CN111777330A - Sanitary ceramic mirror patterned glaze and preparation method thereof - Google Patents
Sanitary ceramic mirror patterned glaze and preparation method thereof Download PDFInfo
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- CN111777330A CN111777330A CN202010485768.8A CN202010485768A CN111777330A CN 111777330 A CN111777330 A CN 111777330A CN 202010485768 A CN202010485768 A CN 202010485768A CN 111777330 A CN111777330 A CN 111777330A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention discloses a sanitary ceramic mirror patterned glaze and a preparation method thereof, wherein the preparation raw materials comprise, by weight, 26-36 parts of quartz, 1-5 parts of alumina, 20-30 parts of potassium feldspar, 3-6 parts of dolomite, 5-15 parts of calcite, 3-6 parts of wollastonite, 1-5 parts of zirconium silicate, 1-6 parts of zinc oxide, 5-10 parts of kaolin and 3-8 parts of copper oxide; the method comprises the steps of ball milling and sieving the preparation raw materials to obtain the glaze slip, and coating the glaze slip on the outer surface of the ceramic body, so that the finally obtained glaze surface has cloud-layer-shaped patterns and a mirror surface effect.
Description
Technical Field
The invention relates to a ceramic glaze and a preparation method thereof, in particular to a sanitary ceramic mirror pattern glaze and a preparation method thereof.
Background
The fancy glaze is a glaze which is attached to the surface of a ceramic body and generates the visual effect of the decorative pattern after being fired. In the prior art, the preparation methods of the pattern glaze mainly comprise two methods, one method is to apply various glazes on a ceramic biscuit and to burn the glaze for multiple times, so that the cost investment is high, the process is complex, and the influence of the burning temperature and the thickness of a glaze layer on the pattern of the glaze is large; the other is that a plurality of glazes are glazed in a plurality of layers and then are sintered at one time, the glazes are fused in the sintering process by utilizing different melting temperatures and glaze layer thicknesses of various glazes, so that patterns are formed, the process requirements on glazing and sintering are higher, and the thickness and sintering temperature of various glaze layers can influence the patterns of the glaze, thereby causing implementation difficulty. In addition, the glaze prepared by the two preparation methods has poor stability, and the pattern effect of the glaze is difficult to achieve uniformity and consistency.
Disclosure of Invention
One of the purposes of the invention is to provide a sanitary ceramic mirror surface pattern glaze which can overcome the defects of the prior art, and the prepared glaze material has good stability and uniform and consistent pattern effect of the fired glaze surface through the improvement of raw material selection and proportion.
In order to achieve the purpose, the invention adopts the following technical scheme:
a pattern glaze for a sanitary ceramic mirror surface,
the preparation raw materials comprise the following components in parts by weight: 26 to 36 parts of quartz, 1 to 5 parts of alumina, 20 to 30 parts of potassium feldspar, 3 to 6 parts of dolomite, 5 to 15 parts of calcite, 3 to 6 parts of wollastonite, 1 to 5 parts of zirconium silicate, 1 to 6 parts of zinc oxide, 5 to 10 parts of kaolin and 3 to 8 parts of copper oxide;
further, the chemical components of the material comprise the following components in percentage by mass: 59 to 70 percent of silicon dioxide, 5 to 15 percent of aluminum oxide, 0.01 to 0.2 percent of ferric oxide, 0.01 to 0.2 percent of titanium dioxide, 8 to 14 percent of calcium oxide, 1 to 2 percent of magnesium oxide, 2.3 to 3.5 percent of potassium oxide, 0.1 to 0.5 percent of sodium oxide, 1 to 6 percent of zinc oxide, 0.5 to 4 percent of zirconium dioxide and 3 to 8 percent of copper oxide.
Preferably, the sanitary ceramic mirror pattern glaze comprises the following raw materials in parts by weight: 32 parts of quartz, 4 parts of alumina, 25 parts of potassium feldspar, 3 parts of dolomite, 14 parts of calcite, 5 parts of wollastonite, 2 parts of zirconium silicate, 1 part of zinc oxide, 8 parts of kaolin and 6 parts of copper oxide;
further, the chemical components comprise the following components in percentage by mass: 62.03 percent of silicon dioxide, 12.50 percent of aluminum oxide, 0.15 percent of ferric oxide, 0.15 percent of titanium dioxide, 11.77 percent of calcium oxide, 1.18 percent of magnesium oxide, 2.92 percent of potassium oxide, 0.21 percent of sodium oxide, 1.10 percent of zinc oxide, 1.40 percent of zirconium dioxide and 6.59 percent of copper oxide.
The invention also aims to provide the preparation method of the patterned glaze for the mirror surface of the sanitary ceramic, which has the advantages of simple process flow, convenient preparation, manpower and material resource saving and contribution to industrial popularization.
The preparation method of the mirror-surface patterned glaze for the sanitary ceramics comprises the following steps:
s1, weighing and mixing the raw materials according to the formula to obtain a glaze preparation raw material;
s2, adding the glaze preparation raw material obtained in the step S1 and water accounting for 40-50% of the weight of the glaze preparation raw material into a rapid ball mill for ball milling to obtain prefabricated glaze slurry;
s3, screening the prefabricated glaze slip prepared in the step S2 to obtain the glaze slip;
s4, applying the glaze slip prepared in the step S3 on the outer surface of the ceramic body in a glaze spraying, pouring or dipping way;
and S5, placing the ceramic blank glazed in the step S4 into a tunnel kiln to be sintered at the high temperature of 1200-1300 ℃ for 15-18 h.
Preferably, in step S2, before the glaze preparation raw material and the water ball mill, sodium carboxymethyl cellulose in an amount of 0.1% to 0.2% by weight of the glaze preparation raw material is further added, and the sodium carboxymethyl cellulose, the glaze preparation raw material and water are added together to the rapid ball mill for ball milling. The addition of sodium carboxymethylcellulose can improve the grinding efficiency and the glaze slip concentration, reduce drying shrinkage, ensure that the glaze and the blank body are combined more firmly and are not easy to fall off.
Preferably, the prefabricated glaze slurry obtained in the step S2 is sieved by a 325-mesh screen, the residue is 0.1-0.2%, and the particles with the particle size less than or equal to 10 mu m account for 68-72%.
Preferably, the concentration of the glaze slurry obtained in the step S3 is 348g/200 mL-352 g/200mL, the fluidity measured by Mariotron is 60S/200 mL-80S/200 mL, and the water retention time is 15 min-25 min.
Preferably, the screen sieved in step S3 is a 200 mesh screen.
Preferably, in step S4, the glazing time is 30S-50S, and the glazing speed is 0.5 mm/30S-0.7 mm/30S.
After adopting the technical scheme, compared with the background technology, the invention has the following advantages:
1. the sanitary ceramic mirror surface pattern glaze material obtained by the specially-made formula has good stability, and the patterns of the fired glaze surface are uniform and consistent;
2. the invention finally obtains the cloud layer pattern glaze with mirror surface effect by utilizing the characteristic of copper oxide floating at high temperature, the difference of high-temperature viscosity of other raw materials, the combined action formed by the proportion of the raw materials and the synergistic action among the steps, the pattern of the glaze surface is stable, uniform and consistent, and the preparation method only needs single glaze material, one-time glazing and one-time firing, compared with the prior multiple glaze materials, the invention has the advantages of simple flow, convenient preparation, manpower and material resource saving and contribution to industrial popularization;
3. the glaze provided by the invention can be used for common sanitary ceramic mud adobe bricks, and has a wide application range.
Drawings
FIG. 1 is a photograph of an example of a visual effect of embodiment 1 of the present invention;
FIG. 2 is a photograph illustrating an example of the visual effect of embodiment 2 of the present invention;
FIG. 3 is a photograph of an example of the visual effect of embodiment 3 of the present invention;
FIG. 4 example photograph of visual effect of embodiment 4 of the present invention;
fig. 5 is a photograph illustrating an example of the visual effect of embodiment 5 of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail below with reference to the following embodiments and the accompanying drawings. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention. The raw materials and equipment used in the present invention are commercially available unless otherwise specified.
The preparation method of the ceramic sanitary ware mirror pattern glaze of embodiments 1 to 5 comprises the following steps:
s1, weighing and mixing the raw materials according to the formula to obtain a glaze preparation raw material;
specifically, the raw material formulations of examples 1 to 5 are shown in table 1, and the chemical composition is shown in table 2.
TABLE 1 sanitary ceramic mirror surface pattern glaze preparation raw material formula of examples 1-5
| Preparation of the starting Material | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 |
| Quartz crystal | 32 | 31 | 31.5 | 32 | 33 |
| Alumina oxide | 4 | 4 | 4.2 | 4.5 | 1.5 |
| Potassium feldspar | 25 | 26 | 25.8 | 30 | 20 |
| Dolomite | 3 | 3.5 | 2.8 | 5.5 | 3 |
| Calcite | 14 | 13.5 | 14.2 | 6 | 15 |
| Wollastonite | 5 | 4.8 | 4.5 | 6 | 4.8 |
| Zirconium silicate | 2 | 2.2 | 2 | 1.5 | 4 |
| Zinc oxide | 1 | 1.5 | 1 | 5 | 1.5 |
| Kaolin clay | 8 | 7.5 | 7.8 | 5 | 10 |
| Copper oxide | 6 | 6 | 6.2 | 4.5 | 7.2 |
Note: in Table 1, the raw materials are counted by weight parts, specifically, each part is 500 g.
TABLE 2 chemical composition of mirror-like patterned glaze for sanitary ceramics of examples 1 to 5
| Chemical composition | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 |
| Silicon dioxide | 62.03 | 61.39 | 61.70 | 62.81 | 61.40 |
| Alumina oxide | 12.50 | 12.47 | 12.78 | 12.37 | 9.74 |
| Ferric oxide | 0.15 | 0.14 | 0.15 | 0.11 | 0.17 |
| Titanium dioxide | 0.15 | 0.14 | 0.15 | 0.11 | 0.18 |
| Calcium oxide | 11.77 | 11.58 | 11.58 | 8.34 | 12.31 |
| Magnesium oxide | 1.18 | 1.27 | 1.13 | 1.48 | 1.21 |
| Potassium oxide | 2.92 | 3.02 | 3.00 | 3.37 | 2.39 |
| Sodium oxide | 0.21 | 0.22 | 0.21 | 0.25 | 0.17 |
| Zinc oxide | 1.10 | 1.65 | 1.10 | 5.34 | 1.66 |
| Zirconium dioxide | 1.40 | 1.54 | 1.40 | 1.02 | 2.82 |
| Copper oxide | 6.59 | 6.58 | 6.80 | 4.80 | 7.95 |
| Total up to | 100 | 100 | 100 | 100 | 100 |
Note: the ingredients in table 2 are given in mass percent (without burn-off).
S2, adding the glaze preparation raw material obtained in the step S1, water accounting for 40-50% of the weight of the glaze preparation raw material and sodium carboxymethyl cellulose accounting for 0.2% of the weight of the glaze preparation raw material into a rapid ball mill for ball milling to obtain prefabricated glaze slurry;
s3, sieving the prefabricated glaze slip prepared in the step S2 by a 200-mesh sieve, and obtaining fine and uniform glaze slip after coarse particles are sieved;
s4, applying the glaze slip prepared in the step S3 on the outer surface of a ceramic body in a glaze spraying, glazing or glaze dipping way, wherein the glaze application time is 30-50S, and the ceramic body can be common sanitary ceramic mud brick in the market, such as a grey brick, which is cast by production mud and comprises the following components (without burning loss): 66.71% of silicon dioxide, 25.65% of aluminum oxide, 0.93% of ferric oxide, 0.22% of titanium dioxide, 1.45% of calcium oxide, 0.82% of magnesium oxide, 3.27% of potassium oxide and 0.95% of sodium oxide.
And S5, placing the ceramic blank glazed in the step S4 into a tunnel kiln to be fired at high temperature to obtain dark green ground color silver gray cloud layered fancy glaze and form a mirror surface effect.
The specific condition parameters of each step of the preparation method of the mirror-surface fancy glaze for the sanitary ceramics of the embodiments 1 to 5 are shown in Table 3.
TABLE 3 concrete condition parameters for each step of the preparation methods of examples 1 to 5
| Step (ii) of | Condition parameter | Unit of | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 |
| S3 | Fineness of glaze | ％ | 0.16 | 0.12 | 0.15 | 0.18 | 0.11 |
| S3 | Glaze materialParticle size | ％ | 70.23 | 70.56 | 70.12 | 69.82 | 70.69 |
| S3 | Concentration of glaze | g/200mL | 349.9 | 350.5 | 351.2 | 349.2 | 348.6 |
| S3 | Fluidity of glaze | s/200mL | 70 | 68 | 72 | 76 | 78 |
| S3 | Time of water retention | min | 16.85 | 17.42 | 16.53 | 17.2 | 18.53 |
| S4 | Glazing speed | mm/30s | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 |
| S4 | Thickness of glaze layer | mm | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 |
| S5 | Firing temperature | ℃ | 1210 | 1206 | 1218 | 1213 | 1215 |
| S5 | Time of firing | h | 16.8 | 16.5 | 15.8 | 16 | 17 |
Note: in Table 3, the fineness of the glaze refers to the percentage of the residue on a 325-mesh sieve, and the particle size of the glaze refers to the percentage of particles with a particle size of 10 μm or less. The method for testing the parameter water retention time comprises the following steps: preparing the above-mentioned green brick, puc circular ring with internal diameter of 45mm and height of 5mm, 10mL injector and stopwatch, placing the puc circular ring on the green brick, using injector to suck 5mL of glaze slurry and inject it into puc circular ring, after the glaze slurry is fully spread on the circular stopwatch, starting timing, stopping timing until the glaze slurry water film is completely disappeared in the circular ring, at this time the time counted by stopwatch is water-retaining time, also called drying speed.
Fig. 1 to 5 show photographs of examples of visual effects in embodiments 1 to 5 of the present invention, and as can be seen from fig. 1 to 5 (partial shooting light shadows do not affect the overall effect), in all embodiments 1 to 5, cloud layered fancy glaze with mirror surface effect (mirror surface effect cannot be shown from black and white pictures of fancy details) is obtained, and the fancy patterns of the glaze are stable, uniform and consistent.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that can be easily conceived by those skilled in the art within the technical scope of the present invention are included in the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.
Claims (10)
1. The utility model provides a sanitary ceramic mirror surface decorative pattern glaze which characterized in that: the preparation raw materials comprise the following components in parts by weight: 26 to 36 parts of quartz, 1 to 5 parts of alumina, 20 to 30 parts of potassium feldspar, 3 to 6 parts of dolomite, 5 to 15 parts of calcite, 3 to 6 parts of wollastonite, 1 to 5 parts of zirconium silicate, 1 to 6 parts of zinc oxide, 5 to 10 parts of kaolin and 3 to 8 parts of copper oxide.
2. The sanitary ceramic mirror-surface fancy glaze of claim 1, wherein: the chemical components of the material are as follows by mass percent: 59 to 70 percent of silicon dioxide, 5 to 15 percent of aluminum oxide, 0.01 to 0.2 percent of ferric oxide, 0.01 to 0.2 percent of titanium dioxide, 8 to 14 percent of calcium oxide, 1 to 2 percent of magnesium oxide, 2.3 to 3.5 percent of potassium oxide, 0.1 to 0.5 percent of sodium oxide, 1 to 6 percent of zinc oxide, 0.5 to 4 percent of zirconium dioxide and 3 to 8 percent of copper oxide.
3. The sanitary ceramic mirror-surface fancy glaze of claim 1, wherein: the preparation raw materials comprise the following components in parts by weight: 32 parts of quartz, 4 parts of alumina, 25 parts of potassium feldspar, 3 parts of dolomite, 14 parts of calcite, 5 parts of wollastonite, 2 parts of zirconium silicate, 1 part of zinc oxide, 8 parts of kaolin and 6 parts of copper oxide.
4. The sanitary ceramic mirror-surface fancy glaze according to claim 3, wherein: the chemical components of the material are as follows by mass percent: 62.03 percent of silicon dioxide, 12.50 percent of aluminum oxide, 0.15 percent of ferric oxide, 0.15 percent of titanium dioxide, 11.77 percent of calcium oxide, 1.18 percent of magnesium oxide, 2.92 percent of potassium oxide, 0.21 percent of sodium oxide, 1.10 percent of zinc oxide, 1.40 percent of zirconium dioxide and 6.59 percent of copper oxide.
5. The method for preparing the mirror-surface fancy glaze for the sanitary ceramics according to any one of claims 1 to 4, which is characterized by comprising the following steps: the method comprises the following steps:
s1, weighing and mixing the raw materials according to the formula to obtain a glaze preparation raw material;
s2, adding the glaze preparation raw material obtained in the step S1 and water accounting for 40-50% of the weight of the glaze preparation raw material into a rapid ball mill for ball milling to obtain prefabricated glaze slurry;
s3, screening the prefabricated glaze slip prepared in the step S2 to obtain the glaze slip;
s4, applying the glaze slip prepared in the step S3 on the outer surface of the ceramic body in a glaze spraying, pouring or dipping way;
and S5, placing the ceramic blank glazed in the step S4 into a tunnel kiln to be sintered at the high temperature of 1200-1300 ℃ for 15-18 h.
6. The method for preparing the mirror-surface fancy glaze for sanitary ceramics according to claim 5, which is characterized in that: in step S2, before the glaze preparation raw material and the water ball mill, sodium carboxymethyl cellulose in an amount of 0.1 to 0.2% by weight of the glaze preparation raw material is further added, and the sodium carboxymethyl cellulose, the glaze preparation raw material and water are added together to the rapid ball mill for ball milling.
7. The method for preparing the mirror-surface fancy glaze for sanitary ceramics according to claim 5, which is characterized in that: the prefabricated glaze slurry obtained in the step S2 is sieved by a 325-mesh screen, the residue is 0.1-0.2%, and the particles with the particle size less than or equal to 10 mu m account for 68-72%.
8. The method for preparing the mirror-surface fancy glaze for sanitary ceramics according to claim 5, which is characterized in that: the glaze slurry obtained in the step S3 has a concentration of 348 g/200-352 g/200mL, a fluidity of 60-80S/200 mL, and a water retention time of 15-25 min.
9. The method for preparing the mirror-surface fancy glaze for sanitary ceramics according to claim 5, which is characterized in that: the screen sieved in step S3 was a 200-mesh screen.
10. The method for preparing the mirror-surface fancy glaze for sanitary ceramics according to claim 3, which is characterized in that: in step S4, the glazing time is 30S-50S, and the glazing speed is 0.5 mm/30S-0.7 mm/30S.
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| CN113735442A (en) * | 2021-09-09 | 2021-12-03 | 广东伟祺艺术玻璃有限公司 | Matte glass ceramic and preparation method thereof |
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