CN108675833B - Manufacturing process of underglaze seven-color ceramic with artistic drawing - Google Patents

Manufacturing process of underglaze seven-color ceramic with artistic drawing Download PDF

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CN108675833B
CN108675833B CN201810511903.4A CN201810511903A CN108675833B CN 108675833 B CN108675833 B CN 108675833B CN 201810511903 A CN201810511903 A CN 201810511903A CN 108675833 B CN108675833 B CN 108675833B
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ceramic
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pigment
painting
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CN108675833A (en
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余彬
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation

Abstract

The invention relates to a manufacturing process of underglaze seven-color ceramic with artistic strokes, which comprises the following steps: (1) preparing a painting material; (2) reprocessing the painting material in the step (1) and painting on the ceramic blank; (3) after the pigment is prepared, coloring the lines drawn in the step (2) by using the pigment of the high-temperature multicolor pigment; (4) after the glaze is prepared, glazing is performed on the ceramic green body. The invention has the advantages that: the seven-color ceramic with the calligraphy style is made of water, so that no peculiar smell is generated during drawing. Because the pigment is sintered at high temperature and is attached under the glaze, the product has no lead and cadmium and strong thermal stability. The color of the picture is rich and vivid, and the colorful ceramic painting enters a harmless era by combining with the attitude of modern people to life, so that the ceramic painting is an expression of modern porcelain made by modern people. The picture may be traditional, but the practice and the product are certain to meet the standard of modern life.

Description

Manufacturing process of underglaze seven-color ceramic with artistic drawing
Technical Field
The invention relates to a manufacturing process of underglaze seven-color ceramic with artistic strokes.
Background
With the continuous improvement of the living standard of people, the requirements on the used objects are higher and higher. The traditional over-glaze painting process is formed by drawing lines with low-temperature black materials and then drawing low-temperature colorful colors and firing at 800 ℃. Chemical raw materials are added during drawing, peculiar smell is generated, and the product after being burnt is not sanitary. However, all colored craft-painting ceramics are made by firing white porcelain and then painting with low-temperature painting material and firing at about 800 degrees (new color, pastel, etc.). The produced overglaze color ceramic is not only harmful to people who draw pictures, but also fades after a long time when the lead and cadmium content of the fired ceramic exceeds the standard.
The underglaze process of the millennium porcelain-making of Jingdezhen is only blue and white, and the five colors under the glaze of Hunan carinling are that a layer of glaze is firstly applied on a blank body, then the blank body is burnt at 900 ℃ to enhance the hardness of the glaze, and then the blank body is painted on the glaze. The glaze has certain fluidity, and the line painting on the glaze can be scattered along with the flow of the glaze in the process of burning. So that fine lines cannot be drawn. The underglaze seven-color painting lines of the invention are directly drawn on the blank and directly contacted with the pug, and the pug does not flow, so the lines cannot move. The picture can be better displayed.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides a manufacturing process of underglaze seven-color ceramic with artistic strokes, and the technical scheme of the invention is as follows:
the manufacturing process of the underglaze seven-color ceramic with artistic strokes comprises the following steps:
(1) preparing a painting material;
(2) reprocessing the painting material in the step (1) and painting on the ceramic blank;
(3) after the pigment is prepared, coloring the lines drawn in the step (2) by using the pigment of the high-temperature multicolor pigment;
(4) after the glaze is prepared, glazing is performed on the ceramic green body.
The step (1) is specifically as follows: weighing the following raw material components, namely 30% of cobalt oxide, 30% of ferric oxide and 40% of chromium sesquioxide, fusing the components, calcining at 1350 ℃, cooling after 8 hours of calcination, putting the mixture into a ball mill, adding water, ball-milling for 24-30 hours, and spin-drying to obtain the powdery black material.
The step (2) is specifically as follows: adding ceramic glue into the black material obtained in the step (1) for the first time, adding water, stirring uniformly, drying in the sun to form cracks, adding the ceramic glue with the same weight as that of the first time again, and uniformly mixing to obtain a painting on a ceramic blank; the mass ratio of the black materials, the ceramic cement and the water is 10:4: 4.
The preparation method of the pigment comprises the following steps: adding a lubricant and white clay on the colorful pigment to ensure that the color is uniformly distributed on the ceramic body and is easier to absorb; wherein the mass ratio of the colorful pigment to the lubricant to the clay is 100:2: 2.
The glaze material preparation process comprises the following steps: adding high-temperature bucket green glaze into the medium-temperature white transparent glaze, then adding high-temperature bright glaze, and finally adding the high-temperature white transparent glaze, so that the thickness of the glaze on a ceramic blank body is 0.5cm, wherein the bucket green glaze increases the transparency of the glaze, the white bright glaze increases the glossiness of the glaze, the temperature white transparent glaze also increases the transparency of the glaze, and the high-temperature transparent glaze increases the hardness of the glaze.
The mass ratio of the medium-temperature white transparent glaze to the high-temperature green glaze to the high-temperature bright glaze is 10:2:3: 5.
The invention has the advantages that: the seven-color ceramic with the calligraphy style is made of water, so that no peculiar smell is generated during drawing. Because the pigment is sintered at high temperature and is attached under the glaze, the product has no lead and cadmium and strong thermal stability. The color of the picture is rich and vivid, and the colorful ceramic painting enters a harmless era by combining with the attitude of modern people to life, so that the ceramic painting is an expression of modern porcelain made by modern people. The picture may be traditional, but the practice and the product are certain to meet the standard of modern life.
Detailed Description
The invention will be further described with reference to specific embodiments, and the advantages and features of the invention will become apparent as the description proceeds. These examples are illustrative only and do not limit the scope of the present invention in any way. It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention, and that such changes and modifications may be made without departing from the spirit and scope of the invention.
Example 1: the invention relates to a manufacturing process of underglaze seven-color ceramic with artistic strokes, which comprises the following steps:
(1) preparing a painting material;
(2) reprocessing the painting material in the step (1) and painting on the ceramic blank;
(3) after the pigment is prepared, coloring the lines drawn in the step (2) by using the pigment of the high-temperature multicolor pigment;
(4) after the glaze is prepared, glazing is performed on the ceramic green body.
The step (1) is specifically as follows: weighing the following raw material components, namely 30% of cobalt oxide, 30% of ferric oxide and 40% of chromium sesquioxide, fusing the components, calcining at 1350 ℃, cooling after 8 hours of calcination, putting the mixture into a ball mill, adding water, ball-milling for 24 hours, and spin-drying to obtain the powdery black material.
The step (2) is specifically as follows: adding ceramic glue into the black material obtained in the step (1) for the first time, adding water, stirring uniformly, drying in the sun to form cracks, adding the ceramic glue with the same weight as that of the first time again, and uniformly mixing to obtain a painting on a ceramic blank; the mass ratio of the black materials, the ceramic cement and the water is 10:4: 4.
The preparation method of the pigment comprises the following steps: adding a lubricant and white clay on the colorful pigment to ensure that the color is uniformly distributed on the ceramic body and is easier to absorb; wherein the mass ratio of the colorful pigment to the lubricant to the clay is 100:2: 2.
The glaze material preparation process comprises the following steps: adding high-temperature bucket green glaze into medium-temperature white transparent glaze (conventional material), then adding high-temperature bright glaze (the medium-temperature general firing temperature is 1200-1250 ℃, and the high-temperature firing temperature is 1320-1380 ℃), and finally adding high-temperature white transparent glaze (conventional material), so that the thickness of the glaze on a ceramic blank is 0.5cm, wherein the bucket green glaze increases the transparency of the glaze, the large white bright glaze increases the glossiness of the glaze, the warm white transparent glaze also increases the transparency of the glaze, and the high-temperature transparent glaze increases the hardness of the glaze.
The mass ratio of the medium-temperature white transparent glaze to the bucket green glaze to the bright glaze to the high-temperature white transparent glaze is 10:2:3: 5.
Example 2: the invention relates to a manufacturing process of underglaze seven-color ceramic with artistic strokes, which comprises the following steps:
(1) preparing a painting material;
(2) reprocessing the painting material in the step (1) and painting on the ceramic blank;
(3) after the pigment is prepared, coloring the lines drawn in the step (2) by using the pigment of the high-temperature multicolor pigment;
(4) after the glaze is prepared, glazing is performed on the ceramic green body.
The step (1) is specifically as follows: weighing the following raw material components, namely 30% of cobalt oxide, 30% of ferric oxide and 40% of chromium sesquioxide, fusing the components, calcining at 1350 ℃, cooling after 8 hours of calcination, putting the mixture into a ball mill, adding water, ball-milling for 30 hours, and spin-drying to obtain the powdery black material.
The step (2) is specifically as follows: adding ceramic glue into the black material obtained in the step (1) for the first time, adding water, stirring uniformly, drying in the sun to form cracks, adding the ceramic glue with the same weight as that of the first time again, and uniformly mixing to obtain a painting on a ceramic blank; the mass ratio of the black materials, the ceramic cement and the water is 10:4: 4.
The preparation method of the pigment comprises the following steps: adding a lubricant and white clay on the colorful pigment to ensure that the color is uniformly distributed on the ceramic body and is easier to absorb; wherein the mass ratio of the colorful pigment to the lubricant to the clay is 100:2: 2.
The glaze material preparation process comprises the following steps: adding high-temperature bucket green glaze into medium-temperature white transparent glaze (conventional material), then adding high-temperature bright glaze (the medium-temperature general firing temperature is 1200-1250 ℃, and the high-temperature firing temperature is 1320-1380 ℃), and finally adding high-temperature white transparent glaze (conventional material), so that the thickness of the glaze on a ceramic blank is 0.5cm, wherein the bucket green glaze increases the transparency of the glaze, the large white bright glaze increases the glossiness of the glaze, the warm white transparent glaze also increases the transparency of the glaze, and the high-temperature transparent glaze increases the hardness of the glaze.
The mass ratio of the medium-temperature white transparent glaze to the bucket green glaze to the bright glaze to the high-temperature white transparent glaze is 10:2:3: 5.
Table 1 shows a comparison of the present application with the prior art.
Figure BDA0001672834290000061
Table 1.

Claims (2)

1. The manufacturing process of the underglaze seven-color ceramic with artistic strokes is characterized by comprising the following steps of:
(1) preparing a painting material;
(2) reprocessing the painting material in the step (1) and painting on the ceramic blank;
(3) after the pigment is prepared, coloring the lines drawn in the step (2) by using the pigment of the high-temperature multicolor pigment;
(4) after the glaze is prepared, glazing is carried out on the ceramic blank;
the step (1) is specifically as follows: weighing the following raw material components, namely 30% of cobalt oxide, 30% of ferric oxide and 40% of chromium sesquioxide, fusing the components, calcining at 1350 ℃, cooling after 8 hours of calcination, putting the components into a ball mill, adding water, ball-milling for 24-30 hours, and spin-drying to obtain a powdery black material;
the step (2) is specifically as follows: adding ceramic glue into the black material obtained in the step (1) for the first time, adding water, stirring uniformly, drying in the sun to form cracks, adding the ceramic glue with the same weight as that of the first time again, and uniformly mixing to obtain a painting on a ceramic blank; the mass ratio of the black materials to the ceramic cement to the water is 10:4: 4;
the glaze material preparation process comprises the following steps: adding high-temperature bucket green glaze into the medium-temperature white transparent glaze, then adding high-temperature bright glaze, and finally adding the high-temperature white transparent glaze, so that the thickness of the glaze on the ceramic blank body is 0.5 cm;
the preparation method of the pigment comprises the following steps: adding a lubricant and white clay to the multicolor pigment, wherein the mass ratio of the multicolor pigment to the lubricant to the white clay is 100:2: 2.
2. The manufacturing process of the underglaze seven-color ceramic painting according to claim 1, wherein the mass ratio of the medium-temperature white transparent glaze to the high-temperature green glaze to the high-temperature bright glaze to the high-temperature white transparent glaze is 10:2:3: 5.
CN201810511903.4A 2018-05-25 2018-05-25 Manufacturing process of underglaze seven-color ceramic with artistic drawing Active CN108675833B (en)

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Publication number Priority date Publication date Assignee Title
CN110527321B (en) * 2019-09-27 2020-12-25 景德镇陶瓷大学 Underglaze color pigment and preparation method and application thereof
CN111333432B (en) * 2020-03-26 2022-02-18 余志刚 Five-color material for ceramic underglaze painting and calligraphy and application method thereof
CN112457059B (en) * 2020-12-07 2023-04-28 余志刚 Pigment for painting and calligraphy under glaze and on color bottom in glaze and application method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103342585A (en) * 2013-07-08 2013-10-09 河南理工大学 Method for decorating domestic ceramic underglaze color
CN107721393A (en) * 2017-09-30 2018-02-23 刘荣杰 A kind of underglaze colour with micro text paints the preparation method of porcelain

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103342585A (en) * 2013-07-08 2013-10-09 河南理工大学 Method for decorating domestic ceramic underglaze color
CN107721393A (en) * 2017-09-30 2018-02-23 刘荣杰 A kind of underglaze colour with micro text paints the preparation method of porcelain

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