying time under the conditions is 10-12 h.
Specifically, the mass fraction of titanium in the spherical titanium alloy metal powder is 90%, the mass fraction of aluminum is 6%, the mass fraction of vanadium is 4%, and the average particle size is 15-53 μm, through the designed spherical titanium alloy metal powder, the mass fraction of titanium in the spherical titanium alloy metal powder is 90%, the mass fraction of aluminum is 6%, the mass fraction of vanadium is 4%, and the average particle size is 15 μm, and the spherical titanium alloy metal powder treated by the soaking solution can improve the fluidity of ingredients, is beneficial to the precipitation of crystals in the sintering process, and greatly improves the color of a metal gloss glaze.
Specifically, the grinding aid is polyacrylamide, the molecular weight of the grinding aid is 2000 ten thousand, and the solid content of the grinding aid is 95%.
The working principle is as follows: when the glazed tile is used, frit particles are prepared, various frit particles are mixed, water is added into the mixture, the mixture is mixed and stirred uniformly, the weight ratio of the mixture to the water is 1:0.55, the mixture is placed into a ball mill for ball milling treatment, then the mixture is sieved, slurry with the particle fineness of 180 meshes is obtained, filter pressing slurry is dehydrated to obtain a mud cake with the water content of 9%, the mud cake is subjected to coarse refining by a mud mill and is aged to prepare particles for standby, then a layer of water repellent is sprayed on the surface of a porcelain tile green body layer or the surface of a glazed layer, then frit particles prepared in the step S1 are laid on the surface of the water repellent in a certain thickness, finally a layer of frit particle fixing adhesive is sprayed, the porcelain tile green body is dried, and the glazed tile with the high-strength three-dimensional effect is obtained.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be able to cover the technical scope of the present invention, the technical solutions and the inventive concepts of the present invention with equivalent or modified alternatives and modifications within the technical scope of the present invention.
Claims (6)
1. A method for manufacturing glazed tiles with glazed three-dimensional effect is characterized by comprising the following operation flows:
step S1: preparing frit particles, mixing various frit particles, adding water into the mixture, and uniformly mixing and stirring to obtain a mixture, wherein the weight ratio of the mixture to the water is 1: 0.55;
step S2: putting the mixture into a ball mill for ball milling treatment, and then sieving to obtain slurry with the particle fineness of 180 meshes;
step S3: filter-pressing the slurry to dewater to obtain mud cakes with the water content of 9 percent, coarsely refining the mud cakes by a mud refining machine, and then aging to prepare the mud cakes into particles for later use;
step S4: secondly, spraying a layer of water repellent on the surface of the porcelain tile green body layer or the surface of the glaze layer, then paving frit particles prepared in the step S1 with a certain thickness on the surface of the water repellent, and finally spraying a layer of frit particle fixing adhesive;
step S5: drying and firing the ceramic tile green body to obtain the glazed tile with high-strength three-dimensional effect.
2. The method of claim 1, wherein the frit bead formulation comprises the following raw materials in parts by weight:
18-25 parts of feldspar powder, 35-55 parts of black talc, 10-19 parts of diatomite, 2.4-5 parts of inorganic nano material, 0.1-0.7 part of silver powder, 2-8 parts of carbonate, 1-5 parts of sulfate, 22-28 parts of spherical titanium alloy metal powder, 20-25 parts of sepiolite, 15-20 parts of nano iron oxide, 9-10 parts of cohesive soil, 5-10 parts of calcined talcum powder, 6-19 parts of magnesia, 1-3 parts of fly ash, 1.5-6 parts of limestone, 11-18 parts of grinding aid and 6-17 parts of magnesium chloride solution.
3. The method of claim 2, wherein the feldspar powder is a mixture of albite powder and potash feldspar powder, and the weight ratio of the albite powder to the potash feldspar powder is 1: 9. .
4. The method as claimed in claim 2, wherein the fineness of the particles prepared in the step S5 is 190-220 meshes, the water content of the mud cake prepared in the step S3 is 9%, the drying temperature in the step S3 is 40-50 ℃, the drying humidity is 60-70%, and the drying time under the conditions is 10-12 h.
5. A method of manufacturing a glazed tile having a glazed spatial effect as claimed in claim 2, wherein the spherical titanium alloy metal powder has a titanium mass fraction of 90%, an aluminum mass fraction of 6%, a vanadium mass fraction of 4% and an average particle size of 15-53 μm.
6. A method of manufacturing a glazed tile having a glazed spatial effect as claimed in claim 2, wherein the grinding aid is polyacrylamide having a molecular weight of 2000 ten thousand and a solid content of 95%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010779596.5A CN111807702A (en) | 2020-08-05 | 2020-08-05 | Method for manufacturing glazed tile with glazed three-dimensional effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010779596.5A CN111807702A (en) | 2020-08-05 | 2020-08-05 | Method for manufacturing glazed tile with glazed three-dimensional effect |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111807702A true CN111807702A (en) | 2020-10-23 |
Family
ID=72863679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010779596.5A Pending CN111807702A (en) | 2020-08-05 | 2020-08-05 | Method for manufacturing glazed tile with glazed three-dimensional effect |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111807702A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115246709A (en) * | 2022-08-01 | 2022-10-28 | 河北浩锐陶瓷制品有限公司 | High-flatness ceramic tile and production process thereof |
| CN116177996A (en) * | 2023-01-07 | 2023-05-30 | 广东欧文莱陶瓷有限公司 | Method for preparing ceramic tile with rich touch sense by adopting partition printing technology |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102108029A (en) * | 2009-12-29 | 2011-06-29 | 陈干礼 | Nanometer intelligent cleaning antibacterial pearl ceramic glaze |
| CN104311157A (en) * | 2014-09-23 | 2015-01-28 | 佛山市禾才科技服务有限公司 | Glazed brick production method |
| CN105439532A (en) * | 2015-11-23 | 2016-03-30 | 黄亚奇 | High-performance pottery and preparation method thereof |
| CN106467413A (en) * | 2015-08-14 | 2017-03-01 | 许昌学院 | The resintering method that imitation Song-Dynasty-style typeface an ancient unit of weight official's porcelain is fired based on nano-sized iron oxide glaze and its serial imitation Song-Dynasty-style typeface an ancient unit of weight official's porcelain fired |
| CN108558211A (en) * | 2018-04-23 | 2018-09-21 | 卢皆彬 | A kind of low fever at temperature metal bright glaze preparation method |
| CN108675756A (en) * | 2018-06-05 | 2018-10-19 | 陈太师 | A kind of glazed tile and preparation method thereof |
| CN109400218A (en) * | 2018-12-20 | 2019-03-01 | 湖北宜都市兴达陶瓷有限公司 | A kind of enameling method for preventing sanitary ceramics from generating pore |
| CN111138165A (en) * | 2019-12-30 | 2020-05-12 | 肇庆乐华陶瓷洁具有限公司 | Brick with temperature for porcelain brick kiln and preparation method and application thereof |
| CN111285606A (en) * | 2020-01-23 | 2020-06-16 | 福建省德化县尚品陶瓷有限公司 | High-hardness wear-resistant ceramic glaze and preparation method thereof |
-
2020
- 2020-08-05 CN CN202010779596.5A patent/CN111807702A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102108029A (en) * | 2009-12-29 | 2011-06-29 | 陈干礼 | Nanometer intelligent cleaning antibacterial pearl ceramic glaze |
| CN104311157A (en) * | 2014-09-23 | 2015-01-28 | 佛山市禾才科技服务有限公司 | Glazed brick production method |
| CN106467413A (en) * | 2015-08-14 | 2017-03-01 | 许昌学院 | The resintering method that imitation Song-Dynasty-style typeface an ancient unit of weight official's porcelain is fired based on nano-sized iron oxide glaze and its serial imitation Song-Dynasty-style typeface an ancient unit of weight official's porcelain fired |
| CN105439532A (en) * | 2015-11-23 | 2016-03-30 | 黄亚奇 | High-performance pottery and preparation method thereof |
| CN108558211A (en) * | 2018-04-23 | 2018-09-21 | 卢皆彬 | A kind of low fever at temperature metal bright glaze preparation method |
| CN108675756A (en) * | 2018-06-05 | 2018-10-19 | 陈太师 | A kind of glazed tile and preparation method thereof |
| CN109400218A (en) * | 2018-12-20 | 2019-03-01 | 湖北宜都市兴达陶瓷有限公司 | A kind of enameling method for preventing sanitary ceramics from generating pore |
| CN111138165A (en) * | 2019-12-30 | 2020-05-12 | 肇庆乐华陶瓷洁具有限公司 | Brick with temperature for porcelain brick kiln and preparation method and application thereof |
| CN111285606A (en) * | 2020-01-23 | 2020-06-16 | 福建省德化县尚品陶瓷有限公司 | High-hardness wear-resistant ceramic glaze and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 梁树林: "《日用陶瓷制造技术》", 31 March 1984, 农业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115246709A (en) * | 2022-08-01 | 2022-10-28 | 河北浩锐陶瓷制品有限公司 | High-flatness ceramic tile and production process thereof |
| CN116177996A (en) * | 2023-01-07 | 2023-05-30 | 广东欧文莱陶瓷有限公司 | Method for preparing ceramic tile with rich touch sense by adopting partition printing technology |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107032772B (en) | A kind of light-transmittance ceramics brick and preparation method thereof | |
| CN112500196B (en) | Ceramic tile with stereoscopic gem particle feeling glaze and preparation method thereof | |
| CN108424111A (en) | A kind of ceramic plate and preparation method thereof greatly of light dry granular polishing | |
| CN103693942A (en) | Low-temperature fast-fired ceramic tile and production process thereof | |
| CN107266023B (en) | Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method | |
| CN106116501A (en) | A kind of method that glazed tile waste residue recycles | |
| CN106220017A (en) | A kind of inhibitor suppressing ceramic tile polishing waste residue high temperature sintering to foam and method | |
| CN109502981A (en) | Golden tailing and granite tailing are the foamed ceramic composite plate and preparation method thereof of major ingredient | |
| CN102503436A (en) | Production method for ultra low temperature rapid firing vitrification ceramic brick | |
| CN110483013A (en) | A kind of high-flatness Dali stone ceramic tile | |
| CN108892490A (en) | A kind of green body and preparation method thereof enhancing Imitation Rock Porcelain Tiles paving adhesion strength | |
| CN106673435A (en) | Wearproof frit dry granules using waste glaze as main raw material and preparation method thereof | |
| CN102093078B (en) | Lightweight energy-saving natural stone simulated ceramic decorative material and manufacturing method thereof | |
| CN101805209A (en) | Matt porcelain glaze prepared by using waste porcelains and production method thereof | |
| CN111807702A (en) | Method for manufacturing glazed tile with glazed three-dimensional effect | |
| US6743383B2 (en) | Process for the production of ceramic tiles | |
| CN102503142B (en) | Dry particles for crystal polishing tiles sintered at one step and application thereof | |
| CN108484114A (en) | A kind of glaze Imitation Rock Porcelain Tiles of high additive polished waste material and preparation method thereof | |
| CN106698945A (en) | Glazed tile with waste glaze as glaze raw material and preparation method thereof | |
| CN101353248A (en) | Method for producing porous brick with construction sanitary ceramic cold-working waste slag | |
| CN106116472A (en) | A kind of method that glazed tile waste residue recycles | |
| CN110511011B (en) | Stain-resistant polished brick and manufacturing method thereof | |
| CN107651940A (en) | A kind of Imitation Rock Porcelain Tiles containing high additive polished waste material and preparation method thereof | |
| TW201741265A (en) | Large ceramic plate and manufacturing method therefor being excellent in freeze-thaw resistance, strength and thermal shock resistance | |
| CN108751714A (en) | A kind of preparation method of wear-resisting glazed ceramic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20201023 |
|
| RJ01 | Rejection of invention patent application after publication |