CN113735442B - Matte glass ceramic and preparation method thereof - Google Patents
Matte glass ceramic and preparation method thereof Download PDFInfo
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- CN113735442B CN113735442B CN202111056948.5A CN202111056948A CN113735442B CN 113735442 B CN113735442 B CN 113735442B CN 202111056948 A CN202111056948 A CN 202111056948A CN 113735442 B CN113735442 B CN 113735442B
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- China
- Prior art keywords
- matte
- matt
- transparent glaze
- glass
- calcite
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- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 239000002241 glass-ceramic Substances 0.000 title claims description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 42
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 33
- 239000011521 glass Substances 0.000 claims abstract description 32
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 24
- 239000006004 Quartz sand Substances 0.000 claims abstract description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 24
- 239000010459 dolomite Substances 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 24
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 18
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 238000002844 melting Methods 0.000 claims abstract description 12
- 230000008018 melting Effects 0.000 claims abstract description 12
- 238000010304 firing Methods 0.000 claims abstract description 11
- 238000005507 spraying Methods 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 5
- 238000000498 ball milling Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a matte glass porcelain and a preparation method thereof, wherein a matte transparent glaze is sprayed on the surface of a blank body of the glass porcelain, and the matte transparent glaze comprises the following raw materials in percentage by weight: 50-60% of quartz sand, 5-10% of calcite, 15-25% of soda ash, 1-3% of alumina and 15-20% of dolomite powder. The matte glass porcelain is prepared by spraying a matte transparent glaze material on the surface of a blank, wherein the glaze material is matte in a molten state and keeps transparent. The preparation method of the matt glass porcelain has simple steps, the melting temperature range of the glaze is adapted to the firing temperature of the glass porcelain product, the structure of the surface of a processed blank body is not damaged, and the surface of the glass porcelain can be prevented from fouling.
Description
Technical Field
The invention relates to the technical field of glaze, in particular to a matte glass ceramic and a preparation method thereof.
Background
In recent years, the 'glass porcelain' mosaic products which are popular in the market have the advantages that the surface gloss of the glass porcelain products can not achieve the 'pure matte' (dull) effect all the time due to the vitreous characteristics of the material components;
in order to meet the requirement of customers on pure matte surface of products, most manufacturers generally adopt an acid pickling method to treat the surface of the glass porcelain, namely: and soaking the high-brightness product in the product in an acid solution for acid cleaning, and corroding the surface structure. The acid washing process has the defects of environmental protection, no pollution, and high cost.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide the glass porcelain, wherein the surface of a glass porcelain blank body is sprayed with a matt transparent glaze to form a matt transparent layer, so that the completely matt appearance is realized, and the color and texture of the product are not influenced. The second purpose of the invention is to provide a preparation method of the glass porcelain, wherein a matt transparent glaze is sprayed on the surface of a blank, and the melting temperature range of the glaze is adapted to the firing temperature of the glass porcelain product to be processed.
One of the purposes of the invention is realized by adopting the following technical scheme:
a matt transparent glaze is sprayed on the surface of a blank of the glass porcelain, and the matt transparent glaze comprises the following raw materials in percentage by weight: 50-60% of quartz sand, 5-10% of calcite, 15-25% of soda ash, 1-3% of alumina and 15-20% of dolomite powder.
Further, the matt transparent glaze comprises the following raw materials in percentage by weight: 50-55% of quartz sand, 5-8% of calcite, 20-25% of soda ash, 2-3% of alumina and 15-20% of dolomite powder.
Still further, the matt transparent glaze comprises the following raw materials in percentage by weight: 52% of quartz sand, 8% of calcite, 21% of soda ash, 3% of alumina and 16% of dolomite powder.
Further, the matt transparent glaze comprises the following raw materials in percentage by weight: 55% of quartz sand, 5% of calcite, 23% of soda ash, 2% of alumina and 15% of dolomite powder.
Still further, the matt transparent glaze comprises the following raw materials in percentage by weight: 58% of quartz sand, 10% of calcite, 15% of soda ash, 2% of alumina and 15% of dolomite powder.
Further, the matt transparent glaze comprises the following raw materials in percentage by weight: 50% of quartz sand, 10% of calcite, 19% of soda ash, 1% of alumina and 20% of dolomite powder.
Still further, the preparation method of the matt transparent glaze comprises the following steps: the quartz sand, calcite, soda, alumina and dolomite powder with the formula ratio are subjected to ball milling and then melted to obtain the matt transparent glaze. Wherein, the technological parameters of ball milling are as follows: ball: the mass ratio of water is 1:2: 0.4-0.5, and the melting temperature is 980-1000 ℃.
Further, the preparation method of the matt transparent glaze has the melting temperature of 980-1000 ℃.
The second purpose of the invention is realized by adopting the following technical scheme:
the preparation method of the matte glass ceramic comprises the following steps: spraying the matt transparent glaze on the surface of a blank, and forming a matt transparent layer on the surface of the blank after sintering; wherein the sintering temperature is 980-1000 ℃.
Compared with the prior art, the invention has the beneficial effects that:
(1) The matte glass porcelain is prepared by spraying a matte transparent glaze material on the surface of a blank, wherein the glaze material is matte in a molten state and keeps transparent.
(2) The invention relates to a matt transparent glaze for matt glass porcelain, which is prepared by mixing quartz sand, calcite, soda ash, alumina and dolomite powder according to formula ratio, performing ball milling, and then melting. The preparation method has simple steps, and the melting temperature range of the glaze is adapted to the firing temperature of the glass ceramic product, so that the structure of the surface of the processed blank is not damaged.
(3) The preparation method of the matte glass porcelain comprises the following steps: after the green body is obtained, spraying a matt transparent glaze on the surface of the green body, and firing the green body and the matt transparent glaze at a high temperature to obtain the glass porcelain, wherein the firing temperature is kept consistent with the melting temperature of the glaze, so that the surface of the glass porcelain is covered by transparent and matt glass, the purpose of matt the surface of the glass porcelain product is achieved, and the surface of the glass porcelain can be prevented from fouling.
Drawings
FIG. 1 is a schematic view of a vitreous porcelain product according to example 1;
FIG. 2 is a schematic view of a vitreous porcelain product according to comparative example 1.
Detailed Description
The present invention is further described with reference to the accompanying drawings and the detailed description, and it should be noted that, in the case of no conflict, any combination between the embodiments or technical features described below may form a new embodiment.
Example 1
A preparation method of matte glass porcelain comprises the following steps: after a blank is prepared, spraying a layer of matt transparent glaze on the blank, and firing at 980 ℃ for 1h to obtain the glass ceramic product shown in figure 1.
The matt transparent glaze comprises the following raw materials in percentage by weight: 52% of quartz sand, 8% of calcite, 21% of soda ash, 3% of alumina and 16% of dolomite powder.
The preparation method of the glaze comprises the following steps: the preparation method of the matt transparent glaze comprises the following steps: the quartz sand, calcite, soda, alumina and dolomite powder with the formula ratio are ball-milled and melted to obtain the matt transparent glaze slip. Wherein, the technological parameters of ball milling are as follows: ball: the mass ratio of water is 1:2:0.4, the melting temperature is 980 ℃.
Example 2
A preparation method of matte glass porcelain comprises the following steps: after a blank is prepared, spraying a layer of matt transparent glaze on the blank, and firing at 1000 ℃ for 1.5h to obtain the matt glass ceramic product.
The matt transparent glaze comprises the following raw materials in percentage by weight: 55% of quartz sand, 5% of calcite, 23% of soda ash, 2% of alumina and 15% of dolomite powder.
The preparation method of the glaze comprises the following steps: the preparation method of the matt transparent glaze comprises the following steps: the quartz sand, calcite, soda, alumina and dolomite powder with the formula ratio are ball-milled and melted to obtain the matt transparent glaze slip. Wherein, the technological parameters of ball milling are as follows: ball: the mass ratio of water is 1:2:0.5, and the melting temperature is 1000 ℃.
Example 3
A preparation method of matte glass porcelain comprises the following steps: after a blank is prepared, spraying a layer of matt transparent glaze on the blank, and firing at 990 ℃ for 1h to obtain the matt glass ceramic product.
The matt transparent glaze comprises the following raw materials in percentage by weight: 58% of quartz sand, 10% of calcite, 15% of soda ash, 2% of alumina and 15% of dolomite powder.
The preparation method of the glaze comprises the following steps: the preparation method of the matt transparent glaze comprises the following steps: the quartz sand, calcite, soda, alumina and dolomite powder with the formula ratio are ball-milled and melted to obtain the matt transparent glaze slip. Wherein, the technological parameters of ball milling are as follows: ball: the mass ratio of water is 1:2:0.4, the melting temperature is 990 ℃.
Example 4
A preparation method of glass ceramic comprises the following steps: after a blank is prepared, spraying a layer of matt transparent glaze on the blank, and firing at 1000 ℃ for 1h to obtain the matt glass ceramic product.
The matt transparent glaze comprises the following raw materials in percentage by weight: 50% of quartz sand, 10% of calcite, 19% of soda ash, 1% of alumina and 20% of dolomite powder.
The preparation method of the glaze comprises the following steps: the preparation method of the matt transparent glaze comprises the following steps: the quartz sand, the calcite, the soda, the alumina and the dolomite powder with the formula ratio are subjected to ball milling and then are melted to obtain the matt transparent glaze slip. Wherein, the technological parameters of ball milling are as follows: ball: the mass ratio of water is 1:2:0.4, the melting temperature is 1000 ℃.
Comparative example 1
Comparative example 1 differs from example 1 in that: the green body of comparative example 1 was not sprayed with glaze. The composition and firing temperature of the green body were the same as those in example 1.
As is clear from fig. 1 to 2, the glass porcelain of example 1 had a matte surface because of the application of the matte transparent glaze, and the color of the body was not affected because the glaze was transparent. The glass porcelain of the comparative example 1 is not subjected to glazing operation, and the surface of the glass porcelain is in a bright state, so that the invention innovatively sprays glaze on the surface of the glass porcelain blank to achieve a matte effect, can replace the existing pickling process, enables the surface of the glass porcelain to be in the matte state, and can achieve an antifouling effect.
The above embodiments are only preferred embodiments of the present invention, and the protection scope of the present invention is not limited thereby, and any insubstantial changes and substitutions made by those skilled in the art based on the present invention are within the protection scope of the present invention.
Claims (8)
1. The matte glass porcelain is characterized in that a matte transparent glaze is sprayed on the surface of a blank body of the glass porcelain, and the matte transparent glaze comprises the following raw materials in percentage by weight: 50-60% of quartz sand, 5-10% of calcite, 15-25% of soda ash, 1-3% of alumina and 15-20% of dolomite powder; the preparation method of the matt transparent glaze comprises the following steps: the quartz sand, calcite, soda, alumina and dolomite powder with the formula ratio are ball-milled and melted to obtain the matt transparent glaze.
2. The matte glass-ceramic according to claim 1, wherein the matte transparent glaze comprises the following raw materials in percentage by weight: 50-55% of quartz sand, 5-8% of calcite, 20-25% of soda ash, 2-3% of alumina and 15-20% of dolomite powder.
3. The matt glass-ceramic as claimed in claim 1, wherein the matt transparent glaze comprises the following raw materials in percentage by weight: 52% of quartz sand, 8% of calcite, 21% of soda ash, 3% of alumina and 16% of dolomite powder.
4. The matt glass-ceramic as claimed in claim 1, wherein the matt transparent glaze comprises the following raw materials in percentage by weight: 55% of quartz sand, 5% of calcite, 23% of soda ash, 2% of alumina and 15% of dolomite powder.
5. The matte glass-ceramic according to claim 1, wherein the matte transparent glaze comprises the following raw materials in percentage by weight: 58% of quartz sand, 10% of calcite, 15% of soda ash, 2% of alumina and 15% of dolomite powder.
6. The matt glass-ceramic as claimed in claim 1, wherein the matt transparent glaze comprises the following raw materials in percentage by weight: 50% of quartz sand, 10% of calcite, 19% of soda ash, 1% of alumina and 20% of dolomite powder.
7. The matte glass-ceramic according to claim 1, wherein the preparation method of the matte transparent glaze has a melting temperature of 980-1000 ℃.
8. The process for the preparation of a matt glass-ceramic as claimed in any of claims 1 to 7, comprising the steps of: spraying the matt transparent glaze on the surface of the blank, and forming a matt transparent layer on the surface of the blank after firing; wherein the sintering temperature is 980-1000 ℃.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202111056948.5A CN113735442B (en) | 2021-09-09 | 2021-09-09 | Matte glass ceramic and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202111056948.5A CN113735442B (en) | 2021-09-09 | 2021-09-09 | Matte glass ceramic and preparation method thereof |
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| CN113735442A CN113735442A (en) | 2021-12-03 |
| CN113735442B true CN113735442B (en) | 2023-03-07 |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6534427B1 (en) * | 2001-12-12 | 2003-03-18 | Christian R. Quemere | Night glow glaze for ceramics |
| CN101993254A (en) * | 2010-11-23 | 2011-03-30 | 大埔漳联瓷业发展有限公司 | Method for manufacturing medium-temperature ceramic matt glaze |
| CN106830689A (en) * | 2017-01-12 | 2017-06-13 | 九牧厨卫股份有限公司 | A kind of preparation method of Sub-shine glaze sanitary ceramics |
| CN106977097A (en) * | 2016-01-15 | 2017-07-25 | 南京豪祺新材料有限公司 | A kind of middle temperature hard-paste raw glaze of transparent high glaze and preparation method thereof |
| EP3414287A1 (en) * | 2016-02-08 | 2018-12-19 | Kaleseramik Canakkale Kalebodur Seramik Sanayi Anonim Sirketi | An inorganic antibacterial amorphous coating for ceramic surfaces |
| CN111777330A (en) * | 2020-06-01 | 2020-10-16 | 福建良瓷科技有限公司 | Sanitary ceramic mirror patterned glaze and preparation method thereof |
| CN112759264A (en) * | 2021-02-27 | 2021-05-07 | 唐山梦牌瓷业有限公司 | Black matte glaze for ceramic production |
-
2021
- 2021-09-09 CN CN202111056948.5A patent/CN113735442B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6534427B1 (en) * | 2001-12-12 | 2003-03-18 | Christian R. Quemere | Night glow glaze for ceramics |
| CN101993254A (en) * | 2010-11-23 | 2011-03-30 | 大埔漳联瓷业发展有限公司 | Method for manufacturing medium-temperature ceramic matt glaze |
| CN106977097A (en) * | 2016-01-15 | 2017-07-25 | 南京豪祺新材料有限公司 | A kind of middle temperature hard-paste raw glaze of transparent high glaze and preparation method thereof |
| EP3414287A1 (en) * | 2016-02-08 | 2018-12-19 | Kaleseramik Canakkale Kalebodur Seramik Sanayi Anonim Sirketi | An inorganic antibacterial amorphous coating for ceramic surfaces |
| CN106830689A (en) * | 2017-01-12 | 2017-06-13 | 九牧厨卫股份有限公司 | A kind of preparation method of Sub-shine glaze sanitary ceramics |
| CN111777330A (en) * | 2020-06-01 | 2020-10-16 | 福建良瓷科技有限公司 | Sanitary ceramic mirror patterned glaze and preparation method thereof |
| CN112759264A (en) * | 2021-02-27 | 2021-05-07 | 唐山梦牌瓷业有限公司 | Black matte glaze for ceramic production |
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| CN113735442A (en) | 2021-12-03 |
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Denomination of invention: A matte glass ceramic and its preparation method Granted publication date: 20230307 Pledgee: China Guangfa Bank Co.,Ltd. Zhaoqing Branch Pledgor: Guangdong Weiqi Art Glass Co.,Ltd. Registration number: Y2024980004911 |