CN108558211A - A kind of low fever at temperature metal bright glaze preparation method - Google Patents
A kind of low fever at temperature metal bright glaze preparation method Download PDFInfo
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- CN108558211A CN108558211A CN201810368779.0A CN201810368779A CN108558211A CN 108558211 A CN108558211 A CN 108558211A CN 201810368779 A CN201810368779 A CN 201810368779A CN 108558211 A CN108558211 A CN 108558211A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
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Abstract
The present invention discloses a kind of preparation method of low fever at temperature metal bright glaze, including following operating procedure：（1）Spherical titanium alloyed metal powder is added into soak, after 4 5min of immersion treatment, takes out and cleans surface；（2）Spherical titanium alloyed metal powder, aluminium powder cream, vanadic anhydride, grinding aid, water are added into ball mill, after ball-milling treatment, mixture is dried, metallic pigments are made；（3）Potassium feldspar, kaolin, atlapulgite, glass powder, metallic pigments, grinding aid, water are added into ball mill, after ball-milling treatment, glaze is made, ceramic body is put into stove after glaze is sprayed on ceramic body surface, after sintering processes, finished product.Metal-lustrous glaze produced by the present invention, the extremely smooth pore-free of glaze, and metallic luster is fine, excellent quality, and especially in the present invention, sintering temperature is relatively low, can be effective energy saving, reduces production cost.
Description
Technical field
The invention belongs to ceramic glaze preparing technical fields, and in particular to a kind of low fever at temperature metal bright glaze preparation side
Method.
Background technology
For metal-lustrous glaze as a kind of special crystalline glaze, the persistence of gloss is fine, gives simple and unsophisticated metallic
Sense, at the same again have good thermal stability, acid-fast alkali-proof, but also can long-time holding surface cleaning, in family wear
If the product for other light appearances of arranging in pairs or groups during repairing, it can perfectly reach light and dark, the simple and unsophisticated soft perfect coordination of color and luster
Artistic effect.Metal-lustrous glaze is all to easily cause environmental pollution in process of production using lead boron as basic glaze, easily make
Operator is endangered by heavy metal lead, is made that improvement on this basis in the prior art, using manganese dioxide, copper oxide
Equal coloring oxides prepare metal-lustrous glaze in ceramic surface, but after using such glaze, sintering temperature is higher, needs 1200
DEG C or more be just avoided that glaze stomata generate, cause the waste of the energy.
Invention content
In order to solve the above technical problem, the present invention provides a kind of low fever into the preparation method of temperature metal bright glaze.
The present invention is achieved by the following technical solutions.
A kind of low fever is at the preparation method of temperature metal bright glaze, including following operating procedure：
（1）Spherical titanium alloyed metal powder is added into soak, after immersion treatment 4-5min, takes out and cleans surface, wherein
Soak is made of the component of following parts by weight：11-18 parts of methylpropene sodium sulfonate, 4-8 parts of sulfuric acid, two molybdic acid hydrate sodium 5-7
Part, 180-200 parts of water；
（2）By weight, by 55-60 parts of spherical titanium alloyed metal powders, 22-28 parts of aluminium powder cream, 4-8 parts of vanadic anhydrides,
1-3 parts of grinding aids, 13-20 parts of water are added into ball mill, and after ball-milling treatment, mixture is dried, and metallic pigments are made；
（3）By weight, by 39-44 parts of potassium feldspars, 8-10 parts of kaolin, 12-16 parts of atlapulgites, 19-24 parts of glass powders,
14-20 parts of metallic pigments, 3-5 parts of grinding aids, 46-54 parts of water are added into ball mill, and after ball-milling treatment, glaze is made, will
After glaze is sprayed on ceramic body surface, ceramic body is put into stove, after 1000-1050 DEG C of sintering processes 15-20min, is made
Finished product.
Specifically, above-mentioned steps（1）In, the mass fraction of sulfuric acid is 6-10%.
Specifically, above-mentioned steps（2）In, the mass fraction of titanium is 90% in spherical titanium alloyed metal powder, the quality point of aluminium
Number is 6%, and the mass fraction of vanadium is 4%, and Average Particle Diameters are 15-53 μm.
Specifically, above-mentioned steps（2）And step（3）In, grinding aid is polyacrylamide, and molecular weight is 20,000,000, Gu
Content is 95%.
Specifically, above-mentioned steps（3）In, heating rate when sintering processes is 3-4 DEG C/min.
From the above technical scheme, it can be seen that the beneficial effects of the invention are as follows：
At the preparation method of temperature metal bright glaze, raw material is easy to get and cheap a kind of low fever provided by the invention, obtained
Metal-lustrous glaze, the extremely smooth pore-free of glaze, and metallic luster is fine, excellent quality, especially in the present invention, sintering temperature
Spend it is relatively low, can be effective energy saving, reduce production cost.Wherein step（1）In, soak treated spherical titanium alloy gold
Belong to powder, the mobility of glaze can be improved, is conducive to the precipitation of crystal during sintering, greatly improves metal-lustrous glaze
Color；Beautiful silvery white metallic luster, while the temperature being sintered is presented after sinter molding in metallic pigments provided by the invention
Spend relatively low, glaze not will produce stomata after firing.
Specific implementation mode
Following embodiment cannot be used for limiting the scope of the invention for illustrating the present invention.The reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of low fever is at the preparation method of temperature metal bright glaze, including following operating procedure：
（1）Spherical titanium alloyed metal powder is added into soak, after immersion treatment 4min, takes out and cleans surface, wherein soaking
Bubble liquid is made of the component of following parts by weight：11 parts of methylpropene sodium sulfonate, 4 parts of sulfuric acid, 5 parts of two molybdic acid hydrate sodium, water 180
Part；
（2）By weight, 55 parts of spherical titanium alloyed metal powders, 22 parts of aluminium powder cream, 4 parts of vanadic anhydrides, 1 part of grinding are helped
Agent, 13 parts of water are added into ball mill, and after ball-milling treatment, mixture is dried, and metallic pigments are made；
（3）By weight, by 39 parts of potassium feldspars, 8 parts of kaolin, 12 parts of atlapulgites, 19 parts of glass powders, 14 parts of metal face
Material, 3 parts of grinding aids, 46 parts of water are added into ball mill, after ball-milling treatment, glaze are made, glaze is sprayed on ceramic blank body surface
Behind face, ceramic body is put into stove, after 1000 DEG C of sintering processes 15min, finished product.
Specifically, above-mentioned steps（1）In, the mass fraction of sulfuric acid is 6%.
Specifically, above-mentioned steps（2）In, the mass fraction of titanium is 90% in spherical titanium alloyed metal powder, the quality point of aluminium
Number is 6%, and the mass fraction of vanadium is 4%, and Average Particle Diameters are 15 μm.
Specifically, above-mentioned steps（2）And step（3）In, grinding aid is polyacrylamide, and molecular weight is 20,000,000, Gu
Content is 95%.
Specifically, above-mentioned steps（3）In, heating rate when sintering processes is 3 DEG C/min.
Embodiment 2
A kind of low fever is at the preparation method of temperature metal bright glaze, including following operating procedure：
（1）Spherical titanium alloyed metal powder is added into soak, after immersion treatment 5min, takes out and cleans surface, wherein soaking
Bubble liquid is made of the component of following parts by weight：15 parts of methylpropene sodium sulfonate, 6 parts of sulfuric acid, 6 parts of two molybdic acid hydrate sodium, water 190
Part；
（2）By weight, 58 parts of spherical titanium alloyed metal powders, 24 parts of aluminium powder cream, 6 parts of vanadic anhydrides, 2 parts of grindings are helped
Agent, 16 parts of water are added into ball mill, and after ball-milling treatment, mixture is dried, and metallic pigments are made；
（3）By weight, by 42 parts of potassium feldspars, 9 parts of kaolin, 14 parts of atlapulgites, 21 parts of glass powders, 16 parts of metal face
Material, 4 parts of grinding aids, 50 parts of water are added into ball mill, after ball-milling treatment, glaze are made, glaze is sprayed on ceramic blank body surface
Behind face, ceramic body is put into stove, after 1030 DEG C of sintering processes 18min, finished product.
Specifically, above-mentioned steps（1）In, the mass fraction of sulfuric acid is 8%.
Specifically, above-mentioned steps（2）In, the mass fraction of titanium is 90% in spherical titanium alloyed metal powder, the quality point of aluminium
Number is 6%, and the mass fraction of vanadium is 4%, and Average Particle Diameters are 30 μm.
Specifically, above-mentioned steps（2）And step（3）In, grinding aid is polyacrylamide, and molecular weight is 20,000,000, Gu
Content is 95%.
Specifically, above-mentioned steps（3）In, heating rate when sintering processes is 4 DEG C/min.
Embodiment 3
A kind of low fever is at the preparation method of temperature metal bright glaze, including following operating procedure：
（1）Spherical titanium alloyed metal powder is added into soak, after immersion treatment 5min, takes out and cleans surface, wherein soaking
Bubble liquid is made of the component of following parts by weight：18 parts of methylpropene sodium sulfonate, 8 parts of sulfuric acid, 7 parts of two molybdic acid hydrate sodium, water 200
Part；
（2）By weight, 60 parts of spherical titanium alloyed metal powders, 28 parts of aluminium powder cream, 8 parts of vanadic anhydrides, 3 parts of grindings are helped
Agent, 20 parts of water are added into ball mill, and after ball-milling treatment, mixture is dried, and metallic pigments are made；
（3）By weight, by 44 parts of potassium feldspars, 10 parts of kaolin, 16 parts of atlapulgites, 24 parts of glass powders, 20 parts of metal face
Material, 5 parts of grinding aids, 54 parts of water are added into ball mill, after ball-milling treatment, glaze are made, glaze is sprayed on ceramic blank body surface
Behind face, ceramic body is put into stove, after 1050 DEG C of sintering processes 20min, finished product.
Specifically, above-mentioned steps（1）In, the mass fraction of sulfuric acid is 10%.
Specifically, above-mentioned steps（2）In, the mass fraction of titanium is 90% in spherical titanium alloyed metal powder, the quality point of aluminium
Number is 6%, and the mass fraction of vanadium is 4%, and Average Particle Diameters are 53 μm.
Specifically, above-mentioned steps（2）And step（3）In, grinding aid is polyacrylamide, and molecular weight is 20,000,000, Gu
Content is 95%.
Specifically, above-mentioned steps（3）In, heating rate when sintering processes is 4 DEG C/min.
Comparative example 1
Spherical titanium alloyed metal powder is without step（1）Soak processing, remaining operating procedure and 1 complete phase of embodiment
Together.
Ceramet bright glaze is made with the method for each embodiment and comparative example respectively, then checks each group ceramet light
The effect of damp glaze, test result are as shown in table 1：
The effect of 1 ceramet bright glaze of table
| Project | The effect of ceramet bright glaze |
| Embodiment 1 | Glaze is smooth, pore-free, silvery white, and metallic luster is fine |
| Comparative example 1 | Glaze is dark, almost pore-free, and metallic luster is poor |
| Embodiment 2 | Glaze is smooth, pore-free, silvery white, and metallic luster is fine |
| Embodiment 3 | Glaze is smooth, pore-free, silvery white, and metallic luster is fine |
As shown in Table 1, at a relatively low sintering temperature, ceramet bright glaze obtained, glaze is smooth, pore-free by the present invention,
Silvery white, metallic luster is fine, not only ensure that the quality of product, but also reduces the consumption of the energy.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting.Although with reference to compared with
Good embodiment describes the invention in detail, it will be understood by those of ordinary skill in the art that, it can be to the technology of invention
Scheme is modified or replaced equivalently, and without departing from the range of technical solution of the present invention, should all cover the power in the present invention
In sharp claimed range.
Claims (5)
1. a kind of low fever is at the preparation method of temperature metal bright glaze, which is characterized in that including following operating procedure：
（1）Spherical titanium alloyed metal powder is added into soak, after immersion treatment 4-5min, takes out and cleans surface, wherein
Soak is made of the component of following parts by weight：11-18 parts of methylpropene sodium sulfonate, 4-8 parts of sulfuric acid, two molybdic acid hydrate sodium 5-7
Part, 180-200 parts of water；
（2）By weight, by 55-60 parts of spherical titanium alloyed metal powders, 22-28 parts of aluminium powder cream, 4-8 parts of vanadic anhydrides,
1-3 parts of grinding aids, 13-20 parts of water are added into ball mill, and after ball-milling treatment, mixture is dried, and metallic pigments are made；
（3）By weight, by 39-44 parts of potassium feldspars, 8-10 parts of kaolin, 12-16 parts of atlapulgites, 19-24 parts of glass powders,
14-20 parts of metallic pigments, 3-5 parts of grinding aids, 46-54 parts of water are added into ball mill, and after ball-milling treatment, glaze is made, will
After glaze is sprayed on ceramic body surface, ceramic body is put into stove, after 1000-1050 DEG C of sintering processes 15-20min, is made
Finished product.
2. a kind of low fever according to claim 1 is at the preparation method of temperature metal bright glaze, which is characterized in that above-mentioned step
Suddenly（1）In, the mass fraction of sulfuric acid is 6-10%.
3. a kind of low fever according to claim 1 is at the preparation method of temperature metal bright glaze, which is characterized in that above-mentioned step
Suddenly（2）In, the mass fraction of titanium is 90% in spherical titanium alloyed metal powder, and the mass fraction of aluminium is 6%, and the mass fraction of vanadium is
4%, Average Particle Diameters are 15-53 μm.
4. a kind of low fever according to claim 1 is at the preparation method of temperature metal bright glaze, which is characterized in that above-mentioned step
Suddenly（2）And step（3）In, grinding aid is polyacrylamide, and molecular weight is 20,000,000, solid content 95%.
5. a kind of low fever according to claim 1 is at the preparation method of temperature metal bright glaze, which is characterized in that above-mentioned step
Suddenly（3）In, heating rate when sintering processes is 3-4 DEG C/min.
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| CN201810368779.0A CN108558211A (en) | 2018-04-23 | 2018-04-23 | A kind of low fever at temperature metal bright glaze preparation method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111807702A (en) * | 2020-08-05 | 2020-10-23 | 广东博德精工建材有限公司 | Method for manufacturing glazed tile with glazed three-dimensional effect |
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| CN101157543A (en) * | 2007-09-27 | 2008-04-09 | 何乾 | Method for making ceramic tile with metallic luster local interspersing surface |
| CN105800932A (en) * | 2016-03-30 | 2016-07-27 | 安徽青花坊瓷业股份有限公司 | Ground glaze for high-temperature in-glaze decoration manufacturing |
| CN106064889A (en) * | 2016-05-30 | 2016-11-02 | 泉州阳光创艺陶瓷股份有限公司 | The noble metal glaze art pottery and manufacture method |
| CN106565281A (en) * | 2016-11-14 | 2017-04-19 | 蒙娜丽莎集团股份有限公司 | Fully-polished-glaze ceramic tile with metal particles and metallic luster and manufacturing method thereof |
| CN107474603A (en) * | 2017-08-29 | 2017-12-15 | 阜南县力韦包装材料有限公司 | One kind lifting metallized film decay resistance method |
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2018
- 2018-04-23 CN CN201810368779.0A patent/CN108558211A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101157543A (en) * | 2007-09-27 | 2008-04-09 | 何乾 | Method for making ceramic tile with metallic luster local interspersing surface |
| CN105800932A (en) * | 2016-03-30 | 2016-07-27 | 安徽青花坊瓷业股份有限公司 | Ground glaze for high-temperature in-glaze decoration manufacturing |
| CN106064889A (en) * | 2016-05-30 | 2016-11-02 | 泉州阳光创艺陶瓷股份有限公司 | The noble metal glaze art pottery and manufacture method |
| CN106565281A (en) * | 2016-11-14 | 2017-04-19 | 蒙娜丽莎集团股份有限公司 | Fully-polished-glaze ceramic tile with metal particles and metallic luster and manufacturing method thereof |
| CN107474603A (en) * | 2017-08-29 | 2017-12-15 | 阜南县力韦包装材料有限公司 | One kind lifting metallized film decay resistance method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111807702A (en) * | 2020-08-05 | 2020-10-23 | 广东博德精工建材有限公司 | Method for manufacturing glazed tile with glazed three-dimensional effect |
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Application publication date: 20180921 |