CN106116501A - A kind of method that glazed tile waste residue recycles - Google Patents

A kind of method that glazed tile waste residue recycles Download PDF

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Publication number
CN106116501A
CN106116501A CN201610481680.2A CN201610481680A CN106116501A CN 106116501 A CN106116501 A CN 106116501A CN 201610481680 A CN201610481680 A CN 201610481680A CN 106116501 A CN106116501 A CN 106116501A
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China
Prior art keywords
waste residue
glazed tile
glazed
base substrate
tile waste
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Pending
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CN201610481680.2A
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Inventor
萧礼标
周锡荣
刘军
刘一军
王贤超
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Monalisa Group Co Ltd
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Monalisa Group Co Ltd
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Priority to CN201610481680.2A priority Critical patent/CN106116501A/en
Publication of CN106116501A publication Critical patent/CN106116501A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201Alkali metal oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3436Alkaline earth metal silicates, e.g. barium silicate
    • C04B2235/3454Calcium silicates, e.g. wollastonite
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The present invention relates to a kind of method that glazed tile waste residue recycles, utilize glazed tile waste residue to prepare secondary and burn ceramic glazed bricks, comprise the steps: the preparation of blank raw material: by contain by mass percentage 30~50% glazed tile waste residue blank raw material mixing and ball milling after powder process form powder, the chemical composition after wherein said blank raw material makes base substrate burn till is: SiO2: 66~71%;Al2O3: 16~18.5%;Fe2O3: 0.1~1.5%;TiO2: 0.1~0.5%;CaO:5.0~8.5%;MgO:0.5~2.0%;K2O:1.2~2.5%;Na2O:1.0~2.2%;By the powder molding of gained, be dried, biscuiting, execute ground-coat enamel, execute cover-coat enamel, glaze firing prepare secondary burn ceramic glazed bricks.Glazed tile producer a large amount of glazed tile waste residue that the present invention both can solve to polish faces the problem of process, can save again substantial amounts of raw material.

Description

A kind of method that glazed tile waste residue recycles
Technical field
The invention belongs to ceramic building material field, be specifically related to a kind of method that glazed tile waste residue recycles.
Background technology
In recent years, while ceramic industry develops rapidly, polishing glazed tile commercially occupation rate is more and more higher, While driving economic development, also bring the problem making us puzzlement, that is, it is a large amount of useless that adobe surface produces after grinding The top of the slag faces process, the most mostly takes the mode of landfill, along with country realizes the strict demand of sustainable development to economy, takes The waste residue that a kind of more scientific mode processes ceramic industry seems the most urgent.
It is known that Ceramic Tiles is divided without glaze series and has glaze series, before polishing glazed tile comes into the market, institute in industry The polished bricks claimed refers to the unglazed tile series of polishing actually, and polishing slag also refers to the waste residue that the unglazed tile of polishing produces, along with Popularizing of polishing glazed tile product, also creates substantial amounts of glazed tile waste residue.Due between unglazed tile and glazed tile in technique, property Having obvious difference on can, the abrading block (including the composition of abrading block, structure) that adobe surface uses in polishing process is the most not With, this also result in polishing slag and glazed tile waste residue has bigger difference in performance.Have in the market and much relate to profit With the Patents of ceramic waste residue, such as application number CN200810220413.5, entitled " a kind of super large specification porous ceramic plate And manufacture method " its feature of patent prepare light porous ceramic mainly by polishing slag foam characteristics at high temperature Plate.Application number CN200910038098.9, entitled " a kind of fine stoneware tile utilizing industrial residue to produce " described industrial residue are porcelain Matter polished bricks polishing process produces sewage collecting and forms, and remains as polishing slag series, and in its illustrated embodiment, product Water absorption rate is beyond the category of fine stoneware tile.CN102617123A, entitled " polishing slag is utilized to manufacture ceramic tile blank and glazed tile Formula and method " disclose utilize polishing slag manufacture secondary burn pottery base substrate method.Pottery involved by above patent Waste residue is all polishing slag.
But, the relevant report of Ceramic Tiles is not the most prepared individually with glazed tile waste residue, it main reason is that Do not make the difference in the characteristic between glazed tile waste residue and polishing slag clear and they separate collections are used.If can handle Both waste residues are used separately, and more can effectively play respective effect.
Summary of the invention
The problem existed for prior art, it is an object of the invention to provide the side that a kind of glazed tile waste residue recycles Method, utilizes glazed tile waste residue to prepare the ceramic glazed bricks that secondary burns.
The present invention provides a kind of method that glazed tile waste residue recycles, and utilizes glazed tile waste residue to prepare the ceramic that secondary burns Glazed tile, comprises the steps:
The preparation of blank raw material: by contain by mass percentage 30~50% glazed tile waste residue blank raw material mixing and ball milling after Powder process forms powder, and the chemical composition after wherein said blank raw material makes base substrate burn till is: SiO2: 66~71%;Al2O3: 16~ 18.5%;Fe2O3: 0.1~1.5%;TiO2: 0.1~0.5%;CaO:5.0~8.5%;MgO:0.5~2.0%;K2O:1.2 ~2.5%;Na2O:1.0~2.2%;
By the powder molding of gained, be dried, biscuiting, execute the end, cover-coat enamel, glaze firing prepare secondary and burn ceramic glazed bricks.
In the present invention, the chemical composition of described glazed tile waste residue can be: burns and loses (IL): 2.0~4.5%;SiO2: 58~ 68%;Al2O3: 19~25%;Fe2O3: 0~2.0%;TiO2: 0~1.0%;CaO:1.0~4.0%;MgO:0~1.5%; K2O:0.5~3.0%;Na2O:1.0~4.0%.
It is preferred that described glazed tile waste residue obtains by the following method: the waste water produced in glazed tile polishing process is converged Collection, to cesspool, adds appropriate flocculant and makes settlement of sewage, becomes moisture content to be less than the filter of 30% sludge press filtration after precipitation Block, then smashes filter block and fully all mixes stand-by.The present invention can collect glazed tile waste residue by simple method.
In the present invention, blank raw material comprises the steps that by mass percentage, glazed tile waste residue 30~50%, clay 12~ 18%, limestone 7~11%, wollastonite 0~3%, quartz 3~13%, remaining be sand material.
It is preferred that during mixing and ball milling, be additionally added relative to raw material gross mass 0~the base substrate reinforcing agent of 0.3%, 0.6~ The waterglass of 1.5% and 0~the dispersant of 0.4%.In the present invention, base substrate reinforcing agent can strengthen the intensity of base substrate, waterglass, Dispersant can improve slurry fluidity.
It is preferred that the mode of described molding is dry-pressing formed, pressing pressure is 28~40MPa.
It is preferred that dried base substrate water content is 0~1.5%.
It is preferred that dried base substrate carries out biscuiting, firing temperature is 1100~1160 DEG C, and firing period is 30~60 points Clock.
It is preferred that base substrate is after biscuiting, execute ground-coat enamel, cover-coat enamel, alternatively, it is also possible to be aided with stamp.
It is preferred that the base substrate after glazing carries out glaze firing, firing temperature is 1010~1060 DEG C, and firing period is 35~60 points Clock.
On the other hand, the secondary that the present invention also provides for being prepared by any one method above-mentioned burns ceramic glazed bricks.
Accompanying drawing explanation
Fig. 1 illustrates the process chart of one example of the present invention.
Detailed description of the invention
The present invention is further illustrated, it should be appreciated that following drawings and embodiments below in conjunction with accompanying drawing and following embodiment It is merely to illustrate the present invention, and the unrestricted present invention.
The present invention provides a kind of method that glazed tile waste residue recycles, and utilizes glazed tile waste residue to prepare secondary and burns ceramic glaze Face brick.In the present invention, ceramic glazed bricks refer to water absorption rate meansigma methods more than 10% have glaze Ceramic Tiles.The present invention is mainly by grinding Send out body recipe, raw material through ball milling, powder process, molding, be dried, biscuiting, glazing, glaze firing technique realize.Hereinafter, as example, The preparation method of the present invention is illustrated with reference to Fig. 1.
The collection of glazed tile waste residue
In the present invention, glazed tile waste residue refers to the sewage warp that glazed tile produces during glaze layer and abrading block mutual grinding when polishing Collection, deposition, the solid waste of filter pressing.It addition, in the present invention, the glazed tile originated as glazed tile waste residue is not had spy Do not limit, can be glazed tile well known in the art.The chemical composition of glazed tile waste residue can be: IL:2.0~4.5%;SiO2: 58~68%;Al2O3: 19~25%;Fe2O3: 0~2.0%;TiO2: 0~1.0%;CaO:1.0~4.0%;MgO:0~ 1.5%;K2O:0.5~3.0%;Na2O:1.0~4.0%.Glazed tile waste residue homogenizing can be collected by the following method: by glaze The waste water produced in brick brick polishing process is pooled to cesspool, adds appropriate flocculant and makes settlement of sewage, by the dirt after precipitation Mud filter pressing becomes moisture content to be less than the filter block of 30%, is then smashed by filter block and fully all mixes stand-by.Described flocculant can be poly-third Acrylamide, aluminum chloride, aluminum sulfate etc..
Body recipe
Glazed tile waste residue ratio 30~50% in formula.In one example, body recipe mainly comprises as glazed tile waste residue 30 ~50%, clay 12~18%, sand material A10~26%, sand material B0~20%, limestone 7~11%, wollastonite 0~ 3%, quartz 3~13%.Wherein, sand material refer in addition to clay already pointed out, limestone, wollastonite, quartz can For the ceramic mineral raw material of Production of Ceramics, its chemical composition requires depending on body recipe chemical composition requires.Sand material A, Sand material B is the different sand materials requiring according to body recipe chemical composition and selecting, and its chemical composition is different, wherein, The chemical composition of sand material A is SiO2: 71.16%, Al2O3: 19.27%, Fe2O3: 1.54%, TiO2: 0.20%, CaO: 0.1%, MgO:0.19%, K2O:0.93%, Na2O:0.12%, burning are lost: 6.44%, and the chemical composition of sand material B is SiO2: 73.6%, Al2O3: 15.77%, Fe2O3: 0.71%, TiO2: 0.16%, CaO:0.74%, MgO:0.25%, K2O:2.86%, Na2O:2.7%, burning are lost: 3.16%.However, it is understood that above-mentioned body recipe is merely illustrative, the body recipe of the present invention does not limits In this, as long as and it meets following body recipe chemical composition and requires.In other words, the concrete raw material of base substrate can be according to base Body formula chemical composition requires rationally to select.Furthermore it is also possible to add relative to this formula gross mass 0~the base substrate increasing of 0.3% Strong agent, to strengthen the intensity of base substrate.As base substrate reinforcing agent, include but not limited to polyvinyl alcohol, dibutyl phthalate.
Body recipe chemical composition can be: SiO2: 66~71%;Al2O3: 16~18.5%;Fe2O3: 0.1~1.5%; TiO2: 0.1~0.5%;CaO:5.0~8.5%;MgO:0.5~2.0%;K2O:1.2~2.5%;Na2O:1.0~2.2%.
According to body recipe by various raw material mixing and ball milling.It addition, it is the most additional relative to base on the basis of body recipe Body formula gross mass 0~the waterglass of 1.5% and 0~the dispersant of 0.4%, so that slurry has rational mobility.Its In, described dispersant includes but not limited to sodium humate, sodium tripolyphosphate etc..Ball milling method can be wet ball grinding, ball-milling medium Can be high alumina ballstone, middle aluminum ballstone, natural cobblestone etc..Ball milling disposed slurry fineness can be 2.5~4.5% (250 mesh screen residue).Will The slurry iron-removing of ball milling gained, sieve, pelletize, prepare powder.Prilling process includes but not limited to that spray tower dusts.
Send press-molding by prepared powder, prepare base substrate.Pressing pressure can be 28~40MPa.Molding specification can be (150~450) × (150~900) × (7~11) mm.
It is 0~1.5% by body drying to water content.Baking temperature can be 140~250 DEG C.Drying time can be 15~ 40 minutes.
Dried base substrate carries out biscuiting, and firing temperature is 1100~1160 DEG C, and firing period is 30~60 minutes.
The billet surface that biscuiting is good executes ground-coat enamel, cover-coat enamel, it is also possible to be aided with stamp, to strengthen the decorative effect of glazed tile.This Invent and glaze and the composition of stamp and method are not particularly limited, composition well known in the art and method can be used.
The base substrate of glazing is carried out glaze firing, and firing temperature is 1010~1060 DEG C, and firing period is 35~60 minutes, can Prepare ceramic glazed bricks.
The secondary of the present invention burns ceramic glazed bricks technical specification and meets pottery brick requirement.
There is advantages that
A kind of glazed tile waste residue circulation utilization method is provided, utilizes glazed tile waste residue to prepare secondary and burn ceramic glazed bricks.The most permissible The glazed tile producer a large amount of glazed tile waste residue solving polishing faces the problem of process, can save again substantial amounts of raw material.
Enumerate embodiment further below to describe the present invention in detail.It will similarly be understood that following example are served only for this Invention is further described, it is impossible to being interpreted as limiting the scope of the invention, those skilled in the art is according to this Some nonessential improvement and adjustment that bright foregoing is made belong to protection scope of the present invention.Following example is concrete Technological parameters etc. are the most only that an example in OK range, i.e. those skilled in the art can be done properly by explanation herein In the range of select, and do not really want to be defined in the concrete numerical value of hereafter example.
In following examples, the technical specification of ceramic glazed bricks meets the requirement of GB/T 4100-2015 (annex L).
In following examples, the chemical composition (wt%) of each raw material is as follows:
In following examples, body recipe chemical composition (wt%) is as follows:
Embodiment 1
Glazed tile waste residue by 50%, the black mud of 14%, the sand material A of 12%, the limestone of 11%, the quartz of 13%, additional The sodium tripolyphosphate mixing and ball milling of the polyvinyl alcohol of 0.3%, the waterglass of 1.3% and 0.25%, slurry iron-removing, sieve after through spray Mist drying-granulating.Powder is compressing through 32MPa pressure, specification 308 × 610 × 9.5mm, and dried base substrate water content is 1.0%.Dry base substrate carries out biscuiting, biscuiting temperature 1145 DEG C, firing period 48 minutes, and the base substrate of biscuiting is executed the end, cover-coat enamel, printed Flower, then through glaze firing, firing temperature is 1040 DEG C, firing period 46 minutes.Finished bricks water absorption rate 17.5~18.2%.
Embodiment 2
Glazed tile waste residue by 40%, the black mud of 16%, the sand material A of 15%, the sand material B of 9%, the limestone of 10%, The quartz of 10%, the sodium tripolyphosphate mixing and ball milling of the polyvinyl alcohol of additional 0.2%, the waterglass of 1.2% and 0.25%, mud Except ferrum, sieve after through spray drying granulation.Powder is compressing through 32MPa pressure, specification 308 × 610 × 9.5mm, after drying Base substrate water content is 1.0%.Dry base substrate carries out biscuiting, biscuiting temperature 1150 DEG C, firing period 48 minutes, the base substrate of biscuiting Execute the end, cover-coat enamel, stamp, then through glaze firing, firing temperature is 1045 DEG C, firing period 46 minutes.Finished bricks water absorption rate 17.0~ 17.6%.
Embodiment 3
Glazed tile waste residue by 30%, the black mud of 16%, the sand material A of 19%, the sand material B of 19%, the limestone of 9%, 2% Wollastonite, the quartz of 5%, the trimerization phosphorus of the dibutyl phthalate of additional 0.15%, the waterglass of 1.1% and 0.15% Acid sodium mixing and ball milling, slurry iron-removing, sieve after through spray drying granulation.Powder is compressing through 32MPa pressure, and specification 308 × 912 × 10.6mm, dried base substrate water content is 0.6%.Dry base substrate carries out biscuiting, biscuiting temperature 1156 DEG C, firing period 52 minutes, the base substrate of biscuiting executed the end, cover-coat enamel, stamp, then through glaze firing, firing temperature is 1045 DEG C, firing period 46 minutes. Finished bricks water absorption rate 16.5~17.2%.
Industrial applicability: the invention provides a kind of method that glazed tile waste residue recycles, utilize glazed tile waste residue system Standby secondary burns ceramic glazed bricks, can solve glazed tile producer a large amount of glazed tile waste residue and face the problem of process, can save again Substantial amounts of raw material, is truly realized recycling of waste material.

Claims (11)

1. the method that glazed tile waste residue recycles, utilizes glazed tile waste residue to prepare secondary and burns ceramic glazed bricks, its feature It is, comprises the steps:
The preparation of blank raw material: by contain by mass percentage 30~50% glazed tile waste residue blank raw material mixing and ball milling after Powder process forms powder, and the chemical composition after wherein said blank raw material makes base substrate burn till is: SiO2: 66~71%;Al2O3: 16~ 18.5%;Fe2O3: 0.1~1.5%;TiO2: 0.1~0.5%;CaO:5.0~8.5%;MgO:0.5~2.0%;K2O:1.2~ 2.5%;Na2O:1.0~2.2%;
By the powder molding of gained, be dried, biscuiting, execute ground-coat enamel, execute cover-coat enamel, glaze firing prepare secondary burn ceramic glazed bricks.
Method the most according to claim 1, it is characterised in that the chemical composition of described glazed tile waste residue is: burn and lose: 2.0 ~4.5%;SiO2: 58~68%;Al2O3: 19~25%;Fe2O3: 0~2.0%;TiO2: 0~1.0%;CaO:1.0~4.0%; MgO:0~1.5%;K2O:0.5~3.0%;Na2O:1.0~4.0%.
Method the most according to claim 1 and 2, it is characterised in that described glazed tile waste residue obtains by the following method: will The sewage produced during glaze layer and abrading block mutual grinding during glazed tile polishing is pooled to cesspool, adds appropriate flocculant and makes Settlement of sewage, becomes moisture content to be less than the filter block of 30% sludge press filtration after precipitation, is then smashed by filter block and the most all mixes and treats With.
The most according to the method in any one of claims 1 to 3, it is characterised in that blank raw material includes: by mass percentage Meter, glazed tile waste residue 30~50%, clay 12~18%, limestone 7~11%, wollastonite 0~3%, quartz 3~13%, remaining be sand Building stones.
Method the most according to any one of claim 1 to 4, it is characterised in that during mixing and ball milling, is additionally added relative to former Material gross mass 0~the waterglass of base substrate reinforcing agent, 0.6~1.5% of 0.3% and 0~the dispersant of 0.4%.
Method the most according to any one of claim 1 to 5, it is characterised in that the mode of described molding is dry-pressing formed, Pressing pressure is 28~40MPa.
Method the most according to any one of claim 1 to 6, it is characterised in that dried base substrate water content be 0~ 1.5%。
Method the most according to any one of claim 1 to 7, it is characterised in that dried base substrate carries out biscuiting, burns till temperature Degree is 1100~1160 DEG C, and firing period is 30~60 minutes.
Method the most according to any one of claim 1 to 8, it is characterised in that execute the end, face on its surface after base substrate biscuiting Glaze, for strengthening decorative effect, can also be aided with stamp after glazing.
Method the most according to any one of claim 1 to 9, it is characterised in that the base substrate after glazing carries out glaze firing, burns Becoming temperature is 1010~1060 DEG C, and firing period is 35~60 minutes.
The secondary that 11. 1 kinds are prepared by the method according to any one of claim 1 to 10 burns ceramic glazed bricks.
CN201610481680.2A 2016-06-23 2016-06-23 A kind of method that glazed tile waste residue recycles Pending CN106116501A (en)

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CN106630625A (en) * 2016-12-26 2017-05-10 澧县新鹏陶瓷有限公司 Method for recycling waste glaze and application of products of method
CN106673434A (en) * 2016-12-26 2017-05-17 澧县新鹏陶瓷有限公司 Fusion cake dry granule mainly prepared from waste glaze and preparation method thereof
CN106673436A (en) * 2017-01-03 2017-05-17 澧县新鹏陶瓷有限公司 Travertine-like ceramic tile taking waste glaze as clinker raw material and preparation method of travertine-like ceramic tile
CN106673435A (en) * 2016-12-26 2017-05-17 澧县新鹏陶瓷有限公司 Wearproof frit dry granules using waste glaze as main raw material and preparation method thereof
CN106698944A (en) * 2017-01-03 2017-05-24 澧县新鹏陶瓷有限公司 Glass ceramic brick using waste glaze material as frit raw material and preparation method thereof
CN106698945A (en) * 2017-01-03 2017-05-24 澧县新鹏陶瓷有限公司 Glazed tile with waste glaze as glaze raw material and preparation method thereof
CN107337455A (en) * 2016-11-29 2017-11-10 佛山市东鹏陶瓷有限公司 A kind of powder dry-pressing formed for Ceramic Tiles and preparation method thereof
CN107337427A (en) * 2016-11-29 2017-11-10 佛山市东鹏陶瓷有限公司 The preparation method and finished product of a kind of dry powder Ceramic Tiles and its base substrate
CN110204344A (en) * 2019-05-21 2019-09-06 广东家美陶瓷有限公司 Green body slurry and preparation method thereof

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CN103693942A (en) * 2013-11-27 2014-04-02 广东家美陶瓷有限公司 Low-temperature fast-fired ceramic tile and production process thereof
CN104529553A (en) * 2014-12-08 2015-04-22 广东宏陶陶瓷有限公司 Glazed tile manufactured by using ceramic waste and having broken diamond sand flashing starlight on surface, and preparation method thereof

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CN102320811A (en) * 2011-05-16 2012-01-18 霍镰泉 Utilize ornamental brick base substrate of polishing slag and sludge silt preparation and preparation method thereof
CN102617123A (en) * 2012-02-29 2012-08-01 广东宏陶陶瓷有限公司 Formula and method for manufacturing ceramic tile blank bodies and glazed tiles by utilizing polished waste residues
CN103693942A (en) * 2013-11-27 2014-04-02 广东家美陶瓷有限公司 Low-temperature fast-fired ceramic tile and production process thereof
CN104529553A (en) * 2014-12-08 2015-04-22 广东宏陶陶瓷有限公司 Glazed tile manufactured by using ceramic waste and having broken diamond sand flashing starlight on surface, and preparation method thereof

Cited By (10)

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Publication number Priority date Publication date Assignee Title
CN107337455A (en) * 2016-11-29 2017-11-10 佛山市东鹏陶瓷有限公司 A kind of powder dry-pressing formed for Ceramic Tiles and preparation method thereof
CN107337427A (en) * 2016-11-29 2017-11-10 佛山市东鹏陶瓷有限公司 The preparation method and finished product of a kind of dry powder Ceramic Tiles and its base substrate
CN107337455B (en) * 2016-11-29 2020-03-17 佛山市东鹏陶瓷有限公司 Powder for dry pressing and forming of ceramic tile and preparation method thereof
CN106630625A (en) * 2016-12-26 2017-05-10 澧县新鹏陶瓷有限公司 Method for recycling waste glaze and application of products of method
CN106673434A (en) * 2016-12-26 2017-05-17 澧县新鹏陶瓷有限公司 Fusion cake dry granule mainly prepared from waste glaze and preparation method thereof
CN106673435A (en) * 2016-12-26 2017-05-17 澧县新鹏陶瓷有限公司 Wearproof frit dry granules using waste glaze as main raw material and preparation method thereof
CN106673436A (en) * 2017-01-03 2017-05-17 澧县新鹏陶瓷有限公司 Travertine-like ceramic tile taking waste glaze as clinker raw material and preparation method of travertine-like ceramic tile
CN106698944A (en) * 2017-01-03 2017-05-24 澧县新鹏陶瓷有限公司 Glass ceramic brick using waste glaze material as frit raw material and preparation method thereof
CN106698945A (en) * 2017-01-03 2017-05-24 澧县新鹏陶瓷有限公司 Glazed tile with waste glaze as glaze raw material and preparation method thereof
CN110204344A (en) * 2019-05-21 2019-09-06 广东家美陶瓷有限公司 Green body slurry and preparation method thereof

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Application publication date: 20161116