CN109761649A - A kind of slate Ceramic Tiles and preparation method thereof with diamond luster effect - Google Patents

A kind of slate Ceramic Tiles and preparation method thereof with diamond luster effect Download PDF

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Publication number
CN109761649A
CN109761649A CN201910234615.3A CN201910234615A CN109761649A CN 109761649 A CN109761649 A CN 109761649A CN 201910234615 A CN201910234615 A CN 201910234615A CN 109761649 A CN109761649 A CN 109761649A
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China
Prior art keywords
parts
slate
diamond
glaze
frit
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CN201910234615.3A
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Chinese (zh)
Inventor
曹端旭
欧志勇
盛正强
李艳君
刘燕燕
黄道聪
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CHONGQING WEIMEI CERAMICS Co.,Ltd.
JIANGXI WONDERFUL CERAMIC Co.,Ltd.
Dongguan City Wonderful Ceramics Industrial Park Co Ltd
Jiangxi Hemei Ceramics Co Ltd
Original Assignee
Chongqing Aestheticism Ceramic Co Ltd
Dongguan Weimei Decorative Materials Co Ltd
Dongguan City Wonderful Ceramics Industrial Park Co Ltd
Jiangxi Hemei Ceramics Co Ltd
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Application filed by Chongqing Aestheticism Ceramic Co Ltd, Dongguan Weimei Decorative Materials Co Ltd, Dongguan City Wonderful Ceramics Industrial Park Co Ltd, Jiangxi Hemei Ceramics Co Ltd filed Critical Chongqing Aestheticism Ceramic Co Ltd
Priority to CN201910234615.3A priority Critical patent/CN109761649A/en
Publication of CN109761649A publication Critical patent/CN109761649A/en
Pending legal-status Critical Current

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Abstract

The present invention relates to Ceramic Tiles technical fields, and in particular to a kind of slate Ceramic Tiles and preparation method thereof with diamond luster effect include the following steps: that embryo brick is made into embryo material by (1);(2) ground coat enamel is applied;(3) clear frit is applied in printing slate class pattern (4);(5) diamond flash of light dry granular glaze is applied;(6) embryo brick is burnt into get the slate Ceramic Tiles described in diamond luster effect.It after the present invention is by applying ground coat enamel on the base face of various performances, is used cooperatively in conjunction with the slate class pattern in later period, clear frit and dry granular glaze with strong flash effect, is manufactured that the slate Ceramic Tiles with diamond claimed flare pellet reconciliation Ricoh pool.Sidelight is visual under natural light, it can be seen that ceramic brick surface has the claimed flare pellet of apparent fine particle shape, the glistening reflecting effect of similar multiple very tiny diamonds;And under optically focused light irradiation, this similar diamond reflection light effect is more obvious, enhances the dicoration of ceramic brick product.

Description

A kind of slate Ceramic Tiles and preparation method thereof with diamond luster effect
Technical field
The present invention relates to Ceramic Tiles technical fields, and in particular to a kind of slate Ceramic Tiles with diamond luster effect and its Preparation method.
Background technique
In the manufacture of architectural pottery, the product glossiness of various Wall or floor tiles has the different forms of expression, such as unglazed, sub- Light, satin, bloom, the different luster effect such as light.Common product is the whole glossiness be burnt by glaze itself come table The glossiness effect of existing product, conventional glaze brick product are mostly matte surface and shining surfaces, and polished bricks, full glaze product of throwing are by polishing After can be only achieved high gloss, it is not the luster effect reflected with glaze itself, and the glossiness of the entire space of a whole page tends to one It causes, does not have too big variation, visual glossiness does not have apparent contrast.Separately have a small amount of Ceramic Tiles modelled after an antique using mica sheet or The flash-point technique of bright glaze, strong illumination have light point reflection.But the shortcomings that this type product, is also obvious:
(1) gloss, flash-point itself black deeper with color, to light color or bright-coloured colour system are generated with mica sheet Product will affect the decorative effect of ceramic brick surface pattern;
(2) flash-point is done with light glaze, glossiness is not strong after firing, and visual gloss contrast is unobvious;
(3) gloss cannot be generated on the sheet cleavage surface direction of slate generates.
Summary of the invention
In order to overcome shortcoming and defect existing in the prior art, the purpose of the present invention is to provide one kind to have diamond light Slate Ceramic Tiles of damp effect and preparation method thereof, Ceramic Tiles obtained have the cleavage gloss of diamond flash effect and slate, Sidelight is visual under natural light, it can be seen that ceramic brick surface has the claimed flare pellet of apparent fine particle shape, it is similar it is multiple very The glistening reflecting effect of tiny diamond, and under optically focused light irradiation, this similar diamond reflection light effect is more obvious, Enhance the dicoration of ceramic brick product.
The purpose of the invention is achieved by the following technical solution:
A kind of slate Ceramic Tiles with diamond luster effect, including from bottom to top successively compound embryo brick, ground glaze layer, figure Pattern layer, transparent glaze layer and diamond flash of light dry granular glaze layer.
A kind of preparation method of the slate Ceramic Tiles with diamond luster effect as described above, includes the following steps:
(1) embryo material is pressed into embryo brick, and is dried in roller kilns;
(2) ground coat enamel is applied on embryo brick surface;
(3) slate class pattern is printed on ground coat enamel surface by 3D printing, forms pattern layer;
(4) clear frit is applied on the surface of the pattern layer;
(5) diamond flash of light dry granular glaze is applied on the surface of clear frit, the diamond dry granular glaze includes following parts by weight Raw material: 60-70 parts of methyl water, 10-20 parts of dry granular and 8-15 parts of clay slip;Wherein, the methyl water is carboxymethyl cellulose water Solution, the dry granular include the chemical composition of following parts by weight: SiO2: 50-60 parts, Al2O3: 15-20 parts, CaO:12-15 Part, K2O:5-8 parts, ZnO:4-7 parts and BaO:8-10 parts.
(6) embryo brick is burnt into get the slate Ceramic Tiles described in diamond luster effect.
After the present invention is by applying ground coat enamel on the base face of various performances, in conjunction with slate class pattern, clear frit and the tool in later period There is the dry granular glaze of strong flash effect to be used cooperatively, is manufactured that the slate ceramics with diamond claimed flare pellet reconciliation Ricoh pool Brick.Sidelight is visual under natural light, it can be seen that ceramic brick surface has the claimed flare pellet of apparent fine particle shape, similar multiple The glistening reflecting effect of very tiny diamond;And under optically focused light irradiation, this similar diamond reflection light effect is brighter It is aobvious, enhance the dicoration of ceramic brick product.
Wherein, the ground coat enamel includes the raw material of following parts by weight: 1-5 parts of zinc oxide, 0-20 parts of zirconium silicate, feldspar of receiving 20-25 parts, 15-20 parts of desiliconization aluminium powder, 5-10 parts of calcite, 5-10 parts of dolomite, aluminium powder 0-8 parts middle, quartz 5-10 parts, kaolinite Native 10-15 parts and frit A20-30 parts;The chemical composition of the frit A are as follows: Si02: 61-64wt%, Al2O3: 13-15wt%, CaO:12-14wt%, MgO:3-4wt%, K2O:2-3wt%, Na2O:2-3wt%, remaining is burning decrement.
The present invention is carried out detailed-oriented by the effect to each chemical composition and the mutual difference between specific ore Analysis, such as the introducing material using desiliconization aluminium powder as aluminium oxide can be conducive to the glossiness for improving dry granular glaze, with kaolin As the introducing material of aluminium oxide, the wearability and chemical stability of dry granular glaze can be improved, using calcite as calcium oxide Material is introduced, can also be improved the wearability and chemical stability of dry granular glaze, and being introduced directly into for zinc oxide, dry granular can be improved Whiteness, thus combine a variety of factors, dry granular glaze obtained have preferable wearability, chemical stability and the reflective light of diamond Pool.
Wherein, the glaze specific gravity of the ground coat enamel is 1.2-1.8, and the ground coat enamel glaze volume of step (2) is 250-610g/m2
Wherein, the clear frit includes the raw material of following parts by weight: receiving 15-25 parts of feldspar, 0-5 parts of talcum, kaolin 10-15 parts, 10-15 parts of calcined earth, A20-30 parts of frit and B25-40 parts of frit;The chemical composition of the frit A are as follows: Si02: 61-64wt%, Al2O3: 13-15wt%, CaO:12-14wt%, MgO:3-4wt%, K2O:2-3wt%, Na2O:2-3wt%, Remaining is burning decrement;The chemical composition of the frit B are as follows: Si02: 44-46wt%, Al2O3: 18-20wt%, CaO:7- 8wt%, MgO:0.5-0.6wt%, K2O:1-2wt%, Na2O:4-5wt%, ZnO:3-5wt%, BaO:16-17wt%, remaining For burning decrement.
Clear frit produced by the present invention is the lower clear frit of glossiness, and is had preferable mobility, and can be filled The gap of dry granular glaze, dry granular and clear frit are fused together and dense distribution is on the surface of Ceramic Tiles, and ceramic surface is presented Concave-convex effect, while there is the speciality of dumb light and diamond flash of light, and the combination of dry granular and clear frit is stablized, and has Ceramic Tiles Preferable wearability.
Wherein, the chemical composition of the frit A are as follows: Si02: 62.99wt%, Al2O3: 14.82wt%, CaO: 13.24wt%, MgO:3.74wt%, K2O:2.58wt%, Na2O:2.1wt%, remaining is burning decrement;The change of the frit B Learn composition are as follows: Si02: 45.33wt%, Al2O3: 19.02wt%, CaO:7.55wt%, MgO:0.58wt%, K2O: 1.75wt%, Na2O:4.71wt%, ZnO:4wt%, BaO:16.74wt%.
Currently preferred frit A and frit B composition can be obviously improved the performance of Ceramic Tiles, conducive to uniformly dividing for dry granular Cloth promotes the dumb light texture of Ceramic Tiles.
Wherein, the glaze specific gravity of the clear frit is 1.2-1.7, and the ground coat enamel glaze volume of step (2) is 220-550g/m2
Wherein, the partial size of the dry granular is 80-150 mesh, and the glaze specific gravity of the diamond dry granular glaze is 1.15-1.3, step (2) ground coat enamel glaze volume is 100-200g/m2.Pass through glaze volume, dry granular partial size and the glaze specific gravity to clear frit, dry granular glaze Control, can control distribution of the dry granular glaze on clear frit, more highlight dumb light gloss and flash of light gloss.
Wherein, step (6) firing temperature is 1100-1250 DEG C, firing time 40-80min.
Wherein, the methyl water the preparation method comprises the following steps: the ratio by carboxymethyl cellulose and water by weight 1:5-7 carries out Mixing, static 10-14h obtain mixed once liquid;Mixed once liquid and water are stirred by weight the ratio of 1:2-4 mixed It closes, adjusts viscosity to get the methyl water is arrived.
The beneficial effects of the present invention are: after the present invention is by applying ground coat enamel on the base face of various performances, in conjunction with the later period Slate class pattern, clear frit and the dry granular glaze with strong flash effect are used cooperatively, and are manufactured that with diamond claimed flare pellet Conciliate the slate Ceramic Tiles in Ricoh pool.Sidelight is visual under natural light, it can be seen that ceramic brick surface has apparent fine particle The claimed flare pellet of shape, the glistening reflecting effect of similar multiple very tiny diamonds;And under optically focused light irradiation, this similar brill Stone reflection light effect is more obvious, enhances the dicoration of ceramic brick product.
Detailed description of the invention
Fig. 1 is the diagrammatic cross-section for the slate Ceramic Tiles that the present invention has diamond luster effect;
1- embryo brick, 2- ground glaze layer, 3- pattern layer, the transparent glaze layer of 4-, 5- diamond flash of light dry granular glaze layer.
Specific embodiment
For the ease of the understanding of those skilled in the art, make below with reference to 1 couple of present invention of examples and drawings further Illustrate, the content that embodiment refers to not is limitation of the invention.
Embodiment 1
As shown in Figure 1, a kind of slate Ceramic Tiles with diamond luster effect, including from bottom to top successively compound embryo brick 1, ground glaze layer 2, pattern layer 3, transparent glaze layer 4 and diamond flash of light dry granular glaze layer 5.
A kind of preparation method of the slate Ceramic Tiles with diamond luster effect as described above, includes the following steps:
(1) embryo material is pressed into embryo brick 1, and is dried in roller kilns;
(2) ground coat enamel is applied on 1 surface of embryo brick;
(3) slate class pattern is printed on ground coat enamel surface by 3D printing, forms pattern layer 3;
(4) clear frit is applied on the surface of the pattern layer 3;
(5) diamond flash of light dry granular glaze is applied on the surface of clear frit, the diamond dry granular glaze includes following parts by weight Raw material: 65 parts of methyl water, 15 parts of dry granular and 12 parts of clay slip;Wherein, the methyl water is carboxymethyl cellulose aqueous solution, described Dry granular includes the chemical composition of following parts by weight: SiO2: 55 parts, Al2O3: 17 parts, CaO:13 parts, K2O:6.5 parts, ZnO:5.5 Part and BaO:9 parts.
(6) embryo brick 1 is burnt into get the slate Ceramic Tiles described in diamond luster effect.
Wherein, the ground coat enamel includes the raw material of following parts by weight: 3 parts of zinc oxide, 10 parts of zirconium silicate, feldspar 22.5 of receiving Part, 17.5 parts of desiliconization aluminium powder, 7.5 parts of calcite, 7.5 parts of dolomite, 4 parts of middle aluminium powder, quartz 7.5 parts, 12.5 parts of kaolin and A25 parts of frit;.
Wherein, the glaze specific gravity of the ground coat enamel is 1.5, and the ground coat enamel glaze volume of step (2) is 430g/m2
Wherein, the clear frit includes the raw material of following parts by weight: receiving 20 parts of feldspar, 2.5 parts of talcum, kaolin 12.5 Part, 12.5 parts of calcined earth, A25 parts of frit and B32 parts of frit;
Wherein, the chemical composition of the frit A are as follows: Si02: 62.99wt%, Al2O3: 14.82wt%, CaO: 13.24wt%, MgO:3.74wt%, K2O:2.58wt%, Na2O:2.1wt%, remaining is burning decrement;The change of the frit B Learn composition are as follows: Si02: 45.33wt%, Al2O3: 19.02wt%, CaO:7.55wt%, MgO:0.58wt%, K2O: 1.75wt%, Na2O:4.71wt%, ZnO:4wt%, BaO:16.74wt%, remaining is burning decrement.
Wherein, the glaze specific gravity of the clear frit is 1.4, and the ground coat enamel glaze volume of step (2) is 380g/m2
Wherein, the partial size of the dry granular is 80-150 mesh, and the glaze specific gravity of the diamond dry granular glaze is 1.2, step (2) Ground coat enamel glaze volume is 150g/m2
Wherein, step (6) firing temperature is 1180 DEG C, firing time 60min.
Wherein, the methyl water the preparation method comprises the following steps: carboxymethyl cellulose and water are mixed by weight the ratio of 1:6 It closes, static 12h obtains mixed once liquid;Mixed once liquid and water are stirred mixing by weight the ratio of 1:3, adjusted Viscosity to get arrive the methyl water.
Embodiment 2
As shown in Figure 1, a kind of slate Ceramic Tiles with diamond luster effect, including from bottom to top successively compound embryo brick 1, ground glaze layer 2, pattern layer 3, transparent glaze layer 4 and diamond flash of light dry granular glaze layer 5.
A kind of preparation method of the slate Ceramic Tiles with diamond luster effect as described above, includes the following steps:
(1) embryo material is pressed into embryo brick 1, and is dried in roller kilns;
(2) ground coat enamel is applied on 1 surface of embryo brick;
(3) slate class pattern is printed on ground coat enamel surface by 3D printing, forms pattern layer 3;
(4) clear frit is applied on the surface of the pattern layer 3;
(5) diamond flash of light dry granular glaze is applied on the surface of clear frit, the diamond dry granular glaze includes following parts by weight Raw material: 60 parts of methyl water, 10 parts of dry granular and 8 parts of clay slip;Wherein, the methyl water is carboxymethyl cellulose aqueous solution, described Dry granular includes the chemical composition of following parts by weight: SiO2: 50 parts, Al2O3: 15 parts, CaO:12 parts, K2O:5 parts, ZnO:4 parts and BaO:8 parts.
(6) embryo brick 1 is burnt into get the slate Ceramic Tiles described in diamond luster effect.
Wherein, the ground coat enamel includes the raw material of following parts by weight: 1 part of zinc oxide receives 20 parts of feldspar, desiliconization aluminium powder 15 Part, 5 parts of calcite, 5 parts of dolomite, 5 parts of quartz, 10 parts of kaolin and A20 parts of frit.
Wherein, the glaze specific gravity of the ground coat enamel is 1.2, and the ground coat enamel glaze volume of step (2) is 250g/m2
Wherein, the clear frit includes the raw material of following parts by weight: receiving 15 parts of feldspar, 10 parts of kaolin, calcined earth 10 Part, A20 parts of frit and B25 parts of frit;The chemical composition of the frit A are as follows: Si02: 61wt%, Al2O3: 15wt%, CaO: 14wt%, MgO:4wt%, K2O:3wt%, Na2O:2wt%, remaining is burning decrement;The chemical composition of the frit B are as follows: Si02: 44wt%, Al2O3: 20wt%, CaO:8wt%, MgO:0.6wt%, K2O:2wt%, Na2O:5wt%, ZnO:3wt%, BaO:16wt%, remaining is burning decrement.
Wherein, the glaze specific gravity of the clear frit is 1.2, and the ground coat enamel glaze volume of step (2) is 220g/m2
Wherein, the partial size of the dry granular is 80 mesh, and the glaze specific gravity of the diamond dry granular glaze is 1.15, the bottom of step (2) Glaze glaze volume is 100g/m2.Lead to wherein, step (6) firing temperature is 1100 DEG C, firing time 40min.
Wherein, the methyl water the preparation method comprises the following steps: carboxymethyl cellulose and water are mixed by weight the ratio of 1:5 It closes, static 10h obtains mixed once liquid;Mixed once liquid and water are stirred mixing by weight the ratio of 1:2, adjusted Viscosity to get arrive the methyl water.
Embodiment 3
As shown in Figure 1, a kind of slate Ceramic Tiles with diamond luster effect, including from bottom to top successively compound embryo brick 1, ground glaze layer 2, pattern layer 3, transparent glaze layer 4 and diamond flash of light dry granular glaze layer 5.
A kind of preparation method of the slate Ceramic Tiles with diamond luster effect as described above, includes the following steps:
(1) embryo material is pressed into embryo brick 1, and is dried in roller kilns;
(2) ground coat enamel is applied on 1 surface of embryo brick;
(3) slate class pattern is printed on ground coat enamel surface by 3D printing, forms pattern layer 3;
(4) clear frit is applied on the surface of the pattern layer 3;
(5) diamond flash of light dry granular glaze is applied on the surface of clear frit, the diamond dry granular glaze includes following parts by weight Raw material: 70 parts of methyl water, 20 parts of dry granular and 15 parts of clay slip;Wherein, the methyl water is carboxymethyl cellulose aqueous solution, described Dry granular includes the chemical composition of following parts by weight: SiO2: 60 parts, Al2O3: 20 parts, CaO:15 parts, K2O:8 parts, ZnO:7 parts and BaO:10 parts.
(6) embryo brick 1 is burnt into get the slate Ceramic Tiles described in diamond luster effect.
Wherein, the ground coat enamel includes the raw material of following parts by weight: 5 parts of zinc oxide, 20 parts of zirconium silicate, receive 25 parts of feldspar, 20 parts of desiliconization aluminium powder, 10 parts of calcite, 10 parts of dolomite, 8 parts of middle aluminium powder, 10 parts of quartz, 15 parts of kaolin and A30 parts of frit.
Wherein, the glaze specific gravity of the ground coat enamel is 1.8, and the ground coat enamel glaze volume of step (2) is 610g/m2
Wherein, the clear frit includes the raw material of following parts by weight: receive 25 parts of feldspar, 5 parts of talcum, 15 parts of kaolin, 15 parts of calcined earth, A30 parts of frit and B40 parts of frit;The chemical composition of the frit A are as follows: Si02: 64wt%, Al2O3: 13wt%, CaO:12wt%, MgO:3wt%, K2O:2wt%, Na2O:2wt%, remaining is burning decrement;The change of the frit B Learn composition are as follows: Si02: 46wt%, Al2O3: 18wt%, CaO:7wt%, MgO:0.5wt%, K2O:1wt%, Na2O:4wt%, ZnO:3wt%, BaO:16wt%, remaining is burning decrement.
Wherein, the glaze specific gravity of the clear frit is 1.7, and the ground coat enamel glaze volume of step (2) is 550g/m2
Wherein, the partial size of the dry granular is 150 mesh, and the glaze specific gravity of the diamond dry granular glaze is 1.3, the bottom of step (2) Glaze glaze volume is 200g/m2.Lead to wherein, step (6) firing temperature is 1250 DEG C, firing time 80min.
Wherein, the methyl water the preparation method comprises the following steps: carboxymethyl cellulose and water are mixed by weight the ratio of 1:7 It closes, static 14h obtains mixed once liquid;Mixed once liquid and water are stirred mixing by weight the ratio of 1:4, adjusted Viscosity to get arrive the methyl water.
Embodiment 4
As shown in Figure 1, a kind of slate Ceramic Tiles with diamond luster effect, including from bottom to top successively compound embryo brick 1, ground glaze layer 2, pattern layer 3, transparent glaze layer 4 and diamond flash of light dry granular glaze layer 5.
A kind of preparation method of the slate Ceramic Tiles with diamond luster effect as described above, includes the following steps:
(1) embryo material is pressed into embryo brick 1, and is dried in roller kilns;
(2) ground coat enamel is applied on 1 surface of embryo brick;
(3) slate class pattern is printed on ground coat enamel surface by 3D printing, forms pattern layer 3;
(4) clear frit is applied on the surface of the pattern layer 3;
(5) diamond flash of light dry granular glaze is applied on the surface of clear frit, the diamond dry granular glaze includes following parts by weight Raw material: 62 parts of methyl water, 13 parts of dry granular and 10 parts of clay slip;Wherein, the methyl water is carboxymethyl cellulose aqueous solution, described Dry granular includes the chemical composition of following parts by weight: SiO2: 52 parts, Al2O3: 18 parts, CaO:14 parts, K2O:7 parts, ZnO:6 parts and BaO:9 parts.
(6) embryo brick 1 is burnt into get the slate Ceramic Tiles described in diamond luster effect.
Wherein, the ground coat enamel includes the raw material of following parts by weight: 2 parts of zinc oxide, 6 parts of zirconium silicate, 24 parts of the feldspar, de- received 17 parts of aluminum silicon powder, 6 parts of calcite, 9 parts of dolomite, 7 parts of middle aluminium powder, 8 parts of quartz, 14 parts of kaolin and A21 parts of frit.
Wherein, the glaze specific gravity of the ground coat enamel is 1.3, and the ground coat enamel glaze volume of step (2) is 300g/m2
Wherein, the clear frit includes the raw material of following parts by weight: receive 22 parts of feldspar, 3 parts of talcum, 11 parts of kaolin, 13 parts of calcined earth, A22 parts of frit and B35 parts of frit.
Wherein, the chemical composition of the frit A are as follows: Si02: 62.99wt%, Al2O3: 14.82wt%, CaO: 13.24wt%, MgO:3.74wt%, K2O:2.58wt%, Na2O:2.1wt%, remaining is burning decrement;The change of the frit B Learn composition are as follows: Si02: 45.33wt%, Al2O3: 19.02wt%, CaO:7.55wt%, MgO:0.58wt%, K2O: 1.75wt%, Na2O:4.71wt%, ZnO:4wt%, BaO:16.74wt%.
Wherein, the glaze specific gravity of the clear frit is 1.5, and the ground coat enamel glaze volume of step (2) is 400g/m2
Wherein, the partial size of the dry granular is 100 mesh, and the glaze specific gravity of the diamond dry granular glaze is 1.2, the bottom of step (2) Glaze glaze volume is 120g/m2.Lead to wherein, step (6) firing temperature is 1150 DEG C, firing time 50min.
Wherein, the methyl water the preparation method comprises the following steps: carboxymethyl cellulose and water are mixed by weight the ratio of 1:6 It closes, static 11h obtains mixed once liquid;Mixed once liquid and water are stirred mixing by weight the ratio of 1:4, adjusted Viscosity to get arrive the methyl water.
Embodiment 5
As shown in Figure 1, a kind of slate Ceramic Tiles with diamond luster effect, including from bottom to top successively compound embryo brick 1, ground glaze layer 2, pattern layer 3, transparent glaze layer 4 and diamond flash of light dry granular glaze layer 5.
A kind of preparation method of the slate Ceramic Tiles with diamond luster effect as described above, includes the following steps:
(1) embryo material is pressed into embryo brick 1, and is dried in roller kilns;
(2) ground coat enamel is applied on 1 surface of embryo brick;
(3) slate class pattern is printed on ground coat enamel surface by 3D printing, forms pattern layer 3;
(4) clear frit is applied on the surface of the pattern layer 3;
(5) diamond flash of light dry granular glaze is applied on the surface of clear frit, the diamond dry granular glaze includes following parts by weight Raw material: 63 parts of methyl water, 18 parts of dry granular and 9 parts of clay slip;Wherein, the methyl water is carboxymethyl cellulose aqueous solution, described Dry granular includes the chemical composition of following parts by weight: SiO2: 52 parts, Al2O3: 16 parts, CaO:14 parts, K2O:7 parts, ZnO:5 parts and BaO:9 parts.
(6) embryo brick 1 is burnt into get the slate Ceramic Tiles described in diamond luster effect.
Wherein, the ground coat enamel includes the raw material of following parts by weight: 2 parts of zinc oxide, 18 parts of zirconium silicate, receive 24 parts of feldspar, 19 parts of desiliconization aluminium powder, 9 parts of calcite, 7 parts of dolomite, 6 parts of middle aluminium powder, 8 parts of quartz, 14 parts of kaolin and A28 parts of frit.
Wherein, the glaze specific gravity of the ground coat enamel is 1.4, and the ground coat enamel glaze volume of step (2) is 500g/m2
Wherein, the clear frit includes the raw material of following parts by weight: receive 22 parts of feldspar, 1 part of talcum, 11 parts of kaolin, 11 parts of calcined earth, A23 parts of frit and B30 parts of frit.
Wherein, the chemical composition of the frit A are as follows: Si02: 62.99wt%, Al2O3: 14.82wt%, CaO: 13.24wt%, MgO:3.74wt%, K2O:2.58wt%, Na2O:2.1wt%, remaining is burning decrement;The change of the frit B Learn composition are as follows: Si02: 45.33wt%, Al2O3: 19.02wt%, CaO:7.55wt%, MgO:0.58wt%, K2O: 1.75wt%, Na2O:4.71wt%, ZnO:4wt%, BaO:16.74wt%.
Wherein, the glaze specific gravity of the clear frit is 1.6, and the ground coat enamel glaze volume of step (2) is 500g/m2
Wherein, the partial size of the dry granular is 130 mesh, and the glaze specific gravity of the diamond dry granular glaze is 1.25, the bottom of step (2) Glaze glaze volume is 180g/m2.Lead to wherein, step (6) firing temperature is 1200 DEG C, firing time 70min.
Wherein, the methyl water the preparation method comprises the following steps: carboxymethyl cellulose and water are mixed by weight the ratio of 1:5 It closes, static 13h obtains mixed once liquid;Mixed once liquid and water are stirred mixing by weight the ratio of 1:3, adjusted Viscosity to get arrive the methyl water.
The present invention carries out wearability, corrosion resistance and anti-pollution according to Ceramic Tiles of the GB/T3810-2016 to embodiment 1-5 Property is tested, and test result is as follows:
Wear-resisting grade Corrosion resistance grade Stain resistance grade
Embodiment 1 4 A 4
Embodiment 2 4 A 4
Embodiment 3 4 A 4
Embodiment 4 3 B 4
Embodiment 5 3 B 4
As seen from the above table, produced by the present invention to have glazed ceramic brick that there is good wearability, corrosion resistance and anti-pollution Property, being suitable for daily household is applicable in, and measuring wear-resisting revolution is 1300-2500, thus wear-resisting grade is 3 or 4, it is contemplated that this Invention is the Ceramic Tiles of diamond luster, thus has also specially observed and recorded during wearability test and made pottery after how many turns Ceramic tile loses diamond luster, wherein being 1500 turns with wear-resisting revolution highest when losing diamond luster of embodiment 1.
Above-described embodiment is the preferable implementation of the present invention, and in addition to this, the present invention can be realized with other way, Do not depart under the premise of present inventive concept it is any obviously replace it is within the scope of the present invention.

Claims (10)

1. a kind of slate Ceramic Tiles with diamond luster effect, it is characterised in that: including from bottom to top successively compound embryo brick, Ground glaze layer, pattern layer, transparent glaze layer and diamond flash of light dry granular glaze layer.
2. a kind of preparation method of slate Ceramic Tiles with diamond luster effect described in claim 1, it is characterised in that: packet Include following steps:
(1) embryo material is pressed into embryo brick, and is dried in roller kilns;
(2) ground coat enamel is applied on embryo brick surface;
(3) slate class pattern is printed on ground coat enamel surface by 3D printing, forms pattern layer;
(4) clear frit is applied on the surface of the pattern layer;
(5) diamond flash of light dry granular glaze is applied on the surface of clear frit, the diamond dry granular glaze includes the raw material of following parts by weight: 60-70 parts of methyl water, 10-20 parts of dry granular and 8-15 parts of clay slip;Wherein, the methyl water is carboxymethyl cellulose aqueous solution, The dry granular includes the chemical composition of following parts by weight: SiO2: 50-60 parts, Al2O3: 15-20 parts, CaO:12-15 parts, K2O: 5-8 parts, ZnO:4-7 parts and BaO:8-10 parts.
(6) embryo brick is burnt into get the slate Ceramic Tiles described in diamond luster effect.
3. a kind of preparation method of slate Ceramic Tiles with diamond luster effect according to claim 2, feature exist In: the ground coat enamel includes the raw material of following parts by weight: 1-5 parts of zinc oxide, 0-20 parts of zirconium silicate receive 20-25 parts of feldspar, desiliconization 15-20 parts of aluminium powder, 5-10 parts of calcite, 5-10 parts of dolomite, aluminium powder 0-8 parts middle, 5-10 parts of quartz, 10-15 parts of kaolin and A20-30 parts of frit;The chemical composition of the frit A are as follows: Si02: 61-64wt%, Al2O3: 13-15wt%, CaO:12- 14wt%, MgO:3-4wt%, K2O:2-3wt%, Na2O:2-3wt%, remaining is burning decrement.
4. a kind of preparation method of slate Ceramic Tiles with diamond luster effect according to claim 3, feature exist In: the glaze specific gravity of the ground coat enamel is 1.2-1.8, and the ground coat enamel glaze volume of step (2) is 250-610g/m2
5. a kind of preparation method of slate Ceramic Tiles with diamond luster effect according to claim 2, feature exist In: the clear frit includes the raw material of following parts by weight: receive 15-25 parts of feldspar, 0-5 parts of talcum, 10-15 parts of kaolin, forge 10-15 parts of earth burning, A20-30 parts of frit and B25-40 parts of frit;The chemical composition of the frit A are as follows: Si02: 61-64wt%, Al2O3: 13-15wt%, CaO:12-14wt%, MgO:3-4wt%, K2O:2-3wt%, Na2O:2-3wt%, remaining is calcination Decrement;The chemical composition of the frit B are as follows: Si02: 44-46wt%, Al2O3: 18-20wt%, CaO:7-8wt%, MgO:0.5- 0.6wt%, K2O:1-2wt%, Na2O:4-5wt%, ZnO:3-5wt%, BaO:16-17wt%.
6. a kind of preparation method of slate Ceramic Tiles with diamond luster effect according to claim 5, feature exist In: the chemical composition of the frit A are as follows: Si02: 62.99wt%, Al2O3: 14.82wt%, CaO:13.24wt%, MgO: 3.74wt%, K2O:2.58wt%, Na2O:2.1wt%, remaining is burning decrement;The chemical composition of the frit B are as follows: Si02: 45.33wt%, Al2O3: 19.02wt%, CaO:7.55wt%, MgO:0.58wt%, K2O:1.75wt%, Na2O: 4.71wt%, ZnO:4wt%, BaO:16.74wt%, remaining is burning decrement.
7. a kind of preparation method of slate Ceramic Tiles with diamond luster effect according to claim 5, feature exist In: the glaze specific gravity of the clear frit is 1.2-1.7, and the ground coat enamel glaze volume of step (2) is 220-550g/m2
8. a kind of preparation method of slate Ceramic Tiles with diamond luster effect according to claim 2, feature exist In: the partial size of the dry granular is 80-150 mesh, and the glaze specific gravity of the diamond dry granular glaze is 1.15-1.3, the ground coat enamel of step (2) Glaze volume is 100-200g/m2
9. a kind of preparation method of slate Ceramic Tiles with diamond luster effect according to claim 2, feature exist In: step (6) firing temperature is 1100-1250 DEG C, firing time 40-80min.
10. a kind of preparation method of slate Ceramic Tiles with diamond luster effect according to claim 2, feature exist It is static in: the methyl water the preparation method comprises the following steps: carboxymethyl cellulose and water are mixed by weight the ratio of 1:5-7 10-14h obtains mixed once liquid;Mixed once liquid and water are stirred mixing by weight the ratio of 1:2-4, adjusted viscous It spends to get the methyl water is arrived.
CN201910234615.3A 2019-03-26 2019-03-26 A kind of slate Ceramic Tiles and preparation method thereof with diamond luster effect Pending CN109761649A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110304945A (en) * 2019-06-21 2019-10-08 佛山市雨果陶瓷有限公司 A kind of wear-resistant ceramic brick and preparation method thereof with diamond luster effect
CN110317051A (en) * 2019-08-02 2019-10-11 佛山市陶莹新型材料有限公司 A kind of diamond dry granular and its processing method
CN110357668A (en) * 2019-08-09 2019-10-22 东莞市唯美陶瓷工业园有限公司 A kind of full throwing glaze Ceramic Tiles and preparation method thereof with graininess flashing ornaments
CN110451802A (en) * 2019-08-15 2019-11-15 蒙娜丽莎集团股份有限公司 A kind of mica sheet decorative porcelain glazed tile and preparation method thereof
CN111704358A (en) * 2020-06-28 2020-09-25 广西蒙娜丽莎新材料有限公司 Porcelain archaized brick with golden glittering effect and preparation method thereof
CN112374919A (en) * 2021-01-12 2021-02-19 佛山市章氏兄弟建材有限公司 Underglaze color flashing luminous combined glazed brick and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103626523A (en) * 2013-11-26 2014-03-12 广东金意陶陶瓷有限公司 Ceramic tile with dry particle glaze-decorated surface and manufacturing method thereof
CN105175022A (en) * 2015-08-27 2015-12-23 广东博华陶瓷有限公司 Glisten glaze ceramic tile
CN105924229A (en) * 2016-04-25 2016-09-07 广东宏宇新型材料有限公司 Glaze for thousand-bead multi-color glazed tile and thousand-bead multi-color glazed tile, and preparation methods thereof
CN106746651A (en) * 2017-01-16 2017-05-31 佛山市道氏科技有限公司 A kind of dry granular glaze with diamond luster effect
CN108251048A (en) * 2018-01-19 2018-07-06 佛山市陶琦新型材料有限公司 Dry granular glaze glue, dry granular glaze, dry granular glazed tile and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103626523A (en) * 2013-11-26 2014-03-12 广东金意陶陶瓷有限公司 Ceramic tile with dry particle glaze-decorated surface and manufacturing method thereof
CN105175022A (en) * 2015-08-27 2015-12-23 广东博华陶瓷有限公司 Glisten glaze ceramic tile
CN105924229A (en) * 2016-04-25 2016-09-07 广东宏宇新型材料有限公司 Glaze for thousand-bead multi-color glazed tile and thousand-bead multi-color glazed tile, and preparation methods thereof
CN106746651A (en) * 2017-01-16 2017-05-31 佛山市道氏科技有限公司 A kind of dry granular glaze with diamond luster effect
CN108251048A (en) * 2018-01-19 2018-07-06 佛山市陶琦新型材料有限公司 Dry granular glaze glue, dry granular glaze, dry granular glazed tile and preparation method thereof

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
池至铣编著: "《陶瓷釉色料及装饰》", 30 November 2015, 北京:中国建材工业出版社 *
罗玉萍等: "《建筑装饰材料工艺》", 31 August 1995, 大连:大连理工大学出版社 *
蔡飞虎等: "《陶瓷墙地砖生产技术》", 31 July 2011, 武汉:武汉理工大学出版社 *
黄惠宁等: "《陶瓷墙地砖数字喷墨印刷技术与设备应用》", 31 May 2018, 北京:中国建材工业出版社 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110304945A (en) * 2019-06-21 2019-10-08 佛山市雨果陶瓷有限公司 A kind of wear-resistant ceramic brick and preparation method thereof with diamond luster effect
CN110317051A (en) * 2019-08-02 2019-10-11 佛山市陶莹新型材料有限公司 A kind of diamond dry granular and its processing method
CN110357668A (en) * 2019-08-09 2019-10-22 东莞市唯美陶瓷工业园有限公司 A kind of full throwing glaze Ceramic Tiles and preparation method thereof with graininess flashing ornaments
CN110451802A (en) * 2019-08-15 2019-11-15 蒙娜丽莎集团股份有限公司 A kind of mica sheet decorative porcelain glazed tile and preparation method thereof
CN111704358A (en) * 2020-06-28 2020-09-25 广西蒙娜丽莎新材料有限公司 Porcelain archaized brick with golden glittering effect and preparation method thereof
CN111704358B (en) * 2020-06-28 2021-03-19 广西蒙娜丽莎新材料有限公司 Porcelain archaized brick with golden glittering effect and preparation method thereof
CN112374919A (en) * 2021-01-12 2021-02-19 佛山市章氏兄弟建材有限公司 Underglaze color flashing luminous combined glazed brick and preparation method thereof

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