CN1042627C - Vitreous jewel colour sand and preparation method - Google Patents
Vitreous jewel colour sand and preparation method Download PDFInfo
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- CN1042627C CN1042627C CN95113937A CN95113937A CN1042627C CN 1042627 C CN1042627 C CN 1042627C CN 95113937 A CN95113937 A CN 95113937A CN 95113937 A CN95113937 A CN 95113937A CN 1042627 C CN1042627 C CN 1042627C
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Abstract
The present invention relates to glass jewel color sand prepared from the components: 20 to 70 wt% of white quartz sand or transparent cullet, 10 to 20 wt% of sodium carbonate, 2 to 15% of calcined borax, 0 to 25% of pulverized coal ash, 0 to 20 wt% of lead oxide, 0.2 to 20 wt% of modifying agent and 0.2 to 5 wt% of pigment. The raw materials are uniformly mixed and sintered, melted at the temperature of 1350 to 1450DEGC, defoamed in a heat preservation way, discharged into water, and quenched in water to form small crushed blocks, and then the small crushed blocks are taken out to be pulverized, dried, sieved and packaged. The present invention has the advantages of convenient technology and easy master. The manufacturing cost is lower than that of natural color sand, and the hardness, the bright and the color of the manufactured color sand are better than those of the existing natural color sand. The color sand has a crystal particle structure, and the artistic effect of the architectural decoration can be obviously increased.
Description
The present invention relates to a kind of raw material of processing building decoration product usefulness, particularly a kind of vitreous jewel colour sand that is applicable to the colorful wall floor tile of processing and preparation method thereof.
At present, along with the development of glass porcelain industry, for building trade provides a large amount of adornments, as glass, ceramics such as clay facing tile, vitreous brick, mosaic, artificial marbles.Its kind hinge is many, and physical dimension is standardized, for beautifying constructure provides decorative art.But the above-mentioned building decoration articles for use raw material color of existing specification is single, and the finished product glaze comes off easily, is subjected to the effect of hardships misty rain and climate change for a long time, can lose surperficial original color and luster gradually.Existing color sand mainly contains natural colour sand and artificial color sand.The color and luster of natural colour sand is better, but of less types, owing to be subjected to the restriction of natural condition, it costs an arm and a leg.Be difficult to meet the need of market.The main manufacture methods of artificial color sand has two kinds.A kind of is that the high-temperature sintering process another kind is a staining.Staining is than high temperature is simple around connection technology, cost is low, but tinctorial quality is poor, and fugitive color, poor durability under sun exposure are so seldom adopt.High temperature generally only adopts quartz sand and pigment to puddle around connection, deliver to after the drying in the stove around knot, then through cooling, broken, sieve.The color sand hardness of making is relatively poor, can not form crystalline-granular texture, and moulding does not have stereoscopic sensation, and the color and luster effect of no natural colour sand influences the artistic decorative effect of its building decoration product of making.
The purpose of this invention is to provide a kind of vitreous jewel colour sand and preparation method thereof, easy, the easy grasp of this method technology, manufacturing cost is far below natural colour sand, color sand hardness, gloss, the color of making is better than existing natural colour sand, and crystalline-granular texture is arranged, can significantly increase the artistic effect of building decoration.
The object of the present invention is achieved like this: raw materials used each components by weight of this coloured silk sand is: white quartz sand or transparent glass cullet: yellow soda ash: forge borax: flyash: tri-lead tetroxide: properties-correcting agent: pigment=(20-70): (10-20): (2-15): (0-25): (0-20): (0.2-20): (0.2-5).
Its preparation method is: take by weighing above-mentioned each component according to quantity, in dress crucible or the sintering oven, in 1350-1450 ℃ of following fusion, be incubated 2-3 hour behind the mixing, in the blowing entry, hardening becomes fine grained chippings behind the froth breaking, takes out pulverizing, drying, presses the desired particle size sorting and packs standby.
Each components by weight of used properties-correcting agent is barium oxide or barium carbonate: zinc oxide: Calcium Fluoride (Fluorspan): saltpetre=(8-12): (1-2): (4-7): (0-3).
Because the present invention is to be major ingredient with silica containing white quartz sand or transparent glass cullet, with yellow soda ash, forge borax and make fusing assistant, take conventional metals oxide colour or alkene ashen material, the high temperature resistant colorant of faience etc. to make pigment, make full use of properties-correcting agent and increase gloss, hardness, colour developing effect, make it fusion under optimal temperature, and after shrend, generate and have color and luster as the pearl, gem-like crystallization, color sand true to nature beautiful in colour, so this method technology is easy, raw material is easy to get, and manufactures too far below natural colour sand.The vitreous jewel colour sand of making not only can exactly like natural colour sand, and color can allocate as required, and its gloss, hardness, color obviously are better than existing like product.The ornament that adopts this coloured silk sand to make also can carry out methods such as three-dimensional paste-on-paste pate-surpate, vacuum plating, laser processing, surface treatment, and with further enhancing decorative artistic effect, this is that the color sand produced of prior art is incomparable.With the present invention's color sand, adopt enamel technology promptly to can be made into colorful glass glaze goods.
Below in conjunction with embodiment the present invention is further described.
Embodiment one: preparation Saphire Brown color sand
Take by weighing raw material according to quantity: 49.46 kilograms in white quartz sand, 16.30 kilograms in yellow soda ash, forge 3.36 kilograms of boraxs, 9.69 kilograms of tri-lead tetroxides, 1.61 kilograms of properties-correcting agent, by 0.20 kilogram of the pigment of tone requirement apolegamy.
The above-mentioned raw materials mixing is packed in crucible or the sintering oven,, is incubated 2 hours in 1350-1450 ℃ of fusion, natural froth breaking or add the finings froth breaking, blowing goes into that hardening becomes fine grained chippings in the pond then, take out pulverize, drying, by the granularity sorting of sieving, pack standby respectively.
Embodiment two: prepare dark brown color sand
Take by weighing raw material according to quantity: 49.14 kilograms of transparent glass cullet and as 15.7 kilograms in 24.60 kilograms in flyash, the yellow soda ash of weighting agent, forge 9.73 kilograms of boraxs, 0.12 kilogram of properties-correcting agent, 0.12 kilogram of pigment.
Following operation steps is with embodiment one.
Embodiment three: prepare dark green color sand
Take by weighing each raw material according to quantity: 47.70 kilograms in white quartz sand, 16.00 kilograms in yellow soda ash, forge 10.75 kilograms of boraxs, 7.89 kilograms of tri-lead tetroxides, 17.11 kilograms of properties-correcting agent, 0.55 kilogram of pigment.
Following operation steps is with embodiment one.
Embodiment four: prepare light green color sand
Take by weighing each raw material according to quantity: 47.70 kilograms in white quartz sand, 15.92 kilograms in yellow soda ash, forge 10.69 kilograms of boraxs, 17.00 kilograms of tri-lead tetroxides, 7.65 kilograms of properties-correcting agent, 1.1 kilograms of pigment.
Following operation steps is with embodiment one.
Embodiment five: prepare blackish green metal damp color sand earlier
Take by weighing raw material according to quantity: 47.18 kilograms of transparent glass cullet and as 18.87 kilograms in 18.87 kilograms in flyash, the yellow soda ash of weighting agent, forge 11.32 kilograms of boraxs, 1.88 kilograms of properties-correcting agent, 1.88 kilograms of pigment.
Following operation steps is with embodiment one.
Embodiment six: use color sand of the present invention and prepare colourful-pearl cameo glass brick
Choose the color sand color of method for preparing by the color of design, take by weighing 20 kilograms of 3-1 millimeter pellets, 30 kilograms of 1-0.6 millimeter pellets, granularity greater than 50 kilograms of 80 powder materials, add 2 kilograms of binding agent sodium carboxymethyl-cellulose aqueous solution by granularity requirements.The above-mentioned raw materials mixing is put into mould pressurize, pressure-controlling is at 0.5-1kpa/cm
2, after the demoulding drying, to go in the High Temperature Furnaces Heating Apparatus in 800-900 ℃ of following sintering, the cooling of coming out of the stove after 20-30 minute is made finished product through surface treatment again.
Embodiment seven: use color sand of the present invention and prepare colorful bossage brick
Choose the color sand color of method for preparing by the color of design, take by weighing 10 kilograms of 3-1 millimeter pellets, 30 kilograms of 1-0.6 millimeter pellets, granularity greater than 60 kilograms of 80 powder materials, add 2 kilograms of binding agent polyvinyl formals by granularity requirements.The above-mentioned raw materials mixing is put into mould pressurize, pressure-controlling is at 0.5-1kpa/cm
2After the die sinking, by the layout requirement required color sand grains is spread in the color sand surface of compacting, or paste-on-paste pate-surpate, dress embossment etc. thereon, pressurization again under the similarity condition, form and partly embed shape, after the demoulding drying, go in the High Temperature Furnaces Heating Apparatus in 850-900 ℃ of following sintering the cooling of coming out of the stove after 20-30 minute, carry out surface coating processing or laser at last and handle, make the bossage brick.
Claims (4)
1, a kind of vitreous jewel colour sand, it is characterized in that raw materials used each components by weight is: white quartz sand or transparent glass cullet: yellow soda ash: forge borax: flyash: tri-lead tetroxide: properties-correcting agent: pigment=(20-70): (10-20): (2-15): (0-25): (0-20): (0.2-20): (0.2-5), each components by weight of used properties-correcting agent is barium oxide or barium carbonate: zinc oxide: Calcium Fluoride (Fluorspan): saltpetre=(8-12): (1-2): (4-7): (0-3).
2, the preparation method of vitreous jewel colour sand according to claim 1, it is characterized in that raw materials used each components by weight is: white quartz sand or transparent glass cullet: yellow soda ash: forge borax: flyash: tri-lead tetroxide: properties-correcting agent: pigment=(20-70): (10-20): (2-15): (0-25): (0-20): (0.2-20): (0.2-5), each components by weight of used property agent is barium oxide or barium carbonate: zinc oxide: Calcium Fluoride (Fluorspan): saltpetre=(8-12): (1-2): (4-7): (0-3), take by weighing above-mentioned each component according to quantity, adorn in crucible or the sintering oven behind the mixing, in 1350-1450 ℃ of following fusion, be incubated 2-3 hour, behind the froth breaking in the blowing entry, hardening becomes fine grained chippings, take out and pulverize, drying is pressed the desired particle size sorting and is packed standby.
3, application rights requires the cameo glass brick of 1 described vitreous jewel colour sand preparation, it is characterized in that selecting sand by the color requirement, pellet 40-60%, the surplus that takes by weighing granularity 0.6-3 millimeter is that granularity is greater than 80 powder materials, 2% binding agent that adds the above-mentioned raw materials gross weight, mix thoroughly to be placed in the mould and pressurize, after the demoulding drying, go into sintering in the High Temperature Furnaces Heating Apparatus, burn till after surface treatment is finished product.
4, plate glass according to claim 3 is characterized in that used binding agent is sodium carboxymethyl-cellulose or polyvinyl formal.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95113937A CN1042627C (en) | 1995-11-23 | 1995-11-23 | Vitreous jewel colour sand and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95113937A CN1042627C (en) | 1995-11-23 | 1995-11-23 | Vitreous jewel colour sand and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1133267A CN1133267A (en) | 1996-10-16 |
| CN1042627C true CN1042627C (en) | 1999-03-24 |
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ID=5080143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95113937A Expired - Fee Related CN1042627C (en) | 1995-11-23 | 1995-11-23 | Vitreous jewel colour sand and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1042627C (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1300031C (en) * | 2004-12-23 | 2007-02-14 | 江阴采麟彩砂制品有限公司 | Color sand and production thereof |
| RU2444480C1 (en) * | 2010-10-13 | 2012-03-10 | Юлия Алексеевна Щепочкина | Crude mixture for making smalt |
| RU2479497C1 (en) * | 2011-12-14 | 2013-04-20 | Юлия Алексеевна Щепочкина | Crude mixture for making artificial stone |
| CN107686375A (en) * | 2017-09-30 | 2018-02-13 | 江苏闽江矿业有限公司 | A kind of quartz sand medium temperature coloring process |
| CN108585513A (en) * | 2018-07-11 | 2018-09-28 | 合肥择浚电气设备有限公司 | A kind of heat-proof corrosion resistant erosion building nucleated glass |
| CN115353311B (en) * | 2022-07-12 | 2024-03-01 | 平泉石尚新材料有限公司 | Environment-friendly colored sand and preparation method thereof |
| CN115025713A (en) * | 2022-07-15 | 2022-09-09 | 平泉石尚新材料有限公司 | Color sand dispersing and granulating device and color sand dispersing and granulating method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031069A (en) * | 1987-07-31 | 1989-02-15 | 南京市住宅建设公司 | Light porous face-decorative material |
| CN1083796A (en) * | 1992-09-09 | 1994-03-16 | 董绍明 | The prescription of colour glass stone brick and manufacture method thereof |
-
1995
- 1995-11-23 CN CN95113937A patent/CN1042627C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031069A (en) * | 1987-07-31 | 1989-02-15 | 南京市住宅建设公司 | Light porous face-decorative material |
| CN1083796A (en) * | 1992-09-09 | 1994-03-16 | 董绍明 | The prescription of colour glass stone brick and manufacture method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1133267A (en) | 1996-10-16 |
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