CN110357668A - A kind of full throwing glaze Ceramic Tiles and preparation method thereof with graininess flashing ornaments - Google Patents
A kind of full throwing glaze Ceramic Tiles and preparation method thereof with graininess flashing ornaments Download PDFInfo
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- CN110357668A CN110357668A CN201910736009.1A CN201910736009A CN110357668A CN 110357668 A CN110357668 A CN 110357668A CN 201910736009 A CN201910736009 A CN 201910736009A CN 110357668 A CN110357668 A CN 110357668A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Ceramic Engineering (AREA)
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Abstract
The present invention discloses a kind of full throwing glaze Ceramic Tiles and preparation method thereof with graininess flashing ornaments comprising by blank compression moulding, is placed in roller kilns and is dried, forms Ceramic Tiles green body；Incrustation is carried out by 3D ink jet printing, offset printing or roller printing in Ceramic Tiles billet surface, forms pattern decorative layer；Apply gold sand dry granular glaze in pattern decorative layer surface, forms gold sand dry granular glaze layer；Apply full throwing glaze in gold sand dry granular glaze layer, is formed and throw glaze layer entirely；Kiln-firing molding, obtains the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments；Full glazed pottery ceramic tile blank of throwing is polished, the full throwing glaze Ceramic Tiles with graininess flashing ornaments are obtained；Wherein, Ceramic Tiles green body is set as color grains spot Ceramic Tiles green body consistent with pattern decorative layer tone；Added with by weight the gold sand dry granular for being 5-30% in gold sand dry granular glaze layer.So that throwing glaze Ceramic Tiles entirely is provided simultaneously with graininess reflecting effect and high glaze glossiness.
Description
Technical field
The present invention relates to architectural pottery production field more particularly to a kind of full throwing glaze ceramics with graininess flashing ornaments
Brick and preparation method thereof.
Background technique
The full Dali stone ceramic tile for throwing glaze handicraft because main imitation natural marble texture, it is bright in luster, pattern is true to nature,
Level is abundant, clarity is high, the feature more than designs and varieties, therefore the favor by market for a long time.In natural marble, often
Because of the construction reason of geology, containing various mineral crystals, these crystal can produce metal-like and flash effect in stone material.
The existing full surface for throwing glaze Ceramic Tiles can also be made and be produced with all kinds of by material application, the method for technique glaze
The luster effect that mineral as stone materials glisten, but these full throwing glaze Ceramic Tiles all flash effects are all stiff and unnatural.One
As the Ceramic Tiles with mineral crystal flash effect be all to adjust glaze using flash of light dry granular material etc. raw materials to make, in ceramics
Brick surface generates flash effect by the reflection to light different angle.
But by adjusting the composition of glaze, the flash of light dry granular material being partially added in glaze is burnt in glaze high temperature
It at rear less stable, easily reacts to each other with glaze, causes flash effect to weaken decorative effect bad；Meanwhile part flash of light dry granular
The fixed cloth of material imposes in the glaze layer of the Ceramic Tiles, this results in the polishing process after firing, and the flash of light of ceramic brick surface is dry
Grain material, which is thrown, to be reamed and leaves hole, pit, can not be told on；Meanwhile part flash of light dry granular material has due to itself
Certain color, and when the color and decorative pattern tone difference of the flash of light dry granular, it is inevitable to decorate table in the Ceramic Tiles
Face can generate more heterochromatic or other coloured pointing object, influence the decorative effect of Ceramic Tiles；Meanwhile glaze glaze adjusted
Glossiness is not high, and product surface is once polished, lustrous surface enhancing, the reflective effect of the class diamond of fine particle shape
Fruit disappears, and no longer has apparent decoration functions.
Therefore, how the Ceramic Tiles of a kind of high glaze glossiness and graininess flash effect decorative effect are being provided, become
Technical problem urgently to be resolved.
Summary of the invention
In view of above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide a kind of with the complete of graininess flashing ornaments
Throw glaze Ceramic Tiles and preparation method thereof, it is desirable to provide there is one kind high glaze glossiness to have graininess flash effect decoration again
The Ceramic Tiles technical solution of effect.
The present invention is in order to solve the above technical problems, the technical solution provided is as follows: a kind of with graininess flashing ornaments
The full preparation method for throwing glaze Ceramic Tiles comprising:
A, it by blank compression moulding, is placed in roller kilns and is dried, form Ceramic Tiles green body；
C, incrustation is carried out by 3D ink jet printing, offset printing or roller printing in the Ceramic Tiles billet surface,
Form pattern decorative layer；
D, apply gold sand dry granular glaze in the pattern decorative layer surface, form gold sand dry granular glaze layer；
E, apply full throwing glaze in the gold sand dry granular glaze layer, formed and throw glaze layer entirely；
F, kiln-firing forms, and obtains the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments；
G, the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments is polished, obtaining has graininess flash of light dress
The full throwing glaze Ceramic Tiles of decorations；
Wherein, the Ceramic Tiles green body is set as, and is mixed with the consistent multicolour particle of the pattern decorative layer tone
At color grains spot Ceramic Tiles green body；
Added with by weight the gold sand dry granular for being 5-30% in the gold sand dry granular glaze layer.
Further, the melt temperature scope of the gold sand dry granular is 1200-1450 DEG C；
The thin gold sand dry granular particle size added in the gold sand dry granular glaze layer includes: 40-60 mesh 0-15%, 60-80 mesh
20-50%, 80-100 mesh 25-60%, 100 5-15% now；
The chemical composition of the gold sand dry granular is by weight percentage, comprising: C 0.68%, O 9.68%, Si
3.40%, Cr 17.11%, Mn 1.91%, Fe 63.01%, Ni 4.21%.
Further, the gold sand dry granular glaze in the step D is applied on pattern decorative layer by silk-screen printing technique, shape
At gold sand dry granular glaze layer；
The composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 50-65%, CMC or stamp material
20-30%, gold sand dry granular 10-30%；
The chemical composition of the clear frit is in percentage by weight, comprising: SiO248.2-55.6%, Al2O3 12.7-
16.1%, Fe2O30-0.3%, CaO 8.4-11.3%, MgO 4.2-6.5%, Na2O 2.6-5.9%, K2O 0.5-
1.8%, ZnO 1.8-5.2%, B2O30.5-1.7%, BaO 4.5-7.2%；
The specific gravity of the gold sand dry granular glaze is 1.40-1.70；
The glaze slurry viscosity of the gold sand dry granular glaze is measured as 15-25s with Marsh funnel；
The mesh number of silk screen used is 40-60 mesh；
The composition of the stamp material is according to parts by weight, comprising: 16 parts of glycerol, 14 parts of ethylene glycol, 4.5 parts of CMC, water 100
Part, 0.15 part of preservative and 0.1 part of degumming agent.
Further, the gold sand dry granular glaze in the step D is applied to figure by getting rid of glaze dotting process or spray glaze handicraft
In case decorative layer, gold sand dry granular glaze layer is formed；
The composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 65-95%, dry granular 5-30%,
Ball clay glaze slip 0-10%；
The specific gravity of the gold sand dry granular glaze is 1.20-1.70；
The glaze slurry viscosity of the gold sand dry granular glaze is measured as 12-30s with Marsh funnel；
The glaze volume of the gold sand dry granular glaze is 40-160g/m2；
The composition of the ball clay glaze slip is according to parts by weight, comprising: 100 parts and water 40-60 parts of ball clay.
Further, the full throwing glaze in the step E is set as throwing clear frit entirely, the full chemical composition for throwing clear frit
In percentage by weight, comprising: SiO248.2-55.6%, Al2O312.7-16.1%, Fe2O30-0.3%, CaO 8.4-
11.3%, MgO 4.2-6.5%, Na2O 2.6-5.9%, K2O 0.5-1.8%, ZnO 1.8-5.2%, B2O3 0.5-
1.7%, BaO 4.5-7.2%；
The full glaze slip specific gravity for throwing clear frit is 1.45-1.80；
The full glaze slurry viscosity for throwing clear frit is measured as 15-38s with Marsh funnel；
The full glaze volume for throwing clear frit is 500-720g/m2。
Further, the firing temperature in the step F is 1100-1250 DEG C；
Firing period is 40-80min.
Further, the Ceramic Tiles green body may be arranged as the solid color base of single color powder；
It further include step B between the step A and the step C, the step B includes: in the ceramic adobe body surface
Face applies ground coat enamel, forms ground glaze layer；
The C setting are as follows: surface is carried out by 3D ink jet printing, offset printing or roller printing in the ground coat enamel layer surface
Decoration forms pattern decorative layer.
Further, added with the gold sand dry granular for being not more than 20% by weight in the ground coat enamel, and the gold sand is dry
The partial size of grain is 40-80 mesh；
The chemical composition of the ground coat enamel is in percentage by weight, comprising:
SiO242.6-49.9%, Al2O315.4-18.3%, Fe2O30%-0.2%, CaO 6.9%-9.4%, MgO
1.1%-4.5%, Na2O 2.3%-7.7%, K2O 0.5%-1.8%, ZnO 1.3%-4.1%, ZrO211.2%-
16.6%；
The glaze slip specific gravity of the ground coat enamel is 1.20；
The glaze slurry viscosity of the ground coat enamel is measured as 15-35s with Marsh funnel；
The glaze volume of the ground coat enamel is 240-610g/m2。
The present invention is in order to solve the above technical problems, the another technical solution provided is as follows: one kind having graininess flash of light dress
The full throwing glaze Ceramic Tiles of decorations, wherein the full throwing glaze Ceramic Tiles with graininess flashing ornaments are by as above described in any item
The preparation method of full throwing glaze Ceramic Tiles with graininess flashing ornaments prepares.
Further, the full throwing glaze Ceramic Tiles with graininess flashing ornaments successively include: from the bottom to top
Ceramic Tiles green body, pattern decorative layer, gold sand dry granular glaze layer and glaze layer is thrown entirely；
Alternatively, Ceramic Tiles green body, ground glaze layer, pattern decorative layer, gold sand dry granular glaze layer and throwing glaze layer entirely；
Wherein, added with by weight the gold sand dry granular for being 5-30%, the gold sand dry granular in the gold sand dry granular glaze layer
The partial size of gold sand dry granular in glaze layer is 40-60 mesh 0-15%, 60-80 mesh 20-50%, 80-100 mesh 25-60%, and 100 now
5-15%；
The gold sand dry granular by weight no more than 20%, and the ground glaze layer gold sand dry granular are added in the ground glaze layer
Partial size be 40-80 mesh.
The utility model has the advantages that the full throwing glaze Ceramic Tiles that the present invention provides a kind of with graininess flashing ornaments and its preparation side
Method comprising: it by blank compression moulding, is placed in roller kilns and is dried, form Ceramic Tiles green body；In ceramic adobe body surface
Face carries out incrustation by 3D ink jet printing, offset printing or roller printing, forms pattern decorative layer；In pattern decorative layer table
Face applies gold sand dry granular glaze, forms gold sand dry granular glaze layer；Apply full throwing glaze in gold sand dry granular glaze layer, is formed and throw glaze layer entirely；Enter
Kiln forms by a firing, and obtains the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments；Full glazed pottery ceramic tile blank of throwing is thrown
Light obtains the full throwing glaze Ceramic Tiles with graininess flashing ornaments；Wherein, Ceramic Tiles green body is set as and pattern decorative layer tone
Consistent color grains spot Ceramic Tiles green body；Added with by weight the gold sand dry granular for being 5-30% in gold sand dry granular glaze layer.Make
It obtains throwing glaze Ceramic Tiles entirely to be provided simultaneously with, graininess reflecting effect and high glaze glossiness；
Pass through the coloured silk for being set as being mixed into the consistent multicolour particle of the pattern decorative layer tone by the ingredient
Coloured particles spot base, and then may be implemented directly to apply pattern decorative layer on the Ceramic Tiles green body, and do not reduce effectively
Reduce the manufacturing cost of the full throwing glaze Ceramic Tiles with graininess flashing ornaments；Meanwhile also effectively avoiding Ceramic Tiles green body
Different from the pattern decorative layer tone, causing to generate in the Ceramic Tiles combination with decorative surfaces more heterochromatic or other has color dot
Shape object, the problem of influencing the decorative effect of Ceramic Tiles.By being mixed in pattern decorative layer surface application, has metal
The gold sand dry granular glaze layer of the reflective gold sand dry granular of grain, and then the full throwing glaze Ceramic Tiles in the present invention have been effectively ensured and have had graininess sudden strain of a muscle
Light decorative effect；
Further, it by applying full throwing glaze in gold sand dry granular glaze layer surface, and then effectively improves and throws glazed pottery entirely
The brightness of the surface glaze layer of ceramic tile；Meanwhile it is anti-effectively to prevent the gold sand dry granular from occurring during forming by a firing with glaze
It should dissolve each other, ensure that flash effect；Also gold sand dry granular is effectively prevented in the polishing process, gold sand dry granular falls off, in institute
It states full glaze ceramic brick surface of throwing and leaves hole, pit or stomata；So that the full throwing glaze Ceramic Tiles in the present invention are provided simultaneously with, particle
Shape reflecting effect and high glaze glossiness.
Detailed description of the invention
Fig. 1 is the preparation method flow diagram of the full throwing glaze Ceramic Tiles in the present invention with graininess flashing ornaments；
Fig. 2 is the schematic perspective view of the full throwing glaze Ceramic Tiles in the present invention with graininess flashing ornaments；
Fig. 3 is the stereochemical structure deformation schematic diagram of the full throwing glaze Ceramic Tiles in the present invention with graininess flashing ornaments；
Fig. 4 is the preparation method process deformation signal of the full throwing glaze Ceramic Tiles in the present invention with graininess flashing ornaments
Figure；
Description of symbols:
11, Ceramic Tiles green body；12, ground glaze layer；13, pattern decorative layer；14, gold sand dry granular glaze layer；15, glaze layer is thrown entirely.
Specific embodiment
The present invention provides a kind of full throwing glaze Ceramic Tiles and preparation method thereof with graininess flashing ornaments, to make the present invention
Purpose, technical solution and effect it is clearer, clear, the present invention is described in more detail below.It should be appreciated that this place
The specific embodiment of description is only used to explain the present invention, is not intended to limit the present invention.
Referring to Fig. 1, the embodiment of the present invention provides a kind of preparation of full throwing glaze Ceramic Tiles with graininess flashing ornaments
Method comprising:
Step S11, it by blank compression moulding, is placed in roller kilns and is dried, form Ceramic Tiles green body；
Step S13, surface is carried out by 3D ink jet printing, offset printing or roller printing in the Ceramic Tiles billet surface
Decoration forms pattern decorative layer；
Step S14, apply gold sand dry granular glaze in the pattern decorative layer surface, form gold sand dry granular glaze layer；
Step S15, apply full throwing glaze in the gold sand dry granular glaze layer, formed and throw glaze layer entirely；
Step S16, kiln-firing forms, and obtains the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments；
Step S17, the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments is polished, obtaining has graininess
The full throwing glaze Ceramic Tiles of flashing ornaments；
Wherein, the Ceramic Tiles green body is set as, and is mixed with the consistent multicolour particle of the pattern decorative layer tone
At color grains spot Ceramic Tiles green body；
Added with by weight the gold sand dry granular for being 5-30% in the gold sand dry granular glaze layer.
In the present embodiment, by setting the ingredient to and the consistent multicolour particle of the pattern decorative layer tone
The color grains spot base being mixed into, and then may be implemented directly to apply pattern decorative layer on the Ceramic Tiles green body, and
The manufacturing cost for effectively reducing the full throwing glaze Ceramic Tiles with graininess flashing ornaments is not reduced；Meanwhile it also effectively avoiding
Ceramic Tiles green body is different from the pattern decorative layer tone, cause the Ceramic Tiles combination with decorative surfaces can generate it is more heterochromatic or
Other coloured pointing object, the problem of influencing the decorative effect of Ceramic Tiles.By being mixed in pattern decorative layer surface application,
Have the gold sand dry granular glaze layer of the reflective gold sand dry granular of metallic particles, and then the tool of the full throwing glaze Ceramic Tiles in the present invention has been effectively ensured
Standby graininess flashing ornaments effect.
Further, it by applying full throwing glaze in gold sand dry granular glaze layer surface, and then effectively improves and throws glazed pottery entirely
The brightness of the surface glaze layer of ceramic tile；Meanwhile it is anti-effectively to prevent the gold sand dry granular from occurring during forming by a firing with glaze
It should dissolve each other, ensure that flash effect；Also gold sand dry granular is effectively prevented in the polishing process, Jinsha dry granular falls off, in institute
It states full glaze ceramic brick surface of throwing and leaves hole, pit or stomata；So that the full throwing glaze Ceramic Tiles in the present invention are provided simultaneously with, particle
Shape reflecting effect and high glaze glossiness.
In one embodiment, the melt temperature scope of the gold sand dry granular is 1200-1450 DEG C；And then it effectively keeps away
Exempt from the gold sand dry granular to exist, be melted during forming by a firing, and then its grain light-reflection effect is made to disappear, ensure that full throwing glaze
The flash effect of Ceramic Tiles.
Further, the thin gold sand dry granular particle size added in the gold sand dry granular glaze layer includes: 40-60 mesh 0-
15%, 60-80 mesh 20-50%, 80-100 mesh 25-60%, 100 5-15% now.And then effectively enrich full throwing glaze ceramics
The granular size range of gold sand dry granular in brick effectively enriches the complete various crystal reflecting effects thrown in glaze Ceramic Tiles, effectively
Improve the full flash effect for throwing glaze Ceramic Tiles.
Further, the chemical composition of the gold sand dry granular is by weight percentage, comprising: C 0.68%, O
9.68%, Si 3.40%, Cr 17.11%, Mn 1.91%, Fe 63.01%, Ni 4.21%.
In one embodiment, the gold sand dry granular glaze in the step D is applied to pattern dress by silk-screen printing technique
It adorns on layer, forms gold sand dry granular glaze layer；
Further, the composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 50-65%,
CMC or stamp material 20-30%, gold sand dry granular 10-30%.By by the gold sand dry granular glaze is set as transparent glaze slip, Jinsha is done
Grain and CMC/ stamp material, effectively improve gold sand dry granular in the full throwing glaze Ceramic Tiles, the linking steady character with glaze,
The full mildness for throwing glaze Ceramic Tiles reflecting effect is improved, effectively prevents throwing glaze Ceramic Tiles luster effect entirely stiff unnatural.
Further, the chemical composition of the clear frit is in percentage by weight, comprising: SiO248.2-55.6%,
Al2O312.7-16.1%, Fe2O30-0.3%, CaO 8.4-11.3%, MgO 4.2-6.5%, Na2O 2.6-5.9%, K2O
0.5-1.8%, ZnO 1.8-5.2%, B2O30.5-1.7%, BaO 4.5-7.2%.
Further, the specific gravity of the gold sand dry granular glaze is 1.40-1.70；The glaze slurry viscosity of the gold sand dry granular glaze uses horse
Family name's funnel is measured as 15-25s；The mesh number of silk screen used is 40-60 mesh.
Further, the composition of the stamp material is according to parts by weight, comprising: 16 parts of glycerol, 14 parts of ethylene glycol, CMC
4.5 parts, 100 parts of water, 0.15 part of preservative and 0.1 part of degumming agent.
In one embodiment, the gold sand dry granular glaze in the step D by get rid of glaze dotting process or spray glaze handicraft,
It is applied on pattern decorative layer, forms gold sand dry granular glaze layer.
Further, the composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 65-95% is done
Grain 5-30%, ball clay glaze slip 0-10%.
Further, the specific gravity of the gold sand dry granular glaze is 1.20-1.70, and the glaze slurry viscosity of the gold sand dry granular glaze uses horse
Family name's funnel is measured as 12-30s, and the glaze volume of the gold sand dry granular glaze is 40-160g/m2。
Further, the composition of the ball clay glaze slip is according to parts by weight, comprising: 100 parts and water 40-60 parts of ball clay.
In one embodiment, the full throwing glaze in the step E is set as throwing clear frit entirely, the full throwing clear frit
Chemical composition is in percentage by weight, comprising: SiO248.2-55.6%, Al2O312.7-16.1%, Fe2O30-0.3%,
CaO 8.4-11.3%, MgO 4.2-6.5%, Na2O 2.6-5.9%, K2O 0.5-1.8%, ZnO 1.8-5.2%, B2O3
0.5-1.7%, BaO 4.5-7.2%.
Further, the full glaze slip specific gravity for throwing clear frit is 1.45-1.80；The full glaze slurry viscosity for throwing clear frit
15-38s is measured as with Marsh funnel；The full glaze volume for throwing clear frit is 500-720g/m2。
In one embodiment, the firing temperature in the step F is 1100-1250 DEG C；Firing period is 40-
80min。
In one embodiment, the Ceramic Tiles green body may be arranged as the solid color base of single color powder；
It further include step B between the step A and the step C, the step B includes: in the ceramic adobe body surface
Face applies ground coat enamel, forms ground glaze layer；
The C setting are as follows: surface is carried out by 3D ink jet printing, offset printing or roller printing in the ground coat enamel layer surface
Decoration forms pattern decorative layer.
It is understood that by the way that ground glaze layer is arranged between the Ceramic Tiles green body and pattern decorative layer, and then it is significant
The level for improving ink-jet decorative pattern, clarity and color effect.
In one embodiment, the gold sand dry granular by weight no more than 20%, and institute are added in the ground coat enamel
The partial size for stating gold sand dry granular is 40-80 mesh；It is understood that in gold sand dry granular glaze mixed gold sand dry granular partial size, less
The partial size of mixed gold sand dry granular in ground coat enamel；And then it realizes and bulky grain gold sand dry granular is disposed in proximity to the ceramic adobe
The internal layer in body surface face, little particle gold sand dry granular are set to the opposite exterior lateral sides of bulky grain gold sand dry granular；Big partial size is effectively ensured
Jinsha dry granular by adequate thickness glaze coat, effectively prevent gold sand dry granular in the polishing process, Jinsha dry granular
It falls off, leaves hole, pit or stomata in the full throwing glaze ceramic brick surface.
Further, the chemical composition of the ground coat enamel is in percentage by weight, comprising: SiO242.6-49.9%,
Al2O315.4-18.3%, Fe2O30%-0.2%, CaO 6.9%-9.4%, MgO 1.1%-4.5%, Na2O 2.3%-
7.7%, K2O 0.5%-1.8%, ZnO 1.3%-4.1%, ZrO211.2%-16.6%.
Further, the glaze slip specific gravity of the ground coat enamel is 1.20；The glaze slurry viscosity of the ground coat enamel is measured as with Marsh funnel
15-35s；The glaze volume of the ground coat enamel is 240-610g/m2。
The full throwing glaze Ceramic Tiles with graininess flashing ornaments that the present invention also provides a kind of, wherein described that there is particle
The full throwing glaze Ceramic Tiles of shape flashing ornaments are by above-described embodiment, the full throwing glaze Ceramic Tiles with graininess flashing ornaments
Preparation method prepare.
It is appreciated that by the way that the ingredient is set as mixing with the consistent multicolour particle of the pattern decorative layer tone
The color grains spot base of synthesis, and then may be implemented directly to apply pattern decorative layer on the Ceramic Tiles green body, and not
Reduce the manufacturing cost for effectively reducing the full throwing glaze Ceramic Tiles with graininess flashing ornaments；Meanwhile it also effectively avoiding making pottery
Ceramic tile blank is different from the pattern decorative layer tone, cause the Ceramic Tiles combination with decorative surfaces can generate it is more heterochromatic or its
Its coloured pointing object, the problem of influencing the decorative effect of Ceramic Tiles.
By being mixed in pattern decorative layer surface application, has the gold sand dry granular of the reflective gold sand dry granular of metallic particles
Glaze layer, and then the full throwing glaze Ceramic Tiles in the present invention have been effectively ensured and have had graininess flashing ornaments effect；Further, pass through
Apply full throwing glaze in gold sand dry granular glaze layer surface, and then effectively improves the brightness of the full surface glaze layer for throwing glaze Ceramic Tiles；
Meanwhile effectively preventing the gold sand dry granular from reacting during forming by a firing with glaze and dissolving each other, it ensure that flash effect；
Also gold sand dry granular is effectively prevented in the polishing process, Jinsha dry granular falls off, and leaves in the full throwing glaze ceramic brick surface
Hole, pit or stomata；So that the full throwing glaze Ceramic Tiles in the present invention are provided simultaneously with, graininess reflecting effect and high glaze gloss
Degree.
Referring to Fig. 2, in one embodiment, the full throwing glaze Ceramic Tiles with graininess flashing ornaments by down toward
On successively include: Ceramic Tiles green body 11, pattern decorative layer 13, gold sand dry granular glaze layer 14 and complete throw glaze layer 15；The wherein gold sand
The gold sand dry granular for being 5-30% is added with by weight in dry granular glaze layer 14, the gold sand dry granular in the gold sand dry granular glaze layer 14
Partial size is 40-60 mesh 0-15%, 60-80 mesh 20-50%, 80-100 mesh 25-60%, 100 5-15% now.
Pass through, directly apply pattern decorative layer 13 on the Ceramic Tiles green body, is ensureing full throwing glazed pottery ceramic tile patterns dress
While adoring effect, its manufacturing cost is reduced；By the application gold sand dry granular glaze layer 14 on the pattern decorative layer 13, and
The full particle for throwing glaze Ceramic Tiles is effectively guaranteed in the gold sand dry granular that various mesh number partial sizes are added in the gold sand dry granular glaze layer 14
Shape flash effect；By applying full throwing glaze layer 15 in the gold sand dry granular glaze layer 14, and then effectively improves and throw glazed pottery entirely
The glossiness on ceramic tile glaze surface layer, while also effectivelying prevent gold sand dry granular in the polishing process, gold sand dry granular falls off, in institute
It states full glaze ceramic brick surface of throwing and leaves hole, pit or stomata, so that the full throwing glaze Ceramic Tiles in the present invention are provided simultaneously with, particle
Shape reflecting effect and high glaze glossiness.
Referring to Fig. 3, further, Ceramic Tiles green body 11, ground glaze layer 12, pattern decorative layer 13, gold sand dry granular glaze layer 14
Glaze layer 15 is thrown with complete.Wherein, added with by weight the gold sand dry granular for being 5-30%, the gold in the gold sand dry granular glaze layer 14
The partial size of gold sand dry granular in sand dry granular glaze layer 14 is 40-60 mesh 0-15%, 60-80 mesh 20-50%, 80-100 mesh 25-60%,
100 5-15% now；The gold sand dry granular by weight no more than 20%, and the ground glaze layer are added in the ground glaze layer 12
The partial size of 12 gold sand dry granulars is 40-80 mesh.
It is appreciated that by applying ground glaze layer 12 on the Ceramic Tiles green body 11, and in the gold sand dry granular glaze layer 14
The gold sand dry granular of the middle certain mesh number partial size of addition, is effectively guaranteed the full graininess flash effect for throwing glaze Ceramic Tiles, effectively
It ensure that the full graininess flash effect for throwing glaze Ceramic Tiles；Also be effectively guaranteed the level of ink-jet decorative pattern, clarity and
Color effect；By being provided with pattern decorative layer 13 on 11 surface of ground glaze layer, ink-jet decorative pattern is effectively guaranteed
Level, clarity and color effect；By applying gold sand dry granular glaze layer 14 on the pattern decorative layer 13, and in the gold sand
The full graininess flash of light effect for throwing glaze Ceramic Tiles is effectively guaranteed in the gold sand dry granular that various mesh number partial sizes are added in dry granular glaze layer
Fruit；By applying full throwing glaze layer 15 in the gold sand dry granular glaze layer 14, and then effectively improves and throw glaze Ceramic Tiles glaze entirely
The glossiness on surface layer, while also effectivelying prevent gold sand dry granular in the polishing process, gold sand dry granular falls off, in the full throwing glaze
Ceramic brick surface leaves hole, pit or stomata, so that the full throwing glaze Ceramic Tiles in the present invention are provided simultaneously with, the reflective effect of graininess
Fruit and high glaze glossiness.
The present invention is further described in detail below by specific embodiment.
Embodiment one:
A kind of preparation method of the full throwing glaze Ceramic Tiles with graininess flashing ornaments comprising:
Step S11, it by blank compression moulding, is placed in roller kilns and is dried, form Ceramic Tiles green body；
Step S13, surface is carried out by 3D ink jet printing, offset printing or roller printing in the Ceramic Tiles billet surface
Decoration forms pattern decorative layer；
Step S14, apply gold sand dry granular glaze in the pattern decorative layer surface, form gold sand dry granular glaze layer；
Step S15, apply full throwing glaze in the gold sand dry granular glaze layer, formed and throw glaze layer entirely；
Step S16, kiln-firing forms, and obtains the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments.
Step S17, the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments is polished, obtaining has graininess
The full throwing glaze Ceramic Tiles of flashing ornaments；
Wherein, the Ceramic Tiles green body is set as, and is mixed with the consistent multicolour particle of the pattern decorative layer tone
At color grains spot Ceramic Tiles green body；
Added with by weight the gold sand dry granular for being 5-30% in the gold sand dry granular glaze layer.
The melt temperature scope of the gold sand dry granular is 1200-1450 DEG C；
The thin gold sand dry granular particle size added in the gold sand dry granular glaze layer includes: 40-60 mesh 0-15%, 60-80 mesh
20-50%, 80-100 mesh 25-60%, 100 5-15% now；
The chemical composition of the gold sand dry granular is by weight percentage, comprising: C 0.68%, O 9.68%, Si
3.40%, Cr 17.11%, Mn 1.91%, Fe 63.01%, Ni 4.21%.
Gold sand dry granular glaze in the step D is applied on pattern decorative layer by silk-screen printing technique, and it is dry to form gold sand
Grain glaze layer；
The composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 50-65%, CMC or stamp material
20-30%, gold sand dry granular 10-30%；
The chemical composition of the clear frit is in percentage by weight, comprising: SiO248.2-55.6%, Al2O3 12.7-
16.1%, Fe2O30-0.3%, CaO 8.4-11.3%, MgO 4.2-6.5%, Na2O 2.6-5.9%, K2O 0.5-
1.8%, ZnO 1.8-5.2%, B2O30.5-1.7%, BaO 4.5-7.2%；
The specific gravity of the gold sand dry granular glaze is 1.40-1.70；The glaze slurry viscosity of the gold sand dry granular glaze is surveyed with Marsh funnel
Obtaining is 15-25s；The mesh number of silk screen used is 40-60 mesh.
The composition of the stamp material is according to parts by weight, comprising: 16 parts of glycerol, 14 parts of ethylene glycol, 4.5 parts of CMC, water 100
Part, 0.15 part of preservative and 0.1 part of degumming agent.
Full throwing glaze in the step E is set as throwing clear frit entirely, and the full chemical composition for throwing clear frit is according to weight
Percentages, comprising: SiO248.2-55.6%, Al2O312.7-16.1%, Fe2O30-0.3%, CaO 8.4-11.3%,
MgO 4.2-6.5%, Na2O 2.6-5.9%, K2O 0.5-1.8%, ZnO 1.8-5.2%, B2O30.5-1.7%, BaO
4.5-7.2%.
The full glaze slip specific gravity for throwing clear frit is 1.45-1.80；The full glaze slurry viscosity for throwing clear frit is leaked with geneva
Bucket is measured as 15-38s；The full glaze volume for throwing clear frit is 500-720g/m2。
Firing temperature in the step F is 1100-1250 DEG C；Firing period is 40-80min.
Embodiment two:
Difference in the present embodiment from above-described embodiment one is:
Gold sand dry granular glaze in the step D is applied on pattern decorative layer by getting rid of glaze dotting process, it is dry to form gold sand
Grain glaze layer；
The composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 65-95%, dry granular 5-30%,
Ball clay glaze slip 0-10%；
The specific gravity of the gold sand dry granular glaze is 1.20-1.70；
The glaze slurry viscosity of the gold sand dry granular glaze is measured as 12-30s with Marsh funnel；
The glaze volume of the gold sand dry granular glaze is 40-160g/m2；
The composition of the ball clay glaze slip is according to parts by weight, comprising: 100 parts and water 40-60 parts of ball clay.
Embodiment three:
Difference in the present embodiment from above-described embodiment one is:
Gold sand dry granular glaze in the step D is applied on pattern decorative layer by spray glaze handicraft, forms gold sand dry granular
Glaze layer；
The composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 65-95%, dry granular 5-30%,
Ball clay glaze slip 0-10%；
The specific gravity of the gold sand dry granular glaze is 1.20-1.70；
The glaze slurry viscosity of the gold sand dry granular glaze is measured as 12-30s with Marsh funnel；
The glaze volume of the gold sand dry granular glaze is 40-160g/m2；
The composition of the ball clay glaze slip is according to parts by weight, comprising: 100 parts and water 40-60 parts of ball clay.
Example IV:
Difference in the present embodiment from above-described embodiment one is:
Please refer to Fig. 4, a kind of preparation method of the full throwing glaze Ceramic Tiles with graininess flashing ornaments comprising:
Step S11, it by blank compression moulding, is placed in roller kilns and is dried, form Ceramic Tiles green body；
Step S12, apply ground coat enamel in the Ceramic Tiles billet surface, form ground glaze layer；
Step S13, surface dress is carried out by 3D ink jet printing, offset printing or roller printing in the ground coat enamel layer surface
Decorations form pattern decorative layer；
Step S14, apply gold sand dry granular glaze in the pattern decorative layer surface, form gold sand dry granular glaze layer；
Step S15, apply full throwing glaze in the gold sand dry granular glaze layer, formed and throw glaze layer entirely；
Step S16, kiln-firing forms, and obtains the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments.
Step S17, the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments is polished, obtaining has graininess
The full throwing glaze Ceramic Tiles of flashing ornaments；
Wherein, the Ceramic Tiles green body is set as, and is mixed with the consistent multicolour particle of the pattern decorative layer tone
At color grains spot Ceramic Tiles green body；
Added with by weight the gold sand dry granular for being 5-30% in the gold sand dry granular glaze layer.
The melt temperature scope of the gold sand dry granular is 1200-1450 DEG C；
The thin gold sand dry granular particle size added in the gold sand dry granular glaze layer includes: 40-60 mesh 0-15%, 60-80 mesh
20-50%, 80-100 mesh 25-60%, 100 5-15% now；
The chemical composition of the gold sand dry granular is by weight percentage, comprising: C 0.68%, O 9.68%, Si
3.40%, Cr 17.11%, Mn 1.91%, Fe 63.01%, Ni 4.21%.
Added with the gold sand dry granular for being not more than 20% by weight in ground coat enamel in the step B, and the gold sand is dry
The partial size of grain is 40-80 mesh；
The chemical composition of the ground coat enamel is in percentage by weight, comprising:
SiO242.6-49.9%, Al2O315.4-18.3%, Fe2O30%-0.2%, CaO 6.9%-9.4%, MgO
1.1%-4.5%, Na2O 2.3%-7.7%, K2O 0.5%-1.8%, ZnO 1.3%-4.1%, ZrO211.2%-
16.6%.
The glaze slip specific gravity of the ground coat enamel is 1.20；The glaze slurry viscosity of the ground coat enamel is measured as 15-35s with Marsh funnel；Institute
The glaze volume for stating ground coat enamel is 240-610g/m2。
Gold sand dry granular glaze in the step D is applied on pattern decorative layer by silk-screen printing technique, and it is dry to form gold sand
Grain glaze layer；
The composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 50-65%, CMC or stamp material
20-30%, gold sand dry granular 10-30%；
The chemical composition of the clear frit is in percentage by weight, comprising: SiO248.2-55.6%, Al2O3 12.7-
16.1%, Fe2O30-0.3%, CaO 8.4-11.3%, MgO 4.2-6.5%, Na2O 2.6-5.9%, K2O 0.5-
1.8%, ZnO 1.8-5.2%, B2O30.5-1.7%, BaO 4.5-7.2%；
The specific gravity of the gold sand dry granular glaze is 1.40-1.70；The glaze slurry viscosity of the gold sand dry granular glaze is surveyed with Marsh funnel
Obtaining is 15-25s；The mesh number of silk screen used is 40-60 mesh.
The composition of the stamp material is according to parts by weight, comprising: 16 parts of glycerol, 14 parts of ethylene glycol, 4.5 parts of CMC, water 100
Part, 0.15 part of preservative and 0.1 part of degumming agent.
Full throwing glaze in the step E is set as throwing clear frit entirely, and the full chemical composition for throwing clear frit is according to weight
Percentages, comprising: SiO248.2-55.6%, Al2O312.7-16.1%, Fe2O30-0.3%, CaO 8.4-11.3%,
MgO 4.2-6.5%, Na2O 2.6-5.9%, K2O 0.5-1.8%, ZnO 1.8-5.2%, B2O30.5-1.7%, BaO
4.5-7.2%.
The full glaze slip specific gravity for throwing clear frit is 1.45-1.80；The full glaze slurry viscosity for throwing clear frit is leaked with geneva
Bucket is measured as 15-38s；The full glaze volume for throwing clear frit is 500-720g/m2。
Firing temperature in the step F is 1100-1250 DEG C；Firing period is 40-80min.
Embodiment five:
Difference in the present embodiment from above-described embodiment four is:
Gold sand dry granular glaze in the step D is applied on pattern decorative layer by getting rid of glaze dotting process, it is dry to form gold sand
Grain glaze layer；
The composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 65-95%, dry granular 5-30%,
Ball clay glaze slip 0-10%；
The specific gravity of the gold sand dry granular glaze is 1.20-1.70；
The glaze slurry viscosity of the gold sand dry granular glaze is measured as 12-30s with Marsh funnel；
The glaze volume of the gold sand dry granular glaze is 40-160g/m2；
The composition of the ball clay glaze slip is according to parts by weight, comprising: 100 parts and water 40-60 parts of ball clay.
Embodiment six:
Difference in the present embodiment from above-described embodiment four is:
Gold sand dry granular glaze in the step D is applied on pattern decorative layer by spray glaze handicraft, forms gold sand dry granular
Glaze layer；
The composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 65-95%, dry granular 5-30%,
Ball clay glaze slip 0-10%；
The specific gravity of the gold sand dry granular glaze is 1.20-1.70；
The glaze slurry viscosity of the gold sand dry granular glaze is measured as 12-30s with Marsh funnel；
The glaze volume of the gold sand dry granular glaze is 40-160g/m2；
The composition of the ball clay glaze slip is according to parts by weight, comprising: 100 parts and water 40-60 parts of ball clay.
It should be noted that in the consistent embodiment six of the above embodiment of the present invention:
The melt temperature scope of the gold sand dry granular can also be 1300-1400 DEG C；
The thin gold sand dry granular particle size added in the gold sand dry granular glaze layer includes: 40-60 mesh 5-10%, 60-80 mesh
25-45%, 80-100 mesh 30-55%, 100 8-13% now；
Embodiment seven:
A kind of full throwing glaze Ceramic Tiles with graininess flashing ornaments successively include: from the bottom to top
Ceramic Tiles green body 11, pattern decorative layer 13, gold sand dry granular glaze layer 14 and full throwing glaze layer 15；The gold sand dry granular glaze layer
In added with by weight the gold sand dry granular for being 5-30%, the partial size of the gold sand dry granular in the gold sand dry granular glaze layer is 40-60
Mesh 0-15%, 60-80 mesh 20-50%, 80-100 mesh 25-60%, 100 5-15% now.
Pass through, directly apply pattern decorative layer on the Ceramic Tiles green body, is ensureing full throwing glazed pottery ceramic tile patterns decoration
While effect, its manufacturing cost is reduced；By applying gold sand dry granular glaze layer on the pattern decorative layer, and in the gold
The full graininess flash of light effect for throwing glaze Ceramic Tiles is effectively guaranteed in the gold sand dry granular that various mesh number partial sizes are added in sand dry granular glaze layer
Fruit；By applying full throwing glaze layer in the gold sand dry granular glaze layer, and then effectively improves and throw glaze Ceramic Tiles glaze surface layer entirely
Glossiness, while also effectivelying prevent gold sand dry granular in the polishing process, gold sand dry granular falls off, in the full throwing glaze ceramics
Brick surface leaves hole, pit or stomata so that the full throwing glaze Ceramic Tiles in the present invention are provided simultaneously with, graininess reflecting effect and
High glaze glossiness.
Embodiment eight:
A kind of full throwing glaze Ceramic Tiles with graininess flashing ornaments successively include: from the bottom to top
Ceramic Tiles green body 11, ground glaze layer 12, pattern decorative layer 13, gold sand dry granular glaze layer 14 and full throwing glaze layer 15；The gold
The gold sand dry granular for being 5-30%, the grain of the gold sand dry granular in the gold sand dry granular glaze layer are added with by weight in sand dry granular glaze layer
Diameter is 40-60 mesh 0-15%, 60-80 mesh 20-50%, 80-100 mesh 25-60%, 100 5-15% now；Add in the ground glaze layer
Added with the gold sand dry granular for being not more than 20% by weight, and the partial size of the ground glaze layer gold sand dry granular is 40-80 mesh.
Pass through, applies ground glaze layer on the Ceramic Tiles green body, and add certain mesh number in the gold sand dry granular glaze layer
The full graininess flash effect for throwing glaze Ceramic Tiles is effectively guaranteed in the gold sand dry granular of partial size, and full throwing glazed pottery is effectively guaranteed
The graininess flash effect of ceramic tile；Also level, clarity and the color effect of ink-jet decorative pattern is effectively guaranteed；By
The ground coat enamel layer surface is provided with pattern decorative layer, and level, clarity and the color effect of ink-jet decorative pattern is effectively guaranteed
Fruit；By applying gold sand dry granular glaze layer on the pattern decorative layer, and various mesh numbers are added in the gold sand dry granular glaze layer
The full graininess flash effect for throwing glaze Ceramic Tiles is effectively guaranteed in the gold sand dry granular of partial size；By in the gold sand dry granular glaze
Apply full throwing glaze layer on layer, and then effectively improves the full glossiness for throwing glaze Ceramic Tiles glaze surface layer, while also effectivelying prevent
In the polishing process, gold sand dry granular falls off gold sand dry granular, leaves hole, pit or gas in the full throwing glaze ceramic brick surface
Hole, so that the full throwing glaze Ceramic Tiles in the present invention are provided simultaneously with, graininess reflecting effect and high glaze glossiness.
In conclusion a kind of full throwing glaze Ceramic Tiles and its manufacturer with graininess flashing ornaments provided by the invention
Method passes through the color grains for being set as being mixed into the consistent multicolour particle of the pattern decorative layer tone by the ingredient
Spot base, and then may be implemented directly to apply pattern decorative layer on the Ceramic Tiles green body, and do not reduce and effectively reduce
The manufacturing cost of full throwing glaze Ceramic Tiles with graininess flashing ornaments；Meanwhile also effectively avoid Ceramic Tiles green body with it is described
Pattern decorative layer tone is different, causes that more heterochromatic or other coloured pointing object can be generated in the Ceramic Tiles combination with decorative surfaces,
The problem of influencing the decorative effect of Ceramic Tiles.By being mixed in pattern decorative layer surface application, it is anti-to have metallic particles
The gold sand dry granular glaze layer of light gold sand dry granular, and then the full throwing glaze Ceramic Tiles in the present invention have been effectively ensured and have had graininess flash of light dress
Adorn effect；Further, it by applying full throwing glaze in gold sand dry granular glaze layer surface, and then effectively improves and throws glaze ceramics entirely
The brightness of the surface glaze layer of brick；Meanwhile effectively preventing the gold sand dry granular from reacting during forming by a firing with glaze
It dissolves each other, ensure that flash effect；Also gold sand dry granular is effectively prevented in the polishing process, gold sand dry granular falls off, described
Full glaze ceramic brick surface of throwing leaves hole, pit or stomata；So that the full throwing glaze Ceramic Tiles in the present invention are provided simultaneously with, graininess
Reflecting effect and high glaze glossiness.
It should be understood that the application of the present invention is not limited to the above for those of ordinary skills can
With improvement or transformation based on the above description, all these modifications and variations all should belong to the guarantor of appended claims of the present invention
Protect range.
Claims (10)
1. a kind of preparation method of the full throwing glaze Ceramic Tiles with graininess flashing ornaments characterized by comprising
A, it by blank compression moulding, is placed in roller kilns and is dried, form Ceramic Tiles green body；
C, incrustation is carried out by 3D ink jet printing, offset printing or roller printing in the Ceramic Tiles billet surface, is formed
Pattern decorative layer；
D, apply gold sand dry granular glaze in the pattern decorative layer surface, form gold sand dry granular glaze layer；
E, apply full throwing glaze in the gold sand dry granular glaze layer, formed and throw glaze layer entirely；
F, kiln-firing forms, and obtains the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments；
G, the full throwing glazed pottery ceramic tile blank with graininess flashing ornaments is polished, obtaining has graininess flashing ornaments
It is complete to throw glaze Ceramic Tiles；
Wherein, the Ceramic Tiles green body is set as, and is mixed into the consistent multicolour particle of the pattern decorative layer tone
Color grains spot Ceramic Tiles green body；
Added with by weight the gold sand dry granular for being 5-30% in the gold sand dry granular glaze layer.
2. the preparation method of the full throwing glaze Ceramic Tiles according to claim 1 with graininess flashing ornaments, feature exist
In,
The melt temperature scope of the gold sand dry granular is 1200-1450 DEG C；
The thin gold sand dry granular particle size added in the gold sand dry granular glaze layer includes: 40-60 mesh 0-15%, 60-80 mesh 20-
50%, 80-100 mesh 25-60%, 100 5-15% now；
The chemical composition of the gold sand dry granular is by weight percentage, comprising: C0.68%, O9.68%, Si3.40%,
Cr17.11%, Mn1.91%, Fe63.01%, Ni4.21%.
3. the preparation method of the full throwing glaze Ceramic Tiles according to claim 2 with graininess flashing ornaments, feature exist
In,
Gold sand dry granular glaze in the step D is applied on pattern decorative layer by silk-screen printing technique, forms gold sand dry granular glaze
Layer；
The composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 50-65%, CMC or stamp material 20-
30%, gold sand dry granular 10-30%；
The chemical composition of the clear frit is in percentage by weight, comprising: SiO248.2-55.6%, Al2O3 12.7-
16.1%, Fe2O30-0.3%, CaO8.4-11.3%, MgO4.2-6.5%, Na2O2.6-5.9%, K2O0.5-1.8%,
ZnO1.8-5.2%, B2O30.5-1.7%, BaO4.5-7.2%；
The specific gravity of the gold sand dry granular glaze is 1.40-1.70；
The glaze slurry viscosity of the gold sand dry granular glaze is measured as 15-25s with Marsh funnel；
The mesh number of silk screen used is 40-60 mesh；
The composition of the stamp material is according to parts by weight, comprising: 16 parts of glycerol, 14 parts of ethylene glycol, CMC4.5 parts, it is 100 parts of water, anti-
0.15 part and 0.1 part of degumming agent of rotten agent.
4. the preparation method of the full throwing glaze Ceramic Tiles according to claim 2 with graininess flashing ornaments, feature exist
In,
Gold sand dry granular glaze in the step D is applied on pattern decorative layer, shape by getting rid of glaze dotting process or spray glaze handicraft
At gold sand dry granular glaze layer；
The composition of the gold sand dry granular glaze is in percentage by weight, comprising: transparent glaze slip 65-95%, dry granular 5-30%, ball clay
Glaze slip 0-10%；
The specific gravity of the gold sand dry granular glaze is 1.20-1.70；
The glaze slurry viscosity of the gold sand dry granular glaze is measured as 12-30s with Marsh funnel；
The glaze volume of the gold sand dry granular glaze is 40-160g/m2；
The composition of the ball clay glaze slip is according to parts by weight, comprising: 100 parts and water 40-60 parts of ball clay.
5. the preparation method of the full throwing glaze Ceramic Tiles according to claim 2 with graininess flashing ornaments, feature exist
In,
Full throwing glaze in the step E is set as throwing clear frit entirely, and the full chemical composition for throwing clear frit is according to weight percent
Than meter, comprising: SiO248.2-55.6%, Al2O312.7-16.1%, Fe2O30-0.3%, CaO8.4-11.3%, MgO4.2-
6.5%, Na2O2.6-5.9%, K2O0.5-1.8%, ZnO1.8-5.2%, B2O30.5-1.7%, BaO4.5-7.2%；
The full glaze slip specific gravity for throwing clear frit is 1.45-1.80；
The full glaze slurry viscosity for throwing clear frit is measured as 15-38s with Marsh funnel；
The full glaze volume for throwing clear frit is 500-720g/m2。
6. the preparation method of the full throwing glaze Ceramic Tiles according to claim 2 with graininess flashing ornaments, feature exist
In,
Firing temperature in the step F is 1100-1250 DEG C；
Firing period is 40-80min.
7. the preparation method of the full throwing glaze Ceramic Tiles according to claim 1-6 with graininess flashing ornaments,
It is characterized in that,
The Ceramic Tiles green body may be arranged as the solid color base of single color powder；
It further include step B between the step A and the step C, the step B includes: to apply in the Ceramic Tiles billet surface
Add ground coat enamel, forms ground glaze layer；
The C setting are as follows: surface dress is carried out by 3D ink jet printing, offset printing or roller printing in the ground coat enamel layer surface
Decorations form pattern decorative layer.
8. the preparation method of the full throwing glaze Ceramic Tiles according to claim 7 with graininess flashing ornaments, feature exist
In,
Added with the gold sand dry granular for being not more than 20% by weight in the ground coat enamel, and the partial size of the gold sand dry granular is 40-
80 mesh；
The chemical composition of the ground coat enamel is in percentage by weight, comprising:
SiO242.6-49.9%, Al2O315.4-18.3%, Fe2O30%-0.2%, CaO6.9%-9.4%, MgO1.1%-
4.5%, Na2O2.3%-7.7%, K2O0.5%-1.8%, ZnO1.3%-4.1%, ZrO211.2%-16.6%；
The glaze slip specific gravity of the ground coat enamel is 1.20；
The glaze slurry viscosity of the ground coat enamel is measured as 15-35s with Marsh funnel；
The glaze volume of the ground coat enamel is 240-610g/m2。
9. a kind of full throwing glaze Ceramic Tiles with graininess flashing ornaments, which is characterized in that described that there are graininess flashing ornaments
Full throwing glaze Ceramic Tiles by the described in any item full throwing glaze Ceramic Tiles with graininess flashing ornaments of such as claim 1-8 system
Preparation Method prepares.
10. the full throwing glaze Ceramic Tiles according to claim 9 with graininess flashing ornaments, which is characterized in that the tool
The full throwing glaze Ceramic Tiles for having graininess flashing ornaments successively include: from the bottom to top
Ceramic Tiles green body, pattern decorative layer, gold sand dry granular glaze layer and glaze layer is thrown entirely；
Alternatively, Ceramic Tiles green body, ground glaze layer, pattern decorative layer, gold sand dry granular glaze layer and throwing glaze layer entirely；
Wherein, added with by weight the gold sand dry granular for being 5-30%, the gold sand dry granular glaze layer in the gold sand dry granular glaze layer
In the partial size of gold sand dry granular be 40-60 mesh 0-15%, 60-80 mesh 20-50%, 80-100 mesh 25-60%, 100 5- now
15%；
The gold sand dry granular by weight no more than 20%, and the grain of the ground glaze layer gold sand dry granular are added in the ground glaze layer
Diameter is 40-80 mesh.
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